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Articles 331 - 360 of 1824

Full-Text Articles in Chemical Engineering

Algorithmic Methods For Developing The Structure Of A Thyristor Electric Drive For Mining Machines, N.R Yusupbekov, O.A. Jumaev, S.S. Turaev Feb 2023

Algorithmic Methods For Developing The Structure Of A Thyristor Electric Drive For Mining Machines, N.R Yusupbekov, O.A. Jumaev, S.S. Turaev

Chemical Technology, Control and Management

The article discusses the creation of algorithmic structures and the development of digital control systems for electric drives of mine-lifting machines, provides some concepts for creating digital control systems using thyristor converters. The analysis of the static volt-ampere characteristics of the thyristor is given, some calculations of the circuits and circuits of the thyristor converter (TP) corresponding to the different modes of operation of the TP are given, and also, based on the synthesis of the dynamic properties and characteristics of the thyristor, an algorithmic structure of the model of the thyristor converter is proposed.

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Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov Feb 2023

Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov

Chemical Technology, Control and Management

The article reveals the meaning and essence of the modeling method in the study of complex technological processes based on the problematic aspects of building multifactorial relationships and the principles for their elimination. In the case of non-linearity of multifactorial connections of a complex system, the expediency of approximating such functions by polynomials is substantiated. The authors' ideas about the increasing importance of interpolation methods in practice against the background of the possibility of simplification based on the use of modern mathematical hardware and software for integration into the process of modeling and optimizing technological processes due to the complexity …

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Structural Model Of The Technological Process Of Storage And Processing Of Oil Raw Materials, N.A Kabulov Feb 2023

Structural Model Of The Technological Process Of Storage And Processing Of Oil Raw Materials, N.A Kabulov

Chemical Technology, Control and Management

The technological method of storing and processing oilseed raw materials is structurally modelled in the article. Additionally, it is suggested that the generalized structure be presented as a three-part scheme, consisting of a raw material department, a processing shop, and transportation networks. On the basis of a thorough examination of the characteristics of the constituent parts of the technological complex, a practical model for the problem of the general characteristics of the technological complex is proposed.

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Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang Feb 2023

Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO2 …

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Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou Feb 2023

Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou

Journal of Electrochemistry

No abstract provided.

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Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li Feb 2023

Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li

Journal of Electrochemistry

Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li2O2 is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li2O2. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li2O2, …

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Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen Feb 2023

Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen

Journal of Electrochemistry

Electrolytic hydrogen production is heavily restricted by high-energy consumption majorly due to the relatively high potential of anodic oxygen evolution reaction (OER). Development of OER-alternative reaction at the anode has been recently proposed as a promising pathway to address the associated issues. In this work, we report a hybrid acid/alkali dual-electrolyte electrolyzer by coupling acidic hydrogen evolution reaction (HER) using commercial Pt/C cathode with alkaline Electrocatalytic glycerol oxidation (GOR) which is implemented by developing a nickel foam (NF) supporting Co3O4 nanosheets anode that shows low overpotential and high selectivity toward GOR for formate production. The hybrid acid/alkali …

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Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun Feb 2023

Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun

Journal of Electrochemistry

Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell, which has already attracted growing popularities. However, current methanol oxidation electrocatalysts fall far short of expectations and suffer from excessive use of noble metal, mediocre activity, and rapid decay. Here we report the Pt anchored on NiFe-LDHs surface hybrid for stable methanol oxidation in alkaline media. Based on the high intrinsic methanol oxidation activity of Pt nanoparticles, the substrates NiFe-LDHs further enhanced anti-poisoning ability and maintained unaffected stability after 200,000 s cycle test compared to commercial Pt/C catalyst. The …

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Supperlattice-Like Structure: Ordered Mass Transfer Endowing High Quality Output Of Fuel Cell, Jian Wang, Wen-Hui Xuan, Qian He, Jing-Xia Jiang, Yuan-Yuan Zhou, Yao Nie, Qiang Liao, Min-Hua Shao, Wei Ding, Zi-Dong Wei Jan 2023

