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2007

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Articles 211 - 240 of 313

Full-Text Articles in Chemical Engineering

Gas-Solid Structure In The Vicinity Of A Sparger Nozzle In A Fluidized Bed, Pierre Sauriol, Heping Cui, Jamal Chaouki May 2007

Gas-Solid Structure In The Vicinity Of A Sparger Nozzle In A Fluidized Bed, Pierre Sauriol, Heping Cui, Jamal Chaouki

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

An experimental approach is proposed to investigate the gas-solid structure in the vicinity of a sparger nozzle in a fluidized bed. The local hydrodynamics were studied under injection velocities ranging between 0 and 100 m/s and three orientations. A fiber-optic probe was used to measure the instantaneous local particle holdup near the tip of the sparger nozzle. Under the investigated conditions, the local gas-solid structure was influenced on the measurement position, nozzle orientation and injection velocity. Four distinct zones were identified from the local particle holdup data, with the boundaries corresponding to characteristic jet lengths. Strong discrepancies were found with …

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Self-Fluidization Of Fastly-Moving Granular Gravity Currents With Implication On Pyroclastic Flows, Piero Bareschino, Antonio Marzocchella, Piero Salatino, Teresita Gravina, Lucio Lirer, Paola Petrosino May 2007

Self-Fluidization Of Fastly-Moving Granular Gravity Currents With Implication On Pyroclastic Flows, Piero Bareschino, Antonio Marzocchella, Piero Salatino, Teresita Gravina, Lucio Lirer, Paola Petrosino

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

The fast motion of gravity currents of group A granular solids is studied with a focus on the dynamical structure of the frontal zone. The frontal zone of the current is “immobilized” and observed in a fixed frame of reference by letting the current flow inside a rotary drum, big enough to make curvature effects negligible. The establishment of a variety of flow regimes, including intermittent avalanching, periodic “plunging breaking” and permanent fluidization of the granular solids in the frontal zone, can be related to flow conditions and to the nature of the granular solids.

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H2-Rich Syngas From Renewable Sources By Dual Fluidized Bed Steam Gasification Of Solid Biomass, Christoph Pfeifer, Tobias Pröll, Bernhard Puchner, Hermann Hofbauer May 2007

H2-Rich Syngas From Renewable Sources By Dual Fluidized Bed Steam Gasification Of Solid Biomass, Christoph Pfeifer, Tobias Pröll, Bernhard Puchner, Hermann Hofbauer

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

Steam gasification of solid biomass yields high quality producer gases that can be used for efficient combined heat and power production (CHP) and as a renewable resource for chemical syntheses. The dual fluidized bed steam gasification technology provides the necessary heat for steam gasification by circulating hot bed material that is heated in a second fluidized bed reactor by combustion of residual biomass char. The hydrogen content in producer gas of such gasifiers is about 40 vol% (dry basis). Addition of carbonates to the bed material and adequate adjustment of operation temperatures in the reactors allow selective transport of CO2 …

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Fluid-Dynamic Investigations In A Cold Model For A Dual Fluidized Bed Biomass Steam Gasification Process: Optimization Of The Cyclone, Andreas Kreuzeder, Christoph Pfeifer, Hermann Hofbauer May 2007

Fluid-Dynamic Investigations In A Cold Model For A Dual Fluidized Bed Biomass Steam Gasification Process: Optimization Of The Cyclone, Andreas Kreuzeder, Christoph Pfeifer, Hermann Hofbauer

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

Gasification of biomass is an attractive technology for combined heat and power production. Although a great deal of research and development work has been carried out during the past decade the commercial breakthrough for this technology is still not in sight. The optimisation of the operation costs influences significantly the economic efficiency. Especially bed material consumption constitutes a major part of expenses in fluidised bed systems. Thus, cyclones for circulating fluidized beds need to be designed properly. A dual fluidized bed steam gasifier is in commercial operation at the biomass CHP (combined heat and power plant) in Güssing, Austria since …

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Combustion Studies Of Sawdust In A Bubbling Fluidized Bed, K.V.N. Srinivasa Rao May 2007

Combustion Studies Of Sawdust In A Bubbling Fluidized Bed, K.V.N. Srinivasa Rao

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

Biomass fuels are difficult to handle due to high moisture and fines content. In the present work, the effect of secondary air injection on combustion efficiency of sawdust in the fluidized bed combustor has been discussed. An enlarged disengagement section is provided to improve combustion of fines. The maximum possible combustion efficiency with saw dust is 99.2 % and is observed at 65 % excess air.

