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Articles 1801 - 1830 of 2337

Full-Text Articles in Chemical Engineering

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner Dec 2009

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mathematics Faculty Publications

A mathematical model for the evolution of pulsed laser-irradiated, molten metallic films has been developed using the lubrication theory. The heat transfer problem that incorporates the absorbed heat from a single laser beam or the interfering laser beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the reflectivity, the peak laser beam …

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Electrocatalytic Activities Of Au-Mmni(3.2)Al(0.2)Mn(0.6)Co(1.00) For Borohydride Oxidation, Gui-Ling Wang, Jin-Cheng Liu, Ke-Ning Sun, Dian-Xue Cao Nov 2009

Electrocatalytic Activities Of Au-Mmni(3.2)Al(0.2)Mn(0.6)Co(1.00) For Borohydride Oxidation, Gui-Ling Wang, Jin-Cheng Liu, Ke-Ning Sun, Dian-Xue Cao

Journal of Electrochemistry

In this work,the electrocatalytic activities of MmNi3.2Al0.2Mn0.6Co1.0, NaOH treated MmNi3.2Al0.2Mn0.6Co1.0 and Au-MmNi3.2Al0.2Mn0.6Co1.0 obtained after NaOH treatment(Mm: misch metal) for NaBH4 oxidation were reported. The electrodes were prepared by electrodeposition, their morphologies were analysized by SEM, their electrocatalytic properties were studied by the linear sweeping test. It was found that the oxidation current density of the Au-MmNi3.2Al0.2Mn0.6Co1.0 was 60 mA·cm-2, it was 3.5 times higher than that at the …

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Indirect Electrosynthesis Of Double Aldehyde Starch Using Pb-(Bro3-/Br-) As Electro-Catalytic Mediator, Ni-Na Chen, Ri-Yao Chen, Xi Zheng, Xiao Chen, Zhen Chen Nov 2009

Indirect Electrosynthesis Of Double Aldehyde Starch Using Pb-(Bro3-/Br-) As Electro-Catalytic Mediator, Ni-Na Chen, Ri-Yao Chen, Xi Zheng, Xiao Chen, Zhen Chen

Journal of Electrochemistry

In this paper,Nafion membrane was used as the separator in the electrolysis cell to indirectly electro-generating the double aldehyde starch(DAS) with BrO3-/Br-as a redox mediator and Pb as an anode.Effects of temperature,concentration of sulfuric acid and starch on the electro-oxidation of DAS were discussed.The steady state polarization curves were obtained.The experiment results showed that the current efficiency was over 50% when the electrolysis current density was 15mA/ cm2.

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Progresses In Electrocatalysis Of Nanomaterials—Tuning The Surface Structure And Property Of Electrocatalysts, Yan-Xia Jiang, Na Tian, Zhi-You Zhou, Sheng-Pei Chen, Shi-Gang Sun Nov 2009

Progresses In Electrocatalysis Of Nanomaterials—Tuning The Surface Structure And Property Of Electrocatalysts, Yan-Xia Jiang, Na Tian, Zhi-You Zhou, Sheng-Pei Chen, Shi-Gang Sun

Journal of Electrochemistry

The property of an electrocatalyst depends strongly on its surface structure.The study of surface structure-catalytic functionality is the base of design and preparation of electrocatalysts of high activity,high stability and high selectivity at microstructure level.In this paper,based mainly on our results concering hydrogen and oxygen adsorption-desorption,ethylene glycol oxidation and CO2 reduction,the research progresses in tuning the surface structure and property of electrocatalysts are summarized.This paper overviews firstly the cyclic voltammetric characteristics,electrocatalytic properties of platinum single crystal planes lying on different crystallographic zones of the unit stereographic triangle of face-centered cubic(fcc) metals.Next,the innovation of electrochemical methods to control the surface …

