Chemical Engineering Commons^™

Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim

Makara Journal of Technology

Chemical Oxygen Demand (COD) reduction of wastewater from soybean tofu production was studied by conducting advanced oxidation process (AOP) using hydrogen peroxide with UV radiation catalysts in a closed cylindrical glass reactor. The hydroxyl radical (*OH) concentration from H2O2 decomposition was modeled, and exponential trends were found for the *OH concentration over radiation time and operation temperature. As a result, it was found that the maximal *OH concentration was 0.209 mol L-1 at 240 minutes and 50 °C. The *OH concentration exponentially increased following rise in operation temperature. The H2O2/UV AOP application reduced COD concentration to approximately 42.41% from 10,545 …

Uplift Of Shoreline Regions On Pagai Island Due To The September 12, 2007 Mw 8.4 Earthquake Captured By Sar Image, Ashar Muda Lubis

Makara Journal of Technology

At least 25 people were killed by the September 12, 2007 Mw 8.4 Bengkulu earthquake, and many buildings were destroyed in Bengkulu and West Sumatra provinces. It is very important to estimate the earth surface deformation due to the earthquake to understand the rupture size and its process. The aim of this research is to estimate the shoreline change and vertical displacement on Pagai Island associated with the September 12, 2007 Mw 8.4 Bengkulu earthquake. The intensity of ALOS-PALSAR satellite images is used to access the pattern of displacement. The result shows that Pagai Island demonstrated huge uplift due to …

Effect Of Fly Ash Fortification In The Manufacture Process Of Making Concrete Towards Characteristics Of Concrete In Sulfuric Acid Solution, Asep Handaya Saputra, Muhammad Shohibi, Masatoshi Kubouchi

Makara Journal of Technology

Fly ash is a silica or alumino silica material that can be used as a constituent of cement in the concrete manufacturing process. Utilization of fly ash aims to improve durability and minimize the reduction of concrete’s compressive strength exposed to an acidic environment, which can be achieved through the pozzolanic reaction of fly ash with Ca(OH)2 within concrete. The reduced content of Ca(OH)2 through pozzolanic reaction will minimize the tendency of ettringite formation (compounds that cause deterioration and decrease the compressive strength of concrete). In order to determine the relation between fly ash replenishment into concrete with concrete’s characteristics …

Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu

Faculty Publications

We demonstrate a new strategy for tuning the size of large-diameter and few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50 to 150 nm by varying the transition metal (TM = Fe, Co, Ni or Mn) used to catalyze graphitization of dicyandiamide. Fe yielded the largest tubes, followed by Co and Ni, while Mn produced a clot-like carbon morphology. We show that morphology is correlated with electrocatalytic activity for the oxygen reduction reaction (ORR). A clear trend of Fe > Co > Ni > Mn for the ORR catalytic activity was observed, in both alkaline media and more demanding acidic media. The Fe-derived N-CNTs exhibited …

Gasification Of Coal And Heat Integration Modification For Igcc - Integrated Gasification Combined Cycle, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Fatma H. Ashour Prof.

Chemical Engineering

Use of energy is closely related to the development of an economy. The most useful form of energy in the modern world is electricity. IGCC has higher fuel flexibility (biomass, refinery residues, petroleum coke, etc.) and generates multiple products (electricity, hydrogen and chemicals like methanol and higher alcohols) and by-products - sulphur, sulphuric acid, slag, etc. IGCC plants include coal preparation unit, air separation unit (ASU) to separate oxygen from air to use it in the gasification process, gasification unit where an incomplete combustion for coal is made to produce Syngas, cleaning unit to remove acid gases and CO2 from …

Application Of Fiscal Incentives For Development Of East Natuna Gas Field For Long-Term National Natural Gas Demand, Marwan Batubara, Widodo Wahyu Purwanto, Akhmad Fauzi

Makara Journal of Technology

East Natuna gas field, which has proven reserves of 46 trillion cubic feet, is projected to meet long-term natural gas needs. However, CO2-content of the gas reserves reaches 71%, leading to expensive development costs. This research investigates the feasibility of the field based on several fiscal incentives. Firstly, gas supply-demand until year 2040 was analyzed. Then, based on the analysis, the field was developed using high CO2 gas separation technology to produce gas of 1300 MMSCFD in 2023, 2600 MMSCFD in 2031, and 3900 MMSCFD in 2039. Finally, the economic feasibility was assessed using cash flow analysis in accordance with …

Thermodynamic Analysis Of Irreversible Heat-Transformers, Niccolo` Giannetti, Arnas Arnas, Andrea Rocchetti, Kiyoshi Saito

