Chemical Engineering Commons^™

Mitigation Of Wellbore Instability In Deviated Wells By Using Geomechanical Models And Mpd Technique, Husam Raad Abbood

Masters Theses

"During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe presents a significant wellbore stability problem for deviated wells. In this study, two solutions are utilized to address this problem. The first approach is a 1-D Geomechanical model of the Mishrif formation compiled based on the state of stress and rock strength parameters. It is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The results of this study show that wells characterized by stuck pipe are drilled along azimuths which promote wellbore collapse. Three different failure criteria, the …

Conceptual Parameters Necessary For Modeling Wettability Alteration In An Enhanced Smart Brine-Chalk System, Ahmed Abdulkareem Hussein Albahrani

Masters Theses

"Achieving higher recovery of oil from proven carbonate reserves around the world is not an easy task. One promising new method, especially for carbonate reservoirs, is the use of "Smart Water" technology, which is an injection water with carefully determined, optimal ionic composition and salinity. Recent experiments have shown good recovery results, but the mechanism of wettability alteration by this fluid are still not well understood. The goal of this study is to review the high and optimal salinity and ionic composition literature plus perform dimensional analysis of key variables in order to shed light on the physical and chemical …

An Investigation Of Plugging And Increasing Oil Recovery In Sandstone Porous Media By Micrometer-Size Particle Gel, Haifeng Ding

Masters Theses

"Micrometer-size particle gel (microgel) has been developed and successfully applied to improve conformance in mature reservoirs. However, quite few researches have been published to address on their effect on oil recovery and rock permeability modification.

This work conducted a series of core flooding experiments to investigate the injectivity, plugging efficiency and improving oil recovery potentials of a couple of microgels synthesized in our lab.

First, this work studied the impact of permeability and crosslinker concentration on PAM type microgel treatment. Results shows that microgel treatment would have a less plugging efficiency in lower permeability rocks, which could be caused by …

Impact Of Repeated Cyclic Production Scheme On Eur In Low-Permeability Reservoirs, Samarth Gupte

Masters Theses

"Productivity in low-permeability reservoirs declines quickly compared to conventional reservoirs. These tight reservoirs have very high initial oil production rates but as soon as the oil near the fractured area is recovered, the production declines rapidly making economic oil and gas production a challenge for the industry. This study investigates the impact of repeated shut-in/production cycles on the ultimate recovery of oil in such environments.

A reservoir model with multiple fractured horizontal well having 30 transverse fractures is created using CMG. Reservoir permeability is varied over the range of 0.000001 md to 10 md and shut-in/production cycles of 2-weeks, 1-month, …

Design, Scale-Up, Six Sigma In Processing Different Feedstocks In A Fixed Bed Downdraft Biomass Gasifier, Sai Chandra Teja Boravelli

Masters Theses

"This thesis mainly focuses on design and process development of a downdraft biomass gasification processes. The objective is to develop a gasifier and process of gasification for a continuous steady state process. A lab scale downdraft gasifier was designed to develop the process and obtain optimum operating procedure.

Sustainable and dependable sources such as biomass are potential sources of renewable energy and have a reasonable motivation to be used in developing a small scale energy production plant for countries such as Canada where wood stocks are more reliable sources than fossil fuels. This thesis addresses the process of thermal conversion …

Study And Development Of Robust Preformed Particle Gels For Conformance Control, Yifu Long

Masters Theses

"To improve the oil recovery of mature reservoirs, technologies referring to conformance control have been widely developed and implemented. Among various technologies, preformed particle gel (PPG) treatment has attracted increasing attentions. PPGs, as a kind of deformable plyometric superabsorbent, could be pumped through injection wells as plugging agents to block the fracture or high-permeability zone in a reservoir.