Supperlattice-Like Structure: Ordered Mass Transfer Endowing High Quality Output Of Fuel Cell, Jian Wang, Wen-Hui Xuan, Qian He, Jing-Xia Jiang, Yuan-Yuan Zhou, Yao Nie, Qiang Liao, Min-Hua Shao, Wei Ding, Zi-Dong Wei

Journal of Electrochemistry

The current or voltage fluctuation in fuel cell operation is harmful to the fuel cell system and power application equipment. Here, we report a technique to eliminate such a fluctuation by the aid of new type of catalysts, superlattice-like mesoporous PtCo catalysts. The current fluctuation in fuel cells catalyzed by two invented catalysts are fixed at as low as 25 mA·cm−2 with a power of 0.75 W·cm−2 or 120 mA·cm−2 with a power of 1.01 W·cm−2, and no noticeable current decay was detected over 100 h. By contrast, a …

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Preface To Special Issue: Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou Jan 2023

Preface To Special Issue: Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou

Journal of Electrochemistry

No abstract provided.

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Recent Advances In Exploring Highly Active & Durable Pgm-Free Oxygen Reduction Catalysts, Yuan Li, Miao-Ying Chen, Bang-An Lu, Jia-Nan Zhang Jan 2023

Recent Advances In Exploring Highly Active & Durable Pgm-Free Oxygen Reduction Catalysts, Yuan Li, Miao-Ying Chen, Bang-An Lu, Jia-Nan Zhang

Journal of Electrochemistry

In order to reduce the considerable usage of expensive but scarce platinum at the cathode in proton exchange membrane fuel cells (PEMFCs), it is necessary to pursue alternatives to platinum. The most promising platinum group metal (PGM)-free catalysts for oxygen reduction reaction (ORR) are atomically dispersed, and nitrogen-coordinated metal site catalysts denoted as M-N-C (M = Fe, Co, or Mn, etc.). Over the last few decades, there have been great advances in these catalysts with high ORR activity and promising initial fuel cell performance approaching traditional Pt/C catalysts. However, the stability of these highly active Fe-N-C catalysts under practical fuel …

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Electrochemical Oxidation Of Ethylene On Palladium Electrode, Wei-Xing Wu, Ying Wang Jan 2023

Electrochemical Oxidation Of Ethylene On Palladium Electrode, Wei-Xing Wu, Ying Wang

Journal of Electrochemistry

The electrochemical oxidation of C2H4 is attracting increasing attention due to its vast potential market. The current electrochemical methods rely on the use of redox mediators, which may produce corrosive intermediates, while direct oxidation is still limited by its low activity and selectivity. Herein, we conducted electrochemical studies to obtain mechanistic insights into the benchmark Pd catalyst. The generated Pd(II) could be the active site for C2H4 oxidation. By designing the pulse sequence, we found the ratio of strongly and weakly adsorbed C2H4 on Pd to be 0.3:1. The result we …

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Influence Of Synthesis Conditions On The Physicochemical And Electrocatalytic Properties Of Non-Stoichiometric Ba2sr2la2ti4o12 Perovskites, Ofeliya Kostadinova, Iliyan Popov, Simeon M. Stankov, Hristo Kolev, Tamara Petkov Jan 2023

Influence Of Synthesis Conditions On The Physicochemical And Electrocatalytic Properties Of Non-Stoichiometric Ba2sr2la2ti4o12 Perovskites, Ofeliya Kostadinova, Iliyan Popov, Simeon M. Stankov, Hristo Kolev, Tamara Petkov

Karbala International Journal of Modern Science

Present work studies the influence of the pretreatment milling media (deionized water (BLTOS-H) and isopropanol (BLTOS-i)) on the surface characteristics, structure, chemical composition and catalytic activity of non-stoichiometric Ba2Sr2La2Ti4O12 perovskites. The IR spectroscopy and XRD analyses shows a difference in the structure and phase composition of the two materials. X-ray photoelectron spectroscopy detects a Ba2+- and La3+-enriched and Sr2+-depleted surface. The BLTOS-i sample appears to exhibit higher specific surface area (SSA) and pore volume in comparison to BLTOS-H. The electrochemical tests showed that BLTOS-H sample have similar behavior to platinum at current densi-ties up to 10 mA cm-2, while BLTOS-i …

