Chemical Engineering Commons^™

Geostatistical Integration Of Geophysical, Well Bore And Outcrop Data For Flow Modeling Of A Deltaic Reservoir Analogue, Hong Tang

LSU Doctoral Dissertations

Significant world oil and gas reserves occur in deltaic reservoirs. Characterization of deltaic reservoirs requires understanding sedimentary and diagenetic heterogeneity at the submeter scale in three dimensions. However, deltaic facies architecture is complex and poorly understood. Moreover, precipitation of extensive calcite cement during diagenesis can modify the depositional permeability of sandstone reservoir and affect fluid flow. Heterogeneity contributes to trapping a significant portion of mobile oil in deltaic reservoirs analogous of Cretaceous Frontier Formation, Powder River Basin, Wyoming. This dissertation focuses on 3D characterization of an ancient deltaic lobe. The Turonian Wall Creek Member in central Wyoming has been selected …

Long Term Pressure Behavior In Turbidite Reservoirs, Feng Wang

LSU Doctoral Dissertations

In this study, we investigated several possible mechanisms that would give rise to the anomalous pressure behavior (early concave-up on Horner plot or upward drift on the derivative curve of the log-log plot and asymmetry between the pressure drawdown and buildup behavior) sometimes encountered in the turbidite reservoirs in GOM primarily using numerical simulation and 2-level experimental designs. We ascertained the most influential parameters to the pressure behavior and identified that multilayer commingled system and the leaky compartment model are the most probable mechanisms to cause the anomalous behavior due to layer or zone property contrast to a certain degree. …

Photocatalysis In A Novel Semiconducting Optical Fiber Monolithic Reactor For Wastewater Treatment, Hongfei Lin

LSU Doctoral Dissertations

The development of photocatalytic reactors is essential for the successful exploitation of heterogeneous photocatalysis on semiconductor particles, which has been shown to be an effective means of removing organic pollutants from wastewater streams. In this dissertation, a novel photocatalytic optical fiber monolith reactor (OFMR), which employed a ceramic multi-channel monolith as a support for TiO2 and quartz fibers inserted inside the monolithic channels as both a light-transmitting conductor and a support for TiO2, was developed for wastewater treatment by investigating the photocatalytic degradation of o-dichlorobenzene (DCB) and phenanthrene (PHE). This configuration provides a high surface area for catalyst coating per …

Chemical Vapor Deposition Of Thin Films For Ulsi Interconnect Metallization, Lidong Wang

LSU Doctoral Dissertations

We have studied the kinetics of copper chemical vapor deposition (CVD) for interconnect metallization using solution delivery of Cu(hfac)2 (Cu(II) hexafluoroacetyl-acetonate) dissolved in isopropanol. We observe a growth rate of 17.7 „b 1.5 nm/min at reference conditions of 300„aC substrate temperature, 0.025 Torr Cu(hfac)2 partial pressure, 1.6 Torr isopropanol (reducing agent), and 80 Torr H2 (carrier gas). The film resistivity approaches the bulk value of copper for film thickness greater than 100 nm. Reaction order experiments show first-order kinetics with respect to Cu(hfac)2 partial pressure and zero-order with respect to isopropanol. A series reaction mechanism including three kinetically significant steps …

Stability, Transport And Applications Of Polyaphrons In Porous Media, Le Yan

LSU Doctoral Dissertations

Polyaphrons are a kind of macroemulsion. The most distinctive feature of polyaphrons is their high stability. On the other hand, certain polyaphrons can be effectively destabilized by multivalent ions. In this dissertation, we devise a novel procedure that utilizes the fact that polyaphrons can be destabilized by certain ions to deliver light chemicals to lower the density of dense non-aqueous phase liquid (DNAPL) contaminants in situ. We first investigate how the stability of diluted polyaphrons is affected by the properties of the continuous phase. We find that polyaphrons can be destabilized by a low concentration of Al3+ or Ca2+ in …

Multiphase Mechanisms And Fluid Dynamics In Gas Injection Enhanced Oil Recovery Processes, Madhav M. Kulkarni

LSU Doctoral Dissertations

Currently, the Water-Alternating-Gas (WAG) process is the most widely practiced horizontal mode gas injection process in the industry. Although this process is conceptually sound, it has resulted in low (5 – 10%) oil field recoveries. Conversely, the gravity stable mode of gas injection has carved its niche as one of the most effective methods of gas injection EOR in the dipping reservoirs and pinnacle reefs. The Gas Assisted Gravity Drainage (GAGD) process is therefore being developed at LSU to extend these highly successful gravity stable applications to horizontal type reservoirs. The dissertation attempts to address six key questions: (i) do …

