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Full-Text Articles in Chemical Engineering

Kinetic Experimental And Modeling Evaluations Of Asphaltene Morphology And Growth Rate Under Varying Temperature And Brine Conditions, Kwamena Ato Quainoo, Abdulmohsin Imqam, Cornelius Borecho Bavoh Jan 2023

Kinetic Experimental And Modeling Evaluations Of Asphaltene Morphology And Growth Rate Under Varying Temperature And Brine Conditions, Kwamena Ato Quainoo, Abdulmohsin Imqam, Cornelius Borecho Bavoh

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The utilization of predictive mechanisms to resolve asphaltene precipitation during oil production is a cleaner and less expensive means than the mechanical/chemical remediation techniques currently employed. Existing models lack predictive success due to opposing views on temperature-asphaltene precipitation interactions. In this study, the effect of varying temperatures (40, 50, 60, 70 80 and 90 °C) and brine concentrations (0 – 5 wt.%) on the long-time kinetics of asphaltene precipitations was evaluated. A series of experiments were conducted using the filtration technique and the confocal microscopy to study asphaltene precipitation on a model oil system consisting of asphaltenes, a precipitant, and …


Risk As A Process: A History Informed Hazard Planning Approach Applied To The 2018 Post-Fire Debris Flows, Montecito, California, Anna Serra-Llobet, John Radke, G. Mathias Kondolf, Larry Gurrola, J. David Rogers, Sarah Lindbergh, Johnny Douvinet Jan 2023

Risk As A Process: A History Informed Hazard Planning Approach Applied To The 2018 Post-Fire Debris Flows, Montecito, California, Anna Serra-Llobet, John Radke, G. Mathias Kondolf, Larry Gurrola, J. David Rogers, Sarah Lindbergh, Johnny Douvinet

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Historical information about floods is not commonly used in the US to inform land use planning decisions. Rather, the current approach to managing floods is based on static maps derived from computer simulations of the area inundated by floods of specified return intervals. These maps provide some information about flood hazard, but they do not reflect the underlying processes involved in creating a flood disaster, which typically include increased exposure due to building on flood-prone land, nor do they account for the greater hazard resulting from wildfire. We developed and applied an approach to analyze how exposure has evolved in …


Magnetic Inversion Approach For Modeling Data Acquired Across Faults: Various Environmental Cases Studies, Khalid S. Essa, Eid R. Abo-Ezz, Neil Lennart Anderson, Omar A. Gomaa, Mahmoud Elhussein Jan 2023

Magnetic Inversion Approach For Modeling Data Acquired Across Faults: Various Environmental Cases Studies, Khalid S. Essa, Eid R. Abo-Ezz, Neil Lennart Anderson, Omar A. Gomaa, Mahmoud Elhussein

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An effective extension to the particle swarm optimizer scheme has been developed to visualize and modelize robustly magnetic data acquired across vertical or dipping faults. This method can be applied to magnetic data sets that support various investigations, including mining, fault hazards assessment, and hydrocarbon exploration. The inversion algorithm is established depending on the second horizontal derivative technique and the particle swarm optimizer algorithm and was utilized for multi-source models. Herein, the inversion method is applied to three synthetic models (a dipping fault model contaminated without and with different Gaussian noises levels, a dipping fault model affected by regional anomaly, …


Impact Of Hvfr Loading Concentrations On Its Viscoelastic Properties And Proppant Transport Performance, Ghith Biheri, Shari Dunn Norman, Abdulmohsin Imqam Jan 2023

Impact Of Hvfr Loading Concentrations On Its Viscoelastic Properties And Proppant Transport Performance, Ghith Biheri, Shari Dunn Norman, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In unconventional reservoirs, increasing the low formation conductivities through hydraulic fracturing may substantially increase oil production from wells. This work of improving the fracture conductivity could be conducted by distributing and transporting proppant within the fracture lengths using high fracture fluid concentrations. This research focused on three areas. First, it assessed the fluid rheology including the viscosity and elasticity of a high viscosity friction reducer (HVFR) and linear guar using deionized (DI) water at different fluid concentrations (i.e., 2, 4, and 8 gpt for the HVFR and 15, 25, and 35 ppt for linear guar), and measured the impact of …


Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water, Xiaojing Ge, Abdulmohsin Imqam, Baojun Bai Jan 2023

Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water, Xiaojing Ge, Abdulmohsin Imqam, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High viscosity friction reducers (HVFRs) have been gaining more attention and increasing in use as proppant carriers. Reusing of produced water has also been driven by both environmental and economic benefits. However, high total dissolved solids (TDS) of produced water and high reservoir temperature significantly decrease the viscoelastic properties of HVFRs even for the cationic ones, which further reduce their proppant transport capabilities. Increasing loadings of HVFRs also has very limited effects on improving their proppant transport performances under high-TDS and high-Temperature conditions. The ultimate objective of this experimental study is to investigate the injection rate effects on the proppant …


Machine Learning Assisted Framework For Advanced Subsurface Fracture Mapping And Well Interference Quantification, Mohammad Faiq Adenan Jan 2023

Machine Learning Assisted Framework For Advanced Subsurface Fracture Mapping And Well Interference Quantification, Mohammad Faiq Adenan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The oil and gas industry has historically spent significant amount of capital to acquire large volumes of analog and digital data often left unused due to lack of digital awareness. It has instead relied on individual expertise and numerical modelling for reservoir development, characterization, and simulation, which is extremely time consuming and expensive and inevitably invites significant human bias and error into the equation. One of the major questions that has significant impact in unconventional reservoir development (e.g., completion design, production, and well spacing optimization), CO2 sequestration in geological formations (e.g., well and reservoir integrity), and engineered geothermal systems (e.g., …


The Effect Of Different Fracturing Fluids On The Productivity Of Multi-Staged Fractured Marcellus Shale Horizontal Wells, Vida Gyaubea Matey-Korley Jan 2023

The Effect Of Different Fracturing Fluids On The Productivity Of Multi-Staged Fractured Marcellus Shale Horizontal Wells, Vida Gyaubea Matey-Korley

Graduate Theses, Dissertations, and Problem Reports (ETD)

While hydraulic fracturing has undeniably improved the production from oil and gas reservoirs, this technology is not without limitations. The primary hurdles lie in the areas of proppant transport, fluid rheology, and stress management. Despite the extensive research conducted in this domain, there remains a considerable amount of work to be done for comprehensive solutions that account for the complex interactions among fracturing fluid, proppant distribution, and geomechanical conditions. Achieving this will then make room for a holistic and efficient hydraulic fracturing strategy.

This study addresses the above-mentioned problem by examining the impact of fluid type on proppant transport and …


Leveraging Artificial Intelligence And Geomechanical Data For Accurate Shear Stress Prediction In Co2 Sequestration Within Saline Aquifers (Smart Proxy Modeling), Munirah Alawadh Jan 2023

Leveraging Artificial Intelligence And Geomechanical Data For Accurate Shear Stress Prediction In Co2 Sequestration Within Saline Aquifers (Smart Proxy Modeling), Munirah Alawadh

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research builds upon the success of a previous project that used a Smart Proxy Model (SPM) to predict pressure and saturation in Carbon Capture and Storage (CCS) operations into saline aquifers. The Smart Proxy Model is a data-driven machine learning model that can replicate the output of a sophisticated numerical simulation model for each time step in a short amount of time, using Artificial Intelligence (AI) and large volumes of subsurface data. This study aims to develop the Smart Proxy Model further by incorporating geomechanical datadriven techniques to predict shear stress by using a neural network, specifically through supervised …


Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao Jan 2023

Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao

Doctoral Dissertations

"Wettability alteration with surfactants has been widely applied to improve oil recovery in carbonate reservoirs. An effective surfactant huff-puff application design requires comprehensive guidelines about where, how, and when this method could be applied. Besides, traditional methods to design an effective application and optimize surfactant performance are dependent on extensive experiments and are time-consuming. This study is to assist in the design of surfactant huff-puff via statistical methods and machine learning techniques.

In this study, a dataset including 402 effective surfactant imbibition tests is established by collecting information from nearly 50 publications. The dataset provides a foundation for further data …


Analyzing Spatio-Temporal Mechanisms Of Land Subsidence In The Parowan Valley, Utah, Usa, Jiawei Li, Ryan G. Smith, Katherine R. Grote Jan 2023

Analyzing Spatio-Temporal Mechanisms Of Land Subsidence In The Parowan Valley, Utah, Usa, Jiawei Li, Ryan G. Smith, Katherine R. Grote