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Evaluating The Impact Of Increased Cycling On Thermal Power Plants Due To Wind Energy Penetration In The Midwest: A Case Study, Joscelyne Larson Jan 2023

Evaluating The Impact Of Increased Cycling On Thermal Power Plants Due To Wind Energy Penetration In The Midwest: A Case Study, Joscelyne Larson

Electronic Theses and Dissertations

One of the most significant shifts in the mix of U.S. electricity generation over the past few years has been the rapid expansion of renewable energy resources, especially solar and wind. However, fossil fuels are still necessary to fulfill the world’s energy requirements. Despite efforts to increase the use of renewable energy sources, these sources can be at times unreliable, causing countries around the world to continue to rely on base load units such as coal and natural gas. This decrease in fossil fuels and increase in renewable energy sources presents many complex issues in terms of power system planning, …

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Running Shoe Pedometer, Benjamin Kasper Jan 2023

Running Shoe Pedometer, Benjamin Kasper

Williams Honors College, Honors Research Projects

Running shoe pedometer aims to solve the issue of worn out running shoes. It can be difficult to know just how many miles you have run in your shoes and when a new pair is needed. Running in old shoes and worn out shoes is heavily linked to injury. My proposed project is a device that is powered by the compressive forces on the shoes soles that counts the number of steps the wearer takes using a microcontroller. Then, when the shoe reaches milestone that indicate it has been used 75% 90% and 100% of its expected life, it will …

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Dynamic Modeling, Data Reconciliation, Parameter Estimation, And Health Monitoring Of A Supercritical Power Plant, Katherine Grace Hedrick Jan 2023

Dynamic Modeling, Data Reconciliation, Parameter Estimation, And Health Monitoring Of A Supercritical Power Plant, Katherine Grace Hedrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the introduction of a larger portion of renewable sources of power coming onto the U.S. power grid in recent decades, the operational strategy of coal-fired power plants has changed significantly to focus more on flexibility in response to the changing energy market. This has naturally led to different operational challenges. Many of these challenges are focused on the boilers within these plants, as they are producing more emissions and experiencing increased damage during load-following, which in turn leads to increased costs from penalties for not achieving emission standards or maintenance costs as boilers accumulate damage from the cycling behavior. …

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Lead Acid Battery Recycling In The Current Tanzania Industrialization Drive: Challenges And Opportunities, Divina D. Kaombe Dec 2022

Lead Acid Battery Recycling In The Current Tanzania Industrialization Drive: Challenges And Opportunities, Divina D. Kaombe

Tanzania Journal of Engineering and Technology (TJET)

ABSTRACT Advancements in automotive technologies, Information and Communications Technology and renewable energy technologies have increased the use of lead acid batteries as a source of portable and rechargeable energy. This has considerably increased the number of spent batteries with adverse effects on the environment and human health; which calls for recycling of spent batteries. This work was conducted to investigate challenges facing the formal business of recycling spent batteries and potential manufacturers of new lead-acid batteries in Tanzania. The work involved collection of information from key stakeholders such as collectors, dealers, Tanzania Revenue Authority and recyclers. It was found out …

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Performance Evaluation Of Udsm Network To Deliver Multimedia Elearning Contents: Case Of Coict, Mercy Mbise Dec 2022

Performance Evaluation Of Udsm Network To Deliver Multimedia Elearning Contents: Case Of Coict, Mercy Mbise

Tanzania Journal of Engineering and Technology (TJET)

The use of technology in education in Sub-Saharan Africa has been reported to be hindered by many factors including inadequate Information and Communication Technology (ICT) infrastructure, low internet speed, and lack of skills to use educational technologies. This paper aim at evaluating how the available ICT infrastructure at the College of Information and Communication Technologies (CoICT) can support, with acceptable Quality of Service (QoS), the delivery of multimedia applications for eLearning services. The evaluation was performed over a network testbed implemented in a computer laboratory for wired and wireless connections. The testbed consisted of five personal computers (PCs) connected via …