Measurement And Modeling Of Fluid-Fluid Miscibility In Multicomponent Hydrocarbon Systems, Subhash C. Ayirala

LSU Doctoral Dissertations

Carbon dioxide injection has currently become a major gas injection process for improved oil recovery. Laboratory evaluations of gas-oil miscibility conditions play an important role in process design and economic success of field miscible gas injection projects. Hence, this study involves the measurement and modeling of fluid-fluid miscibility in multicomponent hydrocarbon systems. A promising new vanishing interfacial tension (VIT) experimental technique has been further explored to determine fluid-fluid miscibility. Interfacial tension measurements have been carried out in three different fluid systems of known phase behavior characteristics using pendent drop shape analysis and capillary rise techniques. The quantities of fluids in …

Modeling Of Cane Sugar Colorant Removal In Packed-Bed Ion Exchange Columns And An Investigation Into Pretreatment Methods, Bruce Malcolm Ellis

LSU Master's Theses

Cane sugar colorants have been extensively researched but still little is known about their exact compositions. Rather than distinct compounds, they are a mixture of many compounds. Some it is assumed can be classified into the pseudo components that have been defined using gel permeation chromatography, based on molecular weight. The defining of these components has allowed the colorants to be modeled independently, instead of as one lumped color parameter. The measured colored components were modeled using a linear driving force adsorption model, which could be applied in the design process for optimizing the decolorizing capacity of the resins. The …

Development And Integration Of New Processes Consuming Carbon Dioxide In Multi-Plant Chemical Production Complexes, Sudheer Indala

LSU Master's Theses

New, energy-efficient and environmentally acceptable, catalytic processes have been identified that can use excess high purity CO₂ as a raw material from the sources available in a chemical production complex. The chemical complex in the lower Mississippi River Corridor has been used to show how these new plants can be integrated into this existing infrastructure using the Chemical Complex and Cogeneration Analysis System. Eighty six published articles of laboratory and pilot plant experiments were reviewed that describe new methods and catalysts to use CO₂ for producing commercially important products. Reactions have been categorized as hydrogenation reactions; hydrocarbon synthesis …

A Re-Evaluation Of Geopressured-Geothermal Aquifers As An Energy Resource, Jeremy Scott Griggs

LSU Master's Theses

The search for more efficient and economical forms of energy generation is a continual process. Natural gas production and electricity generation from geopressured-geothermal aquifers is an unconventional hydrocarbon source that has long been unproductive due to its marginal economics and lack of technological certainty. This thesis demonstrates that, based on modern technological competencies and economic constraints, geopressured-geothermal energy now maintains a viable future as an alternative domestic energy source.

Online Heat Transfer Measurement And Analysis For Sugar Mill Evaporators, David Timothy Solberg

LSU Master's Theses

Fouling and scaling in evaporators has been an area of great interest to raw sugar mills for a number of years and many of the mechanisms causing the scale and the rates of scaling are unknown. In an attempt to quantify the scaling rates and measure the scaling, an online model has been developed to model a system of evaporators. Monitoring the heat transfer coefficient as a function of time enabled measurement of the scaling rate by monitoring the heat transfer coefficient as it decreased with time. It is assumed that the scaling on the juice side of the evaporators …

Trajectory And Window Width Predictions For A Cased Hole Sidetrack Using A Whipstock, Harshad Prakash Patil

LSU Master's Theses

The Trackmaster system manufactured by Smith Services consists of a multi-ramped whipstock and a trimill assembly used to perform a sidetrack from a cased well. Smith Services has observed evidence that the trimill assembly may prematurely leave the face of the whipstock and build excess inclination and dogleg severity or may fall into the original well immediately after leaving the end of the whipstock ramp thus creating a need to predict the borehole trajectory for sidetracking operations. The goal of this project was to predict the borehole trajectory and the window profile cut in the casing by the sidetracking equipment …

Evaluation Of New Methods For Processing Drilling Data To Determine The Cause Of Changes In Bit Performance, Jaime Solano