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Synthesis And Electrocatalytic Properties Of Ni-Pd/C Catalysts With Pd-Enriched Surface, Yu-Mei Chen, Zhi-Xiu Liang, Sheng-Li Chen Nov 2009

Synthesis And Electrocatalytic Properties Of Ni-Pd/C Catalysts With Pd-Enriched Surface, Yu-Mei Chen, Zhi-Xiu Liang, Sheng-Li Chen

Journal of Electrochemistry

The Ni-Pd alloy catalysts with Pd-enriched surface were synthesized through a modified polyol process.The synthesized materials were investigated by XRD and electrochemical methods,and tested as electrocatalysts for CH3OH-tolerant oxygen reduction.The results indicated that the synthesized Ni-Pd nanoparticles possess multiple phases containing Pd-Ni alloy and pure Ni.Comparing with Pd/C,the prepared Ni-Pd/C nanoparticles exhibited better resolved voltammetric peaks between the hydrogen absorption and adsorption,and positively shifted current peaks for the reduction of Pd oxide.The prepared Ni-Pd alloys with Pd-enriched surface have significantly enhanced ORR activity and improved CH3OH tolerance as comparing with Pd/C catalysts.

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Electrooxidation Of Formic Acid On Pd-Ni Alloy Film Electrode-The Effect Of Dealloying, Chao Wang, Fei-Fei Shi, Jin-Yi Wang, Han-Xuan Zhang, Wen-Bin Cai Nov 2009

Electrooxidation Of Formic Acid On Pd-Ni Alloy Film Electrode-The Effect Of Dealloying, Chao Wang, Fei-Fei Shi, Jin-Yi Wang, Han-Xuan Zhang, Wen-Bin Cai

Journal of Electrochemistry

A Pd-Ni alloy film was electrodeposited on Au disc electrode at a constant potential from a weakly basic bath containing PdCl2,NiSO4 and ethylenediamine.The as-deposited film was then subjected to potential cycling in a perchloric acid solution for surface dealloying treatment.The dealloyed Pd-Ni film electrode was examined for the electrocatalytic oxidation of formic acid,and compared with the as-deposited one as well as a Pd film electrode.The FE-SEM and electrochemical measurements on the Pd-Ni films revealed that the dealloying treatment caused a surface roughening and an increase in specific surface reaction area.The ICP-AES and XPS analyses demonstrated that the …

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Research Progress Of Synergistic Effect Of Metal Oxides On Pt-Based Catalysts, Hui-Ping Yuan, Xun Guo, Xin-Ping Qiu, Wen-Tao Zhu, Li-Quan Chen Nov 2009

Research Progress Of Synergistic Effect Of Metal Oxides On Pt-Based Catalysts, Hui-Ping Yuan, Xun Guo, Xin-Ping Qiu, Wen-Tao Zhu, Li-Quan Chen

Journal of Electrochemistry

In this paper,the work of Pt-based catalysts modified by metal oxides as the anode catalysts of direct methanol fuel cell(DMFC) is reviewed.The relationship between the structure and the composition of the catalysts and the reaction mechanism,exiting problems and developing direction are discussed.

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Highly Durable Pt/Ruo2/C Catalyst For The Cathode Of Direct Methanol Fuel Cells, Chun-Yu Du, Tao Dong, Ge-Ping Yin, Peng-Fei Shi Nov 2009

Highly Durable Pt/Ruo2/C Catalyst For The Cathode Of Direct Methanol Fuel Cells, Chun-Yu Du, Tao Dong, Ge-Ping Yin, Peng-Fei Shi

Journal of Electrochemistry

Instability of the carbon-supported Pt(Pt/C) catalyst at the cathode is one of the key technical challenges for the development of Direct Methanol Fuel Cells(DMFCs).In this paper,an efficient approach to enhancing the stability of the cathode catalyst was explored by designing and synthesizing a novel nanocomposite support,RuO2 coated carbon black(RuO2/C).Firstly,a wet chemical method was employed to synthesize the RuO2/C nanocomposite,from which Pt/RuO2/C catalyst was further prepared by a microwave method.The morphology and crystalline structure of the RuO2/C support and Pt/RuO2/C catalyst were then characterized by TEM and XRD.Finally,the electrochemical performance …

