Chemical Engineering Commons^™

Cyclic Voltammetric And In-Situ Ftir Spectroscopic Studies Of Adsorption And Reduction Of No On Electrode Of Pt Nanoparticles, Qian Cheng, Yan-Xia Jiang, Dong-Mei Zeng, Shi-Gang Sun

Journal of Electrochemistry

Adsorption and reduction of NO on electrode of Pt nanoparticles in acid solutions were studied by means of cyclic voltammetry(CV) and in-situ FTIR spectroscopy.The results indicated that the reduction of NO is a complicated process including the adsorption of NO on electrode surface.Two types of surface-bonded NO were determined on Pt nanoparticles.The weakly adsorbed NO was reduced between 0.6 V and-0.05 V,which yielded nitrous oxide(N₂O) and ammonium(NH₄⁺) as products;while the strongly bonded NO was reduced at more negative potentials between-0.05V and-0.15V,producing only NH₄⁺ species.

Synthesis Of α-Mno2 Microspheres For The Application In Supercapacitor, Liang Wang, Gui-Chang Liu, Zhi-Cong Shi

Journal of Electrochemistry

The MnO₂ microspheres were prepared through the oxidation of KMnO₄ and MnCO₃ microspheres precursor.The microstructure and supercapacitor properties of MnO₂ were characterized by XRD,SEM and CV.The results show that MnO₂ was in a poorly crystalline state with α-crystallographic form,the size of microspheres typically ranged from 0.5 to 2 μm.Loading 5 mg·cm^-2 MnO₂ microspheres had excellent capacitance behaviors in 2 mol·L^-1(NH₄)₂SO₄ solution.The specific capacitance was 135.6 F·g^-1 with the scan rate at 2 mV·s^-1,and 118.8 F·g^-1 with the large scan rate at 100 …

Indirect Electrosynthesis Of Double Aldehyde Starch Using Pb-(Bro3-/Br-) As Electro-Catalytic Mediator, Ni-Na Chen, Ri-Yao Chen, Xi Zheng, Xiao Chen, Zhen Chen

Journal of Electrochemistry

In this paper,Nafion membrane was used as the separator in the electrolysis cell to indirectly electro-generating the double aldehyde starch(DAS) with BrO₃^-/Br^-as a redox mediator and Pb as an anode.Effects of temperature,concentration of sulfuric acid and starch on the electro-oxidation of DAS were discussed.The steady state polarization curves were obtained.The experiment results showed that the current efficiency was over 50% when the electrolysis current density was 15mA/ cm².

Improved Implementation Of Kirkwood-Buff Solution Theory In Periodic Molecular Simulations, Joseph W. Nichols, Stan G. Moore, Dean R. Wheeler

Faculty Publications

Kirkwood-Buff (KB) solution theory is a means to obtain certain thermodynamic derivatives from knowledge of molecular distributions. In actual practice the required integrals over radial distribution functions suffer inaccuracies due to finite-distance truncation effects and their use in closed systems. In this work we discuss how best to minimize these inaccuracies under traditional KB theory. In addition we implement a method for calculating KB quantities in molecular simulations with periodic boundary conditions and particularly within the canonical ensemble. The method is based on a finite-Fourier-series expansion of molecular concentration fluctuations and leads to more reliable results for a given computational …

Quantifying And Resolving Multiple Vector Transformants In S. Cerevisiae Plasmid Libraries, Thomas C. Scanlon, Elizabeth C. Gray, Karl E. Griswold

Dartmouth Scholarship

In addition to providing the molecular machinery for transcription and translation, recombinant microbial expression hosts maintain the critical genotype-phenotype link that is essential for high throughput screening and recovery of proteins encoded by plasmid libraries. It is known that Escherichia coli cells can be simultaneously transformed with multiple unique plasmids and thusly complicate recombinant library screening experiments. As a result of their potential to yield misleading results, bacterial multiple vector transformants have been thoroughly characterized in previous model studies. In contrast to bacterial systems, there is little quantitative information available regarding multiple vector transformants in yeast. Saccharomyces cerevisiae is the …

Pegylation Of Niosomes, John A. Elliott

USF Tampa Graduate Theses and Dissertations

The research presented in this dissertation describes the creation and characterization of a novel antibody-vesicle conjugate modified with polyethylene glycol (PEG) that possesses enhanced binding to and uptake by inflammation-activated endothelial cells with improved storage stability and longer shelf-life and potential reduction in immunogenic potential compared to previous designs.

