Chemical Engineering Commons^™

Investigating And Modeling Tar-Mats In A Kuwaiti Carbonate Reservoir And Their Role In Understanding Oil Reserves And Recovery Economics, Abdullah Owidah Almansour

Doctoral Dissertations

"Tar-mat columns exist in many carbonate reservoirs in the Middle East. Historically, tar-mats have been thought to impede primary oil extraction, thus necessitating further improved oil recovery (IOR) technology applications. However, this research considers tar-mats as potential sources for unlocking extremely difficult crude oil, less than 5 ⁰API. The main objective of the study was to understand the qualitative physical and chemical properties of extremely viscous tar-mat oil and the quantitative potential of tar-mats to extract difficult oil.

The physical and chemical geneses of the tar-mat oil were analyzed utilizing several experimental geochemical techniques, including rock evaluation pyrolysis, liquid extracts …

Carbon Dioxide - Heavy Oil Systems: Thermodynamics, Transport And Interfacial Stability, Truynh Quoc My Duy Tran

Doctoral Dissertations

"Conventional oil recovery leaves behind around 67% of original oil in place for light oils and all of it for heavy oils. The carbon dioxide flooding process is the cheapest among the recovery methods for the next stage. The interest here lies in recovering heavy oil. When CO₂ dissolves in oil, it increases the volume of oil, squeezes it out of narrow capillaries and the viscosity of oil drops by up to an order of magnitude. Starting with the available data with and without CO₂ in heavy oil, the free volume theory is used to predict these physical …

Semantic Model And Updated Screening Criteria For Polymer Flooding, Laila Dao Saleh

Doctoral Dissertations

"Enhanced oil recovery (EOR) processes produce oil that conventional methods leave behind, where interfacial forces, heavy oil viscosity, and reservoir heterogeneity make it difficult to produce. Many EOR methods are available but usually cannot be used at the same time for a candidate reservoir. Therefore, it is important to select the most appropriate EOR process from among the possible techniques. EOR screening criteria have been created using EOR datasets and serve as the first step to compare the suitability of each technique for a specific reservoir. Most of these datasets are based on field data collected from EOR surveys published …

Impact Of Slickwater Fracturing Fluid Compositions On The Petrophysical Properties Of Shale And Tightsand, Yongpeng Sun

Doctoral Dissertations

"A tight reservoir always requires hydraulic fracturing before production to increase production rate. The additives in hydraulic fluids are highly considerable for a successful stimulation. A friction reducer is often used to reduce the flowing friction in the wellbore during hydraulic fracturing. Extensive researches have been conducted to examine the extent it can reduce the fluid friction in tubings; however, no research has been reported on its behavior in a reservoir, which is related to the fracture extension. A breaker is also pumped into the formation to degrade the friction reducer. However, it is not clear that what is the …

Experimental And Computational Investigation Of Flow Of Pebbles In A Pebble Bed Nuclear Reactor, Vaibhav B. Khane

Doctoral Dissertations

"The Pebble Bed Reactor (PBR) is a 4th generation nuclear reactor which is conceptually similar to moving bed reactors used in the chemical and petrochemical industries. In a PBR core, nuclear fuel in the form of pebbles moves slowly under the influence of gravity. Due to the dynamic nature of the core, a thorough understanding about slow and dense granular flow of pebbles is required from both a reactor safety and performance evaluation point of view.

In this dissertation, a new integrated experimental and computational study of granular flow in a PBR has been performed. Continuous pebble re-circulation experimental set-up, …

Preformed Particle Gel Transport Through Fractures, Hao Zhang

Doctoral Dissertations

"Polymer gel treatment is one of the most cost-effective methods to control water production in mature oil fields. The main objective of gel treatments is to reduce water or gas flow through high-permeability channels or fractures without damaging productive zones. Preformed particle gels (PPGs) have been applied for conformance control because they can overcome some potential drawbacks inherent in an in-situ gelation system.

In this study, lab experiments were performed to quantify PPG propagation through fractures and fracture-like channels by using screen models and open fracture models. The main findings in these experiments can guide the selection of best particle …

Study And Pilot Test On A Novel Eor Method - Coupling Ppg Conformance Control And Surfactant Flooding, Farag Awadh Muhammed

Doctoral Dissertations

"The interest in enhanced oil recovery (EOR) methods has re-emerged in recent years; however, significant challenges remain for the widespread deployment of these methods. One major downside to the successful application of EOR technologies in mature reservoirs is conformance problems (e.g. heterogeneity). To mitigate these problems, a novel EOR method which couple preformed particle gel (PPGs) conformance treatment with traditional surfactant flooding in one process is introduced.