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Platinum Modified With Hydrogen Molybdenum/Tungsten Bronze As Electrocatalysts For Direct Small Organic Molecule Fuel Cell, Wei-Shan Li, Li-Peng Tian, Jun-Hua Du, Hong-Liang Huang, Wei Li, Li-Xia Zhang, Hong-Yan Yang, Pan-Pan Guo, Zhi-Hui Zhou, Xing-De Xiang, Zhao Fu Nov 2009

Platinum Modified With Hydrogen Molybdenum/Tungsten Bronze As Electrocatalysts For Direct Small Organic Molecule Fuel Cell, Wei-Shan Li, Li-Peng Tian, Jun-Hua Du, Hong-Liang Huang, Wei Li, Li-Xia Zhang, Hong-Yan Yang, Pan-Pan Guo, Zhi-Hui Zhou, Xing-De Xiang, Zhao Fu

Journal of Electrochemistry

There are several problems that limit the application of direct small organic fuel cell,including the use of precious platinum and the activity loss of platinum due to the intermediates poisons from the oxidation of small organic molecules.These problems have attracted wide interest and many solutions have been proposed.We have developed a new method to reduce the platinum usage and improve its activity,based on the modification of platinum with hydrogen molybdenum/tungsten bronze(HxMo(W)O3) was reviewed.

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Preparation Of Pt Nanoflower/Zno Composites Arrays And Their Electrocatalysis For Methanol Oxidation, Li Gao, Yi-Feng E, Lou-Zhen Fan Nov 2009

Preparation Of Pt Nanoflower/Zno Composites Arrays And Their Electrocatalysis For Methanol Oxidation, Li Gao, Yi-Feng E, Lou-Zhen Fan

Journal of Electrochemistry

The Pt nanoflower/ZnO(PtNF/ZnO) nanorod composites arrays were electrochemically prepared by controlling the hydrophobicity and the hydrophilicity of ZnO nanorods arrays.The Pt nanoflowers grew on the tip of ZnO nanorods,which maintain the vertical array of Zno nanorods with a high degree of size uniformity and high surface area.Compared with Pt nanoparticle covered ZnO nanorod arrays,which were prepared by controlling the hydrophilicities of ZnO nanorods and Pt nanoparticles,the PtNF/ZnO displayed highest electrocatalytic activities for the oxidation of methanol.

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Enhanced [Ru(Bpy)3]2+-Mediated Oxidation Of Guanine Prompted By Dhp, Bao-Lian Zhang, Wei Hong, Bao-Yi Lu, Hong Li Nov 2009

Enhanced [Ru(Bpy)3]2+-Mediated Oxidation Of Guanine Prompted By Dhp, Bao-Lian Zhang, Wei Hong, Bao-Yi Lu, Hong Li

Journal of Electrochemistry

The effects of dihexadecyl phosphate(DHP) and multi-walled carbon nanotubes(MWNTs) on the oxidation of guanine mediated by[Ru(bpy)3]2+ on the ITO electrode have been investigated by cyclic voltammetry and differential pulse voltammetry.The results showed that [Ru(bpy)3]2+ can mediate the oxidation.In the range from 0.01 to 0.15 mmol·L-1,peak currents for guanine oxidation mediated by [Ru(bpy)3]2+ increased with the rise of DHP concentrations.On the contrary,cationic surfactant HTAC has the ability to weaken the mediated oxidation of guanine.In addition,the oxidative mechanism of guanine mediated by [Ru(bpy)3]2+ with the participation of DHP …