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Damage Stability Study Of A 500 Dw Ro-Ro Ferry Vessel, Zulfaidah Ariany, Budhi Santoso, Sarwoko Sarwoko, Nauval Abdurrahman Prasetyo Dec 2022

Damage Stability Study Of A 500 Dw Ro-Ro Ferry Vessel, Zulfaidah Ariany, Budhi Santoso, Sarwoko Sarwoko, Nauval Abdurrahman Prasetyo

Makara Journal of Technology

The development of the crossing transportation industry is currently increasing in the island areas. The use of Ro-Ro type ferry boats is extremely efficient in moving people, goods, and vehicles. The current research focuses on the damage stability of the 500 DWT Ro-Ro ferry, which aims to meet the needs of the Ro-Ro ferry in the archipelago area. The previously existing initial design of a barge hull with a main size Lpp = 40.15 m, B = 12 m, H = 3.2 m, and T = 2.15 m was used to analyze the damage stability condition further. First, the drawings …

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Application Of Distributed Fiber-Optic Sensing For Pressure Predictions And Multiphase Flow Characterization, Gerald Kelechi Ekechukwu Dec 2022

Application Of Distributed Fiber-Optic Sensing For Pressure Predictions And Multiphase Flow Characterization, Gerald Kelechi Ekechukwu

LSU Doctoral Dissertations

In the oil and gas industry, distributed fiber optics sensing (DFOS) has the potential to revolutionize well and reservoir surveillance applications. Using fiber optic sensors is becoming increasingly common because of its chemically passive and non-magnetic interference properties, the possibility of flexible installations that could be behind the casing, on the tubing, or run on wireline, as well as the potential for densely distributed measurements along the entire length of the fiber. The main objectives of my research are to develop and demonstrate novel signal processing and machine learning computational techniques and workflows on DFOS data for a variety of …

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Development Of Directed Randomization For Discussing A Minimal Security Architecture, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Akkarakaran Francis Leonard, Kip Nieman, Helen Durand, Katie Tyrrell, Katrina Hinzman, Michael Williamson Dec 2022

Development Of Directed Randomization For Discussing A Minimal Security Architecture, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Akkarakaran Francis Leonard, Kip Nieman, Helen Durand, Katie Tyrrell, Katrina Hinzman, Michael Williamson

Chemical Engineering and Materials Science Faculty Research Publications

Strategies for mitigating the impacts of cyberattacks on control systems using a control-oriented perspective have become of greater interest in recent years. Our group has contributed to this trend by developing several methods for detecting cyberattacks on process sensors, actuators, or both sensors and actuators simultaneously using an advanced optimization-based control strategy known as Lyapunov-based economic model predictive control (LEMPC). However, each technique comes with benefits and limitations, both with respect to one another and with respect to traditional information technology and computer science-type approaches to cybersecurity. An important question to ask, therefore, is what the goal should be of …

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Performance Comparison Of Several Control Algorithms For Tracking Control Of Pantograph Mechanism, Laylaa Mahmoud Eng, Mohamed Shamseldin Dr, Mohamed Sallam Dr, Abdelghany Mohamed Prof Nov 2022

Performance Comparison Of Several Control Algorithms For Tracking Control Of Pantograph Mechanism, Laylaa Mahmoud Eng, Mohamed Shamseldin Dr, Mohamed Sallam Dr, Abdelghany Mohamed Prof

Future Engineering Journal

A sort of parallel manipulator known as a pantograph robot mechanism was created primarily for industrial requests that required high precision and satisfied speed. While tracking a chosen trajectory profile requires a powerful controller. Because it has four active robot links and one robot passive link in place of just two links like the open chain does, it can carry more loads than the open chain robot mechanism while maintaining accuracy and stability. The calculated model for a closed chain pantograph robot mechanism presented in this paper takes into account the boundary conditions. For the purpose of simulating the dynamics …

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Relative Rate Observer Self-Tuning Of Fuzzy Pid Virtual Inertia Control For An Islanded Microgrid, Ahmed H. Mohamed, Helmy M. El Zoghby, Mohiy Bahgat, A. M. Abdel Ghany Nov 2022

