Chemical Engineering Commons^™

Multiphase Mechanisms And Fluid Dynamics In Gas Injection Enhanced Oil Recovery Processes, Madhav M. Kulkarni

LSU Doctoral Dissertations

Currently, the Water-Alternating-Gas (WAG) process is the most widely practiced horizontal mode gas injection process in the industry. Although this process is conceptually sound, it has resulted in low (5 – 10%) oil field recoveries. Conversely, the gravity stable mode of gas injection has carved its niche as one of the most effective methods of gas injection EOR in the dipping reservoirs and pinnacle reefs. The Gas Assisted Gravity Drainage (GAGD) process is therefore being developed at LSU to extend these highly successful gravity stable applications to horizontal type reservoirs. The dissertation attempts to address six key questions: (i) do …

Chemical Vapor Deposition Of Thin Films For Ulsi Interconnect Metallization, Lidong Wang

LSU Doctoral Dissertations

We have studied the kinetics of copper chemical vapor deposition (CVD) for interconnect metallization using solution delivery of Cu(hfac)2 (Cu(II) hexafluoroacetyl-acetonate) dissolved in isopropanol. We observe a growth rate of 17.7 „b 1.5 nm/min at reference conditions of 300„aC substrate temperature, 0.025 Torr Cu(hfac)2 partial pressure, 1.6 Torr isopropanol (reducing agent), and 80 Torr H2 (carrier gas). The film resistivity approaches the bulk value of copper for film thickness greater than 100 nm. Reaction order experiments show first-order kinetics with respect to Cu(hfac)2 partial pressure and zero-order with respect to isopropanol. A series reaction mechanism including three kinetically significant steps …

Long Term Pressure Behavior In Turbidite Reservoirs, Feng Wang

LSU Doctoral Dissertations

In this study, we investigated several possible mechanisms that would give rise to the anomalous pressure behavior (early concave-up on Horner plot or upward drift on the derivative curve of the log-log plot and asymmetry between the pressure drawdown and buildup behavior) sometimes encountered in the turbidite reservoirs in GOM primarily using numerical simulation and 2-level experimental designs. We ascertained the most influential parameters to the pressure behavior and identified that multilayer commingled system and the leaky compartment model are the most probable mechanisms to cause the anomalous behavior due to layer or zone property contrast to a certain degree. …

Modeling The Flow Of Non-Newtonian Fluids In Packed Beds At The Pore Scale, Matthew Balhoff

LSU Doctoral Dissertations

Flow and transport in porous media are important in many science and engineering applications such as composite materials, subsurface water contamination, packed-bed reactors, and enhanced oil recovery. The general approach to modeling such processes is at the continuum scale. Semi-empirical expressions, such as Darcy's law, are substituted for velocity in the continuity equation, which is then coupled with a momentum, mass, and energy balance. While a continuum approach is acceptable in some cases, additional modeling is required for certain non-linear flows, such as multi-phase flows, inertial flows, non-Newtonian flows, and reactive flows. Pore-scale modeling is a first-principles approach to modeling …

Stability, Transport And Applications Of Polyaphrons In Porous Media, Le Yan

LSU Doctoral Dissertations

Polyaphrons are a kind of macroemulsion. The most distinctive feature of polyaphrons is their high stability. On the other hand, certain polyaphrons can be effectively destabilized by multivalent ions. In this dissertation, we devise a novel procedure that utilizes the fact that polyaphrons can be destabilized by certain ions to deliver light chemicals to lower the density of dense non-aqueous phase liquid (DNAPL) contaminants in situ. We first investigate how the stability of diluted polyaphrons is affected by the properties of the continuous phase. We find that polyaphrons can be destabilized by a low concentration of Al3+ or Ca2+ in …

Photocatalysis In A Novel Semiconducting Optical Fiber Monolithic Reactor For Wastewater Treatment, Hongfei Lin

LSU Doctoral Dissertations

The development of photocatalytic reactors is essential for the successful exploitation of heterogeneous photocatalysis on semiconductor particles, which has been shown to be an effective means of removing organic pollutants from wastewater streams. In this dissertation, a novel photocatalytic optical fiber monolith reactor (OFMR), which employed a ceramic multi-channel monolith as a support for TiO2 and quartz fibers inserted inside the monolithic channels as both a light-transmitting conductor and a support for TiO2, was developed for wastewater treatment by investigating the photocatalytic degradation of o-dichlorobenzene (DCB) and phenanthrene (PHE). This configuration provides a high surface area for catalyst coating per …