This dissertation provides a comprehensive study for the proposed method. A series of laboratory tests were carried out to understand the chemical interaction between PPGs and surfactants. A new method to evaluate PPGs …

Degradable Nanocomposite Preformed Particle Gel For Chemical Enhanced Oil Recovery Applications, Paul Tongwa

Doctoral Dissertations

”This work presents two new materials that can be potentially used in conformance control to increase ultimate oil recovery from mature oilfields.

The first product is a degradable nanocomposite preformed particle gel for enhanced in-depth mobility control. Three different types of degradable nanocomposite preformed particle gels were synthesized. These three nanocomposite hydrogels were made using Laponite XLG, Calcium Montmorillonite, and Sodium Montmorillonite nanomaterials. It was observed that after degradation, Laponite XLG nanocomposite hydrogels had the highest post-degradation viscosity (4437 cp), followed by sodium nanocomposite hydrogels (129 cp), and lastly calcium nanocomposite hydrogels (75.5 cp). Thus, degradable Laponite XLG nanocomposite hydrogels …

Multiscale Modeling Of Enzyme-Catalyzed Methanol Production By Particulate Methane Monooxygenase, Katherine K. Bearden

Doctoral Dissertations

In this work, the conversion of methane to methanol by the particulate Methane Monooxygenase (pMMO) enzyme is investigated using a multi-scale modeling approach. This enzyme participates in carbon cycling and aids in the removal of harmful atmospheric methane, converting it to methanol. The interaction between pMMO and a neighboring enzyme that is present in the same organism is studied, and the unknown pMMO active site is elucidated and tested for methane oxidation towards the production of methanol.

Fundamental knowledge of pMMO's mechanism is not fully understood. Understanding how this enzyme works in nature will provide information towards designing efficient synthetic …

Multi-Scale Characterization Of Nanostructured Sodium Aluminum Hydride, Shathabish Narasegowda

Doctoral Dissertations

Complex metal hydrides are the most promising candidate materials for onboard hydrogen storage. The practicality of this class of materials is counter-poised on three critical attributes: reversible hydrogen storage capacity, high hydrogen uptake/release kinetics, and favorable hydrogen uptake/release thermodynamics. While a majority of modern metallic hydrides that are being considered are those that meet the criteria of high theoretical storage capacity, the challenges lie in addressing poor kinetics, thermodynamics, and reversibility. One emerging strategy to resolve these issues is via nanostructuring or nano-confinement of complex hydrides. By down-sizing and scaffolding them to retain their nano-dimensions, these materials are expected to …

Microfluidic Devices Applied On Enriching Post –Translational Modified Proteins For Proteomics, Hui Xia

Doctoral Dissertations

In this work, microfluidic devices were developed for enriching post-translational modified proteins. Post-translational modifications (PTM) of proteins play essential roles in cellular physiology and disease. The identification of protein substrates and detection of modification site helps understand PTM-mediated regulation in essential biological pathways and functions in various diseases. However, PTM proteins are typically present only at trace levels, making them difficult to identify in mass spectrometry based proteomics. This work study is about the design, fabrication and testing of the microfluidic device for the enrichment of abundant amount of PTMs. Carbonylated protein is used as a representative PTM to illustrate …

Coupled Geomechanical Reservoir Simulation, Amin Amirlatifi

Doctoral Dissertations

"Founded by Department Of Energy, the Plains CO₂ Reduction (PCOR) Partnership is investigating the Williston Basin as a candidate for sequestering CO₂ emissions from power plants. The State of Missouri, a member of PCOR, lies at the outermost point on the proposed transportation route and consequently faces the highest CO₂ compression and transportation costs. In order to minimize the cost of CO₂ sequestration, it is desirable to find a storage site within the state. The Lamotte sandstone is identified as a suitable sequestration aquifer formation in Missouri with acceptable permeability, porosity, extension, rock strength and water salinity. Using the finite …

Gas Dynamics And Heat Transfer In A Packed Pebble-Bed Reactor For The 4th Generation Nuclear Energy, Rahman Abdulmohsin

Doctoral Dissertations

"Proper analyses of axial dispersion and mixing of the coolant gas flow and heat transport phenomena in the dynamic core of nuclear pebble-bed reactors pose extreme challenges to the safe design and efficient operation of these packed pebble-bed reactors.