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Parowan Valley, Utah (USA), is an agricultural region experiencing rapid subsidence due to extensive groundwater extraction from aquifers with a significant portion of fine-grained sediments. To analyze the subsidence spatio-temporally, time-series Interferometric Synthetic Aperture Radar (InSAR) of 155 Sentinel-1 C-band scenes were processed. These data showed approximately 30 cm of ground subsidence in Parowan Valley from 2014 to 2020. Because of the high temporal sampling rate of the Sentinel-1 satellite (12-day cycle), it is possible to determine the seasonal changes of ground deformation and relate this to groundwater extraction. To better understand the relationship between ground deformation and groundwater extraction …


Microcrystalline Dolomite In A Middle Permian Volcanic Lake: Insights On Primary Dolomite Formation In A Non-Evaporitic Environment, Xin Jiao, Yi Qun Liu, Wan Yang, Hong Li, Zi Yuan Meng, Min Ru Zhao, Zhe Xuan Li Jan 2023

Microcrystalline Dolomite In A Middle Permian Volcanic Lake: Insights On Primary Dolomite Formation In A Non-Evaporitic Environment, Xin Jiao, Yi Qun Liu, Wan Yang, Hong Li, Zi Yuan Meng, Min Ru Zhao, Zhe Xuan Li

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Lacustrine dolomite nucleation commonly occurs in modern and Neogene evaporitic alkaline lakes. As a result, ancient lacustrine microcrystalline dolomite has been conventionally interpreted to be formed in evaporitic environments. This study, however, suggests a non-evaporitic origin of dolomite precipitated in a volcanic–hydrothermal lake, where hydrothermal and volcanic processes interacted. The dolomite occurs in lacustrine fine-grained sedimentary rocks in the middle Permian Lucaogou Formation in the Santanghu intracontinental rift basin, north-west China. Dolostones are composed mainly of nano-sized to micron-sized dolomite with a euhedral to subhedral shape and a low degree of cation ordering, and are interlaminated and intercalated with tuffaceous …


Finite Line Relief Well System Design For Dams And Levees, Andrew M. Keffer, Erich D. Guy, Katherine R. Grote Jan 2023

Finite Line Relief Well System Design For Dams And Levees, Andrew M. Keffer, Erich D. Guy, Katherine R. Grote

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An Analytical Method is Commonly Used to Design Relief Well Systems by Assuming the Well Line Extends an Infinite Distance Parallel to the Dam or Levee. This Assumption May Be Met in Some Cases, But When a Well Line is of Finite Length, This Can Severely Underestimate Excess Heads. Although These Consequences Have Been Historically Recognized, a Practical Graph-Based Analytical Approach for Finite Well Line Design Has Not Been Developed. Finite Well Lines Exist and Continue to Be Installed at Many Locations, So This Study Developed a Practical Design Method for Such Systems. Analytical Solutions and Numerical Models Were Used …


Electrical Resistivity Tomography Revealing Possible Breaching Mechanism Of A Late Pleistocene Long-Lasted Gigantic Rockslide Dam In Diexi, China, Lanxin Dai, Xuanmei Fan, Dan Wang, Fanyu Zhang, Ali P. Yunus, Srikrishnan Siva Subramanian, J. David Rogers, Hans Balder Havenith Jan 2023

Electrical Resistivity Tomography Revealing Possible Breaching Mechanism Of A Late Pleistocene Long-Lasted Gigantic Rockslide Dam In Diexi, China, Lanxin Dai, Xuanmei Fan, Dan Wang, Fanyu Zhang, Ali P. Yunus, Srikrishnan Siva Subramanian, J. David Rogers, Hans Balder Havenith

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Landslide damming is a widespread phenomenon worldwide and significantly affects the evolution of fluvial landscapes. However, it is rarely witnessed from an antiquities perspective, and the case for observing their internal structure is challenging. We attempt to visualize the subsurface structure and understand the likely breaching mechanism of the late Pleistocene Diexi gigantic landslide dam (longevity of ~ 10 ka), using electrical resistivity tomography (ERT) method. Eight ERT measurements on the Diexi dam body revealed high resistivity zones near the periphery and lower resistivity zones in the middle portion of the profiles. Geomorphological mapping based on the LiDAR data determined …


The Taphonomic Character, Occurrence, And Persistence Of Upper Permian–Lower Triassic Plant Assemblages In The Mid-Paleolatitudes, Bogda Mountains, Western China, Robert A. Gastaldo, Mingli Wan, Wan Yang Jan 2023