In decade usage of PPGs, an intensively employed material is poly(acrylamide) (PAM) based hydrogel. However, conventional PAM gel did reveal deficient in formidable conditions, such as formations with high temperature and high salinity. Therefore, a novel PPG based on starch-grafting-poly(acrylamide)/nano-composite (SAC) hydrogel …

Surface Modification Of Tin Oxide Nanoparticles By Atomic Layer Deposition For Enhanced Electrochemical Performance, Sai Abhishek Palaparty

Masters Theses

"Atomic Layer Deposition is a robust technique used to deposit high quality, conformal, and size-tunable ultrathin films on a substrate. This technique can be used to coat protective films on battery anode and cathode materials for enhanced performance. In the case of cathodes, the ultrathin film provides a protective barrier preventing cationic dissolution. In the case of anodes, the film acts as a supporting matrix reducing strain caused by volume expansions. In these study, we use this technique to coat an optimally thick conductive iron oxide film on tin oxide particles to improve its electrochemical performance at high current densities …

Hydrodynamic Of A Co-Current Gas Liquid Upflow In A Moving Packed Bed Reactor With Porous Catalysts, Ali Jabbar Toukan

Masters Theses

"In this study, the hydrodynamic, i.e. flow regime identification, line average liquid holdup, and the internal liquid holdup of a co-current moving packed bed reactor were studied. For the sake of hydrodynamics study, moving bed reactor is investigated as two-phase upflow packed bed reactor. Scaled down configuration was used to simulate of the moving bed reactors utilized in the industrial process. First, line average liquid holdup is measured with different geometrical configurations covering empty, dry, wet, and packed column under flowrates operation conditions. A new methodology has been developed to determine the line average liquid holdup for a porous catalyst. …

Correlation Anaylsis Of Magnesite Dissolution Rate And Magnesite Spatial Distribution, Yao Wang

Masters Theses

"This thesis presents a correlation analysis of the spatial distribution and permeability of magnesite dissolution and focuses on its overall rate and average porosity. Magnesite dissolution is affected by several aspects.

A reservoir's large spatial distribution can make capturing the magnesite dissolution difficult, so in this study, a variogram was built in Petrel using a percentage variation of magnesite and sand. The variogram also handles different major and minor directions in anisotropy. After building the magnesite model, simulation of magnesite dissolution was achieved in Cruch Flow to get the magnesite dissolution rate and average porosity.

For correlation analysis, a regression …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

Numerical Analysis Of Flexural Slip During Viscoelastic Buckle Folding, Davi Rodrigues Damasceno

Masters Theses

"Flexural slip is considered to be an important folding mechanism contributing in the development of different folds such as chevron, and kink-band buckle folds. Various filed studies have provided a general conceptual and qualitative understanding of flexural slip. However, quantitative evidence of the importance of the flexural slip mechanism during fold evolution is sparse, as the actual amount of surface parallel displacement, and timing, is difficult to measure accurately, due to the lack of suitable strain markers.

In this study 2D finite element analysis is used to overcome these disadvantages and to simulate flexural slip during viscoelastic buckle folding. Variations …

Data Analysis Of Surfactant-Induced Wettability Alteration In Carbonate Reservoirs, Hao Sun

Masters Theses

"Most carbonate formations prove to be oil-wet due to oil aging effect. Therefore it is essential to employ wettability alteration methods for a more effective enhanced oil recovery process. It is confirmed by researchers that surfactant treatment has positive effects on wettability alteration of carbonate rock, from strong oil-wet to intermediate wet or to even weak water-wet. A number of experiments have the same conclusion and yet, a systematic screening guide development with the support of sufficient data analysis is lacking.

This study involves screening guide development for surfactant-induced wettability alteration method. 199 experiments collected from published literatures are analyzed …

Shale Instability Of Deviated Wellbores In Southern Iraqi Fields, Ahmed Ali Shanshool Alsubaih

Masters Theses

"Wellbore instability problems are the cause for the majority of nonproductive time in the southern Iraqi fields' developments. The most severe problem in terms of effort and disbursement which is referred to a pipe sticking in Tanuma shale formation. Examining the drilling data revealed that this phenomenon was mostly related to the shear failure of the wellbore. Thus, a geomechanical analysis and drilling parameters/ practice optimization analysis were performed on a field in southern Iraq based on data from 45 deviated wells. The geomechanics analysis predicted the suitable drilling fluid density to prevent onset shear failure by using the Mogi-Coulomb …

