Chemical Engineering Commons^™

Thermal And -Γ –Ray Irradiation Effects On The Ionic Conductivity Of (Licl)X(Montmorillonite)1-X, Safei Purnama, Aziz Khan Jahja, Takeshi Sakuma

Makara Journal of Technology

Compositesof montmorillonite (MMT) - lithium salts have been prepared using a simple process of powders mixing followed by heating. The powders resulting from this method are expected to beionic conductors with a high ionic conductivity characteristics. This characteristics is also further improved by employing gamma-ray irradiation technique at specified irradiation doses. The best results were obtained for the (LiCl)0.5(MMT)0.5 composite with a room temperature ionic conductivity of 2.192 mS/cm, which then increases to ~5 mS/cm after gamma irradiation at a dose of 400 kGy. This value is equivalent to the value of the ionic conductivity of current commercial rechargeable lithium …

Design Of The Human Assembly Strategy In A Self-Optimizing Assembly Cell: A Case Study Of Indonesians, Novie Susanto, Ratna Purwaningsih, Kharisma Panca Kurniawati

Makara Journal of Technology

This paper presents a continuing study of the human cognitive aspect application in the technical systems. The last studies design a human-centered design based on the German culture. The result shows a significant difference of human performance between Germans and Indonesians. Therefore, this study examines the human cognitive model based on Indonesian culture to investigate whether the different cognitive model based on the culture aspect can improve the human performance. The study was conducted on 60 people classified by age, young (16-34 years old) and old (older than 34 years old). Participants render predictions on an assembly activity for two …

Expression And The Functional Study Of Fusion Proteins Α-Amylase And Hemolysin- Αas An Application In Biofilm Polysaccharide Degradation, Gede Yuda Sugiarta, Anggoro Wiseso, Siska Yuliana Sari, Etri Dian Kamila, Vanessa Geraldine, Diana Christina, Muhammad Hanifi, Dwiantari Satyapertiwi, Robby Hertanto, Budiman Bela, Masafumi Yohda, Muhamad Sahlan

Makara Journal of Technology

Biofilm is an aggregate of consortium bacteria that adhere to each other on a surface. It is usually protected by the exopolysaccharide layer. Various invasive medical procedures, such as catheterization, endotracheal tube installation, and contact lens utilization, are vulnerable to biofilm infection. The National Institute of Health (NIH) estimates 65% of all microbial infections are caused by biofilm. Periplasmic α-amylase (MalS) is an enzyme that hydrolyzes α-1, 4- glicosidic bond in glycogen, starch, and others related polysaccharides in periplasmic space. Another protein called hemolysin-α (HlyA) is a secretion signal protein on C terminal of particular peptide in gram negative bacteria. …

Chlorpyrifos Removal For Wastewater Reuse, Indran Kamalanathan

Chemical Engineering Undergraduate Honors Theses

Approximately 1.2 billion people around the world live in areas of physical water scarcity. This could increase to half of the world’s population by 2030 and could displace 24 to 700 million people unless steps are taken to ensure adequate water supply.¹ Water scarcity is an escalating issue within the United States, specifically in Western inland states with arid climates. This scarcity is encouraging communities to investigate tertiary level municipal wastewater treatment, allowing for reuse of wastewater. Unfortunately, wastewater contains numerous contaminants that are not regulated by the Environmental Protection Agency (EPA) under the Safe Drinking Water Act (SDWA). …

Determination Of Aqueous Surfactant Solution Surface Tensions With A Surface Tensiometer, Remelisa Esteves, Birce Dikici Ph.D, Matthew Lehman, Qayyum Mazumder, Nonso Onukwuba

Beyond: Undergraduate Research Journal

Surfactant solutions are applicable to engineering systems for cooling equipment for electronics. Surfactants can be added to water to improve heat transfer. An application of using aqueous surfactant solutions can be through microchannel heat sink. Although it is ideal to redesign these systems to reduce heat, it is a costly method. Surfactant solutions at optimal solution concentration can be able to transfer heat quickly and effectively with minimum expense. The surface tension of surfactant solutions is an important parameter for boiling heat transfer and must be taken into consideration. The purpose of this research is to measure surface tension of …

Determination Of Surfactant Solution Viscosities With A Rotational Viscometer, Remelisa Esteves, Nonso Onukwuba, Birce Dikici Ph.D

