Chemical Engineering Commons^™

Adsorption Of Cu(Ii) Ions In Aqueous Solution Onto Limonia Acidissima Shellbased Activated Carbon: Kinetic And Isotherm Studies, Abrar Muslim, Syahiddin Dahlan Said, Gita Suci Hariati, Siti Fajar Karina, Fauzi Muhammad Djuned, Rizka Mulyawan

Makara Journal of Technology

Adsorption of Cu(II) ions from aqueous solution using activated carbon prepared from Limonia acidissima fruit shell (LAFS-AC) was conducted in batch mode experiments at pH 5 (±0.15), 100 rpm and 1 atm. The effects of contact time, initial Cu(II) ions concentration, KOH concentration, and adsorption temperature on Cu(II) ions adsorption capacity were investigated. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy analyses were performed to investigate the active site and surface morphology of the LAFS-AC, respectively. The Cu(II) ions adsorption was fitted very well (R2 = 0.94 on average) to the pseudo second-order adsorption kinetic with the adsorption capacity and …

Experimental Study On Automatic Control For Collision Avoidance Of Ships, Daeng Paroka, Muhammad Fahmi Kamil, Andi Haris Muhammad

Makara Journal of Technology

Automatic control system is widely applied to control the ship direction or heading angle in accordance with the decided trajectory. Several methods for improving performance of control system have been developed such as Proportional-Integral-Derivative (PID) control and fuzzy logic based control. Within the last decade, application of automatic control system is not only for ship navigation but also for avoiding collision risk of ships in seaways. This paper discusses the application of automatic control system for avoiding ship collision by free running experiment. Fuzzy logic based control was developed using Mamdani Centroid method to estimate the necessary rudder angle in …

Study On Semiconductor Properties Of Acetylide-Thiourea Fabricated Onto Interdigitated Electrodes (Ides) Platform Towards Application In Gas Sensing Technology, Adibah Izzati Daud, Wan M. Khairul, M. I. N. Isa, Khairul Anuar Abdul Wahid

Makara Journal of Technology

In the past few decades, the unique properties of acetylide and thiourea moieties individually have attracted great attention from researchers in various fields to be developed in numerous applications in advanced materials technology, especially as an active layer in gas sensing devices. The molecular systems of acetylide and thiourea provide a wide range of electronic properties as they possess rigid π-systems in their designated structures. In this study, a derivative of acetylide-thiourea featuring N-(4[4-aminophenyl] ethynyl benzonitrile)-N’-(4-ethyl benzoyl) thiourea (TCN) has been synthesised with the general formula of ArC(O)NHC(S)NHC≡C)Ar adopted the system of D-π-A for the significant development of conductive materials. …

Experimental Study Of The Chimney Height Variation Against Double Pots Biomass Stove Performance, Faisal Faisal, Adi Setiawan, Wusnah Wusnah, Khairil Khairil, Luthfi Luthfi, Mona Fajriana

Makara Journal of Technology

This research aims to get optimal chimneys height of double pots biomass stove. Optimal chimneys height needs to provide best performance of the stove. Experimental study was done by varied the chimney heights. Water boiling test as the standard method was used to obtained stove performance for each chimney height variation. The results showed that best performance stove was the one with 1.65 cm chimney height, with thermal efficiency at 37.66%.

Assessment On Heck-Immine Derivatives As Organic Semiconductor Materials, Rafizah Rahamathullah, Lim Keemi, Wan M. Khairul

Makara Journal of Technology

This paper reports the synthetic, characterization and theoretical evaluation of new class of hybrid Heck-immine system involving mixed moieties of vinylene (C=C) and azomethines (CH=N) which has been successfully integrated into an addition of organic semiconducting materials. The assessment of 4-[(hexyloxyphenyl)methylene]amino)-4’-chloro-stilbene (HEXCS) based on Donor (D)-π-Acceptor (A) was evaluated as active semiconductor material candidates via several spectroscopic and analytical techniques. In turn, the investigation of its potential as dopant system in conductive film was successfully deposited on indium tin oxide (ITO) coated substrate via spin coating method. The relationship between electronic and optical properties, chemical modelling at molecular interactions and …

Innovation Of Hydrocarbon Investigation Using Audio-Magnetotelluric In Cepu Field, Indonesia, Iqbal Fauzi Aditama, Widodo Widodo

Makara Journal of Technology

An audio-magnetotelluric (AMT) survey has been performed at Cepu oil field located in Indonesia. The objective of this research is to detect resistivity structures of this important hydrocarbon rock. This research can be classified as an innovation in application of the AMT method for hydrocarbon exploration. The lack of seismic resolution has been provided by the AMT method, especially in the location of sub-basalt and sub-salt plays. In additional, the cost of AMT survey is quite low compared to seismic. The forward modelling is included in this research to understand the measurement data response from a mathematical model. In the …

Numerical Characterization Of The Flow Field And Heat Transfer Inside The Receiver Of A Parabolic Trough Solar Collector Carrying Supercritical Co2, Samad Gharehdaghimollahajloo

UNLV Theses, Dissertations, Professional Papers, and Capstones

The aim of this research is to provide a detailed numerical analysis of flow field and heat transfer inside the heat collecting element of a parabolic trough collector. The parabolic trough collector is used as the boiler in a direct Super Critical Carbon Dioxide (S-CO2) Brayton cycle.