Relative Rate Observer Self-Tuning Of Fuzzy Pid Virtual Inertia Control For An Islanded Microgrid, Ahmed H. Mohamed, Helmy M. El Zoghby, Mohiy Bahgat, A. M. Abdel Ghany

Future Engineering Journal

Expanding the usage of renewable energy in islanded microgrids leads to a reduction in its total inertia. Low inertia microgrids have difficulties in voltage and frequency control. That affected saving its stability and preventing a blackout. To improve low inertia islanded microgrids' dynamic response and save their stability, this paper presented relative rate observer self-tuning fuzzy PID (RROSTF-PID) based on virtual inertia control (VIC) for an islanded microgrid with a high renewable energy sources (RESs) contribution. RROSTF-PID based on VIC's success in showing remarkable improvement in the microgrid's dynamic response and enhancement of its stability. Moreover, it handles different contingency …

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Cybersecurity And Dynamic Operation In Practice: Equipment Impacts And Safety Guarantees, Kip Nieman, Dominic Messina, Matthew Wegener, Helen Durand Nov 2022

Cybersecurity And Dynamic Operation In Practice: Equipment Impacts And Safety Guarantees, Kip Nieman, Dominic Messina, Matthew Wegener, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Though dynamic operation of chemical processes has been extensively explored theoretically in contexts such as economic model predictive control or even considering the potential for cyberattacks on control systems creating non-standard operating policies, important practical questions remain regarding dynamic operation. In this work, we look at two of these with particular relevance to process safety: (1) evaluating dynamic operating policies with respect to process equipment fidelity and (2) evaluating procedures for determining the parameters of an advanced control law that can promote both dynamic operation as well as safety if appropriately designed. Regarding the first topic, we utilize computational fluid …

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Insight Into The Effects Of Cation Disorder And Surface Chemical Residues On The Initial Coulombic Efficiency Of Layered Oxide Cathode, Jin-Li Liu, Han-Feng Wu, Zhi-Bei Liu, Ying-Qiang Wu, Li Wang, Feng-Li Bei, Xiang-Ming He Nov 2022

Insight Into The Effects Of Cation Disorder And Surface Chemical Residues On The Initial Coulombic Efficiency Of Layered Oxide Cathode, Jin-Li Liu, Han-Feng Wu, Zhi-Bei Liu, Ying-Qiang Wu, Li Wang, Feng-Li Bei, Xiang-Ming He

Journal of Electrochemistry

Lithium layered oxide LiNi0.6Co0.2Mn0.2O2 (NCM622) is one of the most promising cathode materials in high-energy lithium-ion batteries for electric vehicles. However, one drawback for NCM622 is that its initial coulombic efficiency (ICE) is only about 87%, which is at least 6% lower than that of LiCoO2 or LiFePO4. In this work, we investigated the effects of surface chemical residues (e.g., LiOH and Li2CO3) and Li/Ni cation disorder resulted during the sintering on the ICE. We found that the ICE of the as-prepared samples could be boosted …

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Application Of The Core Shell Model For Strengthening Polymer Filament Interfaces, Yu-Chung Lin, Aniket Raut, Yiwei Fang, Yifan Yin, David Sprouster, Tai-De Li, Guillaume Freychet, Mikhail Zhernenkov, Steve Nitodas, Jonathan Sokolov, Yuval Shmueli, Miriam Rafailovich Oct 2022

Application Of The Core Shell Model For Strengthening Polymer Filament Interfaces, Yu-Chung Lin, Aniket Raut, Yiwei Fang, Yifan Yin, David Sprouster, Tai-De Li, Guillaume Freychet, Mikhail Zhernenkov, Steve Nitodas, Jonathan Sokolov, Yuval Shmueli, Miriam Rafailovich

Advanced Science Research Center

While surface segregation has been intensively studied in thin films, relatively little has been investigated in filament geometries. In contrast to thin films, the filament surface forms a continuum, with interactions both at the free air and internal filament interface, which makes it difficult to achieve an equilibrium configuration. This asymmetry has become particularly apparent with the increasing use of additive manufacturing where entire structures are constructed via layered deposition of filamentous layers from a moving thermal nozzle. In addition, this process is highly non-equilibrated with poor thermal retention and is responsible for insufficient filament–filament interfacial fusion and internal pore …