Beyond: Undergraduate Research Journal

Aqueous surfactant solutions are used in engineering systems for improving boiling heat transfer. The purpose of this research is to determine the viscosities of surfactant solutions and to investigate the effect of composition on viscosity. The results obtained can possibly be used as reference for further study in the effects of surfactant solution viscosities on nucleate boiling. A rotational viscometer was used to determine the viscosities of three surfactant solutions – SLS, EH-14, and SA-9 – of various compositions at room temperature. It was discovered that the viscosities of SLS, EH-14, and SA-9 had a nearly consistent pattern as their …

Study Of Poisoning Mechanism Of Hg And As On V2o5–Wo3/Tio2 Scr De-Nox Catalysts, Qingcai Liu, Ming Kong, Lu Yao, Shan Ren, Jian Yang

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Nanostructured Thin Film Synthesis By Aerosol Chemical Vapor Deposition For Energy Storage Applications, Tandeep Singh Chadha

McKelvey School of Engineering Graduate Student Theses & Dissertations

Renewable energy sources offer a viable solution to the growing energy demand while mitigating concerns for greenhouse gas emissions and climate change. This has led to a tremendous momentum towards solar and wind-based energy harvesting technologies driving efficiencies higher and costs lower. However, the intermittent nature of these energy sources necessitates energy storage technologies, which remain the Achilles heel in meeting the renewable energy goals. This dissertation focusses on two approaches for addressing the needs of energy storage: first, targeting direct solar to fuel conversion via photoelectrochemical water-splitting and second, improving the performance of current rechargeable batteries by developing new …

Nanoparticle Formation In The Flame Synthesis Of Multicomponent Nanostructured Materials For Clean Energy Applications, Jiaxi Fang

McKelvey School of Engineering Graduate Student Theses & Dissertations

This dissertation studies the initial stages of particle formation during the combustion synthesis of multicomponent nanomaterials. Combustion is commonly used for the production of nanomaterials at industrial scales and has advantages of high production rates, low waste generation, and scalability. However, there are limitations in being able to apply this synthesis approach to more advanced multicomponent systems. Gas to particle conversion in flames occurs through precursor decomposition, collisional growth, coagulation, condensation, and sintering. There is a fundamental gap in knowledge on the initial stages of particle formation in flames below 2nm due to measurement difficulties and instrumentation limitations. Using a …

Crumpled Graphene Oxide: Aerosol Synthesis And Environmental Applications, Yi Jiang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Environmental technologies, such as for water treatment, have advanced significantly due to the rapid expansion and application of nanoscale material science and engineering. In particular, two-dimensional graphene oxide (GO), has demonstrated considerable potential for advancing and even revolutionizing some of these technologies, such as engineered photocatalysts and membranes. To realize such potential, an industrially scalable process is needed to produce monomeric and aggregation-resistant GO nanostructures/composites, in addition to new knowledge of material properties, behavior, and performance within an environmental context.

Research presented in this thesis addresses both scientific and engineering gaps through the development of a simple, yet robust aerosol-based …

Sugarcane Bagasse As A Carrier For The Immobilization Of Saccharomyces Cerevisiaein Bioethanol Production, Sita Heris Anita, Wibowo Mangunwardoyo, Yopi Yopi

Makara Journal of Technology

Sugarcane bagasse was used as a carrier to immobilize Saccharomyces cerevisiae in bioethanol production. This research aims to study the potential use of sugarcane bagasse as an alternative carrier for cell immobilization and improvement in the production process of cell immobilization in bagasse. The results showed that the physical characteristics of sugarcane bagasse as a carrier were water content (7.77 ± 0.35%), water retention (4.80 ± 0.44 g/g), water absorption index (8.58 ± 0.22 g/g), and lignin content (24.40 ± 1.52 %). Determination of cell retention was performed in an inoculum volume of 50 mL yeast suspension with various carrier …

Study On Oil Palm Fresh Fruit Bunch Bruise In Harvesting And Transportation To Quality, Andreas Wahyu Krisdiarto, Lilik Sutiarso

Makara Journal of Technology

There are losses of production due to oil palm field’s material handling. Activities that may raise the losses are harvesting and transportation, which may cause bruise and damage to fruit. This research was aimed to learn the bruise of fresh fruit bunch (FFB) phenomenon in harvesting and transportation. Method used in this research was measuring the bruise area resulted by FFB falling when harvested, loading (throwing up) FFB to truck bin, and transporting using truck. These data, coupled with weight of bruised fruit, were calculated to get FFB bruise index. Each FFB bruise index is related to potential free fatty …

