Chemical Engineering Commons^™

Experimental Study On Single Cement Fracture Exposed To Co2 Saturated Brine Under Dynamic Conditions, Tevfik Yalcinkaya

LSU Master's Theses

Carbon capture and storage is one of the technologies that could help reduce CO2 concentration in the atmosphere while contributing to cutback of Greenhouse Gas emissions. Depleted oil and gas fields are favorable targets for CO2 storage because existing wells can be readily used as injection wells. However, a number of abandoned wells also serve as gateway to the reservoir which should be considered in the context of effective Carbon capture and storage. Wellbore cement is a very essential element in wellbore systems that serve as a barrier between different zones in the subsurface. The fractures inside wellbore cement sheath, …

The Development And Application Of A Novel Free-Damage Fracturing Fluid (Ph<2), Jin Zhang, Yan Zhang, Yongfu Wu, Xiuqing He, Xinzhu Zhang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

At present, water-Based fracturing fluid systems are mainly polymer (macromolecule) and visco-elastic surfactant (micro molecule). Because of polymer properties and incomplete gelout, the damage to matrices and conductivity of artificial fractures will be inevitable. the surfactant-Based fracturing fluid system is a micro-molecule system not to damage artificial fractures. However, it is difficult to eliminate the damages from rock debris moving and clay swelling information. a novel free-damage fracturing fluid system (FDFF), a cationic surfactant derived from a long chain fatty acid, has been developed and applied in Daqing oil field. FDFF can crosslink in a wide range from a strong …

Alkyl Polyglycoside/1-Naphthol Formulations With Ultra-Low Interfacial Tensions Against N-Octane For Enhanced Oil Recovery, Stefan Iglauer, Yongfu Wu, Patrick Shuler, Yongchun Tang, William Goddard

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We present Alkyl polyglycoside (APG)/1-naphthol formulations which show ultra-low interfacial tensions (IFT) against n-octane. We demonstrate that 1-naphthol is very efficient as a cosolvent in terms of reducing IFT. These formulations are therefore potentially suitable as agents for enhanced oil recovery (EOR). an increasing APG concentration strongly increased viscosity, and the formulations showed shear-thinning behavior. in a core flood EOR test we showed that this type of formulation significantly increased oil production. © 2010, European Association of Geoscientists and Engineers.

Characterization Of Rock/Fluids Interactions At Reservoir Conditions, Dayanand Saini

LSU Doctoral Dissertations

In this study, interfacial phenomena of spreading, wettability, and rock/oil adhesion interactions in complex rock/oil/water systems were characterized at reservoir conditions of elevated pressures and temperatures. Capabilities of both ambient and reservoir condition optical cells were used for measuring the oil/water interfacial tension and dynamic (the water-receding and the water-advancing) contact angles for various complex rock/oil/water systems. Well known sessile oil drop volume alteration method was successfully used in this study for evaluating the applicability of the modified Young’s equation for characterizing the line tension in complex rock/oil/water systems at reservoir conditions. This appears to be first time when rock/fluids …

Downhole Water Loop (Dwl) Well Completion For Water Coning Control --- Theoretical Analysis, Lu Jin

LSU Master's Theses

The Thesis is an analytical and numerical analysis of a new method for completing and producing oil wells affected by water coning. The method enables producing oil with no or minimal water cut while keeping the water subsurface with downhole water loop (DWL) installation. Typically, a DWL well is triple-completed in the oil and water zones with the three completions separated by parkers. The top completion produces oil to the surface while the middle and bottom completions drain from and inject into the bottom water zone, respectively. Segregated-inflow operation of DWL well requires keeping the production and drainage-injection rates below …

Evaluation Of Interwell Connectivity Of Little Creek Field, Mississipii [Sic] From Production Data, Gbemisola Yewande Ogunyomi

LSU Master's Theses

The understanding of geological characteristics and heterogeneity of a reservoir enables better decisions for reservoir development. Statistical methods use universally available injection and production rate data to help evaluate reservoir characteristics and behavior.In this research project, statistical methods typically used to infer communication between injector-producer well pairs in a waterflood reservoir using only production and injection rate data are applied to a CO2 flood. The multivariate linear regression (MLR) technique computes weighting coefficients possibly related to the fraction of the flow in a producer that comes from each of the injectors (Albertoni and Lake, 2002). MLR was applied to the …

The Development Of A Pore Pressure And Fracture Gradient Prediction Model For The Ewing Banks 910 Area In The Gulf Of Mexico, Jeffrey Steven Fooshee