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Authors Index, Xiaotao T. Bi, Franco Berruti, Todd S. Pugsley May 2007

Authors Index, Xiaotao T. Bi, Franco Berruti, Todd S. Pugsley

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

No abstract provided.

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Kinetics Of Surface-Initiated Photoiniferter-Mediated Photopolymerization And Synthesis Of Stimuli-Responsive Polymer Brushes, Santosh Rahane May 2007

Kinetics Of Surface-Initiated Photoiniferter-Mediated Photopolymerization And Synthesis Of Stimuli-Responsive Polymer Brushes, Santosh Rahane

All Dissertations

The focus of this research is to understand the kinetic and mechanistic aspects of surface-initiated photoiniferter-mediated photopolymerization (SI-PMP) and exploit the robustness of SI-PMP to synthesize stimuli-responsive polymer brushes. The 'living' characteristics of dithiocarbamate-based photoiniferter-mediated photopolymerization are well documented. However, in this dissertation I show that the growth of poly(methyl methacrylate) (PMMA) brushes by SI-PMP is nonlinear, suggesting loss of radicals during SI-PMP and, in turn, non-living characteristics. Results from kinetic models in conjunction with experimental results suggest that irreversible bimolecular termination reactions are a primary culprit for the loss of radicals during SI-PMP. To overcome this problem of irreversible …

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Photopolymerization-Induced Directional Crystal Growth In Reactive Mixtures, Soo Jeoung Park, Pankaj Rathi, Thein Kyu May 2007

Photopolymerization-Induced Directional Crystal Growth In Reactive Mixtures, Soo Jeoung Park, Pankaj Rathi, Thein Kyu

College of Polymer Science and Polymer Engineering

Photopolymerization-induced crystallization has been demonstrated in blends of polyethylene oxide-diacrylate at temperatures above the depressed melting temperature of the crystalline component. Upon exposure to ultraviolet irradiation, the melting transition curve moves upward and eventually surpasses the reaction temperature, thereby inducing phase separation as well as crystallization. The present paper demonstrates the occurrence of directionally solidified interface morphologies of polymer crystals subjected to a photointensity gradient. The epitaxially grown seaweed or degenerate structures were observed at the circumference (low-intensity region) while the dense branched spherulites developed at the core high-intensity region.

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Raman Spectroscopy Of The Human Nail: A Potential Tool For Evaluating Bone Health?, Mark R. Towler, A. Wren, N. Rushe, J. Saunders, N. M. Cummins, P. M. Jakeman May 2007

Raman Spectroscopy Of The Human Nail: A Potential Tool For Evaluating Bone Health?, Mark R. Towler, A. Wren, N. Rushe, J. Saunders, N. M. Cummins, P. M. Jakeman

Chemical and Biochemical Engineering Faculty Research & Creative Works

Dual X-ray absorptiometry (DEXA) is the current gold standard for the diagnosis of osteoporosis. However, patients can suffer osteoporotic fractures despite normal bone mineral density, partly because of unmeasured influences of both the protein and mineral phases of bone that are affected in osteoporosis. There is currently no clinically applicable method of evaluating the health of the protein phase. The proteins in human nail (keratin) and bone (collagen) require sulphation and disulphide bond (S-S) formation for structural integrity and disorders of either sulphur metabolism or cystathione beta-synthase can lead to structural abnormalities in these tissues. Raman protein spectra provide a …

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Commensurate Phases Of Gases Adsorbed On Carbon Nanotubes, Angela D. Lueking, W. Milton Cole May 2007

Commensurate Phases Of Gases Adsorbed On Carbon Nanotubes, Angela D. Lueking, W. Milton Cole

Chemical and Biochemical Engineering Faculty Research & Creative Works

A study is presented of the nature of ordered phases of various gases adsorbed on an isolated carbon nanotube. Because the spacing between neighboring adsorption sites depends on the tube's radius R, the equilibrium structure of the ground state is predicted to differ from that observed on planar graphite. Results for this structure are presented for the inert gases and hydrogen as a function of R for zigzag nanotubes.