Automatic Arrhythmia Beat Detection: Algorithm, System, And Implementation, Wisnu Jatmiko, I Md. Agus Setiawan, Muhammad Ali Akbar, Muhammad Eka Suryana, Yulistiyan Wardhana, Muhammad Febrian Rachmadi

Makara Journal of Technology

Cardiac disease is one of the major causes of death in the world. Early diagnose of the symptoms depends on abnormality on heart beat pattern, known as Arrhythmia. A novel fuzzy neuro generalized learning vector quantization for automatic Arrhythmia heart beat classification is proposed. The algorithm is an extension from the GLVQ algorithm that employs a fuzzy logic concept as the discriminant function in order to develop a robust algorithm and improve the classification performance. The algorithm is tested against MIT-BIH arrhythmia database to measure the performance. Based on the experiment result, FN-GLVQ is able to increase the accuracy of …

Optimization Of Electricity Generation Schemes In The Java-Bali Grid System With Co2 Reduction Consideration, Farizal Farizal, Wenty Eka Septia, Amar Rachman, Nasruddin Nasruddin, Teuku Meurah Indra Mahlia

Makara Journal of Technology

This research considers the problem of reducing CO2 emissions from the Java-Bali power grid system that consists of a variety of power-generating plants: coal-fired, natural gas, oil, and renewable energy (PV, geothermal, hydroelectric, wind, and landfill gas). The problem is formulated as linear programming and solved using LINGO 10. The model was developed for a nation to meet a specified CO2 emission target. Two carbon dioxide mitigation options are considered in this study, i.e. fuel balancing and fuel switching. In order to reduce the CO2 emissions by 26% in 2021, State Electric Supply Company (PLN) has to generate up to …

The Knowledge-Based Analysis On Medium Resolution Images Of Remote Sensing To Extraction Information Land Use Type Scs-Cn, The Case Study On Grompol Watershed, Puguh Dwi Raharjo, Totok Gunawan, Mohammad Pramono Hadi

Makara Journal of Technology

Remote sensing imagery Landsat-8 is one image that has a good temporal resolution; in addition to the availability of data, this image can be obtained free of charge. Land cover type SCS-CN is part of a unit of land that affects runoff. The use of medium resolution imagery in reducing the SCS-CN land use type is considered relatively difficult, and it yields less good accuracy. Limitations on multispectral classification only rely on facts derived from spectral reflection, so that the two data are the same since different characteristic results are not so good. This study aims to determine the accuracy …

The Effect Of Irradiation Of Fe And Ar Ion On The Surface Morphology Of Diamond Thin Film Related To The Magnetoresistance Property, Salim Mustofa, Setyo Purwanto, Kenji Mishima

Makara Journal of Technology

The irradiation of Fe and Ar ion was applied on the surface of diamond/Si thin film to know its effect on the morphology of thin film.The magnetoresistance property was also studied. Ion irradiation treatment using Fe ion followed by argon ion at the energy of 70keV and a dose of 1 x 1015 ion/cm2 have been conducted on the surface of two types of thin film, diamond/Si (111) and diamond/Si (100). Both thin films were made by using a CVD method, and the thickness of the thin film is 1000-nm. From simulations using the software called Stopping and Range of …

Use Of Green Mussel Shell As A Desulfurizer In The Blending Of Low Rank Coal-Biomass Briquette Combustion, Mahidin Mahidin, Asri Gani, M. Reza Hani, Muhammad Syukur, Hamdani Hamdani, Khairil Khairil, Samsul Rizal, Abdul Hadi, T.M.I. Mahlia

Makara Journal of Technology

Calcium oxide-based material is available abundantly and naturally. A potential resource of that material comes from marine mollusk shell such as clams, scallops, mussels, oysters, winkles and nerites. The CaO-based material has exhibited a good performance as the desulfurizer or adsorbent in coal combustion in order to reduce SO2 emission. In this study, pulverized green mussel shell, without calcination, was utilized as the desulfurizer in the briquette produced from a mixture of low rank coal and palm kernel shell (PKS), also known as bio-briquette. The ratio of coal to PKS in the briquette was 90:10 (wt/wt). The influence of green …