Electrodeposition Of Feconicu Quaternary System, Qiang Huang

LSU Doctoral Dissertations

Electrodeposition is a cost-effective method to produce thin film materials, which have been used widely in the microelectronic industry, and is advantageous to fabricate metal deposits into recessed and curved areas. In this dissertation, FeCoNiCu quaternary alloy system was investigated, both experimentally and theoretically, for fabrication of multilayers, grating structures, and nanowires. Multilayer structures are composed of alternating ferromagnetic and nonmagnetic nanometric layers, and are of interest due to the giant magnetoresistance (GMR) property it possesses, a change in electric resistance in the presence of an external magnetic field. In addition, the compositional modulation, or the composition contrast, in multilayer …

Chemical Production Complex Optimization, Pollution Reduction And Sustainable Development, Aimin Xu

LSU Doctoral Dissertations

The objective of this research is to propose, develop and demonstrate chemical production complex optimization to determine the optimal configuration of chemical plants in a superstructure of possible plants. The Chemical Complex Analysis System is a new methodology that has been developed to determine the best configuration of plants in a chemical production complex based on the AIChE Total Cost Assessment (TCA) for economic, energy, environmental and sustainable costs. All new, energy-efficient, and environmentally acceptable plants using greenhouse gases that can produce potentially commercial products designed with HYSYS were integrated into the chemical complex using the System. The optimum configuration …

Ceria-Zirconia Oxide High Temperature Desulfurization Sorbent, Kwang Bok Yi

LSU Doctoral Dissertations

High temperature desulfurization of highly reducing coal-derived gases using ceria and ceria-zirconia sorbents is the primary object of this dissertation research. If H2S concentration is reduced to less than 1 ppmv the product gas may be used with fuel cells and downstream catalytic process. CeO2 is reduced to a non-stoichiometric oxide, which is superior to CeO2 in removing H2S. Moreover, ZrO2 addition to CeO2 to form a solid solution, Ce1-xZrxO2, increases the reducibility of CeO2. This should also result in improved desulfurization performance. Pure CeO2 and sorbents, both commercially available and prepared at LSU, were tested. XRD analysis indicated that …

Dynamic Modeling And Parameter Estimation For An Ethlyene-Propylene-Diene Polymerization Process, Rujun Li

LSU Doctoral Dissertations

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A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo-kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The pseudo-homopolymer model is then used as the basis for application of the numerical fractionation method. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point with as few as eleven generations, and in the …

Improved Bottomhole Pressure Control For Underbalanced Drilling Operations, Carlos Perez-Tellez

LSU Doctoral Dissertations

Maintaining underbalanced conditions from the beginning to the end of the drilling process is necessary to guarantee the success of jointed-pipe underbalanced drilling (UBD) operations by avoiding formation damage and potential hazardous drilling problems such as lost circulation and differential sticking. However, maintaining these conditions is an unmet challenge that continues motivating not only research but also technological developments. This research proposes an UBD flow control procedure, which represents an economical method for maintaining continuous underbalanced conditions and, therefore, to increase well productivity by preventing formation damage. It is applicable to wells that can flow without artificial lift and within …

Bioavailability And Bioaccumulation Of Sediment-Associated, Desorption-Resistant Fraction Of Polycyclic Aromatic Hydrocarbon Contaminants, Xiaoxia Lu

LSU Doctoral Dissertations

This study is directed toward identifying and characterizing the bioavailability of both reversibly sorbed and desorption-resistant fraction of hydrophobic organic contaminants in natural biologically active sediments and the corresponding consequences to prediction, control and regulation of these contaminants. The focus is on polycyclic aromatic hydrocarbons (PAHs) with particular emphasis on phenanthrene and benzo[a]pyrene. A quantity of well-characterized and extensively desorbed sediments was prepared by desorbing the lab-inoculated sediment with an isopropanol and electrolyte solution. This procedure was proved to be a very effective method to prepare sediments containing contaminants largely limited to a desorption-resistant compartment. Accumulation of contaminants in the …

Mechanisms And Control Of Water Inflow To Wells In Gas Reservoirs With Bottom Water Drive, Miguel Armenta

LSU Doctoral Dissertations

Water inflow may cease production of gas wells, leaving a significant amount of gas in the reservoir. Conventional technologies of gas well dewatering remove water from inside the wellbore without controlling water at its source. This study addresses mechanisms of water inflow to gas wells and a new completion method to control it. In a vertical oil well, the water cone top is horizontal, but in a gas well, the gas/water interface tends to bend downwards. It could be economically possible to produce gas-water systems without water breakthrough. Non-Darcy flow effect (NDFE), vertical permeability, aquifer size, density of well perforation, …

Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda

LSU Doctoral Dissertations

Electrodeposition is an important component in the fabrication of micro electro mechanical systems (MEMS). Nickel is the most commonly used material to produce three dimensional microstructures and few material alternatives have been demonstrated. In this dissertation, electrodeposited Ni-Cu alloys and nanocomposites are investigated as possible replacements for nickel in microsystems. Ni-Cu alloys are attractive for their corrosion resistance, magnetic and thermophysical properties. Alumina nanoparticulates included into metal matrices improve hardness and tribology of deposits. The Ni-Cu alloys and Ni-Cu-g-Al2O3 nanocomposites were electrodeposited from a citrate electrolyte, both at low and high pH. Electrodeposition experiments were performed in recessed microelectrodes 500 …

Analytical Model To Control Off - Bottom Blowouts Utilizing The Concept Of Simultaneous Dynamic Seal And Bullheading, Victor Gerardo Vallejo-Arrieta

LSU Doctoral Dissertations

The current methods for off - bottom control of blowouts involve pumping kill fluid into the well through an injection string. These are the dynamic kill and the momentum kill. The dynamic kill, which is based on the steady state system analysis approach, and the momentum kill, that is loosely based on the Newton's Second Law of Motion, have been used extensively in off-bottom control of actual blowouts. A comprehensive study of these two concepts was performed. The review included an analytical analysis of the published design techniques for both of these methods. The application of these techniques to several …

The Effects Of Local Hydrodynamics On Mass Transfer In Disordered Porous Media, Gang Guo

LSU Doctoral Dissertations

Interfacial mass transfer in disordered media was studied experimentally and numerically. The dissolution of solid benzoic acid spheres in packed columns showed the existence of spatial variations in mass transfer coefficients in monodisperse and polydisperse packings at the same overall Peclet number. The concept of a local Peclet number (single-particle average) was introduced to quantify the effect of local hydrodynamics on local mass transfer. Correlations between Sherwood number and Peclet number having the form Sh_i=A·(x_iPe)^m were used to quantify data from various sites in each packing. These experiments also showed that the exponent m varies …

Numerical Study Of Water Coning Control With Downhole Water Sink (Dws) Completions In Vertical And Horizontal Wells, Solomon Ovueferaye Inikori

LSU Doctoral Dissertations

Approximately 2.5 billion dollars is spent annually to solve the problem of produced water in oil and gas wells. Downhole Water Sink (DWS) technology is one industry solution to control water coning in oil wells. DWS technology involves the segregated production of oil and water through separate completions with zonal isolation packer. However, several problems have been experienced in the application of the technology in watered-out oil wells. This study identified two factors that could aid in a better modeling of the technology in old vertical wells – inclusion of capillary transition pressures and relative permeability hysteresis. It also identified …

Analysis Of Diagnostic Testing Of Sustained Casing Pressure In Wells, Rong Xu

LSU Doctoral Dissertations

Over 8,000 wells in the Gulf of Mexico exhibit sustained casing pressure (SCP). SCP is defined as “any measurable casing pressure that rebuilds after being bled down, attributable to cause(s) other than artificially applied pressures or temperature fluctuations in the well”. The Minerals Management Service (MMS) regulations consider SCP hazardous and, in principle, require its elimination. In some cases the agency may allow continuing production at a well with SCP by granting a temporary “departure” permit. The departure permits are based on diagnostic tests involving pressure bleed-down through a 0.5-inch needle valve followed by closing the valve and recording pressure …

Mechanism Of The Nicofe Ternary Alloy Deposition, Yun Zhuang

LSU Doctoral Dissertations

Electrodeposited NiCoFe ternary alloys are of interest for their magnetic and thermophysical properties. The reaction rates and resulting composition and current efficiency are often determined empirically, due to a lack of understanding of the electrodeposition mechanism and coupled mass transport. Therefore, the effects of electrolyte concentration, bulk pH and solution agitation are studied over a wide range of applied current densities to investigate the interrelated behavior of the partial reaction rates. The Fe rate during alloy deposition is independent of Co2+ and Fe2+ bulk concentrations, but is enhanced compared with its single metal rate. Both catalytic and inhibiting effects are …