The Taphonomic Character, Occurrence, And Persistence Of Upper Permian–Lower Triassic Plant Assemblages In The Mid-Paleolatitudes, Bogda Mountains, Western China, Robert A. Gastaldo, Mingli Wan, Wan Yang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Bogda Mountains, Xianjiang Uygur Autonomous Region, Western China, Expose an Uppermost Permian–Lower Triassic Succession of Fully Continental Strata Deposited Across Three Graben (Half Graben) Structures in the Mid-Paleolatitudes of Pangea. a Cyclostratigraphy Scheme Developed for the Succession is Subdivided into Three Low-Order Cycles (Wutonggou, Jiucaiyuan, Shaofanggou). Low-Order Cycles Are Partitioned into 1838 High-Order Cycles based on Repetitive Environmental Changes, and their Plant Taphonomic Character is Assessed in . 4700 M of High-Resolution, Measured Sections Distributed Across ~ 100 Km. Four Taphonomic Assemblages Are Represented By: Permineralized Wood (Both Autochthonous and Allochthonous), Megafloral Adpressions (?parautochthonous and Allochthonous) Identifiable to Systematic …


Drainage And Sedimentary Response Of The Northern Andes And The Pebas System To Miocene Strike-Slip Tectonics: A Source To Sink Study Of The Magdalena Basin, S. Zapata, L. Calderon-Diaz, C. Jaramillo, Francisca Oboh-Ikuenobe, J. C. Piedrahita, M. Rodríguez-Cuevas, A. Cardona, E. R. Sobel, M. Parra, V. Valencia, A. Patiño, J. S. Jaramillo-Rios, M. Flores, J. Glodny Jan 2023

Drainage And Sedimentary Response Of The Northern Andes And The Pebas System To Miocene Strike-Slip Tectonics: A Source To Sink Study Of The Magdalena Basin, S. Zapata, L. Calderon-Diaz, C. Jaramillo, Francisca Oboh-Ikuenobe, J. C. Piedrahita, M. Rodríguez-Cuevas, A. Cardona, E. R. Sobel, M. Parra, V. Valencia, A. Patiño, J. S. Jaramillo-Rios, M. Flores, J. Glodny

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Miocene strike-slip tectonics was responsible for creating and closing short-lived (ca. 6 Ma) passages and the emergence of isolated topography in the Northern Andes. These geological events likely influenced the migration and/or isolation of biological populations. To better understand the paleogeography of the Miocene hinterland and foreland regions in the Northern Andes, we conducted a source-to-sink approach in the Magdalena Basin. This basin is located between the Central and Eastern Cordilleras of Colombia and contains an ample Miocene record, which includes Lower Miocene fine-grained strata and Middle Miocene to Pliocene coarsening-up strata. Our study presents a new data set that …


Sedimentological And Geochemical Characterization Of A Varved Sediment Record From The Northern Neotropics, Edward Duarte, Jonathan Obrist-Farner, Susan R.H. Zimmerman, Erik T. Brown, Robert Brown Jan 2023

Sedimentological And Geochemical Characterization Of A Varved Sediment Record From The Northern Neotropics, Edward Duarte, Jonathan Obrist-Farner, Susan R.H. Zimmerman, Erik T. Brown, Robert Brown

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Annually resolved sedimentological records (including annual varves) can be used to develop precise chronologies for key climatic and tectonic events. Varved records, however, are most common in high latitude lakes, resulting in a spatial bias with respect to annually resolved records in tropical regions. Here we report on the sedimentology of two sediment cores from Lake Izabal, eastern Guatemala, that contain a well-preserved thinly laminated section spanning ca. 2200 years of the mid-Holocene. We integrate radiocarbon age-depth modeling, sedimentological observations, laminae counting, µX-ray fluorescence scanning, and multivariate statistical analyses to constrain the nature and chronology of the laminations. Our sedimentological …


Impact Of Composition And Salinity On Swelling And Gel Strength Of Poly (Acrylamide-Co-Acrylic Acid) Preformed Particle Gel, Ahmed Ben Ali, Reem Elaf, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai Jan 2023