Mechanistic Understanding Of Water-Rock Interactions During High-Salinity Water-Flooding Of Carbonate Reservoirs, Pu Han

Masters Theses

"Chemically tuned water-flooding provides a relatively cheap method of enhanced oil recovery from carbonate and sandstone reservoirs. Several possible recovery mechanisms such as mineral dissolution, multi-component ion exchange, double-layer expansion, adsorption/desorption from rock surface, reduction in interfacial tension, and fines migration that have been proposed are widely debated. The combination of these processes may result in wettability alteration that increases sweep efficiency of water-flooding. Here, wettability alteration due to water-rock interactions will be examined numerically.

To evaluate the wettability alteration, separation between breakthrough curves of the non-reactive component and the cations based on the chromatographic separation will be used due …

Evaluating Completion Performance For Gas Wells In The Upper And The Lower Montney Formation, Canada, Omar Qasim Mohammed

Masters Theses

"Identifying the key drivers for success of multiple fractured horizontal wells is not straightforward, especially in unconventional reservoirs like the Montney. Al-Alwani et al. (2015) provided a statistical analysis of Montney completions based on publicly available data. They showed that for the entire well population, cumulative gas recovery per stage, declines as the number of completed stages increase. However, their statistical analysis did not differentiate between completions in the Upper/Middle/Lower Montney, and did not include perforation cluster data.

This work documents the statistical analysis of 296 cased-hole horizontal gas well completions reported in the Upper and the Lower Montney. The …

Characterization Of Fracture Initiation In Non-Cylindrical Buckle Folds Using 3d Finite Element Analysis, Eli Jacob Steinbeck

Masters Theses

"The spatial distribution of fracture sets associated with buckle folds has been well documented in field studies. There are difficulties, however, in placing accurate constraints on the timing of the initiation of individual fracture sets during the deformation history of the fold under in-situ conditions. This study investigates specific conditions that give rise to the initiation of various fracture sets in the hinge and limb of a pericline, based on an analysis of the effective stress evolution during the processes of buckling and erosional unloading. A 3D finite element modeling approach is used to simulate the effective stress evolution in …

Fluid Flow Through Deformation Band, Huining Zhang

Masters Theses

"Cataclastic deformation bands, which are common in porous sandstone, have the potential to restrict fluid flow. Geological studies have shown that permeability of deformation band shear zones can be one to five orders of magnitude less than for the sandstone host rock. However, recent studies based on simplified analytical estimates have shown that fluid flow in jointed deformation bands may not be retarded since joints play an important role in conducting fluids. In this study, 2 dimensional finite element analysis (FEA) is used to simulate the total discharge flow rate through jointed deformations. Variations of single planar and conjugate jointed …

Exploring Reservoir Connectivity With Production Data: Two New Methods And A New Technique, Ghazwan Faisal Jasim Al-Khmaysawee

Masters Theses

"This study presents two new, simple methods to explore reservoir connectivity, which has a significant impact on field development strategy. Identifying reservoir connectivity during primary depletion plays an important role in achieving the most cost-effective and highest production possible. It is also very important in future secondary and tertiary oil recovery, particularly when costs dictate a limited number of wells such as those in deepwater environments.

The presented methods are reciprocal-productivity index versus total field material-balance time trend lines and reciprocal-productivity index versus time trend lines. Those two methods are quick, simple, inexpensive, and only need rate and pressure data …

Bioresponsive Polymer Coating On Nanoparticles, Tunyaboon Laemthong

Masters Theses

"Nanotechnology incorporated with molecular biology became a promising way to treat cancer. The size of nanoparticles enables them to overcome the side effects noticed in cancer treatment like chemotherapy and surgery. Various types and shapes of nanoparticles have been synthesized and used in drug delivery to tumor sites. However, one of problems of using these nanoparticles is the aggregation after injecting them into human body due to flow rate of bloodstream. The coagulation and aggregation will result in clogging blood vessel and lower therapeutic efficacy.