LSU Master's Theses

The purpose of this project is to develop a pore pressure and fracture gradient prediction strategy for the Ewing Banks 910 (EW 910) area. Petrophysical and measured pressure data for eight wells previously drilled in the EW 910 area will be examined and reviewed. This strategy will help design future drilling and completion operations in the aforementioned area. Two pore pressure prediction strategies and one fracture gradient prediction strategy will be reviewed and applied to the available data. The first pore pressure prediction strategy reviewed was developed by W. R. Matthews. This strategy utilizes a geologic age specific overlay which …

Mechanistic Foam Modeling And Simulations: Gas Injection During Surfactant-Alternating-Gas Processes Using Foam-Catastrophe Theory, Ali Afsharpoor

LSU Master's Theses

The use of foam for mobility control is a promising means to improve sweep efficiency in subsurface applications such as improved/enhanced oil recovery and aquifer remediation. Foam can be introduced into geological formations by injecting gas and surfactant solutions simultaneously or alternatively. Alternating gas and surfactant solutions, which is often referred to as surfactant-alternating-gas (SAG) process, is known to effectively create fine-textured strong foams due to fluctuation in capillary pressure. Recent studies show that foam rheology in porous media can be characterized by foam-catastrophe theory which exhibits three foam states (weak-foam, strong-foam, and intermediate states) and two strong-foam regimes (high-quality …

Realtime Reservoir Characterization And Beyond: Cyber-Infrastructure Tools And Technologies, Yaakoub Youssef El-Khamra

LSU Master's Theses

The advent of the digital oil _x000C_eld and rapidly decreasing cost of computing creates opportunities as well as challenges in simulation based reservoir studies, in particular, real-time reservoir characterization and optimization. One challenge our e_x000B_orts are directed toward is the use of real-time production data to perform live reservoir characterization using high throughput, high performance computing environments. To that end we developed the required tools of parallel reservoir simulator, parallel ensemble Kalman _x000C_lter and a scalable work ow manager. When using this collection of tools, a reservoir modeler is able to perform large scale reservoir management studies in short periods …

A Simulation-Based Evaluation Of Alternative Initial Responses To Gas Kicks During Managed Pressure Drilling Operations, Majid Davoudi

LSU Master's Theses

Managed pressure drilling (MPD) is an adaptation of conventional drilling that has been developed to manage and control subsurface pressures in the well in order to minimize specific drilling problems. The constant bottom hole pressure approach (CBHP) is a versatile method of MPD, where a closed annulus allows initial responses to kicks other than simply shutting in the well. The objective of this research was to identify and evaluate the best initial response to gas kicks taken during drilling as a basis for developing reliable well control procedures for CBHP operations. Nine non-circulating and circulating responses (NCRs and CRs) were …

Simulation Study Of Emerging Well Control Methods For Influxes Caused By Bottomhole Pressure Fluctuations During Managed Pressure Drilling, Hakan Guner

LSU Master's Theses

Managed Pressure Drilling (MPD) is an emerging drilling technology that utilizes mud weight, surface backpressure and annular frictional pressure loss (AFP) to precisely control the wellbore pressure. The goal of this project is to identify the most appropriate initial response and kick circulation method for the kicks that result from complications specific to MPD. These complications that can cause a reduction in bottomhole pressure were classified as surface equipment failures and unintended equivalent circulating density (ECD) reductions. Rotating control device (RCD) and pump failures are the examples of surface equipment failures. Pump efficiency loss and BHA position change represent the …

Transition Metal Catalysts For Hydrodesulfurization Reactions Applied To Petroleum Industry, Brenda Torres

Open Access Theses & Dissertations

Catalysis plays a fundamental role in petroleum refining and basic petrochemical industries creating new routes in the development of industrial processes. Moreover, catalysis has become indispensable to the solution of environmental pollution problems and therefore on public health. World wide concerns for preservation of the environment has motivated the development of "Green" catalyst based technologies, to achieve a better utilization of petroleum resources and demands for cleaner transportation fuels. These environmental concerns have led to increasingly drastic regulations on sulfur, nitrogen and aromatics content in fuels. Sulfur content in the motor and diesel fuels is continuously reduced by regulations to …

Progressive Water-Oil Transition Zone Due To Transverse Mixing Near Wells, Shengkai Duan

LSU Doctoral Dissertations

This study derives from observations made in petroleum research and practices of chemical industry that efficient mixing takes place in segregated immiscible fluid flow in granular packs and static mixers. A hypothesis was formulated that transverse mixing (TM) across oil-water interface may occur in segregated inflow to wells resulting in progressive transition zone, more water production, and reduced oil productivity. “Mixing” is broadly interpreted here to address the entire range of stirring, splitting, dispersion and diffusion processes between two fluids.