A single collector is modeled and analyzed with different inlet conditions. The working fluid is supercritical since its pressure is increased to above critical pressure in the compressor while its temperature reaches 300 °C after passing through the recuperators and before entering the solar field. For the first time, this research considers both …

Pollution Prevention In The Great Lakes Basin: Working With Pulp & Paper Manufacturers, Eugene Park

Journal of Environmental Sustainability

In response to growing concerns over persistent toxic substances in the Great Lakes, new initiatives are in place to address and mitigate pollutant loadings to these large natural waterbodies. With support from the U.S. Environmental Protection Agency and New York Department of Environmental Conservation, the New York State Pollution Prevention Institute (NYSP2I) worked with pulp & paper companies in the Great Lakes Basin in an effort to find solutions to reduce environmental impacts from this industry sector. Based on currently available EPA toolkits, NYSP2I developed and utilized an assessment tool called Lean, Energy, and Environment (LE2). Five different paper manufacturers …

Fundamental Studies Of Flame Structure Through Laser Plasma Diagnostics, Wendong Wu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Increasing concerns about air pollution and global climate change are drawing attention to the need for efficiency improvements and emission reductions for combustion processes, which account for more than 85% of energy production in United States. Combustion efficiency and emissions are affected by the mixing and reacting of fuel and oxidizer. Understanding such behavior plays a critical role in flame structure studies and combustion optimization. However, experimentally obtaining mixture fraction, which is a widely used quantity to describe the mixing behavior, has proven to be a challenge, especially for heavier hydrocarbon fuels or fuel rich flames. Moreover, measuring flame temperature …

Modal Phonon Transport Across Interfaces By Non-Equilibrium Molecular Dynamics Simulation, Yang Zhong, Tianli Feng, Xiulin Ruan

The Summer Undergraduate Research Fellowship (SURF) Symposium

Phonons represent the quantization of lattice vibration, responsible for heat transfer in semiconductors and dielectrics. Phonon heat conduction across interfaces is crucially important for the thermal management of real-life devices such as smartphones, electric vehicles, and satellites. Although recent studies have broadly investigated spectral phonon contribution to lattice thermal conductivity, the mechanism of phonon modal transport across interfaces is still not well-understood. Previous models, including the acoustic mismatch model (AMM) and diffuse mismatch model (DMM), only consider elastic process while neglecting inelastic phonon contributions. Herein, we employ spectral Non-Equilibrium Molecular Dynamics Simulation (NEMD) to probe the temperature and heat flux …

Residual Stress Measurements On The Tig Weld Joint Of 57fe15cr25ni Austenitic Steel For Structural Material Applications By Means X-Ray Diffraction Techniques, Parikin Parikin, Agus Hadi Ismoyo, Riza Iskandar, Arbi Dimyati

Makara Journal of Technology

Measurements of residual stress on the 57Fe25Cr15Ni steel plate with no-filler TIG-welding process were carried out. This work was conducted to determine the nature of weld ability in synthesized steel. The bulks were formed in a dimension of 30x20x7 mm3 to ease data retrieval. Results show that the largest residual stress occurred in the weld metal area, amounting to 82.40 MPa with lattice stretching of 0.18%. Conversely, the values decreased to 65.92 MPa and a stretch of 0.14% in the HAZ area. This residual stress is a tensile stress that can reduce the mechanical strength of the material since it …

Personality Trait Based Intervention For Workplace Accident Prevention, Yassierli Yassierli, Nurhayati Nurhayati, Marisa Anatasia, Shamsul Bahri

Makara Journal of Technology

Previous research has suggested that some traits may be useful as the predictors of risk behaviours behaviors. Therefore, personality traits seem to play a role in accident involvement. The purpose of this study is was to explore the relationship between the personality traits based on the Big Five Inventory (BFI) and worker accident experiences in order to elaborate personality traits based intervention for workplace accident prevention. A cross cross-sectional study was conducted among 173 workers in a cement company using a set of questionnaires consisting of respondents’ characteristics, BFI, and self-reported accident experience. The correlations were computed using Goodman Kruskal’s …

Urban Drainage Management And Flood Control Improvement Using The Duflow Case Study: Aur Sub Catchment, Palembang, South Sumatra, Indonesia, Charlotte De Fraiture, Robiyanto Hendro Susanto, F.X. Suryadi, Harrini Mutiara Hapsari Wahyu