LSU Master's Theses

Drilling operations represent the major cost in finding and developing new petroleum reserves. Poor drilling performance when drilling deep shale and strong rocks, as evidenced by slow rate of penetration (ROP), has a significant detrimental impact on drilling costs. Also, it has been concluded that bit balling is the main cause of low ROP when drilling deep, clay-rich shale with water-based mud. In addition, it is estimated that a potential saving in drilling cost of hundreds of millions of dollars a year can be obtained if bit balling is mitigated and ROP is improved. Several methods have been developed in …

Metal-Doped Rare Earth Oxide Catalysts For Condensations To Ketones, Arvind Karkal Bhat

LSU Master's Theses

Metal-doped supported rare earth oxide catalysts were examined to determine their suitability for the decarboxylative condensation of two carboxylic acids to produce ketones. The catalysts were characterized based on chemisorption tests, coke analysis using thermo-gravimetric analysis and X-ray absorption spectroscopy. Effect of catalyst particle size on rate of reaction was studied for various supported cerium oxide catalysts. Catalysts were tested for activity, selectivity, and stability using isothermal fixed bed reactors. Optimal operating conditions for the production of diisopropyl ketone and methyl nonyl ketone were determined. It was found that supported cerium oxide catalysts effectively catalyzed the condensation of isobutyric acid …

Ceria-Zirconia Oxide High Temperature Desulfurization Sorbent, Kwang Bok Yi

LSU Doctoral Dissertations

High temperature desulfurization of highly reducing coal-derived gases using ceria and ceria-zirconia sorbents is the primary object of this dissertation research. If H2S concentration is reduced to less than 1 ppmv the product gas may be used with fuel cells and downstream catalytic process. CeO2 is reduced to a non-stoichiometric oxide, which is superior to CeO2 in removing H2S. Moreover, ZrO2 addition to CeO2 to form a solid solution, Ce1-xZrxO2, increases the reducibility of CeO2. This should also result in improved desulfurization performance. Pure CeO2 and sorbents, both commercially available and prepared at LSU, were tested. XRD analysis indicated that …

Chemical Production Complex Optimization, Pollution Reduction And Sustainable Development, Aimin Xu

LSU Doctoral Dissertations

The objective of this research is to propose, develop and demonstrate chemical production complex optimization to determine the optimal configuration of chemical plants in a superstructure of possible plants. The Chemical Complex Analysis System is a new methodology that has been developed to determine the best configuration of plants in a chemical production complex based on the AIChE Total Cost Assessment (TCA) for economic, energy, environmental and sustainable costs. All new, energy-efficient, and environmentally acceptable plants using greenhouse gases that can produce potentially commercial products designed with HYSYS were integrated into the chemical complex using the System. The optimum configuration …

Electrodeposition Of Feconicu Quaternary System, Qiang Huang

LSU Doctoral Dissertations

Electrodeposition is a cost-effective method to produce thin film materials, which have been used widely in the microelectronic industry, and is advantageous to fabricate metal deposits into recessed and curved areas. In this dissertation, FeCoNiCu quaternary alloy system was investigated, both experimentally and theoretically, for fabrication of multilayers, grating structures, and nanowires. Multilayer structures are composed of alternating ferromagnetic and nonmagnetic nanometric layers, and are of interest due to the giant magnetoresistance (GMR) property it possesses, a change in electric resistance in the presence of an external magnetic field. In addition, the compositional modulation, or the composition contrast, in multilayer …

Removal Of Sustained Casing Pressure Utilizing A Workover Rig, Kevin Soter

LSU Master's Theses

This thesis will analyze the techniques used during the 1989 and 1990 workover programs as well as subsequent operations in 1991/1992. It will also present the techniques and results of the most recent 1999 workover program undertaken to alleviate the most persistent sustained casing pressure (SCP) in a mature Gulf of Mexico field. An extensive literature review is included to better illustrate the complexity of the issues involved and possible SCP mechanisms. The field was drilled during the 1980’s and SCP has been prevalent in some cases previous to initial completion operations. Previous remedial programs resulted in limited success in …

Adsorption Of Aromatic Hydrocarbons At Gas-Water Interface, Suresh Raja

LSU Master's Theses

Adsorption of organic vapors at a gas-water interface has several physical applications with respect to natural processes in the environment. Understanding the adsorption processes is critical in development of risk assessment and modeling of transport and fate of various chemical species that are abundantly present in the environment. Evidences from the works of several researchers point out deviations in gas-liquid partitioning as predicted by Henry’s law. In view of several theories that describe these deviations, adsorption process is hypothesized to be significant in gas-liquid partitioning, in addition to temperature and presence of organic matter, particularly on liquid surfaces with high …

