Chemical Engineering Commons^™

Security Printing: Towards Hologram Printing, Sachin Ravindra Agate

Masters Theses

Today we are facing many situations where the genuineness of the products and documents is questioned. Counterfeiting the original products has become a business of few people, which result in the degradation of quality of products, loss of money and loss of faith of end user. To prevent such malicious act, security features are added in the final product. Security printing is one of those methods that help in preventing counterfeit products and treachery. There are many different security features, which can be added in the security printing. Apart from those features, an embossed hologram is also included in prints …

The Effect Of Wet End Operations On Sizing Loss In Alkaline Papers, Suresh B. Cherukuri

Masters Theses

Changes in wet end of alkaline papermaking affect the size development as well as sizing loss. These changes include pH, alkalinity and type of filler used. Precipitated and ground varieties of carbonate fillers and the alkalinity associated with · them are believed to be the causes for the gradual sizing loss in alkaline papers due the accelerated hydrolysis reaction of sizing chemicals at higher alkalinity.

Precipitated and ground calcium carbonate fillers are used as fillers and compared to non carbonate filler such as kaolin clay for their response to size development and sizing loss at lower and higher alkalinity ranges …

A Study Of Effects Of Flotation Conditions On Flotation Efficiency And Fiber Loss, Wiwat Walaipachara

Masters Theses

Three variables: (1) consistency, (2) agitation, and (3) bubble size were studied for their effects on flotation efficiency and fiber loss. Flotation was done by using a Hallimond apparatus. The floated and non-floated portions were quantified by image analysis based on number of ink particles and total area of ink. The percent fiber loss was calculated from solids' weights of both portions. The floated part was analyzed by a KAJAANI instrument for fiber length average and distribution.

The results showed that flotation efficiency increased with agitation but decreased with increasing consistency. Fiber loss increased with consistency but decreased with increasing …

A Study Of The Effects Of Polyacrylates On Water Retention And Binder Migration Tendencies Of Coatings, Wichan Charoenkitsupat

Masters Theses

Five commercial polyacrylate samples were used to study their effects on viscosity, water holding, and binder migration under non-pressure conditions. The polyacrylates used were different in acid level, degree of crosslinking, and type of polymer (copolymer and terpolymer). A series of coatings was prepared using a number two clay and three styrene-butadiene latexes of similar particle size and T⋁g but different degrees of carboxylation, then the polyacrylates were added at several levels. The coatings were evaluated for rheological properties, water loss rate and binder migration. The results show that with increasing amounts of polyacrylates, the viscosity increased and the water …

A Computer Simulation Of The Rotary Vacuum Filter Brown Stock Washing System Using Distribution Sampling, Edison G. Yiu

Masters Theses

A probabilistic model was utilized to simulate the brown stock washing system's error due to process variability and measurement noise. Mass balances of the washing system were performed using distribution sampling. This model relies on a nonlinear relationship between displacement and dilution, which permitted the generation of displacement ratio based upon wash liquor ratio. Experimental trials were performed on a pilotscale rotary vacuum single-stage washer. Nonlinear first-order relationship appears to characterize a pilotscale washer adequately. Differences were observed between the means and standard deviations of the measured results compared to the simulation output. Future work is needed to identify the …

A Study Of The Effects Of Pigment Size And Shape On Binder Migration, Hee Jong Yang

Masters Theses

The effects of pigment size and shape on coating structure and binder migration has been investigated. Clays and ground calcium carbonates of different particle size distributions were used in coatings with 15 pph SB latex.

Coatings were applied to Mylar and a special Tyvek using a wire wound rod. The coatings were dried slowly under ambient conditions, and using hot air immediately or after having been allowed to reach immobilization through penetration into the Tyvek. The dried coatings were evaluated for water holding, relative pore size and migration using the UV technique to measure the increase in SB latex at …

Prediction Of Paper Color: A Process Simulation Approach, Mayank Chaturvedi

Masters Theses

A simulation model was developed for a dye mixing process and for the prediction of the optical properties of the paper. The model was integrated with the MAPPS (Modular Analysis of Pulp and Paper Systems) simulation software package. The model was validated using dyed handsheets made in a laboratory and dyed paper made on a pilot papermachine. Validation comprised of prediction of the optical properties of the handsheets and the machine-made paper which contained various combinations of three non-fluorescent dyes. Sheet reflectances were predicted at 20 nanometer intervals for discrete light wavelength range of 400 to 700 nanometers and verified …

A Study Of The Effect Of Water-Soluble Polymers On Water Holding And Binder Migration Tendencies Of Coatings, Joginder S. Malik