Initial study showed that a commercial reservoir simulator would not model any transition zone in segregated oil-water flow at high …

Carbon Dioxide Capture From Flue Gases, Mohamed Rashid Al Rashid

Theses

Global warming and climate change are believed to be caused by the greenhouse effect. CO₂ has been regarded as the main contributor to global climate change which directly results in serious environmental problems. Half of the anthropogenic CO₂ emission sources are emitted from the combustion of fossil fuels in industries and power plants worldwide. The absorption behavior of Carbon dioxide from flue gases can be studied using conventional absorber and polymeric hollow fiber membrane contractors. An industrial absorber data was compared with simulated data using hollow fiber membrane contractor using the gPROMs software package. In this analysis, with …

Optimum Non Hydrocarbon Gas Injection Development Process And Ultimate Recovery Maximization., Abdulla A.F. Abed

Theses

A multi layered heterogeneous reservoir was selected for this study. The integrated reservoir characterization model and the pertinent transformed reservoir simulation history matched model were quality assured and quality checked.

The development scheme was identified and selected where the pattern and completion of the wells were defined to fit the heterogeneity of the reservoir characterization model. Lateral and maximum block contact holes were investigated.

The development processes studied were mainly hydrogen sulphide, carbon dioxide, nitrogen and rich hydrocarbon gas. The Water Alternating Gas/ Simultaneous Water Alternating Gas (WAG/SWAG) processes were also assured. In addition to the main gas and WAG/SWAG …

Fault Growth And Propagation During Incipient Continental Rifting: Insights From A Combined Aeromagnetic And Shuttle Radar Topography Mission Digital Elevation Model Investigation Of The Okavango Rift Zone, Northwest Botswana, Baraka D. Kinabo, John Patrick Hogan, Eliot A. Atekwana, Mohamed G. Abdel Salam, Motsoptse P. Modisi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Digital Elevation Models (DEM) extracted from the Shuttle Radar Topography Mission (SRTM) data and high-resolution aeromagnetic data are used to characterize the growth and propagation of faults associated with the early stages of continental extension in the Okavango Rift Zone (ORZ), northwest Botswana. Significant differences in the height of fault scarps and the throws across the faults in the basement indicate extended fault histories accompanied by sediment accumulation within the rift graben. Faults in the center of the rift either lack topographic expressions or are interpreted to have become inactive, or have large throws and small scarp heights indicating waning …

Natrolitite, An Unusual Rock -- Occurrence And Petrographic And Geochemical Characteristics (Eastern Turkey), Emin Ciftci, John Patrick Hogan, Hasan Kolayli, Emin Cadirli

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Very unusual rocks consisting of natrolite (>95 vol.%) ± pargasite (<5 vol.%) and rare albite (<1 vol. %) have been discovered in the Kop mountain range, eastern Turkey. We propose to call these rocks 'natrolitite' and 'pargasite natrolitite'. They were produced by Na Si metasomatism of dikes and stocks of diorite through replacement of the intermediate primary igneous plagioclase to produce natrolite. The metasomatic alteration produced concentric elliptical zones characterized by distinct mineral assemblages centered on intrusions of diorite. The Central Zone 1 consists of variably albitized diorite with preserved magmatic textures (albite ± andesine ± pargasite ± quartz). Transition Zone 2 comprises natrolite-bearing diorite (natrolite ± albite ± andesine ± pargasite ± calcite ± quartz). Marginal Zone 3 is a rock made up almost entirely of natrolite (natrolite ± pargasite ± albite ± calcite ± chlorite). Outer Zone 4 occurs along the boundary between the natrolitite and the surrounding serpentinite and consists of listvenite, a rock which comprises magnesite, quartz, calcite, mica, talc, and hematite, indicating a role for CO₂ in the metasomatic reactions, consistent with the presence of calcite in the alteration zones. Zone 5 consists essentially of brecciated serpentinite with numerous hydrothermal quartz veins and calcite veins. Whole-rock compositions document an increase in Na₂O, Al₂O₃, and H₂O from the core (central zone) to the margin while CaO, MgO, and SiO₂ decrease. Plagioclase abundance and composition also varies outwards from the central core rocks where it occurs as a primary magmatic phase (~95 vol.% An_41-38) …

Experimental Study Of A Foam Flow In Horizontal Pipes: Two Flow Regimes And Its Implications, Miodrag Bogdanovic

