Chemical Engineering Commons^™

Determining The Standard Value Of The Oily Distortion Of Acquisition The Fingerprint Images, Rahmat Syam, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

Determining the Standard Value of the Oily Distortion of Acquisition the Fingerprint Images. This research describes a novel procedure for determining the standard value of the oily distortion of acquisition the fingerprint images based on the score of clarity and ridge-valley thickness ratio. The fingerprint image is quantized into blocks size 32 x 32 pixels. Inside each block, an orientation line, which perpendicular to the ridge direction, is computed. The center of the block along the ridge direction, a two-dimension (2-D) vector V1 (slanted square) with the pixel size 32 x 13 pixels can be extracted and transformed to a …

Are Ieee 754 32-Bit And 64-Bit Binary Floating-Point Accurate Enough?, Bernaridho Hutabarat, I Ketut Eddy Purnama, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

This paper describes a research toward the accuracy of floating-point values, and effort to reveal the real accuracy. The methods used in this research paper are assignment of values, assignment of value of arithmetic expressions, and output the values using floating-point value format that helps reveal the accuracy. The programming-tool used are Visual C# 9, Visual C++ 9, Java 5, and Visual BASIC 9. These tools run on top of Intel 80 x 86 hardware. The results show that 1*10-x cannot be accurately represented, and the approximate accuracy ranges only from 7 to 16 decimal digits.

Formation Of Caco3 Particle And Conductivity Of Na2co3 And Cacl2 Solution Under Magnetic Field On Dynamic Fluid System, Nelson Saksono, Setijo Bismo, Roekmijati Widaningroem, Azwar Manaf

Makara Journal of Technology

Hard water causes the CaCO3 scale formation on the pipe walls and heat exchanger equipments in industrial or domestic water processes. A great number of experimental researches on the prevention of the CaCO3 precipitation process by magnetic field have been carried out. In this research, Na2CO3 and CaCl2 solutions was magnetized in the circulated flow condition (dynamic fluid system). The velocity of fluid and the circulation time was modified to examine its influences to the magnetization process. CaCO3 content was measured by titration method of EDTA complexometry. Conductivity test was conducted to find out hydrate ion bonding. The results showed …

Circuit Design For Sensor Detection Signal Conditioner Nitrate Content, Robeth Viktoria Manurung, Aminuddin Debataraja, Hiskia Hiskia

Makara Journal of Technology

Circuit Design for Sensor Detection Signal Conditioner Nitrate Content. Nitrate is one of macro nutrients very important for agriculture. The availability of nitrate in soil is limited because it is very easy to leaching by rain, therefore nitrate could be contaminated ground water by over-process of fertilizer. This process could also produce inefficiency in agriculture if it happened continuesly without pre-analysis of farm field. The answer those problems, it is need to develop the ion sensor system to measure concentrations of nitrat in soil. The system is consist of nitrate ion sensor device, signal conditioning and data acquisition circuit. The …

Production Of Lovastatin And Sulochrin By Aspergillus Terreus Using Solid State Fermentation, Rizna Triana Dewi, Nina Artanti, Hani Mulyani, Puspa Dewi Narrij Lotulung, Minarti Minarti

Makara Journal of Technology

Lovastatin is an anti-cholesterol agent that was produced by Aspergillus terreus using solid state fermentation (SSF). During this fermentation process, sulochrin is also produced as an unwanted co-metabolite. However, our previous result showed that sulochrin had potential as antidiabetes because it is an inhibitor agent of α-glucosidase. In this paper, we reported our observation on lovastatin and sulochrin production pattern in relation with inhibitor α-glucosidase activity during eleven days fermentation of A. terreus koji (SSF) ethyl acetate extract. Koji obtained from solid state fermentation with rice as the substrate and incubated at room temperature, sample is taken daily for eleven …

The Zonation Of Abration Speed Characteristics And Its Handling Technique Of Jalinbar Of North Bengkulu As Vital Band Transportation, Suwarsono Suwarsono, Supiyati Supiyati, Suwardi Suwardi

Makara Journal of Technology

The Zonation of Abration Speed Characteristics and its Handling Technique of Jalinbar of North Bengkulu as Vital Band Transportation. Jalinbar Bengkulu is a vital infrastructure for traffic service, goods, agriculture products, mining, plantation and oils distribution. Abration due to scour of seawater often make these roads jammed and discrupts the peoples economy movement. The aims of this research was to investigate the abration speed of all segment of Jalinbar. The research method was a combination of two methods: A determination of swash energy of sea water using photometer and determination of rocks binding energy using douche method. The result shows …

The Formation Design Of Noise Reducers From Plywood, Foam, Tray, Dan Coconut Fiber For Static Sources, Melati Ferianita Fachrul, Wisnu Eka Yulyanto, Asharani Merya

