Chemical Engineering Commons^™

Development And Characteristics Of Carbon Nitride Thin Solid Films For Advanced Coating Applications, Muhammad A. Hussain

Theses

Carbon nitride films were synthesized on silicon substrate by reactive magnetron sputtering of graphite target in an environment of Ar and nitrogen gas. The performance of a negative carbon ion source was also investigated to use the source in negative ion-beam-assisted deposition. These films were synthesized at room temperature at a constant pressure of 5 mtorr and at 300 Watts R.17 power, but at different composition of nitrogen in Ar-N₂ gas mixture ranging from 0-53 percent. The films deposited were microscopically smooth, amorphous and their properties found to be varied with nitrogen composition in plasma. The deposition rate was …

Voc Removal From Nitrogen By A Membrane-Based Combined Absorption-Stripping Process, Boya Xia

Theses

A regenerative membrane-based absorption process has been extensively studied to remove volatile organic compounds (VOCs) from air/N₂ using silicone oil as absorbent. The absorbent liquid is regenerated by applying vacuum in a membrane-based stripper. In this process, there are no flooding, loading and entrainment, which limit the gas/liquid flow rate in the traditional absorption process. In the present study, attention has been focused on the removal of volatile component(s) from binary gas mixtures such as methanol-N₂, and toluene-N₂, and from a model multicomponent mixture of gasoline vapor constituents and nitrogen. The process performance was tested …

Recovery Of Intracellular Materials By Electroporation, Wendy Elaine Reid

Theses

Electroporation is commonly used to transfer genetic materials such as DNA into the cell by exposing the cell to a high electric field that momentarily permeabilizes the cell membrane. This premise was utilized to use electroporation as a means of releasing intracellular proteins. A procedure has been developed for the release of intracellular proteins through the use of electroporation. This procedure is a breakthrough. In general, industrial scale techniques to recover proteins from microorganisms are inefficient (Clarkson, 1993). A benefit of this electroporation-based mechanism would be the reduction of steps in the downstream processing required to purify the desired product. …

Mixed Metal Removal And Recovery By Hollow Fiber Membrane-Based Extractive Adsorber, Ramprakash Chilukuri

Theses

The feasibility and efficiency of simultaneous removal of multiple cations as well as anionic heavy metals from wastewater into a mixed extractant kept stagnant on the shell side of a 2-fiber-set hollow fiber membrane extractor operated as a fixed bed adsorber was explored. The novel extracting solvent was a mixture of an acidic or chelating extracting agent for one or more cations and a basic extracting agent, e.g., trioctylamine (TOA) for extracting anions; both were dissolved in the same diluent kerosene for simultaneous and synergistic extraction of cations and anions. In the stripping part of the fixed bed operation, alkaline …

Development Of Aqueous Scrubber To Oxidize And Absorb Nitric Oxide, Wanna Lolertpiphop

Theses

The use of sodium chlorite (NaClO₂) and alkaline aqueous cumene hydroperoxide (CHP) as oxidizing agents to promote the absorption of nitric oxide from flue gases was investigated in a semicontinuous bubbling scrubber. The efficiency of the scrubbing solutions to remove nitric oxide was evaluated as a function of operating conditions such as pH, concentration of the oxidants, residence time, temperature, flue gas compositions.

Under acid conditions, sodium chlorite can stoichiometrically react and absorb 99.5% NO and 80% SO₂ in the same scrubber with 0,672 M NaClO₂ in buffered solution at pH 6, and 0.3 M NaOH. …

Pervaporation-Assisted Esterification Of Salicylic Acid, Chaiya Chandavasu

Theses

The coupling of a pervaporation membrane unit with a reactor has been investigated as a means of improving the overall process efficiency. As model system, the esterification of salicylic acid with methanol in the presence of a homogeneous catalyst was studied in a unit consisting of a batch reactor externally coupled with a pervaporation module containing a composite poly(vinyl alcohol) membrane. The reaction was carried out at temperatures between 336 and 345 K. The catalyst was sulfuric acid at concentrations varying from 0.5 to 2.0 molar. Various initial molar ratios (Θ_B) of methanol and salicylic acid, ranging from …