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Electrocatalytic Performance Of Carbon Supported Ir Catalysts With Different Ir Loadings For Ammonia Oxidation, Yu-Zhi Jiang, Qing-Mei Kong, Tian-Hong Lu, Yi-Ming Zhou, Ya-Wen Tang Nov 2009

Electrocatalytic Performance Of Carbon Supported Ir Catalysts With Different Ir Loadings For Ammonia Oxidation, Yu-Zhi Jiang, Qing-Mei Kong, Tian-Hong Lu, Yi-Ming Zhou, Ya-Wen Tang

Journal of Electrochemistry

The electrocatalytic performance of the Ir/C catalyst as the anodic catalyst in the amperometric and electrochemical NH3 sensor was investigated.The experimental results illustrated that in the NaClO4 neutral electrolyte,the electrocatalytic performance of the Ir/C catalyst for the NH3 oxidation is related to the Ir loading in the Ir/C catalyst.Among the Ir/C catalysts with different Ir loading,the best electrocatalytic activity,stability and sensitivity were achieved by the Ir/C catalyst with 10% Ir loadings.In addition,the current densities of the NH3 oxidation at the Ir/C catalysts with the different Ir loadings were linearly proportional to the NH3 concentration.The Ir/C …

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Synthesis Of α-Mno2 Microspheres For The Application In Supercapacitor, Liang Wang, Gui-Chang Liu, Zhi-Cong Shi Nov 2009

Synthesis Of α-Mno2 Microspheres For The Application In Supercapacitor, Liang Wang, Gui-Chang Liu, Zhi-Cong Shi

Journal of Electrochemistry

The MnO2 microspheres were prepared through the oxidation of KMnO4 and MnCO3 microspheres precursor.The microstructure and supercapacitor properties of MnO2 were characterized by XRD,SEM and CV.The results show that MnO2 was in a poorly crystalline state with α-crystallographic form,the size of microspheres typically ranged from 0.5 to 2 μm.Loading 5 mg·cm-2 MnO2 microspheres had excellent capacitance behaviors in 2 mol·L-1(NH4)2SO4 solution.The specific capacitance was 135.6 F·g-1 with the scan rate at 2 mV·s-1,and 118.8 F·g-1 with the large scan rate at 100 …

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Complex Reduction Preparation Of Carbon Supported Pd Nanoparticle Catalyst And Its Electrocatalysis For Formic Acid Oxidation, Wei He, Yong-Yin Kang, Chong Du, Zhi-Qing Zou, Xiao-Gang Zhang, Hui Yang Nov 2009

Complex Reduction Preparation Of Carbon Supported Pd Nanoparticle Catalyst And Its Electrocatalysis For Formic Acid Oxidation, Wei He, Yong-Yin Kang, Chong Du, Zhi-Qing Zou, Xiao-Gang Zhang, Hui Yang

Journal of Electrochemistry

A simple procedure involved the complexing of PdCl2 with sodium citrate followed by ethylene glycol reduction has been employed for the preparation of carbon-supported Pd nanoparticles(Pd/C).The XRD and TEM characterizations indicate that Pd nanoparticles with a small particle size were well-dispersed on carbon support.The mean particle sizes of the Pd/C catalysts were found to be increased from 2.7 to 5.8 nm with heat-treatments at different temperature.The mass activity of the Pd/C catalyst for formic acid electrooxidation increased with the decrease in Pd particle size.However,the specific activity increased with Pd particle size.Furthermore,the Pd/C catalyst with a particle size of ca.3.6 …

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Cyclic Voltammetric And In-Situ Ftir Spectroscopic Studies Of Adsorption And Reduction Of No On Electrode Of Pt Nanoparticles, Qian Cheng, Yan-Xia Jiang, Dong-Mei Zeng, Shi-Gang Sun Nov 2009

Cyclic Voltammetric And In-Situ Ftir Spectroscopic Studies Of Adsorption And Reduction Of No On Electrode Of Pt Nanoparticles, Qian Cheng, Yan-Xia Jiang, Dong-Mei Zeng, Shi-Gang Sun