Makara Journal of Technology

The Formation Design of Noise Reducers from Plywood, Foam, Tray, dan Coconut Fiber for Static Sources. Research was conducted in a semi-anechoic room using a method referring to the ISO 3745. The design used is the Hemisphere in which the source of noise is analogous to engines in an industry. The value reduction in the rate of sound power is obtained by comparing the sound power level before and after control is given. The noise control test materials used consist of layers of plywood, foam, fiber and tray (egg box). The effectiveness of these materials is tested by measuring the …

Ergonomic Analysis Of Garment Industry Using Posture Evaluation Index (Pei) In Virtual Environment, Erlinda Muslim, Boy Nurtjahyo, Romadhani Ardi

Makara Journal of Technology

Ergonomic Analysis of Garment Industry using Posture Evaluation Index (PEI) in Virtual Environment. This research tried to study, in a virtual environment, the ergonomics of four divisions in garment industry: cutting division, sewing division, button division, and finishing division. Variables that influence the working conditions in each division are different; depend on the real situations that happened. The purpose is to assess the real working conditions based on ergonomics study using Posture Evaluation Index (PEI). PEI integrates the scores of low back analysis (LBA), ovako working posture (OWAS), and rapid upper limb assessment (RULA). Analysis phase was done using digital …

Natural Gas As Petroleum Fuel Substitution: Analysis Of Supply-Demand Projections, Infrastructures, Investments And End-User Prices, Abdul Qoyum Tjandranegara, Arsegianto Arsegianto, Widodo Wahyu Purwanto

Makara Journal of Technology

The petroleum fuels (PF) subsidy has long burdens the government spending, and discourages less expensive energy usage such as natural gas (NG). Exporting NG and importing the more expensive PF products cause financial losses to Indonesia. The lack of NG infrastructure is the main hurdle in maximizing domestic NG usage and so does the perception of its high investment costs burdening government spending and pushing the NG transportation cost up. This study calculates the required NG infrastructure and its investments for several levels of PF substitutions up to 2030. To balance the NG demands, the supply from each field and …

An Investigation Into The Resistance/Powering And Seakeeping Characteristics Of River Catamaran And Trimarana, Murdijanto Murdijanto, I Ketut Aria Pria Utama, Andi Jamaluddin

Makara Journal of Technology

The increase of fuel price has caused fleet operational and shipping business to be in danger situation. The fuel consumption of a ship is influenced by ship volume or wetted area which contributes directly to the increase of ship resistance and the size of main engine. In order to find out the appropriate answers, a series of investigation into river transportation using monohull, catamaran and trimaran types of vessel was carried out. The work focused on the estimation of total resistance and powering as well as seakeeping characteristics and carried out experimentally using tank test and numerically using a ship …

Two-Class Classification With Various Characteristics Based On Kernel Principal Component Analysis And Support Vector Machines, Ivanna Kristianti Timotius, Iwan Setyawan, Andreas Ardian Febrianto

Makara Journal of Technology

Two class pattern classification problems appeared in many applications. In some applications, the characteristic of the members in a class is dissimilar. This paper proposed a classification system for this problem. The proposed system was developed based on the combination of kernel principal component analysis (KPCA) and support vector machines (SVMs). This system has been implemented in a two class face recognition problem. The average of the classification rate in this face image classification is 82.5%.

Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao

Journal of Electrochemistry

Mesoporous nickel oxide has been synthesized by calcining metal-organic coordination precursor.Transmission electron microscopy and BET test showed that the prepared NiO had a regular morphology and displayed a narrow size distribution.Electrochemical tests revealed that such mesoporous NiO had a specific capacity of 72 F·g^-1 at the current of 2.0 A·g^-1.Futhermore,the material showed excellent cycle-life stability.There was no degradation of capacitance after 1000 cycles.

Novel Anion Exchange Membranes Base On Copolymer Of 2-(Diethylamino) Ethyl Methacrylate And Fluoro-Polyacrylate For Alkaline Direct Methanol Fuel Cells, Yan-Mei Zhang, Jun Fang, Ge Yan, Yong-Ze Zhuang

Journal of Electrochemistry

Anion exchange membrane fuel cells,which use anion exchange membranes as polyelectrolytes,have attracted more and more research interests recently.In this work,a series of hydroxyl-conducting anion-exchange membranes based on the copolymer of 2-(Diethylamino)ethyl methacrylate and fluoro-polyacrylate were prepared by radical polymerization,and their potential applications in alkaline fuel cells were assessed.It was shown that the ionic conductivity of the membranes reached 10^-2 S·cm^-1 at room temperature,while the methanol permeability was lower than 10^-7 cm²·s^-1.The maximum power density of fuel cell assembled with this membrane was achieved to be 43.2 mW·cm^-2 at room temperature,indicating possible application …