Impact Of Composition And Salinity On Swelling And Gel Strength Of Poly (Acrylamide-Co-Acrylic Acid) Preformed Particle Gel, Ahmed Ben Ali, Reem Elaf, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The effects of various material compositions and reservoir environments on the ultimate strength and swelling kinetics of a commercial preformed particle gel (PPG) have been investigated. This study used different ratios of acrylamide and acrylic acid copolymers with a specific crosslinker concentration. Results have indicated that increasing the acrylic acid proportion enhances the PPGs' ability to swell but weakens their network structure. In contrast, increasing the crosslinker content decreases the swelling ratio and increases the gel strength. The highest equilibrium swelling capacity among the six preformed particle gel samples was obtained for PPG2, which has the highest acrylic acid amount …


Prediction Of Single Proppant Terminal Settling Velocity In High Viscosity Friction Reducers By Using Artificial Neural Networks And Xgboost, Xiaojing Ge, Rong Lu, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai Jan 2023

Prediction Of Single Proppant Terminal Settling Velocity In High Viscosity Friction Reducers By Using Artificial Neural Networks And Xgboost, Xiaojing Ge, Rong Lu, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High viscosity friction reducers (HVFRs) have been recently gaining more attention and increasing in use, not only as friction-reducing agents but also as proppant carriers. The settling velocity of the proppant is one of the key outputs to describe their proppant transport capability. However, it is influenced by many factors such as fluid properties, proppant properties, and fracture properties. Many empirical/physics-based models and correlations to predict particle settling velocity have been developed. However, they are usually based on certain assumptions and have applicable limits. In contrast, machine learning models can be considered as a black box. The objective of this …


Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman Jan 2023

Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preformed particle gels (PPG) have been widely applied in oilfields to control excessive water production. However, PPG has limited success in treating opening features because the particles can be flushed readily during post-water flooding. We have developed a novel micro-sized Re-crosslinkable PPG (micro-RPPG) to solve the problem. The microgel can re-crosslink to form a bulk gel, avoiding being washed out easily. This paper evaluates the novel microgels' transport and plugging performance through super-permeable channels. Micro-RPPG was synthesized and evaluated for this study. Its storage moduli after fully swelling are approximately 82 Pa. The microgel characterization, self-healing process, transportation behavior, and …


Laboratory Investigation Of Regained Rock Permeability Using High Viscosity Friction Reducer In Comparison To Linear Guar Fracture Fluids, Ghith Biheri, Abdulmohsin Imqam Jan 2023

Laboratory Investigation Of Regained Rock Permeability Using High Viscosity Friction Reducer In Comparison To Linear Guar Fracture Fluids, Ghith Biheri, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Hydraulic fracturing is a method employed for extracting oil and gas from unconventional reservoirs by pumping a mixture of water, sand, and additives into the reservoirs to fracture oil formations. A high viscosity friction reducer (HVFR) based on polyacrylamide is a popular chemical that has been employed recently during hydraulic fracturing treatments to help transport proppant and to reduce friction. However, the use of HVFRs at high concentrations, especially in regions with high concentration levels of total dissolved solids (TDS), has raised concerns over the possibility of formation damage. In this research, a new type of HVFR was investigated for …


The Influence Of Tropical Atlantic Sea-Surface Temperatures And The North Atlantic Subtropical High During The Maya Droughts, Derek K. Gibson, Jonathan Obrist-Farner, Brooke A. Birkett, Jason H. Curtis, Melissa A. Berke, Peter M.J. Douglas, Prudence M. Rice, Jeremy Maurer Jan 2023

The Influence Of Tropical Atlantic Sea-Surface Temperatures And The North Atlantic Subtropical High During The Maya Droughts, Derek K. Gibson, Jonathan Obrist-Farner, Brooke A. Birkett, Jason H. Curtis, Melissa A. Berke, Peter M.J. Douglas, Prudence M. Rice, Jeremy Maurer

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The frequency and duration of Late-Holocene hydrologic extremes in northern Guatemala were investigated using multiple sedimentological and geochemical proxies preserved in a sediment core collected from Lake Petén Itzá. A general trend of increasing aridity in the Maya Lowlands during the past 2000 years was punctuated by several multidecadal- to centennial-scale drought events recorded in the Petén Itzá sediments. In particular, the period spanning the Maya Terminal Classic Period and the Medieval Climate Anomaly (MCA), between 800 and 1300 CE, was marked by several extreme droughts and included the driest conditions of the past 2000 years between 950 and 1100 …


Insights To Surfactant Huff-Puff Design In Carbonate Reservoirs Based On Machine Learning Modeling, Ya Yao, Yue Qiu, Yue Cui, Mingzhen Wei, Baojun Bai Jan 2023