Journal of Electrochemistry

Adsorption and reduction of NO on electrode of Pt nanoparticles in acid solutions were studied by means of cyclic voltammetry(CV) and in-situ FTIR spectroscopy.The results indicated that the reduction of NO is a complicated process including the adsorption of NO on electrode surface.Two types of surface-bonded NO were determined on Pt nanoparticles.The weakly adsorbed NO was reduced between 0.6 V and-0.05 V,which yielded nitrous oxide(N2O) and ammonium(NH4+) as products;while the strongly bonded NO was reduced at more negative potentials between-0.05V and-0.15V,producing only NH4+ species.

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Electrocatalysis In Polymer Electrolyte Membrane Fuel Cells, Li Li, Si-Guo Chen, Xue-Qiang Qi, Yao-Qiong Wang, Meng-Bo Ji, Lan-Lan Li, Zi-Dong Wei Nov 2009

Electrocatalysis In Polymer Electrolyte Membrane Fuel Cells, Li Li, Si-Guo Chen, Xue-Qiang Qi, Yao-Qiong Wang, Meng-Bo Ji, Lan-Lan Li, Zi-Dong Wei

Journal of Electrochemistry

This review presents the study of Chongqing University in electrocatalysis for polymer electrolyte membrane fuel cells(PEMFCs).Based on the understanding to the performance degradation of PEMFCs' catalysts,the university has being concentrated on how to increase the activity,stability and utility of noble metal catalysts.It covers the molecular design of near-surface alloy catalysts for improvement of activity to oxygen reduction reaction(ORR) and resistance to foreign poison species,selective deposition of Pt on the so-called "three-phase interface" for a high Pt utility,and invention of anti-flooding electrode against water flooding in the catalyst layer of the membrane assemble electrode(MEA),and so on.The catalytic mechanism of electrode reactions …

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Electrocatalysis Of Myoglobin-Chitosan-Au Colloid Film Modified Glass Carbon Electrode, Yu-Hua Qin, Jun Guo, Hui Xu, Li-Heng Zhou, Sheng-Tian Wang Nov 2009

Electrocatalysis Of Myoglobin-Chitosan-Au Colloid Film Modified Glass Carbon Electrode, Yu-Hua Qin, Jun Guo, Hui Xu, Li-Heng Zhou, Sheng-Tian Wang

Journal of Electrochemistry

The cyclic voltammgram of Mb/AAO/Au Colloid/GCE shows a pair of well-defined and nearly reversible peaks at about-0.20 V(vs.Ag/AgCl) in 0.1 mol/L NaAc-HAc buffer(pH = 5.4),being the characteristic peaks of the Mb heme Fe(Ⅲ) / Fe(Ⅱ)redox couples.The electron transfer between Mb and the electrode was greatly enhanced under present testing conditions.The effects of scan rate,pH and buffers concentration on the electrochemical behaviors of Mb were studied in detail.Position of the Soret absorbance band suggested that Mb in chitosan-colloidal gold hept its secondary structure similar to the native states.Oxygen was catalytically reduced by Mb in chitosan-colloidal gold films.

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Aligned Nanotubule Membranes, Bruce J. Hinds Iii Nov 2009

Aligned Nanotubule Membranes, Bruce J. Hinds Iii

Chemical and Materials Engineering Faculty Patents

A method is provided for producing a permeable membrane, comprising the steps of aligning a plurality of hollow nanotubules to form a mat, coating the mat with a continuous polymer matrix to form a membrane. The membrane is etched (a) to open the plurality of hollow nanotubules and form pores and (b) to oxidize the carboxyl groups to carboxylate groups. At least one additional functional unit having at least one available amine group to bind the at least one additional functional unit to the nanotubule end carboxylate group may be provided. Membranes fabricated in accordance with the method of the …