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Using Cross-Sectioned Multilayer Polymer Film And Surface Modification To Form Chemically Patterned Substrates , Chun Zhang May 2007

Using Cross-Sectioned Multilayer Polymer Film And Surface Modification To Form Chemically Patterned Substrates , Chun Zhang

All Dissertations

Highly layered structures are important to micro- and nanofabrication technologies for understanding and controlling surface structures through manipulation of chemical and physical interactions. The objective of this work was to develop a new approach to create micro- and nanopatterned surfaces using multilayer polymer films of commercially available and inexpensive polymers instead of inorganic substrates. As an example, linear low density polyethylene (LLDPE) and ethylene-co-acrylic acid copolymer (EAA) were used as alternating inert and reactive polymers, respectively. Thin cross-sections of the multilayer molded sheets were prepared by ultra-microtoming.
As a precursor to the multilayer work, surface modification of EAA was conducted …

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Biomass And Coal Fly Ash In Concrete: Strength, Durability, Microstructure, Quantitative Kinetics Of Pozzolanic Reaction And Alkali Silica Reaction Investigations., Shuangzhen Wang Apr 2007

Biomass And Coal Fly Ash In Concrete: Strength, Durability, Microstructure, Quantitative Kinetics Of Pozzolanic Reaction And Alkali Silica Reaction Investigations., Shuangzhen Wang

Theses and Dissertations

Biomass represents an important sustainable energy resource, with biomass-coal cofiring representing among the most effective and cost efficient CO2 reduction strategies. Fly ash generated during coal combustion represents a technically advantageous, inexpensive, and environmentally beneficial admixture in concrete production, partially replacing cement. However, strict interpretation of American Society of Testing and Materials (ASTM) and American Concrete Institute (ACI) standards prohibits use of fly ashes from any source other than coal in concrete production; therefore, fly ash from biomass coal cofiring is excluded from use in concrete. This dissertation discusses biomass impacts on concrete properties through experiments conducted on several combinations …

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Modeling Three Reacting Flow Systems With Modern Computational Fluid Dynamics, Ralph J. Price Apr 2007

Modeling Three Reacting Flow Systems With Modern Computational Fluid Dynamics, Ralph J. Price

Theses and Dissertations

Computational fluid dynamics (CFD) modeling and analysis were used in three projects: solar CO2 conversion modeling, improved coal combustion modeling using STAR-CD, and premixed combustion modeling. Each project is described below. The solar CO2 conversion modeling project involved CFD simulations of a prototype solar CO2 converter that uses sunlight to dissociate CO2 into CO and O2. Modeling was used to predict the performance of this prototype converter using three CFD software packages, and involved predicting the flow, heat transfer, and chemical kinetics. Accuracy was determined by comparison of model predictions and experimental data. Parametric modeling studies were performed in order …

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Simple: System Automatic Essay Assessment For Indonesian Language Subject Examination, Anak Agung Putri Ratna, Bagio Budiardjo, Djoko Hartanto Apr 2007

Simple: System Automatic Essay Assessment For Indonesian Language Subject Examination, Anak Agung Putri Ratna, Bagio Budiardjo, Djoko Hartanto

Makara Journal of Technology

SIMPLE: System Automatic Essay Assessment for Indonesian Language Subject Examination. Evaluation of study of a student is a very important aspect of an educational process. Evaluation is aimed at measuring the level of student understanding of the given lecture materials. Measuring student understanding of the course material, using essay-type exam, is generally used as the evaluation tool. In this essay-type exam, the student has to answer questions using sentences, whereby choices of possible answers are not indicated. The student has to answer the questions with his/her sentences. The answers may vary, since it reflects the student’s best thoughts of the …