Targeted drug delivery provides an effective means of delivering therapeutic concentrations of a drug to the site or organ of action. The drug is delivered using a niosome, a vesicle with an aqueous core and a bilayer membrane composed of non-ionic surfactants and cholesterol. Antibodies that recognize specific cell antigens are …

Dilute Sulfuric Acid Pretreatment Of Switchgrass In Microwave Reactor For Biofuel Conversion: An Investigation Of Yields, Kinetics,, Oscar Martin

Theses and Dissertations

Lignocellulosic materials provide a raw material source for biofuel conversion and offer several advantages over fossil fuels- usage of a renewable resource, reduced greenhouse emissions, a decreased dependence on foreign oil, and stimulation of the agricultural sector. However, a primary technological challenge in converting lignocellulosic biomass into fuel is overcoming the recalcitrance of its matrix to enzymatic hydrolysis. To overcome these problems for chemical processing, naturally occurring cellulose biomass must be pretreated before it can be further processed using enzymatic hydrolysis or bioconversion. The goal of this work was to develop a model that predicts the glucose yield (pretreatment and …

Temperature-Induced Restructuring Of Self-Assembled Ptpd Nanoparticle Superlattices, Guoqiang Ren, Yangchuan Xing

Chemical and Biochemical Engineering Faculty Research & Creative Works

PtPd nanoparticle superlattices were prepared at room temperature and investigated for their restructuring at elevated temperatures. the PtPd nanoparticles were spherical with a diameter of 3.5±0.3nm and were capped with surfactants of oleic acids and oleylamine. Images of the nanoparticle superlattices were taken using a transmission electron microscope. Analysis of the images with fast Fourier transform (FFT) revealed whether the superlattices were crystalline or amorphous. It was found that the critical temperature that induced a phase transition of PtPd superlattices from a crystalline state to an amorphous state fall in the range of 100-110 °C. Meanwhile, heat-induced restructuring transformed less-ordered …

Aligned Nanotubule Membranes, Bruce J. Hinds Iii

Chemical and Materials Engineering Faculty Patents

A method is provided for producing a permeable membrane, comprising the steps of aligning a plurality of hollow nanotubules to form a mat, coating the mat with a continuous polymer matrix to form a membrane. The membrane is etched (a) to open the plurality of hollow nanotubules and form pores and (b) to oxidize the carboxyl groups to carboxylate groups. At least one additional functional unit having at least one available amine group to bind the at least one additional functional unit to the nanotubule end carboxylate group may be provided. Membranes fabricated in accordance with the method of the …

Semi-Automatic Image Segmentation For Volumetric Visualization Of Pelvis Ct Scan-Images, Suprijanto Suprijanto, Farida I. Muchtadi, Irwan Setiawan

Makara Journal of Technology

Semi-Automatic Image Segmentation for Volumetric Visualization of Pelvis CT Scan-Images. The current development of computerized tomography (CT) has enable us to obtain cross sectional image using multi slicing techniques in an order of few seconds. The obtained images represent several tissue structures on cross section slice being imaged. One challenge to help diagnosis using CT images is extracting an anatomic structure of interest using a method of image segmentation and volumetric visualization with the assistance of computers. In case of volumetric visualization of pelvis bones extracted from multi-slice CT images, whole images which are containing part of pelvis bone structures …

Implementation Of Six Sigma Method To Maintain The Quality Of Construction Projects, Yusuf Latief, Retyaning Puji Utami

Makara Journal of Technology

Implementation of Six Sigma Method to Maintain The Quality of Construction Projects. Six sigma (6-sigma) is a method that widely developed in the world, especially in manufacturing industry to decrease failures in achieving good quality in construction projects. The objective of this research is to explore the existing condition of quality management and the aplication of 6-sigma method in maintaining quality of construction projects. Structured interviews to experienced experts and people who were recommended by their companies were conducted. Non-parametric analysis using frequencies distribution procedures were used for analysis. The result shows that existing condition in quality management of construction …

Mechanical Properties Of Ramie Fiber Reinforced Epoxy Lamina Composite For Socket Prosthesis, Tresna P. Soemardi, Widjajalaksmi Kusumaningsih, Agustinus Purna Irawan

Makara Journal of Technology

Mechanical properties of ramie fiber reinforced epoxy lamina composite for socket prosthesis. This paper presents an investigation into the application of natural fiber composite especially ramie fiber reinforced epoxy lamina composite for socket prosthesis. The research focuses on the tensile and shear strength from ramie fiber reinforced epoxy lamina composite which will be applied as alternative material for socket prosthesis. The research based on American Society for Testing Material (ASTM) standard D 3039/D 3039M for tensile strength and ASTM D 4255/D 4255M-83 for shear strength. The ramie fiber applied is a fiber continue 100 % Ne14'S with Epoxy Resin Bakelite …