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Effects Of Ph On Calcium Carbonate Precipitation Under Magnetic Field, Nelson Saksono, Yuliusman Yuliusman, Setijo Bismo, Roekmijati W. Soemantojo, Azwar Manaf Nov 2009

Effects Of Ph On Calcium Carbonate Precipitation Under Magnetic Field, Nelson Saksono, Yuliusman Yuliusman, Setijo Bismo, Roekmijati W. Soemantojo, Azwar Manaf

Makara Journal of Technology

Magnetic field effect on CaCO3 precipitation is the key parameter in evaluating the effectiveness of Anti-scale Magnetic Treatment (AMT). The purpose of this study was to investigate magnetic fields influence on CaCO3 precipitation in high and low super-saturated CaCO3 solution by varied pH CaCO3 solution using circulation flow fluid system. The observation results in the high super saturated solution (pH 8.5) showed the increase of precipited CaCO3 in magnetized solutions compared to those in non-magnetic solution during circulation process. In the low super-saturated CaCO3 solution (pH 6.4) it was found that magnetic treatment increased CaCO3 precipitation after circulation process. In …

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Intermetallic Cu3sn Phase Layer On Electrode’S Tip Of Galvanized Resistance Spot Welding, Muhammad Anis, Aulia Irsyadi, Deni Ferdian Nov 2009

Intermetallic Cu3sn Phase Layer On Electrode’S Tip Of Galvanized Resistance Spot Welding, Muhammad Anis, Aulia Irsyadi, Deni Ferdian

Makara Journal of Technology

Intermetallic Cu3Sn Phase Layer on Electrode’s Tip of Galvanized Resistance Spot Welding. A resistance spot welding method is commonly used in automotive industries application. In a resistance spot welding method, the copper electrode has a significant role as an electric current carrier for joining thin metal sheet. This research was focused on studying the effect of tin layer at the electrode tip for joining galvanized steel sheet. The main variable of this research is in the thickness of the intermetallic Cu3Sn layer. The result showed that the introduction of tin layer less than 1 μm in thickness on the electrode …

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Semi-Automatic Image Segmentation For Volumetric Visualization Of Pelvis Ct Scan-Images, Suprijanto Suprijanto, Farida I. Muchtadi, Irwan Setiawan Nov 2009

Semi-Automatic Image Segmentation For Volumetric Visualization Of Pelvis Ct Scan-Images, Suprijanto Suprijanto, Farida I. Muchtadi, Irwan Setiawan

Makara Journal of Technology

Semi-Automatic Image Segmentation for Volumetric Visualization of Pelvis CT Scan-Images. The current development of computerized tomography (CT) has enable us to obtain cross sectional image using multi slicing techniques in an order of few seconds. The obtained images represent several tissue structures on cross section slice being imaged. One challenge to help diagnosis using CT images is extracting an anatomic structure of interest using a method of image segmentation and volumetric visualization with the assistance of computers. In case of volumetric visualization of pelvis bones extracted from multi-slice CT images, whole images which are containing part of pelvis bone structures …

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Implementation Of Six Sigma Method To Maintain The Quality Of Construction Projects, Yusuf Latief, Retyaning Puji Utami Nov 2009

Implementation Of Six Sigma Method To Maintain The Quality Of Construction Projects, Yusuf Latief, Retyaning Puji Utami

Makara Journal of Technology

Implementation of Six Sigma Method to Maintain The Quality of Construction Projects. Six sigma (6-sigma) is a method that widely developed in the world, especially in manufacturing industry to decrease failures in achieving good quality in construction projects. The objective of this research is to explore the existing condition of quality management and the aplication of 6-sigma method in maintaining quality of construction projects. Structured interviews to experienced experts and people who were recommended by their companies were conducted. Non-parametric analysis using frequencies distribution procedures were used for analysis. The result shows that existing condition in quality management of construction …

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Simple Ml Detector For Multiple Antennas Communication System, Ahmad Taqwa, Soegijardjo Soegijoko, Sugihartono Sugihartono, Suhartono Tjondronegoro Nov 2009