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Utilization Of Bagasse Cellulose For Ethanol Production Through Simultaneous Saccharification And Fermentation By Xylanase, M. Samsuri, Misri Gozan, R. Mardias, M. Baiquni, Heri Hermansyah, Anondho Wijanarko, Bambang Prasetya, M. Nasikin Apr 2007

Utilization Of Bagasse Cellulose For Ethanol Production Through Simultaneous Saccharification And Fermentation By Xylanase, M. Samsuri, Misri Gozan, R. Mardias, M. Baiquni, Heri Hermansyah, Anondho Wijanarko, Bambang Prasetya, M. Nasikin

Makara Journal of Technology

Utilization of Bagasse Cellulose for Ethanol Production through Simultaneous Saccharification and Fermentation by Xylanase. Bagasse is a solid residue from sugar cane process, which is not many use it for some product which have more added value. Bagasse, which is a lignosellulosic material, be able to be use for alternative energy resources like bioethanol or biogas. With renewable energy resources a crisis of energy in Republic of Indonesia could be solved, especially in oil and gas. This research has done the conversion of bagasse to bioethanol with xylanase enzyme. The result show that bagasse contains of 52,7% cellulose, 20% hemicelluloses, …

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Discrepancy In Determination Of Chi Parameters By Melting Point Depression Versus Small-Angle Neutron Scattering In Blends Of Deuterated Polycarbonate And Isotactic Poly(Methyl Methacrylate), Thein Kyu, Rushikesh A. Matkar, Dong Soo Lim, Chechian Ko Apr 2007

Discrepancy In Determination Of Chi Parameters By Melting Point Depression Versus Small-Angle Neutron Scattering In Blends Of Deuterated Polycarbonate And Isotactic Poly(Methyl Methacrylate), Thein Kyu, Rushikesh A. Matkar, Dong Soo Lim, Chechian Ko

College of Polymer Science and Polymer Engineering

The discrepancy in the chi interaction parameters of deuterated polycarbonate/isotactic poly(methyl methacrylate) blends as determined by the melting point depression approach and the small-angle scattering technique is reported. We have modified the Flory diluent theory by removing the inherent assumption of complete rejection of the solvent from the crystal solid by taking into consideration the crystal-amorphous, amorphous-crystal, and crystal-crystal interactions. The discrepancy in chi values obtained by the two methods is discussed.

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A Correlation Between Velocity Profile And Molecular Weight Distribution In Sheared Entangled Polymer Solutions, Pouyan E. Boukany, Shi-Qing Wang Apr 2007

A Correlation Between Velocity Profile And Molecular Weight Distribution In Sheared Entangled Polymer Solutions, Pouyan E. Boukany, Shi-Qing Wang

College of Polymer Science and Polymer Engineering

In this work we attempt to answer several questions concerning the flow characteristics of entangled polymer solutions in a sliding plate shearing cell. We explore (a) how the molecular weight distribution affects the velocity profile in simple shear, (b) whether the observed shear banding is consistent with a nonmonotonic constitutive model, (c) whether the flow response and velocity profiles are different in simple shear depending on the different modes of shear. Our results provide a comparison with recent reports on a polydisperse polymer sample [Tapadia and Wang, Phys. Rev. Lett. 96, 016001 (2006); Tapadia, et al., Phys. Rev. Lett. 96, …

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Biodesulphurization Within Natural Gas In Oil And Gas Field, Sri Astuti Rahayu, M. Fierdaus, Syafrizal Syafrizal, M. Udiharto Apr 2007

Biodesulphurization Within Natural Gas In Oil And Gas Field, Sri Astuti Rahayu, M. Fierdaus, Syafrizal Syafrizal, M. Udiharto

Makara Journal of Technology

The presence of sulphur compounds in natural gas can interfere to the quality of natural gas. The decline of combustion gas capacity, metal instrument corrosion in gas piping, and the environmental pollution from gas emission can affect by their presence. Bio-filter is one of the methods that selected to reduce sulphur content in natural gas. A lab scale study of hydrogen sulphide reduction in natural gas had conducted in oil and gas field using bio-filter method. The bio-filter system (±1 L volume) contains an active carbon and thiosulphide medium as a substrate, Thiobacillus thioparus as a single culture of sulphur …

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Producing Biodiesel From Jatropha In Egypt: The Research Of Emmanuel Pitia, Tammy Wolf Apr 2007

Producing Biodiesel From Jatropha In Egypt: The Research Of Emmanuel Pitia, Tammy Wolf

Inquiry Journal 2007

No abstract provided.