LSU Master's Theses

Although foam has been widely used in many scientific and engineering applications, the current understanding of foam rheology in pipes is still very limited because of its complex nature. This experimental study, for the first time, investigates the flow rheology of foams in pipes by placing a special emphasis on two distinct foam flow regimes. A wide range of experimental conditions are examined in this study, which include five different surfactant formulations (Cedepal FA-406, Petrostep CG-50, Stepanform 1050, Aquet TD-600, and Ultra-Palmolive), three different surfactant concentrations (0.1, 1, and 5 wt %), two different pipe diameters (0.5 and 1 inch …

Evaluation Of Sweep Efficiency Of A Mature Co2 Flood In Little Creek Field, Mississippi, Didem Senocak

LSU Master's Theses

CO2 displacement is the most widely used EOR process, but poor sweep efficiency and large CO2 utilization rates are limitations to the economic and technical success of CO2 floods. Developing a methodology to maximize the sweep efficiency and minimize the CO2 utilization rate would greatly improve the economics of these fields. This thesis evaluates the sweep efficiency of a successful, late-in-life, continuous injection CO2 flood at the Little Creek Field, Mississippi. In this work, we evaluate several heterogeneity measures in terms of recovery efficiency and utilization rate. Core studies available from 41% of the wells in the field were used …

Groundwater Circulation Well Operation Using Wind Turbine–Generated Energy, Ron Gallagher, Andrew Curtis Elmore

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An investigation was conducted regarding the potential economic benefits associated with using a wind turbine to power a groundwater circulation well (GCW) at the former Nebraska Ordnance Plant Superfund site. the first phase of the investigation used a 10-kilowatt-rated grid inter-tie wind turbine to partially offset the purchase of electricity from the utility company. the second phase consisted of the conversion of the grid inter-tie system to an off-grid system that stored energy using batteries. during the second phase, the GCW system was operated using either wind turbine power or utility power, and the other system components were operated using …

Nitrogen And Hydrogen Plasma Treatments Of Multiwalled Carbon Nanotubes, John G. Jones, A. R. Waite, Christopher Muratore, Andrey A. Voevodin

Chemical and Materials Engineering Faculty Publications

This article investigates plasma treatment of vertically aligned multiwall carbon nanotube (CNT) films in different plasma environments for modification of surface chemistry and morphology. The surfaces of the CNTs were functionalized with a pulsed dc plasma treatment, where the power was directly applied to the nanotube film in low pressure argon/nitrogen and argon/hydrogen backgrounds. Optical emission spectroscopy was used to detect atomic and molecular excitations in the gas mixtures as well as in pure gases in the vicinity of the CNT films. In situx-ray photoelectron spectroscopy was performed on the treated samples to examine CNT surface chemistry after treatment. …

Continuous Reservoir Model Updating By Ensemble Kalman Filter On Grid Computing Architectures, Xin Li

LSU Doctoral Dissertations

A reservoir engineering Grid computing toolkit, ResGrid and its extensions, were developed and applied to designed reservoir simulation studies and continuous reservoir model updating. The toolkit provides reservoir engineers with high performance computing capacity to complete their projects without requiring them to delve into Grid resource heterogeneity, security certification, or network protocols.

Continuous and real-time reservoir model updating is an important component of closed-loop model-based reservoir management. The method must rapidly and continuously update reservoir models by assimilating production data, so that the performance predictions and the associated uncertainty are up-to-date for optimization. The ensemble Kalman filter (EnKF), a Bayesian …

Reservoir Characterization Using Seismic Inversion Data, Subhash Kalla

LSU Doctoral Dissertations

Reservoir architecture may be inferred from analogs and geologic concepts, seismic surveys, and well data. Stochastically inverted seismic data are uninformative about meter-scale features, but aid downscaling by constraining coarse-scale interval properties such as total thickness and average porosity. Well data reveal detailed facies and vertical trends (and may indicate lateral trends), but cannot specify intrawell stratal geometry. Consistent geomodels can be generated for flow simulation by systematically considering the precision and density of different data. Because seismic inversion, conceptual stacking, and lateral variability of the facies are uncertain, stochastic ensembles of geomodels are needed to capture variability.