Potency Of Thermoelectric Generator For Hybrid Vehicle, Nandy Putra, Raldi Artono Koestoer, Mohammad Adhitya, Ardian Roekettino, Bayu Trianto

Makara Journal of Technology

Potency of Thermoelectric Generator for Hybrid Vehicle. Thermoelectric Generator (TEG) has been known as electricity generation for many years. If the temperature difference occurred between two difference semi conductor materials, the current will flow in the material and produced difference voltage. This principle is known as Seebeck effect that is the opposite of Peltier effect Thermoelectric Cooling (TEC). This research was conducted to test the potential of electric source from twelve peltier modules. Then, these thermoelectric generators were applied in hybrid car by using waste heat from the combustion engine. The experiment has been conducted with variations of peltier module …

Effects Of Ph On Calcium Carbonate Precipitation Under Magnetic Field, Nelson Saksono, Yuliusman Yuliusman, Setijo Bismo, Roekmijati W. Soemantojo, Azwar Manaf

Makara Journal of Technology

Magnetic field effect on CaCO3 precipitation is the key parameter in evaluating the effectiveness of Anti-scale Magnetic Treatment (AMT). The purpose of this study was to investigate magnetic fields influence on CaCO3 precipitation in high and low super-saturated CaCO3 solution by varied pH CaCO3 solution using circulation flow fluid system. The observation results in the high super saturated solution (pH 8.5) showed the increase of precipited CaCO3 in magnetized solutions compared to those in non-magnetic solution during circulation process. In the low super-saturated CaCO3 solution (pH 6.4) it was found that magnetic treatment increased CaCO3 precipitation after circulation process. In …

Performance Of Hollow Fiber Membrane Gas-Liquid Contactors To Absorb Co2 Using Diethanolamine (Dea) As A Solvent, Sutrasno Kartohardjono, Pan Ade Nata, Eko Prasetio, Yuliusman Yuliusman

Makara Journal of Technology

This study uses DEA solution to absorb CO2 from the gas flow through the hollow fiber membrane contactors. This study aims to evaluate the performance of hollow fiber membrane contactors to absorb CO2 gas using DEA solution as solvent through mass transfer and hydrodynamics studies. The use of DEA solution is to reduce the mass transfer resistance in the liquid phase, and on the other side, the large contact area of the membrane surface can cover the disadvantage of membrane contactors; additional mass transfer resistance in the membrane phase. During experiments, CO2 feed flows through the fiber lumens, while the …

Intermetallic Cu3sn Phase Layer On Electrode’S Tip Of Galvanized Resistance Spot Welding, Muhammad Anis, Aulia Irsyadi, Deni Ferdian

Makara Journal of Technology

Intermetallic Cu3Sn Phase Layer on Electrode’s Tip of Galvanized Resistance Spot Welding. A resistance spot welding method is commonly used in automotive industries application. In a resistance spot welding method, the copper electrode has a significant role as an electric current carrier for joining thin metal sheet. This research was focused on studying the effect of tin layer at the electrode tip for joining galvanized steel sheet. The main variable of this research is in the thickness of the intermetallic Cu3Sn layer. The result showed that the introduction of tin layer less than 1 μm in thickness on the electrode …

Simple Ml Detector For Multiple Antennas Communication System, Ahmad Taqwa, Soegijardjo Soegijoko, Sugihartono Sugihartono, Suhartono Tjondronegoro

Makara Journal of Technology

Simple ML Detector for Multiple Antennas Communication System. In order to support providing broadband wireless communication services against limited and expensive frequency bandwidth, we have to develop a bandwidth efficient system. Therefore, in this paper we propose a closed-loop MIMO (Multiple-Input-Multiple-Output) system using ML (Maximum Likelihood) detector to optimize capacity and to increase system performance. What is especially exciting about the benefits offered by MIMO is that a high capacity and performance can be attained without additional frequency-spectral resource. The grand scenario of this concept is the attained advantages of transformation matrices having capability to allocate transmitted signals power suit …

Fabrication Of Spherical Cao-Sro-Zno-Sio2 Particles By Sol-Gel Processing, Ill Yong Kim, Mark R. Towler, Anthony Wren, Chikara Ohtsuki