In this thesis, a solution to the aggregation problem was proposed, which is coating biopolymer …

Sensitivity Analysis Of Geomechanical Parameters In A Two-Way Coupling Reservoir Simulation, Hector Gabriel Donoso

Masters Theses

"Currently reservoir simulators model geomechanical effects such as compaction, subsidence, fault reactivation, breach of the seal integrity, etc. using only the rock compressibility to change the pore volume. However, rock compressibility as a scalar quantity is unfit to represent the true rock mechanics in the reservoir. In order to accurately represent geomechanical effects in a reservoir simulation, a two-way coupling simulation of the stress analyzer and the reservoir simulator was done. Based on the poroelasticity theory during the production or depletion of the reservoir the porosity and permeability changed due to the stress or pore pressure changes.

A sensitivity analysis …

Single Phase Gas Flow Response Of Fractured Horizontal And Vertical Wells To Repeated Production, Divya Kandlakunta

Masters Theses

"Historically, the conventional approach to well production has been to produce continuously, minimizing interruptions to flow insofar as possible. Yet some operators have observed improved well flow rates and ultimate recovery after a significant well shut-in periods. These production increases have not been documented. This study investigates the production impact of cyclic production/shut-in on fractured vertical and horizontal gas well performance.

A numerical reservoir model in Stimplan software was used to model production in fracture stimulated vertical and horizontal gas wells. Reservoir permeability is varied over a range of 0.0001 md to 1 md, and the shut-in period was varied …

Computational Fluid Dynamic Analysis In High Permeability Hydraulic Fractured Horizontal Gas Wells, Hrithu Vasudevan

Masters Theses

"Hydraulic fracturing of horizontal wells in unconventional reservoirs has become the dominant type of well completion performed in the United States. In very low permeability reservoirs (~.00001-.0001 mD), the wellbore is aligned with the minimum horizontal stress, and the completion includes multiple transverse fractures. These fractures may be placed with either open hole sleeve type completion systems (OHMS), or cased hole plug and perf systems (P-n-P). In slightly higher permeability reservoirs (1 to 10 mD) multiple longitudinal fractures have been found to be preferred to completions with transverse fractures.

This study presents an evaluation of gas well productivity for both …

Simulation Of Lateral Migration And Sedimentation Of A Flexible Fiber In A Vertical Weak Shear Flow, Ali Ibrahim Neamah Neamah

Masters Theses

This research is a thorough numerical investigation and critical analysis of lateral migration of a deformable particle settling in a vertical weak shear flow. Under the vertical weak shear fluid, the deformable particle may move either to the coagulation area, or the dispersion area, depending on Reynolds numbers, shear Reynolds number, fiber flexibility, and aspect ratio. In this study, a lattice Boltzmann equation is used to solve Navier-Stokes equation and a flexible particle method is employed to attack the problem of motion of a flexible fiber. A bounce-back rule is used to deal with moving boundaries interacting with fluids. Several …

Formulation And Evaluation Of Soy Polymer Based, Gravure Printed Resistive Inks For Applications In Printed Electronics, Bhushan Hiralal Patil

Masters Theses

Today, the majority of the commercially available conductive inks are formulated using expensive metallic particles, such as silver and gold. Most of the inks use volatile solvents in the formulation, which are hazardous to the environment as emission of VOCs is the major concern. In the case of water-based inks, usually petroleum-based acrylic polymers are used. Apart from being nonrenewable raw materials, acrylic polymers are carcinogenic in nature. Also, acrylic polymers are used in a variety of applications, such as the automotive, medical device, paint, and adhesive industries. Often times, the ink industry has to compete with other industries for …

Oxidized Phospholipids Regulation Of The Monocyte Recruitment Parthway In Human Aortic Endothelial Cells, Piao Jian Tan