Apparent Porosity And Compressive Strength Of Heat-Treated Clay/Iron Sand/Rice Husk Ash Composites Over A Range Of Sintering Temperatures, M. Nizar Machmud, Zulkarnain Jalil, Mochammad Afifuddin

Makara Journal of Technology

Novel composites of clay/iron sand/rice husk ash (RHA) have been developed. Electric furnace was used to perform heat treatment on the composites to study the effect of sintering temperature on their apparent porosity and compressive strength. Two types of RHA with different bulk density were prepared to gain an understanding of the influence of apparent porosity on compressive strength of the heat-treated composites over a range of sintering temperatures. Heattreated composites, made of clay/iron sand and clay/RHA, were also prepared as a referenced material. X-ray diffraction (XRD) analysis was further performed to comprehensively discuss the role of iron sand on …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

Influence Of Socio-Demography And Operating Streetscape On Last-Mile Mode Choice, M. Meng, P. P. Koh, Y. D. Wong

Journal of Public Transportation

This study investigated how personal and operational factors (travel distance and streetscape) influence traveler mode choice decisions for the last-mile home-bound trip stage from rail transit stations. Personal factors include the socio-demography of travelers, and attributes of the streetscape include the built environment (degree of areal development), prevalence of cycling, availability of short-range transport modes, and walking/cycling infrastructure. Interviewers randomly intercepted pedestrians to administer a mode choice survey at five rail transit station exits and engaged all available cyclists at bicycle parking areas in the vicinity of stations in Singapore. A multimodal logit regression model revealed a significant relationship between …

Modeling, Simulation, And Analysis Of Lithium-Ion Batteries For Grid-Scale Applications, Matthew Thomas Lawder

McKelvey School of Engineering Graduate Student Theses & Dissertations

Lithium-ion batteries have become universally present in daily life, being used across a wide range of portable consumer electronics. These batteries are advantageous compared to other forms of energy storage due to their high energy density and long cycle life. These characteristics make lithium-ion batteries advantageous for many new and developing applications that require large scale energy storage such as electric vehicles and the utility grid. Typical uses for lithium-ion batteries require consistent cycling patterns that are predictable and easy to approximate across all uses, but new large scale applications will have much more dynamic demands. The cycling patterns for …

Nanofiltration Rejection Of Contaminants Of Emerging Concern From Municipal Water Resource Recovery Facility Secondary Effluents For Potable Reuse Applications, Steven Michael Jones

Graduate Theses and Dissertations

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient and the upcycling of contaminants of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place.

There are no federal Safe Drinking Water Act (SDWA) regulations in place specifically for direct potable reuse (DPR) of WRRF effluent. Out of necessity, some states are developing their own DPR reuse regulations. Currently, reverse osmosis (RO) is the default full advanced treatment (FAT) …

Removal Of Endocrine Disrupting Compounds From Secondary Municipal Wastewater, Dustin R. Resz

Chemical Engineering Undergraduate Honors Theses

Approximately 1.2 billion people around the world live in areas of physical water scarcity. This could increase to half of the world’s population by 2030 and could displace 24 to 700 million people unless steps are taken to ensure adequate water supply.1 Water scarcity is an escalating issue within the United States, specifically in Western inland states with arid climates. This scarcity is encouraging communities to investigate tertiary level municipal wastewater treatment, allowing for reuse of wastewater. Unfortunately, wastewater contains numerous contaminants that are not regulated by the Environmental Protection Agency (EPA) under the Safe Drinking Water Act (SDWA). Many …

Werc Task #1 - Efficiency And Particulate Matter Emissions Testing Of Wood Burning Heating Units, Jonathan A. Shumaker

Chemical Engineering Undergraduate Honors Theses

A design of a method for calculating the efficiency and particulate matter emission rates was developed for use on wood stoves. The project was completed for the WERC competition which is an international design contest. The prevalence of wood burning as a form of heating, current EPA regulations, and current market conditions were major factors in forming the necessity of this testing method. Design was not limited to outlining the design specifications, the apparatus was built and run. Optimization of the method continued until completion of the project. If the method would continue to be improved then it would be …

Optimizing Chemical & Rheological Properties Of Rejuvenated Bitumen, Dominic Nguyen, Hamzeh Haghshenas Fatmehsari, Santosh Kommidi, Yong-Rak Kim

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Bitumen has long been a material used in the construction of roadways, yet new pavement only consists of low fractions of recycled materials due to poor compatibility of aged bitumen and new materials. Thus, rejuvenators, chemical additives, have been used in an attempt to re-balance the chemical composition and restore the physical properties of aged bitumen back to its virgin state. A fundamental understanding of how one particular rejuvenator, soybean oil, revitalizes bitumen was investigated using a multi-scale approach.