Simple Ml Detector For Multiple Antennas Communication System, Ahmad Taqwa, Soegijardjo Soegijoko, Sugihartono Sugihartono, Suhartono Tjondronegoro

Makara Journal of Technology

Simple ML Detector for Multiple Antennas Communication System. In order to support providing broadband wireless communication services against limited and expensive frequency bandwidth, we have to develop a bandwidth efficient system. Therefore, in this paper we propose a closed-loop MIMO (Multiple-Input-Multiple-Output) system using ML (Maximum Likelihood) detector to optimize capacity and to increase system performance. What is especially exciting about the benefits offered by MIMO is that a high capacity and performance can be attained without additional frequency-spectral resource. The grand scenario of this concept is the attained advantages of transformation matrices having capability to allocate transmitted signals power suit …

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Mechanical Properties Of Ramie Fiber Reinforced Epoxy Lamina Composite For Socket Prosthesis, Tresna P. Soemardi, Widjajalaksmi Kusumaningsih, Agustinus Purna Irawan Nov 2009

Mechanical Properties Of Ramie Fiber Reinforced Epoxy Lamina Composite For Socket Prosthesis, Tresna P. Soemardi, Widjajalaksmi Kusumaningsih, Agustinus Purna Irawan

Makara Journal of Technology

Mechanical properties of ramie fiber reinforced epoxy lamina composite for socket prosthesis. This paper presents an investigation into the application of natural fiber composite especially ramie fiber reinforced epoxy lamina composite for socket prosthesis. The research focuses on the tensile and shear strength from ramie fiber reinforced epoxy lamina composite which will be applied as alternative material for socket prosthesis. The research based on American Society for Testing Material (ASTM) standard D 3039/D 3039M for tensile strength and ASTM D 4255/D 4255M-83 for shear strength. The ramie fiber applied is a fiber continue 100 % Ne14'S with Epoxy Resin Bakelite …

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Potency Of Thermoelectric Generator For Hybrid Vehicle, Nandy Putra, Raldi Artono Koestoer, Mohammad Adhitya, Ardian Roekettino, Bayu Trianto Nov 2009

Potency Of Thermoelectric Generator For Hybrid Vehicle, Nandy Putra, Raldi Artono Koestoer, Mohammad Adhitya, Ardian Roekettino, Bayu Trianto

Makara Journal of Technology

Potency of Thermoelectric Generator for Hybrid Vehicle. Thermoelectric Generator (TEG) has been known as electricity generation for many years. If the temperature difference occurred between two difference semi conductor materials, the current will flow in the material and produced difference voltage. This principle is known as Seebeck effect that is the opposite of Peltier effect Thermoelectric Cooling (TEC). This research was conducted to test the potential of electric source from twelve peltier modules. Then, these thermoelectric generators were applied in hybrid car by using waste heat from the combustion engine. The experiment has been conducted with variations of peltier module …

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Performance Of Hollow Fiber Membrane Gas-Liquid Contactors To Absorb Co2 Using Diethanolamine (Dea) As A Solvent, Sutrasno Kartohardjono, Pan Ade Nata, Eko Prasetio, Yuliusman Yuliusman Nov 2009

Performance Of Hollow Fiber Membrane Gas-Liquid Contactors To Absorb Co2 Using Diethanolamine (Dea) As A Solvent, Sutrasno Kartohardjono, Pan Ade Nata, Eko Prasetio, Yuliusman Yuliusman

Makara Journal of Technology

This study uses DEA solution to absorb CO2 from the gas flow through the hollow fiber membrane contactors. This study aims to evaluate the performance of hollow fiber membrane contactors to absorb CO2 gas using DEA solution as solvent through mass transfer and hydrodynamics studies. The use of DEA solution is to reduce the mass transfer resistance in the liquid phase, and on the other side, the large contact area of the membrane surface can cover the disadvantage of membrane contactors; additional mass transfer resistance in the membrane phase. During experiments, CO2 feed flows through the fiber lumens, while the …