Makara Journal of Technology

Urban flooding often times staggers the livelihood in an urban area, which most likely happens in the lowland urban area. Therefore, the existing urban drainage system should be improved in order to tackle the upcoming urban flooding events, which are more than likely to be more devastating than those in the previous years. The research location is in Palembang, Sumatra, Indonesia, where 30% of its urban part is a lowland area. The selected Aur Sub Catchment is located in Silaberanti. The main objective of this research is to improve the current drainage system in order to achieve the optimal design …

Ethanol Purification Using Activated Natural Zeolite, Chandra Wahyu Purnomo, Nelliza Putri, Indra Perdana, Hirofumi Hinode

Makara Journal of Technology

Bio ethanol is one of the potential fuels in the future. However, ethanol in water mixture has an azeotropic concentration of 95.6 wt. %, which makes it difficult to purify further. The common method of purification is by using an azeotropic distillation column, which requires an intensive energy and an addition of specific solvent. In this study, ethanol purification is done using an adsorption column packed with zeolite Raschig rings. The natural zeolite ring was modified beforehand using the NaOH solution to enhance the material’s water adsorption performance. The ethanol purity can reach more than 99% with the modified zeolite …

An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh

Makara Journal of Technology

The synthesis and utilization of C-C bonds formation are concerned about the key steps for the building of several conducting molecular electronics involving many asymmetric catalysts approached, which is an essential task that most researchers would ignore in preparing these materials to enhance the production yield of cross-coupling materials. Despite the enormous progress, there still remains a great demand for economic and practicable cross-coupling processes involving ultra-low catalyst loadings with high turnover numbers due to the employment of conventional metal catalyst. Thus, there has been an excessive interest to cultivate non-phosphine palladium catalysts for excellent achievement of activity, stability, and …

A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin

Makara Journal of Technology

The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …

Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri

Makara Journal of Technology

In this study, polyurethane (PU) films from palm kernel oil-based polyester (PKO-p) incorporated multi-walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid dispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator for 30 min followed by mixing with isocyanate to produce PU-MWNTs composite films. The mechanical properties, swelling, water vapour transmission rate (WVTR) and conductivity of the PU-MWNTs composite films are examined. Results show that the toughness (T) or flexibility, the tensile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase …

Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees

Makara Journal of Technology

We present a systematic scanning tunneling microscopy (STM) study of bias-dependent imaging of disulfur diarylethene (2S-DE) molecules on octanethiol (C8) monolayer at room temperature. In a rigid confinement of the C8 matrix, we did not observe any significant variation in the appearance of the 2S-DE. On the contrary, a reversal in the apparent height of the 2S-DE was present when the molecule was situated on a gold vacancy island. We attributed this finding to the presence of a new electronic state that became accessible for a tunneling event. In addition, the C8 surface structure underwent a reversible phase transformation from …

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Drawing And Twisting Of Graphene Fibers, Gregory T. Lane, Robert J. Sekerak, Isaias Diaz

Mechanical Engineering

The aim of this project was to develop a more automated process for drawing and twisting of graphene fibers than was currently in place. This was implemented by having two chemical baths with variable speed rollers at either end, and intermediate roller to spool fiber between stages, and a twisting cylinder with integral spool to twist the fiber as it is collected. The goal was to have this first iteration deliver a working prototype, however due to manufacturing delays and timing constraints, that will be missed. A second follow-on project would be able to continue the work presented here and …

Computational Fluid Dynamics Modeling And Simulations Of Fast Fluidized Bed And Moving Bed Reactors For Chemical Looping Combustion, Mengqiao Yang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Chemical-looping combustion (CLC) is a next generation carbon capture technology with high efficiency and low cost. To assess the potential of this technology for industrial scale power plants, thousands of laboratory scale and many pilot-scale plants have been designed and tested. In recent years, to obtain a thorough understanding of the hydrodynamic behavior inside the reactors and chemical looping combustion process, high-fidelity numerical simulation using Computational Fluid Dynamics(CFD) have been performed. However, CFD simulations in the literature have been limited reported compared to the laboratory scale experiments.

