Chemical Engineering Commons^™

Experimental Evaluation Of Three Different Humidity Conditions To Physical And Mechanical Properties Of Three Different Mixtures Of Unfired Soil Bricks, Heru Purnomo, Srikandi Wahyu Arini

Makara Journal of Technology

Unfired brick is considered as a more environmentally friendly material than fired brick. It has lower mechanical properties than that of fired brick where humidity influences both bricks. Physical and mechanical properties of unfired bricks made of three kinds of mixtures were studied experimentally under three humidity conditions. The first kind of unfired brick was made only with soil and water while the second type was made of a mixture of soil, water and lime, and the third type was a mixture of soil, water, lime and uniform treated coir where 4% of lime mass was substituted with coir mass. …

Influence Of Tempering And Cryogenic Treatment On Retained Austenite And Residual Stresses In Carbonitrided 18crnimo7-6 Low Alloy Steel, Richard Katemi

Tanzania Journal of Engineering and Technology (TJET)

This work investigated the influence of tempering conditions coupled with cryogenic treatment on thermal stabilization of retained austenite and residual stress distributions in carbonitrided 18CrNiMo76 low alloy steel samples. The carbonitriding conditions were set to enable attaining surface carbon and nitrogen content of 0.87 and 0.34 mass.-percent respectively. After carbonitriding, some of the samples were subjected to varying tempering conditions followed by cryogenic treatment at-120 °C using nitrogen gas. Analysis of both retained austenite and residual stresses was conducted using X-ray diffraction. In the as-quenched state, carbonitrided samples contained 52 mass.-percent. Samples that were directly subjected to the cryogenic treatment …

Biomethane Production From Distillery Wastewater, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Distillery wastewater treatment is a great ecological problem, for example, India produces 2.7 billion liters of alcohol that results in 40 billion liters of wastewater. However, this material can be seen as a resource since 11 million cubic meters of biogas at 60% methane could be produced in addition to cleaning the water. The distillery has two options of what to do with the biogas. The first is to use the biogas to fuel the distillery making the production plant more energy efficient and removing some of the need to buy natural gas. The other is to upgrade the biogas …

Electrochemically Reactive Membranes For Efficient Biomass Recovery, Pollutant Degradation And Commercialization, Likun Hua

Dissertations

Micropollution in natural waters such as rivers and groundwater aquifers is a widespread problem that prevents these potentially potable sources from being used as drinking water. In the United States, approximately two-thirds of the over 1,200 most serious hazardous waste sites in the nation are contaminated with trichloroethylene (TCE), a potentially carcinogenic compound. Other emerging and environmentally persistent organic micropollutants include polyromantic hydrocarbons (PAHs), organophosphate flame retardants, endocrine disrupting compounds (EDCs), pesticides, herbicides, pharmaceuticals and personal care products (PPCPs). Membrane filtration is one of the most efficient separation processes widely used for water treatment and pollutant removal. However, traditional membrane …

How Moisture Content Levels And Packing Density In Soil Affect Crude Oil Spreads, Shaylin N. Williams

Venture: The University of Mississippi Undergraduate Research Journal

Crude oil spills are one of the most destructive disasters that can occur, and they are extremely difficult to recover from. Many studies focus on what can be done to clean these crude oil spills, but more research should be focused on means of prevention. Currently, very little is known about how the moisture content levels and the packing efficiency of soil can affect an oil spill. These two factors alone can offer a variety of information to environmental agencies, manufacturers, and refineries. Through utilization of a chemical engineering lab, a recording mechanism, and ImagePro software, data was collected and …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Molecularly Conductive Behavior Of Blended Polymer Electrolyte-Based Cmc/Pva, Noor Saadiah Mohd Ali, Dishen Zhang, Yuki Nagao, Ahmad Salihin Samsudin

Makara Journal of Technology

This study investigated the electrical conduction and structural behavior of blended polymer electrolyte (BPE)-based carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) in the development of solid-state electrochemical devices. Based on impedance spectroscopy and correlating Fourier transform infrared (FTIR) with thermogravimetric analysis, a framework was proposed to explain the structural enhancement of the BPE system. As revealed by FTIR, the optimum conductivity of CMC/PVA BPEs was 9.21 × 10−6 Scm−1 for 80:20 composition attributed to the intermolecular attraction between the polymers. Thermal stability of the CMC/PVA was influenced by the formation of a hydrogen bond between the hydroxyl (-OH), carboxylate (-COO-), …