Biodegradation Of Naphthalene Using Pseudomonas Putida (Atcc 17484) In Batch And Chemostat Reactors, Jay Boyd Best

Theses

Kinetic experiments were conducted using Pseudomonas putida (ATCC 17484) to determine the rate of growth when naphthalene was provided as a sole carbon source in suspended biomass systems. Batch and chemostat reactors were used under three sets of conditions: non-aerated, aerated at 29.5° C, and aerated at 25.5° C. A number of concentrations were tested under each set of conditions. Data regression was used to determine parameters for Monod (non-inhibitory), Andrews (inhibitory), and zero-order kinetics. Although the Andrews fit of the data provided a slightly lower sum-of-squares error (SSE), the amount of data scatter and the weak inhibition made the …

Soot Capture In An Electrocatalytic Reactor, Thana Slanvetpan

Theses

A major problem with many soot emission control devices is the fact that they quickly become loaded with soot which must be removed by a regeneration process. A soot capture reactor using a large flow channel was studied in order to eliminate channel plugging and avoid regeneration. Electrostatic precipitation was used in order to enhance particle diffusion to the catalyst wall of the reactor tube. The system effectiveness for soot capture was measured with filter paper sampling of the incoming versus the outgoing flow through the reactor. Soot filter loadings were analyzed by laser optical transmission. From the soot filter …

Membrane-Based Reactors For Ozonolysis Of Organic Pollutants In Aqueous And Gaseous Streams, Purushottam V. Shanbhag

Dissertations

Many gaseous and aqueous waste streams contain multiple organic pollutants at low concentration levels. It is not economical to recover and reuse these compounds; it would be advantageous to destroy them efficiently within the waste stream. This work employed ozone, a powerful oxidizing agent, in concert with a compact membrane-based phase-contacting device. Three types of membrane devices were studied: two of them (the single-phase membrane ozonator and the two-phase membrane ozonator) treated organic pollutants in wastewater, while the third (the integrated absorption-oxidation membrane ozonator) removed volatile organic compounds (VOCs) from a gaseous waste stream.

In the single-phase membrane ozonator, the …

Growth Of Grass Shrimp, Palaemonetes Pugio, In A Contaminated And An Uncontaminated Site, Suruchi Bhan

Theses

Previous experiments have found that grass shrimp, Palaemonetes pugio, from a contaminated site, Piles Creek (PC). in Linden. New Jersey, are larger than those from a relatively pristine reference site, Sheepshead Creek, located in Tuckerton (T), New Jersey.

This study investigated the possibility that PC conditions provide more food for the shrimp, possibly by being a eutrophic environment. thus allowing for greater growth. or that salinity, toxicants, or other factors at. PC stimulate growth. The current experiment indicated that PC conditions do not foster greater growth for the shrimp than T conditions and that PC shrimp are not inherently …

An Investigation Into The Feasibility Of Utilizing Pneumatic Ultrasonic Devices Coupled With Pneumatic Fracturing In Enhancing Removal Of Volatile Organic Compounds From Soils, Hugo J. Fernandez

Theses

A bench scale investigation was conducted in a Plexiglass ™ Test cell 1 foot square by 2 feet in height, packed with 400 mesh sand to a density of 100 lb. /ft³. The sand was contaminated with a mixture of 10% ethanol and 90% water by weight having a total weight of 11.1 pounds, before it was packed in the test cell. A geotextile 1/2 inch thick was used as a simulated fracture and was placed 3 inches from the bottom of the tank. A siren and a whistle were tested in this fracture.