In this thesis, cold flow simulations of a CLC fuel reactor are performed …

Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity, Muhamad Sahlan, Dara Dienayati, Darul Hamdi, Soraya Zahra, Heri Hermansyah, Malyn Chulasiri

Makara Journal of Technology

Propolis, a wax bee glue, have antioxidant activity and effective as broad spectrum UVB and UVA photoprotection sunscreens agent. To improve photoprotection activity in sunscreen cream, the propolis was encapsulated by casein micelle. The Indonesian propolis was extracted by ethanol and separated the wax by freeze precipitation. The extract was encapsulated by casein and reduced their size by ball mill homogenizer with the encapsulation efficiency about 80% and size of particles about 80 nm. The particles was applied in sunscreen cream, evaluate their stabillity and photoprotection activity Sun Protection Factor (SPF) spectrophotometer (Optometric 290s). The results shows that the selected …

Synthesis Of Libob Fine Powder To Increase Solubility, Etty Marti Wigayati, Titik Lestariningsih, Christin Rina Ratri, Ibrahim Purawiardi, Bambang Prihandoko

Makara Journal of Technology

Lithium bis (oxalate) borate or LiBOB compound has captured interest of researchers, because it is potentially viable to be used as electrolyte salt in lithium-ion battery system. This compound is easy to synthesize and considered to be more environmentally friendly compared to conventional electrolyte salt because LiBOB does not contain halogen element. This research focused on the synthesis of LiBOB fine powder, which main purpose is improving LiBOB salt solubility in liquid electrolyte solution. This will aid the ion transfer between electrodes which in turn will increase the electrolyte performance. Solid state reaction was employed in this experiment. Synthesis of …

A Plastic Design Method For Rc Moment Frame Buildings Against Progressive Collapse, Hadi Faghihmaleki

Makara Journal of Technology

In this study, progressive collapse potential of generic 3-, 8- and 12-storey RC moment frame buildings designed based on IBC-2006 code was investigated by performing non-linear static and dynamic analyses. It was observed that the model structures had high potential for progressive collapse when the second floor column was suddenly removed. Then, the size of beams required to satisfy the failure criteria for progressive collapse was obtained by using the virtual work method; i.e., using the equilibrium of the external work done by gravity load due to loss of a column and the internal work done by plastic rotation of …

In Vitro Toxicity Evaluation Of Caffeine Imprinted Polymer (Caf-Mip) For Decaffeination Method On Normal Chang Liver Cells, Fatimah Hashim, Faizatul Shimal Mehamod, Naizatul Akmal Nawi

Makara Journal of Technology

Over consuming of caffeine is one of the factors to a few health problems such as insomnia, hypertension and cardiovascular disease. This preliminary study was conducted to evaluate the Caffeine-Imprinted Polymer (CAF-MIP) toxicity that was synthesized for a new alternative method for decaffeination. It is crucial to evaluate the toxicity of CAF-MIPas this product is potential to be used as complimentary with any drinks containing caffeine. In this study, the CAF-MIP toxicity potential was confirmed on Normal Chang Liver cell (NCLC) based on its IC50 value andacridine orange and propidium iodide (AO/PI) staining for mode of cell death observation.Proliferation assay …

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …

Sorption And Ion Exchange Behaviour Of Natural Zeolite Packing, Chandra Wahyu Purnomo, Bernice Lenora, Wiratni Budhijanto, Hirofumi Hinode

Makara Journal of Technology

It is well known that zeolite is an efficient metal ions adsorbent. The excess charge of the zeolite building blocks i.e. (AlO4)-5 and (SiO4)-4 creating a negative surface charge that attract metal cations. Beside the surface charge, zeolite also has three dimensional pore structure and reasonably large surface area which also can be used as adsorption sites. Ease of cation uptake make it suitable for many process with adsorption and desorption application. This study was conducted to observe the sorption and ion exchange behaviour of zeolite-betonite rings toward iron and cobalt cations. The results shows that the adsorption patterns follow …

Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable …

Purification Simulation With Vapor Permeation And Distillation-Adsorption In Bioethanol Plant, Misri Gozan, Mia Sari Setiawan, Kenny Lischer

Makara Journal of Technology

High purity of Bioethanol is required in biofuel mixing with gasoline (EXX). In bioethanol production line, the azeotropic property of ethanol-water becomes the barrier for purification process. This study examined two bioethanol separation processes by support of simulation tools, Superpro Designer 9.0 software. Ethanol purity and a low costeconomical process were the major considerations. Purification method of vapor permeation membrane technology was compared with distillation-adsorption method. Data from previous lab experiments and some literatures were used. The results showed that distillation-adsorption method is more economical compared to vapor permeation technology. Payback period of the simulation is 3.9 years and 4.3 …

In-House Fabrication Of Temperature Sensitive Paint For Turbine Cooling Research, Mayur D. Patel, Mark A. Ricklick

Beyond: Undergraduate Research Journal

The Temperature Sensitive Paint (TSP) is a widely used method in measuring and visualizing flow separation and heat transfer. Compared to the cost and time consumption needed for methods such as pitot tubes, temperature sensitive paint is a cheaper alternative. Due to high usage in College of Engineering research projects, it was determined that in house fabrication of temperature sensitive paint would reduce time and cost limitations. For initial stages, literature research was performed to determine the recipe of intensity based TSP with luminophore and polymer binder that operated optimum at temperatures from 0-100°C. Europium III thenoyltrifluoroacetonate was determined to …