Makara Journal of Technology

Absorption heat transformers extend the possibilities for efficient and environment-friendly energy conversion processes. Based on a general thermodynamic model of three-thermal cycles with finite thermal capacity of the heat sources, this paper is intent upon analyzing and optimizing the performance of absorption heat transformers, by including the influence of irreversibility in the analytical expression of the system efficiency. Dimensionless parameters for an overall optimization are defined and a first screening is performed to clarify their influence. Dependence on the main factors is highlighted to suggest how to change them in order to enhance the whole system performance. Under this point …

A New Method For Simulating Power Flow Density Focused By A Silicon Lens Antenna Irradiated With Linearly Polarized Thz Wave, Catur Apriono, Eko Tjipto Rahardjo, Norihisa Hiromoto

Makara Journal of Technology

A terahertz system uses dielectric lens antennas for focusing and collimating beams of terahertz wave radiation. Linearly polarized terahertz wave radiation has been widely applied in the terahertz system. Therefore, an accurate method for analyzing the power flow density in the dielectric lens antenna irradiated with the linearly polarized terahertz wave radiation is important to design the terahertz systems. In optics, ray-tracing method has been used to calculate the power flow density by a number density of rays. In this study, we propose a method of ray-tracing combined with Fresnel’s transmission, including transmittance and polarization of the terahertz wave radiation …

High Temperature Corrosion Of Aluminized Aisi 4130 Steel With The Different Composition Of Nacl/Na2so4 Deposits, Mohammad Badaruddin, Chaur Jeng Wang, Yudhistyra Saputra, Abu Khalid Rivai

Makara Journal of Technology

The high temperature corrosion of AISI 4130 steel can be increased by hot-dip aluminizing coating. The aluminized steel specimens with the deposit composition of 100/0, 30/70, 50/50, 70/30, and 0/100 (wt.%) NaCl/Na2SO4 were oxidized at 750 °C for 1-49 h periods. According to a parabolic rate constant (kp) value, the aluminized steel with deposit composition of 70/30 NaCl/Na2SO4 shows the highest kp value (3.71 × 10-11 g2cm- 4s-1), later followed by the kp value of 3.35 × 10-11 g2cm-4s-1 for 100/0 and the lowest kp value is 7.731 × 10-12 g2cm-4s-1 for 0/100. Whereas, the kp value for the aluminized …

Effects Of Supplier-Manufacturer Relationships On Supply-Chain Performance Of Manufacturing Industries In Indonesia, Rachmad Hidayat, Khisbullah Hudha, Sabarudin Akhmad

Makara Journal of Technology

The present study describes the relationships between commitment, communication, satisfaction, trust, relationship quality with suppliers, and supply-chain performance. The population of the study was manufacturing companies in Indonesia. Respondents were the chief executive officers or corporate secretaries or the designated managers involved in strategic decision making. Samples were taken by using a proportional area random sampling technique. Structural Equation Modeling (SEM) was used for analysis. Results of both direct and indirect testing of hypothesis indicated two hypotheses of positive and significant effects and nine hypotheses of positive but insignificant effects. Those hypotheses of positive and significant effects were the direct …

Stochastic Optimization Of Supply Chain Risk Measures –A Methodology For Improving Supply Security Of Subsidized Fuel Oil In Indonesia, Adinda Yuanita, Andi Noorsaman Sommeng, Anondho Wijonarko

Makara Journal of Technology

Monte Carlo simulation-based methods for stochastic optimization of risk measures is required to solve complex problems in supply security of subsidized fuel oil in Indonesia. In order to overcome constraints in distribution of subsidized fuel in Indonesia, which has the fourth largest population in the world—more than 250,000,000 people with 66.5% of productive population, and has more than 17,000 islands with its population centered around the nation's capital only—it is necessary to have a measurable and integrated risk analysis with monitoring system for the purpose of supply security of subsidized fuel. In consideration of this complex issue, uncertainty and probability …

Transmission Electron Microscopy Characterization Of High-Temperatur Oxidation Of Fe-20cr-5al Alloy Prepared By Focused Ion Beam Technique, Mohammad Dani, Pudji Untoro, Teguh Yulius Surya Panca Putra, Parikin Parikin, Joachim Mayer, Arbi Dimyati