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Methods For Cancer Detection, Kimberly W. Anderson, Kimberly M.L. May, Leonidas G. Bachas Sep 2009

Methods For Cancer Detection, Kimberly W. Anderson, Kimberly M.L. May, Leonidas G. Bachas

Chemical and Materials Engineering Faculty Patents

A method is provided for detecting an analyte indicative of a cancer or a metastatic disease condition, which utilizes the ability of the analyte to induce permeability in a barrier. The method includes providing a biosensor having a barrier which is substantially impermeable to an ion, a permeable membrane which is selective for the ion, and a detector capable of detecting the ion. The biosensor is contacted with a sample including at least one of the ion and the analyte, wherein the analyte causes at least a portion of the ion to pass through the barrier and the membrane. Passage …

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Synthesis And Characterization For A New Organic Cathode Material Of Lithium-Ion Batteries——Poly Sulfurized Chloranilic Acid(Psca), Kai Liu, Jian-Ming Zheng, Gui-Ming Zhong, Yong Yang Aug 2009

Synthesis And Characterization For A New Organic Cathode Material Of Lithium-Ion Batteries——Poly Sulfurized Chloranilic Acid(Psca), Kai Liu, Jian-Ming Zheng, Gui-Ming Zhong, Yong Yang

Journal of Electrochemistry

A new organic cathode material,poly sulfurized chloranilic acid(PSCA),has been successfully synthesized for lithium-ion batteries. 13C solid state NMR and FTIR results indicated that the chorine in chronailic acid was substituted by sulfur after sulfurization. The electrochemical measurements showed that the initial discharge capacity of PSCA was up to 287.6 mAh/g,and 169.9 mAh/g still remained after 100 cycles when cycled between 1.5～3.6 V at the current density of 15 mA/g.

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A Direct Borohydride Fuel Cell With Fecopc2-Catalysed Cathode, Jin-Fu Ma, Yan Liu, Jun-Hua Lai, Yong-Ning Liu Aug 2009

A Direct Borohydride Fuel Cell With Fecopc2-Catalysed Cathode, Jin-Fu Ma, Yan Liu, Jun-Hua Lai, Yong-Ning Liu

Journal of Electrochemistry

In this paper,a membraneless direct borohydride fuel cell was investigated. Cyclic voltammograms of FeCoPc2-modified glassy carbon electrode in the alkaline solution show that FeCoPc2 was active for oxygen reduction reaction. In addition, the steady-state polarization curve tests indicate that FeCoPc2 had better activity than FePc,CoPc or FePc+CoPc, which is due to its conjugated effect and synergistic effect of Fe and Co. Finally, a maximum power density of 110 mW/cm2 was attained, and the 25-day life test shows that the direct borohydride fuel cell had a good stability.

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Electrochemical Reduction Of Nitrobenzene In Different Ionic Liquids, Jun-Li Fan, Wei-Lin Ye, Rong Wang, Li-Qun Xu, Xia-Qin Wu Aug 2009

Electrochemical Reduction Of Nitrobenzene In Different Ionic Liquids, Jun-Li Fan, Wei-Lin Ye, Rong Wang, Li-Qun Xu, Xia-Qin Wu

Journal of Electrochemistry

Electrochemical reduction of nitrobenzene at glassy carbon electrode in different ionic liquids,such as N-methylimidazolium-p-toluene sulfonic acid ([Mim][PhSO3]) and ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]) have been investigated by cyclic voltammetry. Experimental results showed that only a cathodic current peak was observed in [Mim][PhSO3],which is a diffusional controlled irreversible reaction. And two pairs of current peaks were obtained in [Bmim][PF6] in the same potential range,indicating showed that the reduction products of nitrobenzene were different in different ionic liquids.

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