Dynamic Modeling And Analysis Of Oscillatory Bioreactors, Yongchun Zhang

LSU Doctoral Dissertations

Dynamic modeling of bioreactors is a challenging problem. The complexity of first principle models also make model validation and analysis very difficult and model-based controller design practically intractable. This thesis has focused on finding an effective tool for model dynamic analysis, construction of low-dimension model and simple and effective controller design. The validity of a biochemical reactor model often is evaluated by comparing transient responses to experimental data. Dynamic simulation can be rather inefficient and ineffective for analyzing bioreactor model. Bifurcation analysis is found to be a powerful tool for obtaining a more efficient and complete characterization of the model …

Numerical Reservoir Characterization Using Dimensionless Scale Numbers With Application In Upscaling, Djuro Novakovic

LSU Doctoral Dissertations

Dimensionless space provides a tool for analyzing the behavior of complex systems described by mathematical relationships. The limited application of dimensionless variables in numerical reservoir simulation and experimental design motivated the development of a complete set of dimensionless scaling groups. Inspectional analysis yielded 8 dimensionless groups completely describing the flow system. Further analysis of fluid interaction reduced the number of dimensionless groups to 7. The newly developed dimensionless equations and groups were used for analytical and numerical reservoir characterization, quantifying the behavior of differential and difference equations employed in fluid flow in three-dimensional porous media. The behavior of the dimensionless …

High Resolution Modeling Of Transport In Porous Media, Guangli Liu

LSU Doctoral Dissertations

This dissertation presents research on the pore-level modeling of transport in porous media. The focus of this work is on high-resolution modeling, a rigorous approach that represents detailed geometry and first-principle physics at the streamline scale. Three major topics are presented in this dissertation: an efficient approach for solving Stokes flow in essentially arbitrary disordered porous media, high-resolution versus network simulations of dispersion phenomena, and a stochastic model for solving interfacial mass transfer from source spheres in porous media. First an approach was developed for solving the Stokes flow problem in a comparatively large, very heterogeneous two-dimensional porous media with …

Experimental Evaluation Of Control Fluid Fallback During Off-Bottom Well Control In Vertical And Deviated Wells, Fernando Sebastian Flores-Avila

LSU Doctoral Dissertations

This study measured the liquid fallback during simulated blowout conditions. The purpose of the study was to establish a basis for developing a procedure for controlling blowouts that relies on the accumulation of liquid kill fluid injected while the well continues to flow. The results from experiments performed with air, water, 10.5 ppg and 12.0 ppg mud in an experimental 48 ft flow loop at 0°, 20°, 40°, 60° and 75° deviation angles from the vertical, as well as results from full-scale experiments performed with natural gas and water based drilling fluid in a vertical 2787-foot deep research well, are …

Log-Derived Cation Exchange Capacity Of Shaly Sands : Application To Hydrocarbon Detection And Drilling Optimization, Gamze Ipek

LSU Doctoral Dissertations

Researchers at Louisiana State University, LSU, have introduced several petrophysical models expressing the electric properties of shaly sands. These models, to be used for hydrocarbon detection, are based on the Waxman and Smits concept of supplementing the water conductivity with a clay counterions conductivity. The LSU models also utilize the Dual Water theory, which relates each conductivity term to a particular type of water, free and bound, each occupying a specific volume of the total pore space. The main difference between these models and the other shaly sand models is that the counterion conductivity is represented by a hypothetical sodium …

Thermal Rheological Analysis Of Cure Process Of Epoxy Prepreg, Liangfeng Sun

LSU Doctoral Dissertations

The cure process of epoxy prepreg used as composite pipe joints was studied by means of differential scanning calorimetry (DSC), Bohlin Rheometer and other techniques. Isothermal DSC measurements were conducted between 110 and 220 oC, at 10 oC intervals. The results show that the complete cure reaction could be achieved at oC. The isothermal cure process was simulated with the four-parameter autocatalytic model. Except in the late stage of cure reaction, the model agrees well with the experimental data, especially at high temperatures. To account for the effect of diffusion on the cure rate, a diffusion factor was introduced into …

Numerical Studies Of Reactive Polymer Flows In Porous Materials, Honggao Liu

LSU Doctoral Dissertations

This dissertation presents a new numerical model of reactive polymer flow in heterogeneous porous media. A moment representation of the log-normal polymer molecular weight distribution is used to model polymer as a multi-component species. Three leading moments are used to simulate the polymer transport and reaction processes in a two-dimensional porous medium. A new operator splitting technique that allows the moment equations for polymerization to be incorporated into a finite-difference transport model is developed. The novelty of this approach is the use of two different dependent variables (for the transport versus reaction parts of the problem). It is significant from …