Makara Journal of Technology

The Focused Ion Beam (FIB) technique was applied for cross section preparation of the oxidized alloy for Transmission Electron Microscopy (TEM) study. Prior to preparation, the specimens of Fe-20Cr-5Al alloy sheet were oxidized in air at 1200 oC for 2 minutes, 10 minutes, 2 hours, and 100 hours. The microstructure and elemental composition of the samples were characterized using TEM equipped with an Energy Dispersive X-Ray Spectroscopy (EDX). The Electron Energy Loss Spectroscopy (EELS) was used to determine of the light elements. The TEM investigation reveals remarkable microstructure evolution of the specimens during oxidation which generally exhibit a typical multi-layer …

Swelling-Etching Characterization Of Copper (I) Oxide - Pdms For The Development Of Micro/Nano - Particles Composite Mems Corrosion Sensor, Abdoul Kader Maiga

Graduate Theses and Dissertations

The primary objective for this thesis is to contribute to the understanding of the oxide removal process for a corrosion sensing device. The goal for designing such a device is for monitoring corrosion on metallic structures. The sensing material (6.35mm x 1mm discs) of the device is composed of copper (I) oxide particles mixed in some polydimethylsiloxane (PDMS). The PDMS, “housing,” is meant for controlling the oxidation rate through the sensing material. A solvent was used to facilitate the etchant diffusion through the PDMS matrix. Toluene and acetic acid were the ideal solvent and etchant, respectively, for carrying out the …

Effects Of Biomass Moisture Content On Volatile Flame Length During Cofiring With Coal, Matthew Pollard

McKelvey School of Engineering Graduate Student Theses & Dissertations

Cofiring biomass with coal can contribute to meeting Renewable Portfolio Standards (RPS) and reduce pollutant emissions. The physical characteristics and composition of biomass can vary significantly, which can affect the combustion characteristics. When cofiring biomass with coal, these differences can impact the structure of the volatile flame, the region where combustion of volatiles dominates. The length and location of the volatile flame is important to flame stability and determines the location and extent of volatile release. This has an effect on pollutant emissions, such as NOx (nitrogen oxides). Previously, the effects of parameters such as cofiring ratio, particle size, and …

Characterization Of Nano-Porous Si-Cu Composites To Enhance Lubricant Retention Impacting The Tribological Properties Of Sliding Surfaces, Julius Sheldon Morehead

Graduate Theses and Dissertations

As the expectations for modern machinery's tribological and thermal performances continue to rise, the retention of lubricant on the contact surfaces of their sliding components becomes an increasingly important issue. Friction and wear cause heat-related failures which lead to catastrophic damage to machinery. Evaporation of a lubricant's volatile constituents as well as lubricant migration leads not only to a reduction in lubricant quantity but also in its quality, thus facilitating component failures. In order to enhance component reliability, the surface should incorporate features that actively retain lubricants. The unique properties of nano-porous topographies such as their high surface area-to-volume ratio …

Phonon-Drag Contribution To Seebeck Coefficient Of Ge-On-Insulator Substrate Fabricated By Wafer Bonding Process, Veerappan Manimuthu, Shoma Yoshida, Yuhei Suzuki, Faiz Salleh, Mukannan Arivanandhan, Yoshinari Kamakura, Yasuhiro Hayakawa, Hiroya Ikeda

Makara Journal of Technology

In order to build high-sensitivity infrared photodetectors using SiGe nanowires, we investigate the thermoelectric characteristics of Ge-on-insulator (GOI) layers as a reference for SiGe. We fabricate p-type GOI substrates with an impurity concentration of 1016-1018cm-3 by a wafer-bonding process using Ge and oxidized Si wafers. Annealing treatment is performed in order to further increase the bonding strength of Ge/SiO2 interface. We measure the Seebeck coefficient in the temperature range of 290-350 K. The Seebeck coefficient of the GOI layers is very close to the theoretical value for Ge, calculated on the basis of carrier transport. Hence, there is a small …

Group Decisions In Value Management, Christiono Utomo, Farida Murti, Arazi Idrus

Makara Journal of Technology

This research deals with a technique to expedite group decision making during the selection of technical solutions for value management process. Selection of a solution from a set of alternatives is facilitated by evaluating using multicriteria decision making techniques. During the process, every possible solution is rated on criteria of function and cost. Function deals more with quality than with quantity, and cost can be calculated based on the theoretical time value of money. Decision-making techniques based on satisfying games are applied to determine the relative function and cost of solutions and hence their relative value. The functions were determined …

Fiber Optic Ring Resonator Sensor Detection Technique Based On Spectral Intensity Integration, Purnomo Sidi Priambodo, Sasono Rahardjo, Gunawan Witjaksono, Djoko Hartanto