The main objectives of the present work are advancing the knowledge of the coolant gas dispersion and extent of mixing and the convective heat transfer coefficients in the studied packed pebble-beds. The study also provides the needed benchmark data for modeling and simulation validation. Hence, a separate effect pilot-plant scale and cold-flow experimental setup was designed, developed and used to carry …

Behavior And Effects Of Nanoparticles In Complex Fluid Systems, Chen Wang

Doctoral Dissertations

"The development of nanoscale technologies has greatly expanded the scientific and engineering horizons and also has the potential to turn molecular discoveries into worldwide benefits on multiple fronts. Despite recent extensive efforts, the focus of nanoparticle studies has been on their synthesis and various possible derivatives. In this dissertation, molecular based modeling and simulation studies have been performed to characterize and understand the behavior, properties, and effects of nanoparticles in some important material systems. The results show that small nanoparticles that are highly faceted have significant shape effects, which are not captured by classical continuum-based approaches. When dissolved in confined …

Effect Of Dense Heat Exchanging Internals On The Hydrodynamics Of Bubble Column Reactors Using Non-Invasive Measurement Techniques, Mohammed Khloofh Al Mesfer

Doctoral Dissertations

"Given their efficiency and capital cost reduction, bubble/slurry bubble column reactors are the reactors of choice for Fischer-Tropsch (FT) synthesis, offering clean alternative fuels and chemicals. FT synthesis is an exothermic process that requires many heat exchanging tubes in order to remove heat efficiently and maintain the desired temperature and isothermal operating condition. The impact of the heat exchanging tubes (internals) on the hydrodynamics is not fully understood. Reliably designing and scaling up bubble column reactors requires proper understanding of hydrodynamics, as well as heat and mass transfer parameters.

The main objective of this work is to advance the understanding …

Modeling And Analysis Of Dynamic Behavior Of Adsorption Stratified Column Beds Packed With Partially Fractal Porous Adsorbent Particles, Min Li

Doctoral Dissertations

"In this work novel porous adsorbent media having partially fractal structures and stratified packed-beds are constructed and their dynamic performance with respect to their adsorptive capacity through the construction and solution of rigorous models is studied. The results show that conventional columns packed with partially fractal porous adsorbent particles provide larger breakthrough times and dynamic utilization of the adsorptive capacity of the column when compared with those of conventional columns employing conventional adsorbent particles which do not possess a partially fractal structure. Furthermore, stratified column beds exhibit superior species separation performance than conventional columns when they are packed with either …

Minimizing Formation Damage For Preformed Particle Gels Treatment In Mature Reservoirs, Mahmoud Omran Elsharafi

Doctoral Dissertations

"This research studied the effect of preformed particle gels (PPGs) on unswept, low-permeable zones/areas. The objective was to find methods that minimized the damage caused by PPGs on unswept, low-permeable zones/areas, thus improving PPG treatment efficiency. These results can help to identify of the best PPG types, particle sizes, and brine concentrations for specific reservoirs and treatments. This study used sandstone core samples with various degrees of permeability. Two types of particle gels, a strong Daqing gel (DQ) and a weak Liquiblock™ 40k gel (40K), were used, each with a different strength.

This research included two stages. Firstly, both a …

Heat Transfer And Bubble Dynamics In Bubble And Slurry Bubble Columns With Internals For Fischer-Tropsch Synthesis Of Clean Alternative Fuels And Chemicals, Moses Odongo O. Kagumba

Doctoral Dissertations

"Synthesis gas, a mixture of CO and H₂ obtained from coal, natural gas and biomass are increasingly becoming reliable sources of clean synthetic fuels and chemicals and via Fischer-Tropsch (F-T) synthesis process. Slurry bubble column reactor is the reactor of choice for the commercialization of the F-T synthesis. Even though the slurry bubble column reactors and contactors are simple in structures, their design, scale-up, operation, and performance prediction are still challenging and not well understood due to complex interaction of phases. All the studies of heat transfer have been performed without simultaneously investigating the bubble dynamics adjacent to the heat …