Multistage Sonication Effect On The Composition And Properties Of Degraded Chitosan Product, Nurul Laili Arifin, Emma Savitri, Anjar Indah, Fesa Putra, Sumarno Sumarno

Makara Journal of Technology

The sonication method randomly breaks polymer chains to produce a varied distribution of products. A scheme with multi-stage sonication steps is proposed to identify oligomers and low molecular weight chitosan based on changes to the degrad-ed product. For each sonication level, 1% (w/v) chitosan in 1% (v/v) aqueous acetic acid was sonicated for 120 min at 60 °C. The products of the sonication treatment were deprotonized by adding an alkali solution, freeze dried and insoluble product re-sonicated until a low molecular weight was produced. Low molecular weight chitosan/insoluble products were character-ized with Fourier-transform infrared spectra (FT-IR) and X-ray diffraction (XRD) …

Study Of Zno Nanospheres Fabricated Via Thermal Evaporation For Solar Cell Application, Fatin Farisha Alia Azmi, Bouchta Sahraoui, Saifful Kamaluddin Muzakir

Makara Journal of Technology

A solar cell is a device that absorbs light energy to generate electrical energy. A typical example of a solar cell is the quantum dot solar cell (QDSC), which consists of three main components: (i) fluorophore: the component that absorbs light and generates excited state electrons and holes, (ii) photoelectrode: the component that transports the excited state electron and prevents recombination of excited state electrons and holes, and (iii) electrolyte: the component that re-plenishes the vacancy left by the excited electron in the hole. Despite the increasing number of research in the QDSC field, to date, a device with significant …

Electrical Properties Of A Novel Solid Biopolymer Electrolyte Based On Algi-Nate Incorporated With Citric Acid, Ahmad Faizrin Ahmad Fuzlin, Noor Syahida Ismail, Yuki Nagao, Ahmad Salihin Samsudin

Makara Journal of Technology

In the present study, a novel solid biopolymer electrolyte (SBE) system is introduced by doping citric acid into alginate polymer. A sample of the alginate-citric acid SBE system was prepared via a solution casting technique. Using electrical impedance spectroscopy (EIS), the electrolytes of alginate-citric acid analyzed from 5 Hz to 1 MHz achieved the highest conductivity at 20 wt.% of 5.49 × 10-7 S cm-1. The temperature dependence of various citric acid amounts obeyed the Arrhenius rule with R2~1, where all SBE systems were thermally activated with increasing temperature. The dielectric studies of the alginate-citric acid SBE system showed non-Debye …

Wavelet Transform On Digital Rainbow Hologram Based On Spectral Compression For Quality Enhancement In 3d Display Media, Ucuk Darusalam, Panca Dewi Pamungkasari

Makara Journal of Technology

A digital rainbow hologram (DRH) is a potential next-generation three-dimensional display media for the development of modern and smart electronics devices. It is one of the methods that can support the characteristic whereby a realistic display media occupies the space that the real object would have occupied. Since a rainbow hologram records a large amount of spatial or temporal frequency component from the object that represents the rainbow spectrum, a large amount of information needs to be decoded digitally. In this paper, to reconstruct a DRH, we propose a novel method based on the modulation of red, green, and blue …

Data Fusion Method Based On Adaptive Kalman Filtering, Bernadus Herdi Sirenden

Makara Journal of Technology

This paper discusses data fusion methods to combine the data from a rotary encoder and ultrasonic sensor. Both sensors are used in a micro-flow calibration system developed by the Research Center of Metrology LIPI. The methods studied are hierarchical data fusion and Kalman filtering. Three types of Kalman filters (KFs) are compared: the conventional Kalman filter and two adaptive Kalman filters. Moreover, a method to combine the uncertainty results from KF in hierarchical data fusion is proposed. The aim of this study is to find appropriate methods of data fusion that can be implemented in micro-flow calibration systems. Data from …

Sorption-Based Energy Storage Systems: A Review, Kyaw Thu, Nasruddin Nasruddin, Sourav Mitra, Bidyut Baran Saha