Makara Journal of Technology

Resonant field phenomenon in optical ring resonator has been a major theme for various studies and can be used for various sensor applications. The spectral response shape changes are subjects to be discussed and analyzed for detection in optical sensor system. The spectral response changes are caused by various factors ranging from refractive index of the surrounding medium, medium loss due to absorption and scattering, and coupling variation between waveguides. These optical phenomena are mostly used for bio-sensor applications, since it is free from electromagnetic interference (EMI) and non-physically destructive. In this paper, we discuss our current research in developing …

Seebeck Coefficient Of Soi Layer Induced By Phonon Transport, Faiz Salleh, Takuro Oda, Yuhei Suzuki, Yoshinari Kamakura, Hiroya Ikeda

Makara Journal of Technology

The Seebeck coefficient of a patterned Si wire on P-doped SOI (Si-on-insulator) layer with a carrier concentration of 1018 cm-3 was measured near room temperature. The Seebeck coefficient is found to be smaller than that in the SOI layer and to be closer to the calculated Seebeck coefficient including the electronic contribution. The decrease in the Seebeck coefficient of Si wire is likely to occur due to the elimination of the contribution of phonon drag part. From the theoretical calculation of scattering rates by considering the scattering processes in phonon system, it is considered that an increase in phonon-boundary scattering …

Hazard-Driven Drivers’ Behaviours Towards Vehicle-To-Median Safe Distances, Martha Leni Siregar

Makara Journal of Technology

A median is required for a two-way road to separate traffic from opposing lanes and to prevent head-on collisions. However, studies indicate that medians are also perceived as hazards which need to be avoided during driving. This hazard perception is manifested in drivers’ changing behavior towards various types of medians along the driving lanes inform of their tendency to allow various safe distances to the medians. The Indonesian Highway Capacity Manual (IHCM) does not differentiate between types of medians and the influence on the drivers’ choice of safe margin to the medians. Therefore, this study looks into how the existence …

Construction Of A Novel Method Of Measuring Thermal Conductivity For Nanostructures, Hiroya Ikeda, Shoma Yoshida, Yuhei Suzuki, Veerappan Manimuthu, Faiz Salleh, Fujio Kuwahara, Masaru Shimomura, Kenji Murakami

Makara Journal of Technology

With the aim of characterizing the thermal conduction in a nanometer-scaled materials, we have constructed a novel method on the basis of an ac calorimetric method. In this method, periodic sample heating is performed by light irradiation and the corresponding periodic temperature is detected by infrared irradiative thermometer. This makes us measure the thermal diffusivity out of contact with the objective sample. In the present study, we confirm to measure the thermal diffusivity of bulk Si and Cu by this non-contact method with halogen-lamp irradiation. In determining the thermal diffusivity from the relationship between distance deviation and delay time, the …

The Effects Of The Types Of Milk (Cow, Goat, Soya) And Enzymes (Rennet, Papain, Bromelain) Toward Cheddar Cheese Production, Ariestya Arlene, Anastasia Prima Kristijarti, Ivana Ardelia

Makara Journal of Technology

The objectives of this research are to study the effects of different types of milk and enzymes toward the yield and quality (moisture, ash, protein, fat content, and texture) of cheddar cheese and the interaction between those two variables during the process. The types of milk are cow, goat, and soya milk, while the types of enzymes are rennet, papain, and bromelain enzymes. Regarding the procedure, the milk is first pasteurized before CaCl2 and Lactobacillus lactis that acts as the acidifier starter as much as 0.2% (w/v) and 0.5% of the milk volume are added respectively. The amount of enzyme …

Energy And Exergy Analysis Of Kalina Cycle For The Utilization Of Waste Heat In Brine Water For Indonesian Geothermal Field, Nasruddin Nasruddin, Agus Noor Sidiq, Abdulmajeed Mohamad, Rama Usvika

Makara Journal of Technology

The utilization of waste heat in a power plant system—which would otherwise be released back to the environment—in order to produce additional power increases the efficiency of the system itself. The purpose of this study is to present an energy and exergy analysis of Kalina Cycle System (KCS) 11, which is proposed to be utilized to generate additional electric power from the waste heat contained in geothermal brine water available in the Lahendong Geothermal power plant site in North Sulawesi, Indonesia. A modeling application on energy and exergy system is used to study the design of thermal system which uses …

A Versatile Microparticle-Based Immunoaggregation Assay For Macromolecular Biomarker Detection And Quantification, Haiyan Wu, Yu Han, George G. Chase, Qiong Tang, Chen-Jung Lee, Bin Cao, Jiang Zhe, Gang Cheng