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Production Of Medium Chain Length Polyhydroxyalkanoates From Oleic Acid Using Pseudomonas Putida Pga1 By Fed Batch Culture, Sidik Marsudi, Irene K.P. Tan, Seng Neon Gan, K. B. Ramachandran Apr 2007

Production Of Medium Chain Length Polyhydroxyalkanoates From Oleic Acid Using Pseudomonas Putida Pga1 By Fed Batch Culture, Sidik Marsudi, Irene K.P. Tan, Seng Neon Gan, K. B. Ramachandran

Makara Journal of Technology

Bacterial polyhydroxyalkanoates (PHAs) are a class of polymers currently receiving much attention because of their potential as renewable and biodegradable plastics. A wide variety of bacteria has been reported to produce PHAs including Pseudomonas strains. These strains are known as versatile medium chain length PHAs (PHAs-mcl) producers using fatty acids as carbon source. Oleic acid was used to produce PHAs-mcl using Pseudomonas putida PGA 1 by continuous feeding of both nitrogen and carbon source, in a fed batch culture. During cell growth, PHAs also accumulated, indicating that PHA production in this organism is growth associated. Residual cell increased until the …

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Mechanical Study On Using Of Accr Thermal Conductor At 500 Kv Sutet, Suprihadi Prasetyono Apr 2007

Mechanical Study On Using Of Accr Thermal Conductor At 500 Kv Sutet, Suprihadi Prasetyono

Makara Journal of Technology

Mechanical Study on using of ACCR Thermal Conductor at 500 kV SUTET. At the height of electricity demand increasing recently, circumstance of environment more limited and also expense of high investment, making thermal conductor (conductor thermal resistance) considered to be one of alternative in the electricity transmission bottlenecks. These days it has been developed thermal conductor ACCR (Aluminium Conductor Composite Reinforced) which can operate with temperature up to 240oC, so that making the current carrying capacity being higher than conventional conductor. This research aimed to study load current leading to mechanical characteristic ACCR conductor included tension, length of elongation and …

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Production Of Hydrogen And Sulfur From Hydrogen Sulfide In A Nonthermal-Plasma Pulsed Corona Discharge Reactor, Morris D. Argyle, Gui-Bing Zhao, Sanil John, Ji-Jun Zhang, Jerry C. Hamann, Suresh S. Muknahallipatna, Stanislaw Legowski, John F. Ackerman Apr 2007

Production Of Hydrogen And Sulfur From Hydrogen Sulfide In A Nonthermal-Plasma Pulsed Corona Discharge Reactor, Morris D. Argyle, Gui-Bing Zhao, Sanil John, Ji-Jun Zhang, Jerry C. Hamann, Suresh S. Muknahallipatna, Stanislaw Legowski, John F. Ackerman

Faculty Publications

Hydrogen Sulfide (H2S) dissociation into hydrogen and sulfur has been studied in a pulsed corona discharge reactor (PCDR). Due to the high dielectric strength of pure H2S (~2.9 times higher than air), a non-thermal plasma could not be sustained in pure H2S at discharge voltages up to 30kV with our reactor geometry. Therefore, H2S was diluted with another gas with lower dielectric strength to reduce the breakdown voltage. Breakdown voltages of H2S in four balance gases (Ar, He, N2 and H2) have been measured at different H2S concentrations and pressures. Breakdown voltages are proportional to the partial pressure of H2S …

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Construction Of Short-Length High-Rates Ldpc Codes Using Difference Families, Deny Hamdani, Ery Safrianti Apr 2007

Construction Of Short-Length High-Rates Ldpc Codes Using Difference Families, Deny Hamdani, Ery Safrianti