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study was concerned with the fabrication of ceramic CaO-SrO-ZnO-SiO₂ spherical particles, which are novel candidates for the glass phase in glass polyalkenoate cements (GPCs). GPCs made from these glasses have potential as bone cements because, unlike conventional GPCs, they do not contain aluminum ions, which inhibit the calcification of hydroxyapatite in the body. The glass phase of GPCs require a controllable glass morphology and particle size distribution. Sol-gel processing can potentially be used to fabricate homogenous ceramic particles with controlled morphology. However, a thorough study on preparation conditions of spherical CaO-SrO-ZnO-SiO₂ particles by sol-gel processing has, to …

Characterisation And Mechanical Testing Of Hydrothermally Treated Ha/Zro2 Composites, D. J. Curran, T. J. Fleming, G. Kawachi, C. Ohtsuki, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Hydrothermal treatment is traditionally employed to improve the sinterability of powder compacts by reducing porosity and increasing apparent density. The effect of hydrothermal treatment on green powder compacts has been assessed in order to better understand how treatment may affect the sinter ability of the bodies. Laboratory synthesized nano sized hydroxyapatite (HA) and a commercial zirconia (ZrO₂) powder have been ball milled together to create composite mixtures containing 0-5 wt% ZrO₂ loadings. Disc shaped bodies have been formed using uniaxial and subsequent isostatic pressure. The resultant coherent samples were subjected to hydrothermal treatment at either 120 or …

Analysis Of Γ-Irradiated Synthetic Bone Grafts By ²⁹Si Mas-Nmr Spectroscopy, Calorimetry And Xrd, D. Boyd, S. Murphy, Mark R. Towler, A. W. Wren, S. Hayakawa

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ca-Sr-Zn-Si glasses have demonstrated excellent biocompatibility both in vitro using the MTT assay with L929 mouse fibroblast cells, and in vivo using healthy and ovariectomized female Wistar rats. However, the biological evaluation of the materials was performed on glass granules that were autoclaved, rather than γ-irradiated; the sterilisation procedure required prior to implantation of these materials in the human body. Given the fact that when a glass is exposed to ionizing radiation changes in its physical properties can take place, it is imperative to determine whether the structure of such glasses will be altered as a result of exposure to …

Optimizing The Release And Methylation Of Bacterial Endospore Dipicolinic Acid, Aaron N. Nackos

Theses and Dissertations

Rapid, portable detection of biological threat agents such as Bacillus anthracis endospores (“spores”) is extremely important given the real and perceived threats of bioterrorism. Gas chromatography-mass spectrometry (GC-MS) is an excellent general means for chemical detection, although special sample preparation and specialized equipment are required to employ GC-MS for detecting biological agents such as spores in the field. A GC sample introduction probe consisting of a helical wire that can be retracted inside a syringe needle, called a coiled wire filament (CWF), was employed as a simple, passively-heated means to introduce the mixture of spores plus reagents for thermochemolysis methylation …

Fabrication Of High-Capacity Biomolecular Carriers From Dispersible Single-Walled Carbon Nanotube-Polymer Composites, Pu Zhang, David B. Henthorn

Chemical and Biochemical Engineering Faculty Research & Creative Works

One of the most interesting applications for carbon nanotubes is as a support material for bioanalytical devices. in this work, we successfully used an ultraviolet light initiated "graft from" polymerization method to fabricate polymer functionalized carbon nanotubes (PFCNTs) with pendant chains of various functionalities, including poly (ethylene glycol) chains to boost dispersibility and pendant epoxy groups for protein conjugate sites. a model enzyme, alkaline phosphatase, was used to study biomolecule loading efficiency as well as the retention of enzyme activity. Samples with various ratios of the two monomers were fabricated to optimize their use in aqueous environments, and an optimal …

Simple Agarose-Chitosan Gel Composite System For Enhanced Neuronal Growth In Three Dimensions, Zheng Cao, Ryan J. Gilbert, Wei He

Chemical and Biochemical Engineering Faculty Research & Creative Works

A simplified approach to increase neuronal attachment on an agarose hydrogel was proposed by blending agarose with another biocompatible polysaccharide, chitosan. The stiffness of the agarose gel was maintained despite the inclusion of chitosan, as determined by rheological tests. The structure of the blended hydrogels was characterized using light microscopy and scanning electron microscopy. An in vitro cell study revealed that the blends promoted neuron adhesion. The concentration of chitosan in the hydrogel had great influence on the morphology of neurons. An optimum range of chitosan concentration in agarose gel, to enhance neural cell attachment and differentiation, was identified based …

Computing Arrival Cost Parameters In Moving Horizon Estimation Using Sampling Based Filters, Sridhar Ungarala