Insights To Surfactant Huff-Puff Design In Carbonate Reservoirs Based On Machine Learning Modeling, Ya Yao, Yue Qiu, Yue Cui, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants could react with adsorbates on carbonate rock surface to alter wettability from oil-wetness to water-wetness, which is effective to enhance oil recovery. Surfactant huff-puff treatment is mostly applied for this purpose and the resulting surfactant performance is the outcome of complex interfacial processes. Currently, the effect of important parameters on surfactant performance is not completely reported and the contribution of each parameter to surfactant performance is hard to be quantified. Traditional methods to optimize surfactant performance are time-consuming and show strong dependency on extensive experiments. in this paper, we address these problems from machine learning (ML) perspectives. Several ML …


Experimental Investigation Of The Interface And Wetting Characteristics Of Rock-H2-Brine Systems For H2 Geological Storage, Mirhasan Hosseini Jan 2023

Experimental Investigation Of The Interface And Wetting Characteristics Of Rock-H2-Brine Systems For H2 Geological Storage, Mirhasan Hosseini

Theses: Doctorates and Masters

The projected rise in demand for hydrogen (H2) production is a response to several factors, including greenhouse gas emissions caused by burning fossil fuels, depletion of fossil fuel reserves, and their uneven distribution around the earth. Thus, increased requirement for large-scale hydrogen storage solutions is anticipated to overcome imbalance between energy demand and supply. Deep underground formations such as salt caverns and porous reservoir rocks (e.g., depleted hydrocarbon reservoirs and deep saline aquifers) are necessary to achieve such volumes in practice. This process is known as underground hydrogen storage (UHS) which is technically very similar to underground natural gas storage. …


Comprehensive Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For The Water Management Of Reservoir With Concentrated Divalent Ions, Tao Song, Mohamed Ahdaya, Zhanmiao Zhai, Thomas P. Schuman, Baojun Bai Jan 2023

Comprehensive Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For The Water Management Of Reservoir With Concentrated Divalent Ions, Tao Song, Mohamed Ahdaya, Zhanmiao Zhai, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

As one of the most widely used technology to ameliorate the reservoir's heterogeneity, polymer gels have been applied for more than 60 years. However, how to plug fractured reservoirs with significant abnormal features, high temperature and high salinity, especially the divalent cations, is still a challenging target. This work systematically evaluated a novel salt-resistant re-crosslinkable preformed particle gel (SR-RPPG) designed for fractured reservoirs with excellent salt resistance (up to 5 % CaCl2). We evaluated the swelling kinetics, thermal stability and plugging efficiency of this SR-RPPG. We assessed the swelling kinetic and re-crosslinking behavior of the SR-RPPG through the …


Re-Assembling Polymer Particle Package For Conformance Control And Fluid Loss Control, Jingyang Pu, Baojun Bai, Thomas P. Schuman Jan 2023

Re-Assembling Polymer Particle Package For Conformance Control And Fluid Loss Control, Jingyang Pu, Baojun Bai, Thomas P. Schuman

Patents

This invention is broadly concerned with compositions and processes for oilfield applications. More specifically, this invention relates to novel polymer constructed packages that, when pumped into a petroleum well, provide tunable characteristics of transformation and delayed self-assembly with each other under reservoir conditions to yield strong, elastic, bulk gel materials. The compositions comprise a polymer, assembling agents, and optional additives used for the re-assembly stage are uniformly-distributed within the initial gel particles. The polymer particle packages absorb water and swell upon exposure to water, thus exposing the "assembling agents" that enable re-assembly. Both swelling and re-assembly are proportionally controlled via …


Investigations Of A Surrogate Fuel Based On Fischer-Tropsch Gtl And Ctl In Cvcc, Idi And Di Compression Ignition Engines, Amanda C. Weaver Jan 2023

Investigations Of A Surrogate Fuel Based On Fischer-Tropsch Gtl And Ctl In Cvcc, Idi And Di Compression Ignition Engines, Amanda C. Weaver

College of Graduate Studies: Theses & Dissertations

With the increase in availability, feedstocks, and properties of alternative fuels, compatibility issues emerge between current engine platforms often requiring a limit on the blend percentage of alternative fuel in conventional fuel or alteration to the engine platform. Two key metrics were identified, autoignition quality and lubrication characteristics, as vital for the proper function of a compression ignition engine, and if the blend of alternative fuels matches these two criteria for the diesel standard, then the resulting blend percentage can be considered as a viable alternative for complete replacement of conventional petroleum ULSD. Autoignition quality was matched using blends S-8, …