Fourier-transform infrared spectroscopy (FTIR) was used to determine the changes in chemical properties of pure and rejuvenated virgin and aged samples. …

Thermal Properties, Crystallinity, And Oxygen Permeability Of Na-Montmorillonite Reinforced Plasticized Poly(Lactic Acid) Film, Kurniawan Yuniarto, Yohanes Aris Purwanto, Setyo Purwanto, Bruce A. Welt, Hadi Karia Purwadaria, Titi Candra Sunarti

Makara Journal of Technology

Introducing unmodified organically clay/Na-montmorillonite (Na-MMT) was applied into plasticized poly(lactic acid) PLA to produce film composites by direct casting. Film composite structure, the crystallinity degree and form, and thermal properties were carried out using X-ray diffraction and differential scanning calorimetry. The effect of Na- MMT to the tortuous path and the crystallinity degree in the plasticized film composites were calculated in oxygen barrier properties. Chromatogram film composites resulted in an intercalated structure that showed peak diffraction angle shift at about 0.2o. Then, a peak diffraction pattern was indicated in α-form crystal structure. Plasticized PLA has a crystallinity degree at 34%, …

Residual Strength Analysisof Asymmetrically Damaged Ship Hull Girderusing Beam Finite Element Method, Muhammad Zubair Muis Alie

Makara Journal of Technology

The objective of the present study is to analyze the residual strength of asymmetrically damaged ship hull girder under longitudinal bending. Beam Finite Element Method is used for the assessment of the residual strength of two single hull bulk carriers (Ship B1 and Ship B4) and a three-cargo-hold model of a single-side Panamax Bulk Carrier in hogging and sagging conditions. The Smith’s method is adopted and implemented into Beam Finite Element Method. An efficient solution procedure is applied; i.e. by assuming the cross section remains plane, the vertical bending moment is applied to the cross section and three-cargo-hold model. As …

Discrete Power Control In Heterogenous Networks, Yuanyuan Wang, Wibowo Hardjawana, Branka Vucetic

Makara Journal of Technology

In heterogeneous networks (HetNets) where femtocell base stations (FBSs) are deployed within the radio coverage of macrocell base stations (MBSs) to increase network capacity, co-channel interference limits overall system performance with universal frequency reuse. This paper investigates new distributed downlink discrete power control scheme for FBSs in HetNets with FBSs cooperation. The objective of the proposed power control scheme is to maximize the number of simultaneous FBSs transmissions in a single transmission wireless channel where each FBS is allowed to transmit only if the signal-to-interference-noise ratio (SINR) requirements for both FBSs and MBS users are satisfied. We apply a stochastic …

Multi-Project Scheduling Cost Optimization In A Machine Manufacturer Engineer-To-Order, Farizal Farizal, Amar Rachman, Tifani Tandean, Sumarsono Sudarto, Katsuhiko Takahashi

Makara Journal of Technology

This paper discusses the utilization of mixed integer linear programming (MILP) model to optimize cost for multiproject scheduling in a machine maker company. The objective is to minimize total project’s penalty cost and labor cost. The model formulated shows how to achieve the objective i.e. whether to use outsourcing or overtime to finish all projects. The model of multi-project scheduling was solved by Branch & Bound algorithm coded in Lingo 14.0 software. The case study shows that if a company wants to minimize lateness, it should use overtime instead of outsourcing, which minimize total lateness of projects by 144 days …

Analysis Of Arm Movement Prediction By Using The Electroencephalography Signal, Reza Darmakusuma, Ary Setijadi Prihatmanto, Adi Indrayanto, Tati Latifah Mengko, Lidwina Ayu Andarini, Achmad Furqon Idrus

Makara Journal of Technology

Various technological approaches have been developed in order to help those people who are unfortunate enough to be afflicted with different types of paralysis which limit them in performing their daily life activities independently. One of the proposed technologies is the Brain-Computer Interface (BCI). The BCI system uses electroencephalography (EEG) which is generated by the subject’s mental activity as input, and converts it into commands. Some previous experiments have shown the capability of the BCI system to predict the movement intention before the actual movement is onset. Thus research has predicted the movement by discriminating between data in the “rest” …