Masters Theses

Water-soluble polymers are being used in the paper coating industry for a variety of purposes including the development of water holding, viscosity control, structure and binder migration control. This study was designed to evaluate the degree that selected types of water-soluble polymers (carboxymethylcellulose, hydroxyethylcellulose, sodium alginate, polyvinyl alcohol and a polyacrylate) influence these properties. The methodology comprised of recently developed techniques in which water holding, immobilization solids and binder migration could all be measured for similar coatings applied on a paper-like porous substrate. The results illustrated that watersoluble polymers affect both the water-loss rate and binder migration, but reduce the …

Structural, Depositional, And Diagenetic Controls On Reservoir Development: St. Peter Sandstone, Newaygo County, Michigan, Mark S. Caldwell

Masters Theses

Enhanced reservoir quality in the Middle Ordovician St. Peter Sandstone is observed in gas bearing zones in wells located on domal structures. Geometry and degree of this enhanced porosity development is the result of the interplay of structural, depositional, and diagenetic controls. An integrated subsurface study of the Woodville/Goodwell field area was performed in order to document controls on hydrocarbon accumulation.

Recurrent structural growth of domal features throughout the Paleozoic is well documented by isopach mapping. Burial and thermal history studies indicate that hydrocarbons were generated in Ordovician aged source rocks during late Devonian to early Mississippian time, and accumulated …

Reactivities Of Some Aromatic Compounds At Supercritical Water Conditions, Chun-Cheng Tsao

Masters Theses

The goals of this study are the removal of nitrogen from the extraction products of coal by Supercritical Water and the development of an understanding of the reactions leading to this removal. Six model compounds with structures similar to the intermediates of the coal liquefaction processes were studied. Benzylamine generated toluene through hydrogen abstraction after the C-N bond rupture. To a lesser extent, the oxidation of the benzylic carbon took place leading to benzene formation. Both reaction pathways occurred with equal probability for benzylidenebenzylamine, producing comparable yields of benzene and toluene. Benzaldehyde generated benzene through the oxidation/decarboxylation sequence. Benzyl alcohol …

Sedimentology Of The Bedford-Berea Sequence (Early Mississippian), Williams Field, Michigan, David Alan Balthazor

Masters Theses

The Berea Sandstone has produced in excess of 1.6 million barrels of oil in the Williams field since discovery in 1980. Seven lithofacies are identified from conventional core in the Bedford-Berea sequence. These facies are interpreted as deltaic deposits comprising prodelta (Bedford Shale), delta front, destructive marine shale, abandoned distributary channel-fill, interdistributary bay-fill, transgressive marine sandstone, and marine shale (Sunbury Shale) facies. Passive channel-fill facies truncate reservoir sandstone bodies and compartmentalize the field NW-SE across the trend of the northwestplunging anticline.

The two reservoir facies in the Williams field are the delta front and transgressive marine sandstones. The sandstone framework …

Effect Of Refining On The Brightness Of Softwood Ctmp And Tmp Pulps, Ashok Kumar Mishra

Masters Theses

The main objective of this study was to investigate the effect of refining on the brightness of softwood chemithermomechanical (CTMP) and thermomechanical (TMP) pulps. Seven different pulps were refined using a laboratory Valley beater. Brightness, opacity, tensile index, TEA, and fines content of these pulps were determined at four different freeness levels. Scattering (s) and absorption (k) coefficients of these pulps were calculated. One-way analyses of variance (ANOVA) were applied to determine the significance of change in brightness.

Changes in s-values were significantly affected by fiber morphology of different wood species. Refining increased the k-values of the pulps. When the …

Quantification Of Refining Actions, Hari R. Goyal

Masters Theses

The repeated action of compression-decompression pulses on a wet web of fiber, created by dropping a weight from a height, loosens the internal structure of the fiber. The impaction of fiber did not cause any change in average weighted fiber length, fine content or Canadian Standard Freeness. The sheet made from these fibers showed an increase in tensile strength with increased number of impacts or impact intensity.

In a blend of impacted fibers (internally fibrillated), abraded fibers (externally fibrillated) and fines (fibers shorter than 0.23 mm and created by prolonged beating in a Valley beater), fines were found to be …

Energy Considerations In Stock Preparation Refining Modified By Recycling, Rajendra D. Deshpande

Masters Theses

Experiments were conducted to study the effect of refining on virgin fibers as well as on recycled fibers. Interaction effects of recycling and type of treatment of virgin fibers on characteristics of secondary fiber were studied. A significant reduction in drainage properties of the furnish for both hardwood and softwood pulps were observed. This reduction in properties was found proportional to the amount of refining. It is necessary to achieve required strength properties at higher freeness values, if fibers are to be recycled. This can be done by improvement in uniformity or homogeneity of refining and by gentler and less …

A Laboratory Simulation Of A Rotary Vacuum Drum Brownstock Washer, Hugh E. Muller

Masters Theses

Mass balances can quantify the dilution and thickening of a liquor/fiber suspension on a brownstock washer. However, the complex displacement process necessitates an empirical approach. Given empirical data, washers can be optimized through use of efficiency factors with mass balances.