Makara Journal of Technology

Low-density parity-check (LDPC) code is linear-block error-correcting code defined by sparse parity-check matrix. It is decoded using the massage-passing algorithm, and in many cases, capable of outperforming turbo code. This paper presents a class of low-density parity-check (LDPC) codes showing good performance with low encoding complexity. The code is constructed using difference families from combinatorial design. The resulting code, which is designed to have short code length and high code rate, can be encoded with low complexity due to its quasi-cyclic structure, and performs well when it is iteratively decoded with the sum-product algorithm. These properties of LDPC code are …

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Kinetic Model For Triglyceride Hydrolysis Using Lipase:Review, Heri Hermansyah, A. Wijanarko, Dianursanti Dianursanti, Misri Gozan, Praswasti P. D.K Wulan, Rita Arbianti, Roekmijati W. Soemantojo, Tania Surya Utami, Yuliusman Yuliusman, Momoji Kubo, Naomi Shibasaki Kitakawa, Toshiy Yonemoto Apr 2007

Kinetic Model For Triglyceride Hydrolysis Using Lipase:Review, Heri Hermansyah, A. Wijanarko, Dianursanti Dianursanti, Misri Gozan, Praswasti P. D.K Wulan, Rita Arbianti, Roekmijati W. Soemantojo, Tania Surya Utami, Yuliusman Yuliusman, Momoji Kubo, Naomi Shibasaki Kitakawa, Toshiy Yonemoto

Makara Journal of Technology

Triglyceride hydrolysis using lipase has been proposed as a novel method to produce raw materials in food and cosmetic industries such as diacylglycerol, monoacylglycerol, glycerol and fatty acid. In order to design a reactor for utilizing this reaction on industrial scale, constructing a kinetic model is important. Since the substrates are oil and water, the hydrolysis takes place at oil-water interface. Furthermore, the triglyceride has three ester bonds, so that the hydrolysis stepwise proceeds. Thus, the reaction mechanism is very complicated. The difference between the interfacial and bulk concentrations of the enzyme, substrates and products, and the interfacial enzymatic reaction …

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Sulfonation Of Cptfe Film Grafted Styrene For Proton Exchange Membrane Fuel Cell, Yohan Yohan Apr 2007

Sulfonation Of Cptfe Film Grafted Styrene For Proton Exchange Membrane Fuel Cell, Yohan Yohan

Makara Journal of Technology

Sulfonation of cPTFE Film grafted Styrene for Proton Exchange Membrane Fuel Cell. Sulfonation of γ-ray iradiated and styrene-grafted crosslinked polytetrafluoroethylene film (cPTFE-g-S film) have been done. The aim of the research is to make hydropyl membrane as proton exchange membrane fuel cell. Sulfonation was prepared with chlorosulfonic acid in chloroethane under various conditions. The impact of the percent of grafting, the concentration of chlorosulfonic acid, the reaction time,and the reaction temperature on the properties of sulfonated film is examinated. The results show that sulfonation of surface-grafted films is incomplete at room temperature. The increasing of concentration of chlorosulfonic acid and …

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Continuous Co-Separation By Liquid Absorption In Aqueous Cuprous Chloride (Cucl) And Magnesium Chloride (Mgcl2) Solution, Paul J. Foster Mar 2007

Continuous Co-Separation By Liquid Absorption In Aqueous Cuprous Chloride (Cucl) And Magnesium Chloride (Mgcl2) Solution, Paul J. Foster

Theses and Dissertations

The purpose of the research was to design, build, test, and recommend a process to economically separate CO from a gas mixture of CO, CO2, and O2. The general method considered in this research to accomplish the separation was liquid absorption in a packed column. Several experiments were performed to identify the best process solution to use in a prototype. The experiments, based on the COSORB process, consisted of CuCl mixed with a complexing agent (metal tri-chloride) and a solvent (metal tetra-chloride, toluene, ethanol, etc.). The best method consisted of an aqueous solution of CuCl and MgCl2, which has previously …

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Structure And Nitrogen Chemistry In Coal, Biomass, And Cofiring Low-Nox Flames, Bradley David Damstedt Mar 2007