Chemical & Biomedical Engineering Faculty Publications

Moving horizon estimation (MHE) is a numerical optimization based approach to state estimation, where the joint probability density function (pdf) of a finite state trajectory is sought, which is conditioned on a moving horizon of measurements. The joint conditional pdf depends on the a priori state pdf at the start of the horizon, which is a prediction pdf based on historical data outside the horizon. When the joint pdf is maximized, the arrival cost is a penalty term based on the a priori pdf in the MHE objective function. Traditionally, the a priori pdf is assumed as …

Nonlinearity In Large Amplitude Oscillatory Shear (Laos) Of Different Viscoelastic Materials, Xin Li, Shi-Qing Wang, Xiaorong Wang

College of Polymer Science and Polymer Engineering

The present work investigates nonlinear behavior in large amplitude oscillatory shear (LAOS) of four different polymeric materials using simultaneous conventional rheometric measurements and particle-tracking velocimetric observations. In contrast to most studies in the literature that treat nonlinearity in LAOS in steady state, we emphasize by the present four examples that nonlinearity in LAOS often arise in complex fluids due to time-dependent rearrangement of their microstructures in response to LAOS. Consequently, no correlation is obvious between strain dependence of the steady-state stress response and the time-dependent characteristics of the steady-state response. For instance, a highly viscoelastic material made of nano-sized polybutadiene …

The Effect Of Glass Synthesis Route On Mechanical And Physical Properties Of Resultant Glass Ionomer Cements, A. Wren, O. M. Clarkin, F. R. Laffir, C. Ohtsuki, I. Y. Kim, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glass ionomer cements (GICs) have potential orthopaedic applications. Solgel processing is reported as having advantages over the traditional melt-quench route for synthesizing the glass phase of GICs, including far lower processing temperatures and higher levels of glass purity and homogeneity. This work investigates a novel glass formulation, BT 101 (0.48 SiO₂-0.36 ZnO-0.12 CaO-0.04 SrO) produced by both the melt-quench and the solgel route. The glass phase was characterized by X-ray diffraction (XRD) to determine whether the material was amorphous and differential thermal analysis (DTA) to measure the glass transition temperature (T_g). Particle size analysis (PSA) was …

Methods For Cancer Detection, Kimberly W. Anderson, Kimberly M.L. May, Leonidas G. Bachas

Chemical and Materials Engineering Faculty Patents

A method is provided for detecting an analyte indicative of a cancer or a metastatic disease condition, which utilizes the ability of the analyte to induce permeability in a barrier. The method includes providing a biosensor having a barrier which is substantially impermeable to an ion, a permeable membrane which is selective for the ion, and a detector capable of detecting the ion. The biosensor is contacted with a sample including at least one of the ion and the analyte, wherein the analyte causes at least a portion of the ion to pass through the barrier and the membrane. Passage …

The Extraction Of Cytochrome C And Dsred2 Into Reverse Micelles, Michelle Baker

Theses and Dissertations

Cytochrome c and DsRed2 were successfully extracted into reverse micelles by the contacting of an aqueous protein-containing phase with an organic phase. Two important properties that differentiate the extraction profiles of these proteins are pI and size. Cytochrome c is a relatively small, monomeric protein with a pI of 10.6. It was easily extracted into reverse micelles with the anionic surfactant AOT. DsRed2, however, is a large tetramer with a p1 of 6.3. It could not be extracted into AOT, but was extracted with the cationic surfactant CTAB, and with a wider error range than cytochrome c. CD data indicate …

Phage-Induced Alignment Of Membrane Proteins Enables The Measurement And Structural Analysis Of Residual Dipolar Couplings With Dipolar Waves And Lambda-Maps, Sang Ho Park, Woo Sung Son, Rishi Mukhopadhyay, Homayoun Valafar, Stanley J. Opella

Faculty Publications

At pH > 6 added filamentous bacteriophage fd is compatible with many of the detergents used to solubilize membrane proteins for solution NMR studies of membrane proteins and, therefore, serves as an alignment media. In combination with strained polyacrylamide gel alignment, Dipolar Waves can be used to directly assess the secondary structure and a λ-map extracts the order tensors for de novo structure calculation of membrane proteins without distance restraints.

Chemical-Free Iron Removal And Disinfection Unit Of Drinking Water For Single House Application, Michael O'Hehir

Masters

The supply of safe drinking water is a major worldwide problem. In the developed world the frequency of water related problems are increasing The shortage of fresh water supply is as a result of pollution from industrial, agricultural and natural disasters. To make water suitable for human consumption, it must first be treated. However, consumers do not always receive potable water even after public treatment. In some cases the consumer must treat the water being supplied to them, or have to source their own water from private wells and treat it prior to use. The purpose of this research was …