Mechanical Engineering Faculty Research

The rapid, sensitive and low-cost detection of macromolecular biomarkers is critical in clinical diagnostics, environmental monitoring, research, etc. Conventional assay methods usually require bulky, expensive and designated instruments and relative long assay time. For hospitals and laboratories that lack immediate access to analytical instruments, fast and low-cost assay methods for the detection of macromolecular biomarkers are urgently needed. In this work, we developed a versatile microparticle (MP)-based immunoaggregation method for the detection and quantification of macromolecular biomarkers. Antibodies (Abs) were firstly conjugated to MP through streptavidin-biotin interaction; the addition of macromolecular biomarkers caused the aggregation of Ab-MPs, which were subsequently …

Coalescence-Induced Jumping Of Droplet: Inertia And Viscosity Effects, Samaneh Farokhirad, Jeffrey F. Morris, Taehun Lee

Publications and Research

The problem of coalescence-induced self-propelled jumping of droplet is studied using three-dimensional numerical simulation. The focus is on the effect of inertia and in particular the effect of air density on the behavior of the merged droplet during jumping. A lattice Boltzmann method is used for two identical, static micro-droplets coalescing on a homogeneous substrate with contact angle ranging from 0◦ to 180◦. The results reveal that the effect of air density is significant on detachment of the merged droplet from the substrate at the later stage of the jumping process; the larger the air density, the larger the jumping …

Modeling Of Spallation Phenomenon In An Arc-Jet Environment, Raghava Sai Chaitanya Davuluri

Theses and Dissertations--Mechanical and Aerospace Engineering

Space vehicles, while entering the planetary atmosphere, experience high loads of heat. Ablative materials are commonly used for a thermal protection system, which undergo mass removal mechanisms to counter the heat rates. Spallation is one of the ablative processes, which is characterized by the ejection of solid particles from the material into the flow. Numerical codes that are used in designing the heat shields ignore this phenomenon. Hence, to evaluate the effectiveness of spallation phenomenon, a numerical model is developed to compute the dynamics and chemistry of the particles. The code is one-way coupled to a CFD code that models …

Stabilizing Electrochemical Carbon Capture Membrane With Al2O3 Thin-Film Overcoating Synthesized By Chemical Vapor Deposition, Jingjing Tong, Fengzhan Si, Lingling Zhang, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

Development of high-efficiency and cost-effective carbon capture technology is a central element of our effort to battle the global warming and climate change. Here we report that the unique high-flux and high-selectivity of electrochemical silver-carbonate dual-phase membranes can be retained for an extended period of operation by overcoating the surfaces of porous silver matrix with a uniform layer of Al₂O₃ thin-film derived from chemical vapor deposition.

Modeling Of Biomass Torrefaction And Pyrolysis And Its Applications, Jordan L. Klinger

Dissertations, Master's Theses and Master's Reports - Open

Utilizing biomass provides a possible near-term alternative solution for fossil energy dependence in both electricity generation and transportation. Though thermochemical conversion can produce solid/liquid fuels that are compatible in existing infrastructure, detailed scientific chemical and mechanistic understanding are still being developed. In contribution to these efforts, this work is focused on development of a semiempirical, lumped parameter, chemical kinetic model to describe the degradation of woody biomass.

The initial kinetic model was developed in the torrefaction region to describe the gas-phase evolution of products (water, organic acids, permanent gases, and furfural) through a three consecutive reaction model. In this model, …

Process Simulation Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell Stack, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

Biomass gasification-solid oxide fuel cell (BG-SOFC) combined heat and power (CHP) systems are of major interest in the context of climate change mitigation, energy security and increasing energy efficiency. Aspen Plus is employed to simulate various BG-SOFC CHP systems. The aim of the research work is to investigate the technical feasibility of these systems and to study the influence of important operating parameters and examine integration options. Systems based on dual fluidised bed steam gasification and tubular SOFC technologies are modelled. The cathode recycle and electric heater integration options are not attractive in comparison to the base case anode recycle …

Design Of Gan-Based Low-Loss Y-Branch Power Splitter, Retno Wigajatri Purnamaningsih, Irma Saraswati, Nji Raden Poespawati, Elhadj Dogheche

Makara Journal of Technology

We present a Y-branch power splitter design with a multimode section using GaN on Sapphire at telecommunication wavelength. The GaN sample optical properties were also investigated, resulting in a refractive index for the GaN layers nTE=2.289±0.001 and nTM=2.324±0.00. Optimization of the structure parameters for this structure was conducted accurately using BPM methods. The results demonstrated the possibility of realizing a GaN-based Y-branch power splitter for various applications.