A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi

Journal of Electrochemistry

Titanium-supported nanoporous palladium electrode(nanoPd /Ti) was prepared by a hydrothermal process in the presence of the ligand EDTA and using formaldehyde as reducing agent.SEM images showed that the size of Pd particles was about 60 nm and the Pd particles were connected with each other to form a three-dimensional network structure.Cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were applied to evaluate the electrocatalytic activity of the nanoPd/Ti electrode towards methanol oxidation in alkaline solution.CV results showed that the nanoPd /Ti electrode presented high anodic peak densities and a low onset potential for methanol oxidation.Also nanoPd /Ti electrode showed excellent CO tolerance …

Electrochemical Deposition Of Zinc Oxide Crystal Whiskers, Peng-Zeng Lu, Su Li, Jin-Qian Jia, Zhen-Hai Liang

Journal of Electrochemistry

Pine needle ZnO crystal whiskers were electrodeposited by anodization of zinc foil.The crystal whiskers were characterized by scanning electron microscopy(SEM) and X-ray diffraction(XRD) spectroscopy.The results show that the lengths and diameters of ZnO crystal whiskers are 200~300 nm and 20~50 nm,respectively,with the ratio of the length to diameter ranging from 10~15.The whiskers belong to wurtzite ZnO(JCPDS 36-1451) with good crystallinity and high purity.The crystalization behavior of ZnO was studied by cyclic voltammetry.The effects of the surface oxide layer at the zinc substrates and the [Zn(OH)₄]^2-concentration of the aqueous electrolyte on the formation of zinc oxide whiskers …

Electrocatalytic Oxidation Of Hydrazine At Rutin Carbon Nanotubes Modified Electrode, Hong-Fang Zhang, Qing-Lin Sheng, Jian-Bin Zheng

Journal of Electrochemistry

The electrochemical behavior and electrocatalytic oxidation of hydrazine on rutin multiwall carbon nanotubes modified glassy carbon electrode were studied by cyclic voltammetry.The experimental results indicated that the electrode exhibits good electrocatalytic activity to hydrazine at a reduced oxidation potential of 262 mV.The amperometric response of the modified electrode showed linear increase after successive addition of hydrazine in the concentration range of 2.5×10^-6~1.0×10^-4 mol·L-1 with a detection limit of 5×10^-7 mol·L^-1.

Electrooxidation Of Methanol On Multilayer Films Of Polypyrrole-Platinum Electrode, Ling Zhang, Long-Zhen Zheng

Journal of Electrochemistry

Multilayer films of polypyrrole-platinum electrode were fabricated by cyclic voltammetric technique.Electro-oxidation of methanol on this electrode was investigated with the aid of cyclic voltammetry and chronoamperometry.Results demonstrated that the multilayer of polypyrrole-platinum electrode behaved better electrocatalytic performance for electro-oxidaton of methanol and better poison resistant.Furthermore,with the increase of deposited platinum loadings,the rate controlling step on electro-oxidation reaction of methanol was changed from CO oxidation to sorption-desorption of hydrogen.

Electrochemical Investigation Of Chromium Nanocarbide Coated Ti-6al-4v And Co-Cr-Mo Alloy Substrates, Viswanathan Swaminathan, Haitong Zeng, Daniel Lawrynowicz, Zongtao Zhang, Jeremy L. Gilbert

Biomedical and Chemical Engineering - All Scholarship

This study investigated the electrochemical behavior of chromium nano-carbide cermet coating applied on Ti–6Al–4V and Co–Cr–Mo alloys for potential application as wear and corrosion resistant bearing surfaces. The cermet coating consisted of a highly heterogeneous combination of carbides embedded in a metal matrix. The main factors studied were the effect of substrate (Ti–6Al–4V vs. Co–Cr–Mo), solution conditions (physiological vs. 1 M H₂O₂ of pH 2), time of immersion (1 vs. 24 h) and post coating treatments (passivation and gamma sterilization). The coatings were produced with high velocity oxygen fuel (HVOF) thermal spray technique at atmospheric conditions to …

Modeling Diverse Physics Of Nanoparticle Self-Assembly In Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mathematics Faculty Publications

Presents physics behind dewetting of thin liquid films and mathematical/computational modeling tools (Educational/Research presentation for senior physics majors).

Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine

Mathematics Faculty Publications

The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.

Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu Tekalign, Margo Levine

Mathematics Faculty Publications

The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.