Carbon Dioxide Capture From Flue Gas Using Regenerable Sodium-Based Sorbents, Ya Liang

LSU Master's Theses

The overall objective of this project is to develop a simple and inexpensive process to separate carbon dioxide (CO2) as an essentially pure stream from a fossil fuel combustion gases using a regenerable sodium-based sorbent. This objective of this phase of the project is to evaluate CO2 capture using sodium-based sorbents in single-cycle and multicycle tests as a function of calcination and carbonation conditions. The sorbent precursors investigated were sodium bicarbonates supplied by Church and Dwight, Inc., and natural trona supplied by Solvay. All precursors were first calcined to sodium carbonate and then converted to sodium bicarbonate (NaHCO3) or Wegscheider’s …

An Experimental Study Of The Applicability Of Flooding Phenomena To The Dynamic Lubrication Method Of Well Control, Rishi R. Ramtahal

LSU Master's Theses

This research investigates the feasibility of the dynamic lubrication method of well control as an alternative to conventional stepwise lubrication. The applicability of flooding phenomena to dynamic lubrication and its use in an optimization method to maximize pumping rates was also investigated. An experimental approach was taken in which experiments were conducted in a 13’ long laboratory apparatus designed to emulate the geometry in a wellhead and also in a full-scale research well. The laboratory experiments were conducted to visually investigate the mechanism of flooding and derive a flooding correlation applicable to this type of system. The full-scale experiments were …

Immiscible And Miscible Gas-Oil Displacements In Porous Media, Madhav Mukund Kulkarni

LSU Master's Theses

Gas Injection is the second largest EOR process in U.S. To increase the extent of the reservoir contacted by displacing fluids, gas and water are injected intermittently - water-alternating-gas (WAG) process, is widely practiced. This experimental study is aimed at evaluating the WAG process performance in short and long cores as a function of gas-oil miscibility and brine composition. This performance evaluation has been carried out by comparing oil recoveries between WAG injection and continuous gas injection (CGI). Miscible (2500 psi) and immiscible (500 psi) floods were conducted using Berea cores, n-Decane and two different brines, namely the commonly used …

Forced Bubble Columns, Jia Ma

LSU Master's Theses

In many chemical, biochemical and pharmaceutical industrial processes, bubble breakage is very important for gas component to dissolve and react with surrounding liquid. The overall mass transfer performance can be improved greatly when the interfacial gas-liquid area is increased due to bubble breakup. In forced bubble columns operating at low forcing frequency (<30Hz) and small forcing amplitude (<3mm), bubbles undergo phenomenal breakage. Mass transfer coefficient, kLa, is increased to 250%~625% of the no forcing value depending on flow regime and configuration of membrane and piston. Two different mechanisms, induced shear slug breakage in the gas feeder tube for bubbly flow and resonant frequency bubble breakage in the column fluid phase for jet flow, seem to at work.

A Novel Hydrogen And Oxygen Generation System, Zhiyong Peng

LSU Master's Theses

This study examined the three phases of the sorption-enhanced SMR process for H2 production: production of low-CO hydrogen using the standard Ni-based reforming catalyst and high purity CaO sorbent precursor, evaluation of combined reforming catalyst-sorbent samples supplied by TDA, and an Aspen simulation study of the process for simultaneous production of H2 and O2. The production of low-CO (<20ppmv) hydrogen was studied using the single-step sorption-enhanced steam methane reforming process. The effects of temperature, volumetric feed rate, and feed gas composition on the purity of H2 and the content of CO were investigated. The feasibility of producing 95+% H2 with CO content of less than 20ppmv was experimentally proven in a test at 480¡ãC and 5 atm using a commercial Ni-based catalyst and the calcium-based CO2 sorbent. The feed gas contained 20% CH4 and 80% H2O, while the product gas contained 97.8% H2 and 17 ppmv CO. With this low CO concentration, the product can be used in a proton exchange membrane (PEM) fuel cell without further purification. The catalyst-sorbent samples from TDA Research Inc. were extensively studied and evaluated with respect to their performance in the steam-reforming reaction using both the fixed-bed reactor system and TGA. The activity of the catalyst samples having different compositions was examined and compared at different temperatures and space velocities using a feed gas containing 11.1% CH4 with a steam-to-carbon (S/C) ratio of 3.0. The sorption activity and durability was also examined in the TGA system. The overall hydrogen and oxygen co-production process was studied and evaluated using the Aspen Plus simulator. Material and energy balance calculations showed that this system can produce 99+% purity hydrogen and oxygen simultaneously with efficient energy integration. This process is balanced on power consumption and generation, so no external power is required.