Scaleup And Hydrodynamics Study Of Gas-Solid Spouted Beds, Shreekanta Basavaraj Aradhya

Doctoral Dissertations

"A thorough understanding of the complex flow structure of gas-solid spouted bed is crucial for design, scale-up and performance. Advanced gas-solid optical probes were developed and used to evaluate different hydrodynamic parameters of spouted beds. These optical probes measure solids concentration, velocity and their time series fluctuations. Since solids concentration needs to be converted to solids holdup through calibration, for meaningful interpretation of results, a novel calibration method was proposed (which is inexpensive and reliable compared to the current reported methods) and validated in the present study. The reported dimensionless groups approach of spouted bed scale-up was assessed and was …

Establishing Well Operability Limits For Frac Pack Sandface Well Completions Using A Screen Erosion Model And Well Completion Score Card, Rickey Hendrix

Doctoral Dissertations

"Completion quality has a direct impact upon the maximum production rate at which a frac pack well should be operated. Best practices for frac pack well completions ensure the highest possible quality for the well completion. A novel frac pack well completion score card was developed based on best practices for frac pack well completions identified through consultation with industry experts. The score card systematically combines and assesses completions data readily available standard completion reports. The outcome of the score card process is a numerical completion quality rating, which combines all well design and frac pack operations information.

The completion …

Nanoscale Metal Oxide And Supported Metal Catalysts For Li-Air Battery, Kan Huang

Doctoral Dissertations

"The dissertation work focuses on research and development of durable nanoscale catalysts and supports for rechargeable Li-air batteries that use aqueous catholytes. Transition metal oxides, TiO₂ and Nb₂O₅ in particular, were prepared from a sol-gel process in the form of nanocoatings (5~50 nm) on carbon nanotubes (CNTs) and studied as catalyst supports. Carbon doping in the oxides and post annealing significantly increased their electronic conductivity. Pt catalyst on the support with TiO₂ (Pt/c-TiO₂/CNTs) showed a much better oxygen reduction reaction (ORR) activity than a commercial Pt on carbon black (Pt/C). Negligible loss ( …

Investigation Of Wellbore Stability In A North Sea Field Development, Steven Austin Hilgedick

Doctoral Dissertations

"Planning drilling operations is key to the development of oil and natural gas fields. As part of well design, wellbore stability and pore pressure analysis are main factors in determining the safe operating window for selecting mud density. The motivation for this research was to conduct wellbore stability based on exploration wells as basis for planning new offshore field developments with deviated and horizontal wells. A second objective was to investigate the use of a probabilistic approach to wellbore stability, and compare it to the conventional deterministic methods, in order to evaluate the value of including a probabilistic approach to …

Meso-Scale Fluidic Devices With Chemical Sensors For Biological Applications, Satya Gowthami Achanta

Doctoral Dissertations

"Molecular oxygen and humidity are some of the major environmental quantities being measured for various industrial and commercial applications. This dissertation focuses on the design, fabrication and characterization of optofluidic biosensor systems for oxygen and humidity quantification using color charge-coupled device (CCD) camera as a photodetector and LED panel as an excitation source. Meso-scale fluidic devices with integrated oxygen and humidity sensors for potential applications to hydrotropic and oxytropic studies of small plant roots have been investigated in this study. Meso-scale sensor platform was fabricated using porphyrine complex as the sensitive dye embedded within Ethyl Cellulose (EC) polymer matrix. Green …

A Methodology For Statistical Propped Fracture Treatment Design In Fluvial Environments, Prue Elizabeth Smith

Doctoral Dissertations

"Treatment design for hydraulic fracturing historically has been deterministic in nature. In a deterministic design, required variables can be determined and are assumed to be laterally continuous. This is difficult for geologic settings in general, but nearly impossible in fluvial geologic environments where the second assumption is violated.

Recent work has employed statistical methods to account for the complexity and heterogeneity in fluvial environments. Statistical design tools have been used to assist with improving the design process in complex fluvial geologic systems. Currently, the statistical design tools must be created using a "trial and error" process, which requires first completing/fracturing …

Global Homotopy Continuation And Stability Analysis: Optimal Application To Chemical Engineering Design, David Anthony Harney

Doctoral Dissertations

"The design of chemical engineering process equipment routinely necessitates the solution of large systems of non-linear equations. The processing speed of standard desktop computers have allowed for equation-oriented process simulators to become commercially viable. For a fully equation-oriented simulator to be competitive with standard iterative solvers, a robust and reliable non-linear equation solver is required and standard Newton methods fail to provide the necessary reliability.