An Artificial Neural Network Approach To Predicting Formation Stress In Multi-Stage Fractured Marcellus Shale Horizontal Wells Based On Drilling Operations Data, Moudhi Alawadh Jan 2023

An Artificial Neural Network Approach To Predicting Formation Stress In Multi-Stage Fractured Marcellus Shale Horizontal Wells Based On Drilling Operations Data, Moudhi Alawadh

Graduate Theses, Dissertations, and Problem Reports (ETD)

The distribution of the anisotropic minimum horizontal stress, both in horizontal and vertical directions, is necessary for effective hydraulic fracture treatment design in Marcellus Shale horizontal wells. Typically, the minimum horizontal stress can be estimated sonic logs. However, sonic log data is not commonly available for the horizontal Marcellus shale wells due to the complexity and cost. The objective of this research is to predict the anisotropic minimum horizontal stress by utilizing drilling parameters including depth, weight-on-bit (WOB), revolution per minute (RPM), standpipe pressure, torque, pump flow rate, and the rate of penetration (ROP). More specifically, artificial neural network (ANN) …


Measurement Of Volumetric Deformation, Strain Localization, And Shear Band Characterization During Triaxial Testing Using A Photogrammetry-Based Method, Sara Fayek, Xiong Zhang, Xiaolong Xia, Qingqing Fu, Jeffrey D. Cawlfield Jan 2023

Measurement Of Volumetric Deformation, Strain Localization, And Shear Band Characterization During Triaxial Testing Using A Photogrammetry-Based Method, Sara Fayek, Xiong Zhang, Xiaolong Xia, Qingqing Fu, Jeffrey D. Cawlfield

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Triaxial Testing Has Been Routinely Used as a Standard Laboratory Test that Allows Correct Determination of Soil Characteristics. Previously the Volumetric Strain of the Triaxial Specimen Was Considered to Be Uniformly Distributed Along with the Specimen during the Isotropic and Deviatoric Loading. Although This Assumption Might Hold True under Isotropic Loading, the Effects of Restrained Ends and Disturbance during the Procedures of Specimen Installation and Testing Can Cause Nonuniform Strains throughout the Whole Specimen. This Paper Investigates the Effects of Specimen Preparation and Misalignment on the Strain Uniformity Along with the Soil Specimen during Triaxial Testing. a Series of Consolidated …


Analysis Of Plastic Pyrolysis Oil Separation Using Chemcad, Brian Berish, Juliana Mcgaffic Jan 2023

Analysis Of Plastic Pyrolysis Oil Separation Using Chemcad, Brian Berish, Juliana Mcgaffic

Williams Honors College, Honors Research Projects

Excessive plastic waste is a massive global issue. Plastic pyrolysis is a process of melting plastic in the absence of oxygen to create an wax-oil type substance called pyrolysis oil. This project will use a ChemCAD simulation to perform a distillation of a predetermined plastic pyrolysis oil into usable products. Heat integration will be used to construct a heat exchanger network and estimate utility usage. Sizing and costing of all equipment will be calculated and an overall cost analysis of the completed simulation will be performed to determine the economic viability of plant construction. Market research for potential products will …


Point Density For Soil Specimen Volume Measurements In Image-Based Methods During Triaxial Testing, Sara Fayek, Xiong Zhang, Javad Galinmoghadam, Jeffrey D. Cawlfield Jan 2023

Point Density For Soil Specimen Volume Measurements In Image-Based Methods During Triaxial Testing, Sara Fayek, Xiong Zhang, Javad Galinmoghadam, Jeffrey D. Cawlfield

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Discrete Measurement Targets Were Frequently Utilized in Image-Based Methods on the Specimen's Surface to Monitor the Soil Specimen during Triaxial Testing. However, the Required Density of Measurement Targets that Should Be Used in Triaxial Testing to Achieve Highly Accurate Volume Measurement Has Not Been Investigated. to overcome This Limitation, This Paper Presents a Parametric Study to Determine the Optimum Target/point Densities to Be Utilized on the Triaxial Soil Specimen Surface to Achieve the Desired Level of Volume Measurement Accuracy in Image-Based Methods. LiDAR Scanning Was Applied to Establish the "Ground Truth" Volume of the Specimen. the Effects of Deformation and …