Because empirical data is difficult to obtain, a laboratory washing method was developed to empirically generate displacement efficiencies on pulp under mill washer conditions. Reproducible data generated by this method resulted in a displacement/dilution function as seen on mill washers. A laboratory simulation using mill samples, exclusive of problems for one vacuum drum, resulted in comparable efficiencies with less than …

A Computer Simulation Of The Rotary Drum Brownstock Washer System Using The Monte Carlo Method Of Distribution Sampling, Jacqueline K. Pease

Masters Theses

A steady-state probabilistic model is chosen to simulate the brownstock washing system's uncertainty which arises from unpredictable process fluctuations and measurement noise. Distribution sampling is used to construct multiple mass balances of a washing system. Included in this model is a linear relationship describing the correlation between dilution and displacement which allows displacement ratio to be generated based on dilution factor. This is an improvement over a similar, earlier model which considers all variables to be independent. There is no statistical difference between the mean output of the simulation and the means of data sets collected at two different mills. …

Shear Induced Anisotropy In The Rheology Of Solids Dispersions, Nicholas G. Triantafillopoulos

Masters Theses

Under strong hydrodynamic forces, solids dispersions could no longer be considered isotropic fluid s but rather two-phase systems. The continuous (dispersing) phase was only sheared in side an effective gap determined in a Couette flow device by the presence of solid (dispersed) phase in to suspension. Three parameters, the effective gap, percent gap reduction and the relative shear volume, were incorporated to account for the influence of solids in the rheology of their suspension.

The objectives of this study were: (1) to investigate the role of solids volumetric concentration, particle size, nominal gap and continuous phase viscosity on Hercules Hi-Shear …

A Study Of The Models Describing Fines And Filler Retention By Utilizing Cationic Starch As The Retention Aid, Nen-Sen Chen

Masters Theses

Fines and filler retention under dynamic conditions was studied in this thesis work. Zeta potential of samples are also measured. Dynamic Retention/Drainage Jar and Lazer-Zee Meter were used to accomplish this work. The results have been analyzed by statistical methods. When cationic starch was utilized as a retention aid the pH affected its efficiency, probably because the charge of cationic starch was dependent on pH. This effect was detected by utilizing two-way analysis of variance to find the sources of its interactions with molecular weight and agitation rate. The mechanism was thus determined. At pH 3 and 4, charge neutralization …

The Evaluation Of Corrosion Inhibitors For Controlling Corrosion In Closed Paper Mill White Water Systems, Ifeanyi E. C. Okeke

Masters Theses

No abstract provided.

An Application Of Infrared Spectroscopy To The Study Of Binder Migration In Paper Coatings, Fred E. Huang

Masters Theses

Multiple internal reflectance (MIR) was used to study binder migration of paper coatings. Casein and an acrylic latex were selected as binders because of their characteristic infrared absorption bands. The coatings analyzed were prepared on the Western Michigan University Pilot Coater using the airknife coating method at different coating speeds. A surface grinder was used to obtain several layers of coating for surface studies.

It was concluded that the MIR technique could satisfactorily be used in the binder migration studies. Its success mainly depends on the precision of surface grinding, caliper measurement and infrared characteristics of the binders. The results …

Theoretical Thermodynamic Functions For Argon, Peter Yi-Ren Sheh

Masters Theses

No abstract provided.

Sodium-Initiated Polymerization Of Alpha-Methylstyrene In The Vicinity Of Its Reported Ceiling Temperature, Shuenn-Long Ou

Dissertations

No abstract provided.

Inhibitors And Retarders For The Free Radical Polymerization Of Alpha-Methylstyrene, Alexander Accetta

Masters Theses

No abstract provided.

A Quantitative Analysis By Emission Spectroscopy Of The Metallic Constituents Of Biological Samples After Treatment By A Carcinogenic Agent, Charles R. Frydrych

Masters Theses

No abstract provided.

The Influence Of Ionic Polarizability On The High Temperature Mechanical Properties Of Ionic Crystals, William A. Johnston

Masters Theses

No abstract provided.