Homotopy continuation methods have been proposed as a way to greatly expand the domain of convergence of the process simulator's equation solving algorithm. This research expands upon existing homotopy continuation algorithms, investigates bounding algorithms, corrector …

Modeling Carbon Sequestration In Transition Zone To Optimize Storage Potential, Fang Yang

Doctoral Dissertations

"Shallow aquifers are potential candidates for carbon sequestration because of their wide distribution and low injection cost. Injected CO₂ in a shallow region segregates into two zones according to CO₂ phases within the initial reservoir pressure and the maximum bottom hole pressure: gas zone and transition zone. Transition zone is a better option because of favorable CO₂ properties. This work investigated the CO₂ storage potential in transition zone using the compositional simulator CMG-GEM and a design of experiment software iSIGHT. First, it addressed the basic characteristics of CO₂ sequestration in transition zone, and then modeled CO₂ injection with simultaneous water …

Glycerin Reformation In High Temperature And Pressure Water, Jason W. Picou

Doctoral Dissertations

"The noncatalytic reformation of glycerin in supercritical water was studied in a Haynes 282 tubular reactor. In order to determine which parameters were the most influential, a 2³ experimental matrix was conducted, with temperatures of 500 and 700⁰C, water/glycerin molar ratios of 3:1 and 13:1, and residence times of 30 and 90 seconds, all at a pressure of 24 MPa. It was found that temperature had the largest effect on the two gasification parameters deemed most important, gasification percentage and hydrogen yield. Based on this, the effect of temperature was further investigated by looking at 5⁰C intervals from 500 to …

Organoclay Dispersion In Linear Low-Density Polyethylene And Maleated Linear Low-Density Polyethylene Via Supercritical Carbon Dioxide Processing, Matthew J. Factor

Doctoral Dissertations

"Research into polymer-clay nanocomposites (PCN's) has been ongoing for decades as a result of the property enhancements offered by clay. To fully exploit these property enhancements, organically modified clays (organoclays) are utilized to promote clay delamination by reducing the disparity between the hydrophilicity of the clay and the hydrophobicity of the highly used polyolefin polymer. Since the organic modification of organoclays can degrade at temperatures typical to many polymers during melt-mix processing, this work utilizes the low-temperature processing fluid supercritical carbon dioxide (scCO₂) to disperse an organoclay into the highly used polymer LLDPE and ascertains the associated processing conditions for …

Updated Eor Screening Criteria And Modeling The Impacts Of Water Salinity Changes On Oil Recovery, Ahmad Aladasani

Doctoral Dissertations

"Developing technologies for enhanced oil recovery (EOR) from existing oil fields would supply the world's energy needs for several decades. The application of EOR in many major oil-producing countries remains in its conceptual stage. Thermal and gas EOR methods achieve high incremental rates; however, their application range has not broadened significantly as they have matured, while the rate at which new, promising EOR methods such as Low-salinity water flooding (LSWF) are being implemented is alarming. Despite, the potential of LSWF its development and application has been hindered by the lack of consensus concerning its recovery mechanism(s). Every oil reservoir has …

Free-Radical Maleation Of Poly(Butylene Adipate-Co-Terephthalate) In Supercritical Carbon Dioxide And Its Effect On The Percolation And Deformation Mechanism Of Layered Silicate Nanocomposites, Alexandria Niemoeller

Doctoral Dissertations

The utilization of compostable polymers such as poly(butylene adipate-co-terephthalate) (PBAT) in single-use packaging applications can mitigate the water, solvents, and energy required for processing plastic waste. PBAT exhibits exceptional elongational properties, but its moderate water vapor permeability and low tensile modulus limit the applications in which PBAT can be employed. In this work, PBAT nanocomposites were produced at various loadings of organically-modified montmorillonite. The secondary structure of nanoparticles formed within the PBAT matrix was evident in the terminal region of the linear viscoelastic response under oscillatory shear, and a percolation threshold was determined to occur at 3.88% clay by weight. …