Structure And Nitrogen Chemistry In Coal, Biomass, And Cofiring Low-Nox Flames, Bradley David Damstedt

Theses and Dissertations

Addressing global climate change will require increasing sustainable energy usage. Cofiring biomass fuels with coal for electrical power generation is an efficient, cost effective method of CO2 mitigation. This work is an experimental investigation of the flame structure and nitrogen chemistry differences occurring between coal, biomass and cofiring flames. A pilot-scale facility was fired with a dual-feed low-NOx burner capable of independently conveying 2 separate fuels unblended to the burner. Spatially detailed gas species measurements were made for 8 flames, including a coal, straw, finely ground straw, wood, and 4 straw/coal cofiring flames. Particle samples were also obtained from 5 …

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The Role Of Ultrasound Cavitation In Liposome Size Reduction, William G. Pitt, Eric S. Richardson, Dixon J. Woodbury Mar 2007

The Role Of Ultrasound Cavitation In Liposome Size Reduction, William G. Pitt, Eric S. Richardson, Dixon J. Woodbury

Faculty Publications

Liposome size is a vital parameter of many quantitative biophysical studies. Sonication, or exposure to ultrasound, is used widely to manufacture artificial liposomes, yet little is known about the mechanism by which liposomes are affected by ultrasound. Cavitation, or the oscillation of small gas bubbles in a pressure-varying field, has been shown to be responsible for many biophysical effects of ultrasound on cells. Collapse cavitation is manifested in the acoustic spectrum by an f/2 subharmonic and an increase in broadband noise. In this study, we attempted to correlate the presence of cavitation with a decrease in liposome size. Lipid suspensions …

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Thermoeconomics Of Seasonal Latent Heat Storage System, Yaşar Demirel, H. Hüseyin Öztürk Mar 2007

Thermoeconomics Of Seasonal Latent Heat Storage System, Yaşar Demirel, H. Hüseyin Öztürk

Papers in Thermal Mechanics

A simple thermoeconomic analysis is performed for a seasonal latent heat storage system for heating a greenhouse. The system consists of three units that are a set of 18 packed-bed solar air heaters, a latent heat storage tank with 6,000 kg of technical grade paraffin wax as phase-changing material, and a greenhouse of 180m2. The cost rate balance for the output of a unit is used to estimate the specific cost of exergy for a yearly operation. Based on the cost rate of exergy, fixed capital investment, operating cost, and economic data, approximate cash-flow diagrams have been prepared. The systems …

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Fabrication And Performance Of Ni-Scsz Cermet Anode Modified By Coating With Gd0.2Ce0.8O2 For A Sofc, Ren-Zhu Liu, Bo Huang, Xiao-Feng Ye, Shao-Rong Wang, Jia-Di Cao, Huai-Wen Nie, Ting-Lian Wen Feb 2007

Fabrication And Performance Of Ni-Scsz Cermet Anode Modified By Coating With Gd0.2Ce0.8O2 For A Sofc, Ren-Zhu Liu, Bo Huang, Xiao-Feng Ye, Shao-Rong Wang, Jia-Di Cao, Huai-Wen Nie, Ting-Lian Wen

Journal of Electrochemistry

A Ni-scandia-stabilized zirconia(Ni-ScSZ) cermet anode modified by coating with nano-sized gadolinium-doped ceria(GDC,Gd0.2Ce0.8O2) was prepared using a simple combustion process for the solid oxide fuel cell(SOFC) running on methane fuel. X-ray diffraction(XRD) and scanning electron microscopy(SEM) indicated that the surface of Ni-ScSZ was coated by nano-sized GDC particles(<100nm). Single cell testing showed that the 2.0%(by mass) GDC-coated Ni-ScSZ anode had better performance. The highest power densities of the cell with this anode were 825 and 848mW/cm2 at 850℃ in humidified hydrogen and methane, respectively, whereas the corresponding values were 584 and 586mW/cm2 for the cell with Ni-ScSZ anode.Electrochemical impedance spectra(EIS) illustrated that the cell with Ni-ScSZ anode exhibited far greater impedances than the cell with 2.0%(by mass) GDC-coated Ni-ScSZ anode.Then the …

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