Makara Journal of Technology

Mismatched timing between the supply and demand of energy calls for reliable storage systems. Energy storage systems have become further significant with the widespread implementation of renewable energy. These systems can mitigate problems that are often associated with renewable energy sources such as supply unreliability while meeting the de-mand during peak hours. Energy can be stored in various forms, yet storage systems can be generally grouped based on their output forms, namely (i) electricity and (ii) heat or thermal energy. Electrical energy is the most convenient and effective form since it can power almost all modern devices. However, the electricity …

Use Of Penetrating Asphalt Emulsions To Address High-Void Pavement Areas, Andrew Eicher, Curt Higginbotham

Purdue Road School

Longitudinal joints are high in air voids due to compaction limitations. Lowering the void content of these areas improves the durability of the pavement. Project data indicate that rapid penetrating emulsion (RPE) fills the voids beneath the surface of the pavement, reducing air and water intrusion while maintaining surface texture, whereas traditional emulsions seal the surface only. Lab tests have been developed to quantify the penetrating ability of an emulsion and resistance to water exposure. Join us for a discussion.

Urea Functionalization Of Ultrasound-Treated Biochar: A Feasible Strategy For Enhancing Heavy Metal Adsorption Capacity, Baharak Sajjadi, James William Broome, Wei Yin Chen, Daniell L. Mattern, Nosa O. Egiebor, Nathan Hammer, Cameron L. Smith

Faculty and Student Publications

© 2018 Elsevier B.V. The main objective of a series of our researches is to develop a novel acoustic-based method for activation of biochar. This study investigates the capability of biochar in adsorbing Ni(II) as a hazardous contaminant and aims at enhancing its adsorption capacity by the addition of extra nitrogen and most probably phosphorous and oxygen containing sites using an ultrasono-chemical modification mechanism. To reach this objective, biochar physically modified by low-frequency ultrasound waves (USB) was chemically treated by phosphoric acid (H3PO4) and then functionalized by urea (CO(NH2)2). Cavitation induced by ultrasound waves exfoliates and breaks apart the regular …

Modeling Of Leakage Through Fault-Zone Structures In Co2 Geological Storage, Dayna Rodriguez Zambrano

LSU Master's Theses

Faults intersecting target geological CO₂ storage zones have important implications for storage integrity. Potential leakage pathways due to fluid over-pressurization are investigated in this project to ensure long-term containment of injected CO₂. Numerical flow simulations coupled with a geomechanical module are presented in this work with the purpose of determining the extent of CO₂ up-fault migration, the driving mechanisms of leakage and the corresponding response of quantified pore pressure and stress variations.

This study uses dual-continuum models performed by using CMG (2017) to correctly account of flow through fractures in a fault damage zone. Numerical simulations …

Thermomechanical Analysis Of Rock Asperity In Fractures Of Enhanced Geothermal Systems, Chao Zeng

Doctoral Dissertations

"Enhanced Geothermal Systems (EGS) offer great potential for dramatically expanding the use of geothermal energy and become a promising supplement for fossil energy. The EGS is to extract heat by creating a subsurface system to which cold water can be added through injection wells. Injected water is heated by contact with rock and returns to the surface through production well. Fracture provides the primary conduit for fluid flow and heat transfer in natural rock. Fracture is propped by fracture roughness with varying heights which is called asperity. The stability of asperity determines fracture aperture and hence imposes substantial effect on …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …

Literature Survey Of Wet-Waste And Hydrothermal Carbonization System: A Comparative Evaluation, Ramat Olaide Yusuf

Dissertations and Theses

This thesis describes the process of Hydrothermal carbonization and a comparative assessment on recent work done on the process using different feedstocks such as Raw Apple (RA), Apple chip pomace (ACP), apple juice pomace (AJP), grape pomace (GP), macadamia nut-shell (MNS), Sewage Sludge (SS), Poultry Litter (PL) and Grape Marc (GM). The data obtained from the literature survey was compared with the data obtained by the CCL team on the SWPS gasifier (HTC of poultry litter) to obtain how carbon conversion efficiency, syngas composition, thermal efficiency, char production rate, gas production rate and energy utilization vary with carbonization process conditions, …