The data were divided …

Low Pressure Chemical Vapor Deposition Of Silicon Carbonitride Films From Tri(Dimethylamino) Silane, Rajive Shah

Theses

A literature study to investigate the incorporation of silicon into SiC and Si₃N₄ films from various organosilanes was carried out. The Arrhenius activation energy for the synthesis of silicon, silicon carbide and silicon nitride films from various organosilanes range from 165-210 kJ/mol. A review of recent studies have indicated that silicon deposition is the rate determining step in the synthesis of silicon from silane. It is proposed here that this hypothesis can be established for the synthesis of silicon carbide, silicon nitride and silicon carbonitride film. Limited experiments indicated that the silicon deposition is a rate determining …

Decontamination Of Aquifers Via Air Sparging/Biofiltration : An Experimental Study, Armando Mora Tellez

Theses

In this study experiments were performed in order to show feasibility of an integrated air sparging/biofiltration process for cleaning contaminated groundwater. Feasibility was also meant in the sense of meeting regulatory constraints. Using toluene as model compound and changing flowrates for the sparged air, it was shown that despite fluctuations in the toluene concentration at the inlet of the biofilter, the concentrations at the outlet of the unit were essentially constant over long periods of time and remained below the levels dictated by environmental regulations. However an increase in outlet concentrations at levels not meeting regulatory constraints was observed after …

Optimization Of Ion-Exchange Chromotography With Multiple Gradient Inputs For Protein Separations, Tariq Mahmood

Theses

Gradient elution chromatography is an efficient technique for adjusting the retention of sample components during liquid chromatographic separations. However, the optimization of gradient elution is usually done by trial and error. Thus, for large scale processes this results in expensive and time consuming design and operations. Peak resolution that describes the degree of separation is a commonly used parameter for chromatographic processes. However, in processes where operating time and product dilution are of great importance, resolution alone is not adequate for describing the separation efficiency.

A new parameter "resolution optimization factor" is used for the optimization of gradient elution processes. …

A Student Training Manual For Running The Hysim Computer Simulation Program, Roberta Rosty

Theses

Hyprotech's HYSIM computer simulation program is used in the chemical processing industry (CPI) to simulate unit operations, which aid in the design of various different kinds of processing plants. It is important then that chemical engineering students should gain early exposure to a simulation program such as HYSIM, in order to facilitate their comprehension of process engineering design work using this type of program, and to bridge the gap between the textbook knowledge they gain of unit operations in the classroom with some of the actual process engineering work-a-day methods available for solving problems.

The objective of this work was …

A Controlled Release Technique Using Microporous Membranes, Stephanie Farrell

Dissertations

A novel controlled release device based on aqueous-organic partitioning is described. The device comprises a reservoir, bounded by a microporous or porous membrane in the form of a hollow fiber or flat film. The reservoir liquid phase and the pore liquid phase are immiscible. The agent partitions between the phases at the aqueous-organic interface of the reservoir and the pore mouth, and then diffuses through the membrane pore liquid into a surrounding aqueous solution. The partition coefficient significantly influences the rate of release of the agent by reducing the driving force for diffusion across the fluid-filled membrane pore. The performance …

Vapor-Liquid Phase Equilibria Of Nonideal Fluids With A Ge-Eos Model, Socrates Ioannidis

Dissertations

This study dealt with the prediction and correlation of vapor-liquid equilibria behavior of nonideal fluids. The thermodynamic formalism of the G^E-EoS models, which combines the two traditional methods γ-Φ and Φ-Φ used so far for low and high pressure phase equilibria correlations respectively, has been combined with the 1FG^E model, based on one-fluid theory, to produce a more consistent approach to the phase equilibrium problem.

In the first part of our study we examine the predictive abilities of our model for vapor-liquid equilibria of highly nonideal fluids. The results establish the fact that the Huron-Vidal mixing rule …

Removal Of Volatile Organic Compounds From Contaminated Groundwater By Pervaporation, Sukla Chandra

Theses

Effective removal of non-aqueous phase liquid pools in groundwater and volatile organic compounds (VOCs) from contaminated soils can be achieved by surfactant flushing. This surfactant-rich ground water contains VOCs like trichloroethylene (TCE), dichloroethylene (DCE), etc. Membrane pervaporation technique is employed here to remove TCE from these micellar systems where a very high percentage of the VOC is trapped inside the micellar core. The micellar solution flows through the bore of microporous hydrophobic hollow fibers wherein the micelles break down and release the surfactants and the TCE. The TCE is then removed through the pores and a nonporous thin silicone skin …

Solids Suspension And Power Dissipation In Stirred Tanks Agitated By An Impeller Near The Tank Bottom, Ernesto Uehara-Nagamine

Theses

In this work, the effect of very small impeller clearances off the tank bottom, C, on complete solid off-bottom suspension, Njs, was investigated. Four types of impellers were used six-blade flat-disk turbine, six-blade flat-blade turbine, six-blade flat (45 degreees) pitched-blade turbine, and the high efficiency impeller Chemineer HE-3. The effects of the impeller diameter, D, tank diameter, T, and solids loading, X, were quantified. The presence of two impellers was analyzed using impellers of the same type and size.