In this …

Using Science, Engineering, And Education To Address Water Supply Challenges In The Highlands Of Guatemala, Andrew Curtis Elmore, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

The Guatemalan Highlands is a Popular Destination for Non-Government Organizations Interested in Performing Relief Projects. U.S.-Based Organizations Such as Rotary International, Engineers Without Borders, and Various Religious Organizations Travel to Guatemala to Conduct Humanitarian Activities Which May Be Effective for the Short Term, But It is Not Clear that the Efforts Have a Systematic Impact. Students and Faculty at the University of Missouri-Rolla Have Systematically Studied Water Supply Issues Including Undergraduate and Graduate Research Projects and Undergraduate Engineering Courses Such as International Capstone Design. Materials Engineers Have Been Involved in the Study of Ceramic-Based Water Treatment Devices. These Microfilters Have …

Signaling Pathways Activated By Interleukin-2 And Interluekin-4 Receptors Mediate T Lymphocyte Clonal Expansion, Kristen K. Comfort

Chemical and Materials Engineering Faculty Publications

Cells sense and respond to chemical and physical stimuli through signal transduction pathways, which mediate cell proliferation, differentiation, migration, and survival. The cytokines interleukin-2 (IL-2) and interleukin-4 (IL-4) are key regulators of the adaptive immune system, particularly influencing the clonal expansion and differentiation of T cells. At least in culture, both synergistic and antagonistic effects of IL-2 and IL-4 co-stimulation have been reported; the antagonism, when observed, is thought to arise from the utilization of a common subunit shared by IL-2 and IL-4 receptors. We have sought to characterize IL-2 and IL-4 signaling at the level of intracellular pathways activated …

Hydrological Monitoring With Hybrid Sensor Networks, Thomas V. Freiberger, Sahra Sedigh, Estella A. Atekwana

Electrical and Computer Engineering Faculty Research & Creative Works

Existing hydrological monitoring systems suffer from short- comings in accuracy, resolution, and scalability. Their fragility, high power consumption, and lack of autonomy necessitate frequent site visits. Cabling requirements and large size limit their scalability and make them prohibitively expensive. The research described in this paper proposes to alleviate these problems by pairing high-resolution in situ measure- ment with remote data collection and software maintenance. A hybrid sensor network composed of wired and wireless connections autonomously measures various attributes of the soil, including moisture, temperature, and resistivity. The mea- surements are communicated to a processing server over the existing GSM cellular …

Production Data Analysis Of Shale Gas Reservoirs, Adam Michael Lewis

LSU Master's Theses

Hydrocarbon resources from unconventional shale gas reservoirs are becoming very important in the United States in recent years. Understanding the effects of adsorption on production data analysis will increase the effectiveness of reservoir management in these challenging environments. The use of an adjusted system compressibility proposed by Bumb and McKee (1988) is critical in this process. It allows for dimensional and dimensionless type curves to be corrected at a reasonably fundamental level, and it breaks the effects of adsorption into something that is relatively simple to understand. This coupled with a new form of material balance time that was originally …

Simulation Study Evaluating Alternative Initial Responses To Formation Fluid Influx During Managed Pressure Drilling, Asis Kumar Das

LSU Master's Theses

Managed pressure drilling is an innovative technique to precisely manage wellbore pressure. It is particularly applicable for reducing the risk of a kick or lost returns when drilling with a narrow window between pore pressure and fracture pressure. The constant bottomhole pressure method of managed pressure drilling uses annular frictional pressure and choke pressure in addition to mud hydrostatic pressure to achieve precise wellbore pressure control. This project investigated alternative initial responses to kicks to determine which would be most effective and reliable under different well scenarios when applying the constant bottomhole pressure method of managed pressure drilling. Three different …

Mechanistic Modeling Of An Underbalanced Drilling Operation Utilizing Supercritical Carbon Dioxide, Faisal Abdullah Aladwani

LSU Doctoral Dissertations

Mechanistic modeling of an underbalanced drilling operation using carbon dioxide has been developed in this research. The use of carbon dioxide in an underbalanced drilling operation eliminates some of the operational difficulties that arises with gaseous drilling fluids, such as generating enough torque to run a downhole motor. The unique properties of CO₂, both inside the drill pipe and in the annulus are shown in terms of optimizing the drilling operation by achieving a low bottomhole pressure window. Typically CO₂ becomes supercritical inside the drill pipe at this high density; it will generate enough torque to run …

Oil Bypassing By Water Invasion To Wells: Mechanisms And Remediation, Juan Carlos Hernandez

LSU Doctoral Dissertations

This study addresses oil bypassing caused by water invasion to wells in edge and bottom water-drive oil reservoirs – a significant problem worldwide. It is shown that the amount of by-passed (not recovered) oil is significant and could be predicted analytically and reduced by modifying well’s completion. A large statistical sample from the population of possible reservoir-well systems with edge and bottom-water has been created theoretically using several databases of actual reservoirs properties worldwide. Dimensional analysis allowed converting reservoir properties distributions into dimensionless group distributions. Then, the amount of by-passed oil was correlated with the dimensionless groups using designed experiments …