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Electrochemical Syntheses Of Nanomaterials And Small Molecules For Electrolytic Hydrogen Production, Jia-Qi Wei, Xiao-Dong Chen, Shu-Zhou Li Oct 2022

Electrochemical Syntheses Of Nanomaterials And Small Molecules For Electrolytic Hydrogen Production, Jia-Qi Wei, Xiao-Dong Chen, Shu-Zhou Li

Journal of Electrochemistry

Hydrogen is a clean, efficient, renewable energy resource and the most promising alternative to fossil fuels for future carbon-neutral energy supply. Therefore, sustainable hydrogen production is highly attractive and urgently demanded, especially via water electrolysis that has clean, abundant precursors and zero emission. However, current water electrolysis is hindered by the sluggish kinetics and low cost/energy efficiency of both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). In this regard, electrochemical synthesis offers prospects to raise the efficiency and benefit of water electrolysis by fabricating advanced electrocatalysts and providing more efficient/value-adding co-electrolysis alternatives. It is an eco-friendly and facile …

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Catalytic Effect Of Disordered Ru-O Configurations For Electrochemical Hydrogen Evolution, Xue Sun, Ya-Jie Song, Ren-Long Li, Jia-Jun Wang Oct 2022

Catalytic Effect Of Disordered Ru-O Configurations For Electrochemical Hydrogen Evolution, Xue Sun, Ya-Jie Song, Ren-Long Li, Jia-Jun Wang

Journal of Electrochemistry

Phase engineering is considered as an effective method for modulating the electronic structure and catalytic activity of catalysts. The disordered conformation of amorphous materials allows flexible reforming of the surface electronic structure, showing their attractiveness as catalysts for hydrogen evolution reaction (HER). Herein, we designed and developed an amorphous ruthenium dioxide (a-RuO2) catalyst with a disordered Ru-O configuration. The conformational relationship between Ru-O ordering and HER performance is established by combining advanced electron microscopic techniques with detailed electrochemical tests. Specifically, the disordered Ru-O coordination significantly enhanced the HER catalytic activity in both acidic and alkaline media, ultimately leading …

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A Self-Supported Ru-Cu3P Catalyst Toward Alkaline Hydrogen Evolution, Zi-Xuan Wan, Chao-Hui Wang, Xiong-Wu Kang Oct 2022

A Self-Supported Ru-Cu3P Catalyst Toward Alkaline Hydrogen Evolution, Zi-Xuan Wan, Chao-Hui Wang, Xiong-Wu Kang

Journal of Electrochemistry

Transition metal phosphide (TMP) is a kind of effective catalysts toward hydrogen evolution reaction (HER) in alkaline electrolytes. However, the performance of TMP catalysts is strongly limited by water splitting. In this work, we developed a method to prepare a copper foam (CF) supported Ru-doped Cu3P catalyst (Ru-Cu3P/CF) by a consecutive growth of Cu(OH)2 nanoarrays, soaking in RuCl3 solution and phosphorization. A large surface area was obtained by the self-supported catalysts with the appropriative Ru doping. As an excellent HER catalyst, it exhibited a low overpotential of 95.6 mV at a current density of …

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Alkaline Water Electrolysis For Efficient Hydrogen Production, Wen-Fu Xie, Ming-Fei Shao Oct 2022

Alkaline Water Electrolysis For Efficient Hydrogen Production, Wen-Fu Xie, Ming-Fei Shao

Journal of Electrochemistry

Hydrogen production from water electrolysis is a sustainable and environmentally benign strategy in comparison with fossil fuel-based hydrogen. However, this promising technique suffers from the high energy consumption and unsatisfactory cost due to the sluggish kinetics of both half reaction and inferior stability of electrocatalysts. To address this challenge, herein, we present a timely and comprehensive review on advances in alkaline water electrolysis that is already commercialized for large scale hydrogen production. The design principles and strategies with aiming to promote the performance of hydrogen generation are discussed from the view of electrocatalyst, electrode, reaction and system. The challenges and …

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