Typically, Njs and the power consumption were found to decrease with the impeller clearance. However, for lower C/T values, a slight …

Removal Of Gasoline-Based Hydrocarbons By Vapor Permeation Membranes, Shivashanker Bagavandoss

Theses

Removal and recovery of evaporated lighter gasoline fractions can be effectively implemented by selectively permeating the hydrocarbons (HCs) and other volatile organic compounds (VOCs) from the vented air streams through nonporous hydrophobic polymeric membranes subjected to vacuum on the permeate side and then condensing these organics from the permeate. Such a vapor permeation process employing spiral-wound membranes has already been commercialized for VOCs. In this study, attention has been focused on removal of hydrocarbons from nitrogen flowing through the bore of microporous hydrophobic hollow fibers with a specially engineered nonporous silicone coating on the outside surface with a view to …

Fuel-Rich Combustion Of Ethylene And Air In A Two Stage Turbulent Flow Reactor, Tara Byrnes Salem

Theses

This thesis presents experimental and modeling results from the combustion of ethylene and air in a two stage turbulent flow reactor. This work is motivated by the continuing concern over combustion by-products. The first half of the research effort focused on the validation of the reactor as a perfectly stirred reactor and a plug flow reactor (PSR+PFR) sequence. Using four detailed reaction mechanisms, measured concentrations of carbon oxides, oxygen, and light hydrocarbon concentrations were modeled. Within the accuracy of the data, the mechanism of Mao (1995) yielded the best results. However, it was observed that the success of the reactor …

Reaction Kinetics Of Methanol And Mtbe Oxidation And Pyrolysis, Wen-Chiun Ing

Dissertations

This study presents experimental data on the decomposition of methanol in several different reaction environments - fuel lean to stoichiometric at a temperature range of 873 and 1073 K and a pressure range of I and 5 atm. Methane fuel is also added in several of the systems studied in order to provide experimental data to understand the methanol addition effect on the methane oxidation.

Computer codes: ThermCal, ThermSrt and ThermCvt have been developed for the thermal property calculations of stable molecules by the Benson group additivity method and of radicals by the NJIT hydrogen bond increment method.

Pressure dependent …

Emulsion Liquid Membrane Removal Of Arsenic And Strontium From Wastewater : An Experimental And Theoretical Study, Ding-Wei Zhou

Dissertations

The emulsion liquid membrane (ELM) technique has been successfully applied on the removal of arsenic (As) from metallurgical wastewater and the removal of strontium (Sr) horn radioactive wastewater. This study consisted of experimental work and mathematical modeling.

Extraction of arsenic by an emulsion liquid membrane was firstly investigated. The liquid membrane used was composed of 2-ethylhexyl alcohol (2EHA) as the extractant, ECA436OJ as the surfactant, and Exxsol D-8O solvent (or heptane) the diluent. The sulfuric acid and sodium hydroxide solutions were use I as the external and internal phases, respectively. The arsenic removal efficiency reached 92% within 15 minutes in …

Removal Of Vocs From Waste Gas Streams By Cyclic Membrane Separation Techniques, Gordana Obuskovic

Theses

In this study, new separation techniques called Flow Swing Membrane Absorption Permeation (FSMABP) and Flow Swing Membrane Permeation (FSMP) were used for the removal of the volatile organic compounds (VOCs). In both cases, processes are cyclic in terms of feed flow while desorption of the VOCs is constantly taking place. The transport mechanism in the FSMABP process is selective permeation followed by absorption of the VOCs into the stagnant nonvolatile absorbent liquid on the shell side of the membrane module and then desorption through a similar polymeric membrane. In the FSMP process, VOCs selectively permeate through the membrane into the …

Mass Transfer Of Pryene Between A Solid Phase And Oil/Water Suspensions, Sachin Ashok Purekar

Theses

This study dealt with understanding the partitioning of pyrene between water and mineral oil, and the mass transfer of pyrene from solid particles to oil/water suspensions.