Investigation Of Qualitative Methods For Diagnosis Of Poor Bit Performance Using Surface Drilling Parameters, Arash Aghassi

LSU Master's Theses

Bit performance in deep shale when using water-based mud is typically poor. This study is part of a larger research project to improve that performance entitled "Automated Rig Controls for Improved Drilling Costs." The objective of the project is diagnosis of changes in drill bit performance to provide a logical basis for automating draw works control, maximizing bit performance, and reducing drilling costs. The specific goal of this study is a means to diagnose bit performance, specifically to identify bit balling and lithology changes, using real-time drilling data. The research began by identifying symptoms relating to specific causes of bit …

Application Of Mechanistic Models In Predicting Flow Behavior In Deviated Wells Under Ubd Conditions, Faisal Abdullah Aladwani

LSU Master's Theses

Underbalanced drilling (UBD) has increased in recent years because of the many advantages associated with it. These include increase in the rate of penetration and reduction of lost circulation and formation damage. Drilling of deviated and horizontal wells also increased since recovery can be improved from a horizontal or a deviated well. The drilling of deviated wells using UBD method will reduce several drilling related problems such as hole cleaning and formation damage. Prediction of flow and pressure profiles while drilling underbalanced in such wells will help in designing and planning of the well. The main aim of this research …

Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda

LSU Doctoral Dissertations

Electrodeposition is an important component in the fabrication of micro electro mechanical systems (MEMS). Nickel is the most commonly used material to produce three dimensional microstructures and few material alternatives have been demonstrated. In this dissertation, electrodeposited Ni-Cu alloys and nanocomposites are investigated as possible replacements for nickel in microsystems. Ni-Cu alloys are attractive for their corrosion resistance, magnetic and thermophysical properties. Alumina nanoparticulates included into metal matrices improve hardness and tribology of deposits. The Ni-Cu alloys and Ni-Cu-g-Al2O3 nanocomposites were electrodeposited from a citrate electrolyte, both at low and high pH. Electrodeposition experiments were performed in recessed microelectrodes 500 …

Improved Bottomhole Pressure Control For Underbalanced Drilling Operations, Carlos Perez-Tellez

LSU Doctoral Dissertations

Maintaining underbalanced conditions from the beginning to the end of the drilling process is necessary to guarantee the success of jointed-pipe underbalanced drilling (UBD) operations by avoiding formation damage and potential hazardous drilling problems such as lost circulation and differential sticking. However, maintaining these conditions is an unmet challenge that continues motivating not only research but also technological developments. This research proposes an UBD flow control procedure, which represents an economical method for maintaining continuous underbalanced conditions and, therefore, to increase well productivity by preventing formation damage. It is applicable to wells that can flow without artificial lift and within …

Dynamic Modeling And Parameter Estimation For An Ethlyene-Propylene-Diene Polymerization Process, Rujun Li

LSU Doctoral Dissertations

New Page 1

A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo-kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The pseudo-homopolymer model is then used as the basis for application of the numerical fractionation method. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point with as few as eleven generations, and in the …

Bioavailability And Bioaccumulation Of Sediment-Associated, Desorption-Resistant Fraction Of Polycyclic Aromatic Hydrocarbon Contaminants, Xiaoxia Lu

LSU Doctoral Dissertations

This study is directed toward identifying and characterizing the bioavailability of both reversibly sorbed and desorption-resistant fraction of hydrophobic organic contaminants in natural biologically active sediments and the corresponding consequences to prediction, control and regulation of these contaminants. The focus is on polycyclic aromatic hydrocarbons (PAHs) with particular emphasis on phenanthrene and benzo[a]pyrene. A quantity of well-characterized and extensively desorbed sediments was prepared by desorbing the lab-inoculated sediment with an isopropanol and electrolyte solution. This procedure was proved to be a very effective method to prepare sediments containing contaminants largely limited to a desorption-resistant compartment. Accumulation of contaminants in the …