Masters Theses

Low-density lipoprotein particles in blood plasma invade the endothelium and become oxidized, creating risk of CHD associated with atherosclerosis, the main underlying condition in coronary heart disease. Oxidation products of the phospholipid 1-palmitoyl- 2-arachidonoyl-sn-glycerol-3-phosphatidylcholine (PAPC) are bioactive components of minimally oxidized LDL that stimulate endothelial cells that line the artery, leading to monocyte binding and atherosclerosis. It is hypothesized that the regulation of the monocyte recruitment pathway by these oxidized phospholipids is mediated by the binding of OxPAPC to one or more mediating proteins. Human recombinant VEGFR2, GRP78, and EP2bind to OxPNB, a biotinylated analog of OxPAPC, demonstrated using Western …

The Design Of Nanostructures From The Blending Of Flowing Agents Influencing Critical Properties Of A Pharmaceutical Formulation, Casey F. Kick

Masters Theses

In the pharmaceutical manufacturing process, it is well known that flowing agents such as MgSt and Cab-O-Sil widely affect critical flow properties that influence the finished product performance of oral dosage tablets. Though the effects of flowing agents are beneficial to some extent, the sensitivity of the pharmaceutical formulation to process shearing of flowing agents during blending can be catastrophic which often results in product and batch failures. Hence it is essential to study the concentration of flowing agents and chemical nature of active pharmaceutical ingredients (API) with respect to applied process shear on formulations. Previous studies have shown that …

Development And Verification Of A Method To Determine The Long Term Load Carrying Performance Of A Double Sided Pressure Sensitive Adhesive Tape, Rahal Rasheed

Masters Theses

Acrylic foam pressure sensitive adhesive (PSA) tapes are used in various applications as an alternative of mechanical fasteners, especially in areas like structural bonding which requires demanding bond strength and durability.

This research focuses on comparing design values of acrylic foam PSA using static shear test method and dynamic shear test method in accordance of J0MP0164 standard specification. Static shear test has lots of disadvantages; but on the other hand it is the test that mimics the real life usage of a tape in a real life application. Dynamic shear test is a faster way of testing and gives a …

Impact Of Calendering And Silver Addition To Carbon Nanotube-Based Electrodes Used In Printed Multi-Layer Capacitors, Ramea Awni Al-Mubarak

Masters Theses

As the demand for global energy increases, the need for development of alternative clean and sustainable energy technology increases. Creating advanced energy devices with a large storage capacity plays a significant role in this development. This research focused on investigating the performance of capacitor devices used as energy storage cells by optimizing and determining the impact of silver percentage and structure (nano-wires or silver flake) added to CNT ink on the conductivity of printed layers, and studying the influence of calendering the multi-layer capacitor electrodes. Multi-layer capacitors were fabricated by screen printing three alternative layers of conductive and dielectric inks …

Low Melting Glass Frit As An Adhesion And Resistivity Promotor To Silver Nanoparticle Ink Photonically Sintered On Indium Tin Oxide Coated Glass, Jason J. Kleiner

Masters Theses

The objective of this study was the fabrication of a printed circuit resulting from the photonic drying/sintering of conductive circuits, printed using silver nano ink layered on a film of low melting glass frit onto indium tin oxide (ITO) coated glass substrate through the flexographic printing method. The fabrication process flow included material preparation, printing, and photonic drying/sintering in that order.

Investigation of the breakthrough photonic drying/sintering method was studied by varying sintering parameters, specifically the amount of heat energy applied to each specimen, and the speed at which it was applied. Additionally, the adhesion promoting properties of a never …

Simulation Of Drainage Rates Of A Flexible Fiber Network On Wire Screen, Yihsin Tang

Masters Theses

A forming process of a fiber mat over a filter or wire net/screen, which can move horizontally, is numerically simulated. A lattice Boltzmann equation is used to simulate fluid velocity, vorticity and structures and a lattice spring model is employed to mimic the collective motion of up to 750 flexible fibers, with aspect ratio of 20.

The interaction between the fluid and fibers is handled by an immersed boundary method. The fiber motion is driven by the hydrodynamic forces and the gravity of both fluid and solid fibers and disturbed by the horizontal shear force between the fluid and the …