It was found that when pyrene is dissolved in mineral oil, the amount transferred to water is negligible even after 10 days of phase contact.

Glass beads and sand were used as model solid phases to simulate soil and PAH (pyrene)-contaminated industrial sludges.

The transfer of pyrene from glass beads to mineral oil when no water phase is present was quantified. Mass transfer coefficients, and their dependence on the rate of environment shaking were …

An Investigation Of The Mechanism Of Advanced Oxidation Processes (Aop) Involving Free Radicals And Charged Species., Yaw-Kuen Lin

Dissertations

Hydrogen peroxide is a key component in Advanced Oxidation Processes (AOP). Its decomposition at different pH conditions has been studied and some interesting results were observed. When the pH value of hydrogen peroxide solution is less than 9, its rate of decomposition is independent of pH. On the other hand, in the pH range of 9-12.6, its rate of decomposition increases as pH increases, and goes through a maximum value then suddenly decreases with respect to pH. A reaction kinetic model with three rate constants in the form of beta probability function was used to describe the experimental data of …

Comparison Of Reductive Dehalogenation By Microbial Populations On Adsorptive Versus Non-Adsorptive Bioreactor Support Materials, Linda S. Colella

Theses

The overall performance of two bioreactors was studied. The reactor with a wood-based activated carbon as a biosupport completely dehalogenated a higher feed concentration of trichlorophenol than that with Manville beads. The carbon reactor was further characterized by the development of adsorption isotherms for most of the class of chlorophenols. Competitive adsorption wag investigated using an anaerobic medium, and a lignite-based carbon was studied for comparison. The order of adsorption strength on both carbons is trichloropenols> dichlorophenols> monochlorophenols, with the wood-based carbon having higher overall adsorption than the lignite-based carbon. The presence of the anaerobic medium decreased the extent of …

Determination Of Physical Parameters Affecting Biofiltration Of Vocs, Steven Matthew Wojdyla

Theses

This study dealt with the determination of physical and design parameters affecting the transient behavior of classical biofilters employed in removal of VOCs from airstreams. The column packing material consisted of a mixture of peat and perlite particles (2:3, v:v). The design parameters investigated were the density of the packing material, its porosity, and the void fraction of the filter-bed. The physical parameters investigated were the characteristics of adsorption equilibrium between VOCs and packing material, and the mass transfer coefficients of VOCs to the packing material.

The density of the packing material was found to be 0.679 x 106 g-packing/ …

Removal Of Vocs From Air By Absorption And Stripping In Hollow Fiber Devices, Tarun K. Poddar

Dissertations

Large volumes of exhaust air streams contaminated with volatile organic compounds (VOCs) such as toluene, xylene, acetone etc. are discharged into the atmosphere by various industrial facilities. Common technologies for VOC emission abatement e.g., activated carbon adsorption, absorption in a liquid, incineration and catalytic oxidation, have many strengths as well as considerable limitations. In this study, a regenerative absorption-based removal of VOCs from N₂ in an inert, nonvolatile, organic liquid flowing in compact hollow fiber devices has been developed. The process eliminates flooding, loading and entrainment encountered in conventional absorption devices.

Contaminated air/N₂ stream was fed through the …

Computer-Aided Process Design For Waste Minimization, Konstadinos Abeliotis

Dissertations

Problems related to process design with environmental considerations have been studied in this dissertation. A new heuristic design methodology has been formulated with the objective of minimizing the adverse environmental impact of chemical processes.

This hierarchical methodology starts with the definition and analysis of a process flowsheet followed by quantification of the process environmental loads. The quantification of environmental loads is an essential aspect of this methodology, because it serves as the comparative measure for environmental performance.

If the calculated environmental loads do not satisfy the environmental constraints (e.g., regulatory limits), waste minimization is investigated in the following order:

• Pollution …