Reinforced Chitosan-Based Heart Valve Scaffold And Utility Of Bone Marrow-Derived Mesenchymal Stem Cells For Cardiovascular Tissue Engineering, Mohammad Z. Albanna

Wayne State University Dissertations

Recent research has demonstrated a strong correlation between the differentiation profile of mesenchymal stem cells (MSCs) and scaffold stiffness. Chitosan is being widely studied for tissue engineering applications due to its biocompatibility and biodegradability. However, its use in load-bearing applications is limited due to moderate to low mechanical properties. In this study, we investigated the effectiveness of a fiber reinforcement method for enhancing the mechanical properties of chitosan scaffolds. Chitosan fibers were fabricated using a solution extrusion and neutralization method and incorporated into porous chitosan scaffolds. The effects of different fiber/scaffold mass ratios, fiber mechanical properties and fiber lengths on …

Investigation On Water-Borne Intumescent Fire Protective Coatings For Steel., Yew Ming Chian

Student Works (2010-2019)

This research studies the efficiency of different water-borne intumescent formulations which incorporate chicken eggshell (CES) as a novel bio-filler, designed to protect steel in the event of a fire. The coating is based on these three flame-retardant additives: ammonium polyphosphate phase II, melamine and pentaerythritol (combination referred to as AMP). CES, silica fume (SF) and epoxy emulsion were incorporated either individually or in combination into the flame-retardant additives. The first part of the study develops and evaluates AMP, AMP+SF and AMP+SF+CES intumescent formulation systems, respectively. The best formulation produced was the AMP+SF+CES system which was subsequently selected for the next …

Solution Phase And Membrane Immobilized Iron-Based Free Radical Reactions: Fundamentals And Applications For Water Treatment, Scott Romak Lewis

University of Kentucky Doctoral Dissertations

Membrane-based separation processes have been used extensively for drinking water purification, wastewater treatment, and numerous other applications. Reactive membranes synthesized through functionalization of the membrane pores offer enhanced reactivity due to increased surface area at the polymer-solution interface and low diffusion limitations. Oxidative techniques utilizing free radicals have proven effective for both the destruction of toxic organics and non-environmental applications. Most previous work focuses on reactions in the homogeneous phase; however, the immobilization of reactants in membrane pores offers several advantages. The use of polyanions immobilized in a membrane or chelates in solution prevents ferric hydroxide precipitation at near-neutral pH, …

Understanding And Improving Lithium Ion Batteries Through Mathematical Modeling And Experiments, Rutooj D. Deshpande

Theses and Dissertations--Chemical and Materials Engineering

There is an intense, worldwide effort to develop durable lithium ion batteries with high energy and power densities for a wide range of applications, including electric and hybrid electric vehicles. For improvement of battery technology understanding the capacity fading mechanism in batteries is of utmost importance. Novel electrode material and improved electrode designs are needed for high energy- high power batteries with less capacity fading. Furthermore, for applications such as automotive applications, precise cycle-life prediction of batteries is necessary.

One of the critical challenges in advancing lithium ion battery technologies is fracture and decrepitation of the electrodes as a result …

New Media Icc Profiles Construction And Concerns, Reem El Asaleh

Dissertations

With the advent of the modern digital technology, users can now capture an image and reproduce it between different media, such as display it on LCD monitor or tablet computer, print it on desktop printer or send it to a printing press. The challenge has been then to maintain the accuracy of image colors during this reproduction, which has led to the development of Color Management Systems. Using these systems, the color reproduction across-media will be accomplished using device ICC profiles that describe each device’s color characterization data in a standardized format based on International Color Consortium (ICC) specifications.

ICC …

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …

Studies On Silicon Nmr Characterization And Kinetic Modeling Of The Structural Evolution Of Siloxane-Based Materials And Their Applications In Drug Delivery And Adsorption, Jyotrhirmai Ambati

University of Kentucky Doctoral Dissertations

This dissertation presents studies of the synthetic processes and applications of siloxane-based materials. Kinetic investigations of bridged organoalkoxysilanes that are precursors to organic-inorganic hybrid polysilsesquioxanes are a primary focus. Quick gelation despite extensive cyclization is found during the polymerization of bridged silane precursors except for silanes with certain short bridges. This work is an attempt to characterize and understand some of the distinct features of bridged silanes using experimental characterization, kinetic modeling and simulation. In addition to this, the dissertation shows how the properties of siloxane- materials can be engineered for drug delivery and adsorption.

The phase behavior of polymerizing …

Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen

Journal of Electrochemistry

The cathode materials of LiFePO₄ were prepared via a hydrothermal reduction method using FeCl₃ as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO₄ was obtained based on the test results of XRD and FTIR.Carbon-coated LiFePO₄ was synthesized by pyrolysisng glucose at high temperature.The morphologies of pure LiFePO₄ displayed cluster-like while the LiFePO₄/C displayed sphere-like particles.The electrochemical test showed that the LiFePO₄/C had good rate performance,while LiFePO₄ delivered much lower discharge capacity.

Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang

Journal of Electrochemistry

The PbO₂ anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO₂ films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF₄-increased PbO₂ electrodeposition rate;the prepared lead dioxide consisted of β-PbO₂;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe³⁺.The FB/F-Fe-PbO₂ electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO₂ crystals.