Synthesis, Characterization And Applications Of Reduced Graphene Oxide And Composite Membranes For Selective Separations And Removal Of Organic Contaminants, Ashish Aher

Theses and Dissertations--Chemical and Materials Engineering

Among the next generation materials being investigated for membrane development, partially reduced Graphene Oxide (rGO) has received increasing attention from the membrane community. rGO-based nanofiltration membranes have shown promising results in applications such as partial desalination, organic contaminant removal, gas-phase separations, and separations from solvent media. rGO offers a unique platform compared to common polymeric membranes since it can be used for separation applications in both aqueous and organic solvent media. An rGO-based platform could also be utilized to synthesize reactive membranes, giving rGO membranes the additional capability of reactively removing organic contaminants. This research focuses on the synthesis of …

Experimental And Numerical Characterization Of Multiphase Subsurface Oil Release, Feng Gao

Dissertations

Subsurface oil release is commonly encountered in the natural environment and engineering applications and has received the substantial attention of researchers after the disastrous Deepwater Horizon Blowout oil spill in 2009. The main focus on the present research is to systematically study the hydrodynamics of underwater oil jet under a variety of conditions, including the effect of dispersant and different gas to oil ratios (GOR) by using experimental measurement as well as a Computational Fluid Dynamics (CFD) approach, from which the measured turbulent characteristics (e.g., velocity, turbulent kinetic energy, turbulence dissipation rate, etc.) of underwater oil jet are thoroughly examined …

Mechanisms Of Calcium Phosphate Mineralization On Biological Interfaces And Their Engineering Applications, Doyoon Kim

McKelvey School of Engineering Graduate Student Theses & Dissertations

All living organisms utilize phosphorus (P) as an essential component of their cell membranes, DNA and RNA, and adenosine triphosphate. Bones, in addition to bearing loads, play an important role in balancing P levels in our bodies. In bones, a network of collagen templates and calcium phosphate (CaP) nanocrystals builds hierarchical levels, from nano- to macroscale. Within this architecture, the thermodynamic properties of CaP minerals are influential. Despite the importance of nucleation, growth, and crystallization in collagen structures for tissue development, little kinetic study of these processes has been conducted due to the limited in situ techniques for monitoring these …

Community-Scale Water Treatment Systems In The Dominican Republic, Jonathan Racey, Annabelle Papai, Elise Fischer, Becca Johnson

Engagement & Service-Learning Summit

Engagement and Service-Learning Summit: Reciprocal and Sustainable Partnerships

Ascorbic Acid Degradation In Cut Lemon Packaged Using Oxygen Scavenging Active Film During Storage, Kurniawan Yuniarto, Setyo Purwanto, Bruce Ari Welt, Anang Lastriyanto

Makara Journal of Technology

Oxygen scavenging active film can be used to prevent diffusion of free oxygen due to the action of permeation mechanism. In this study, biodegradable oxygen scavenging plastic film was designed by incorporating an antioxidant agent into plasticized polylactic acid or PLA-PEG (PPLA). Butylated hydroxytoluene (BHT) was added at different concentrations into the matrix of the PPLA film using a direct casting method to produce oxygen scavenging active film. The antiradical activity of the oxygen scavenging active film was observed, which could be applied for preventing vitamin C degradation in cut lemon during storage. The antiradical activity of the active film …

Conversion Of Heat Energy From Cooling Water Of Diesel Engine To Electrical Energy Using Thermoelectric Generator, Muhammad Hasan Albana

Makara Journal of Technology

This research objective is to convert heat from the radiator fluid of a diesel engine to electrical energy by utilizing a thermoelectric generator (TEG). The TEG consists of 20 semiconductors (TE modules) and is equipped with a heat sink. The research shows that using the TEG, the heat of radiator fluid can be converted to electrical energy, although the electricity generated is small. The maximum electrical voltage generated by the TEG when modules were connected in series was 10 volts. When the TE modules were connected in parallel and series-parallel, the maximum voltages generated were 2.11 and 2.53 volts, respectively. …

Immittance Response On Carboxymethyl Cellulose Blend With Polyvinyl Alcohol- Doped Ammonium Bromide-Based Biopolymer Electrolyte, Norfatihah Mazuki, Yuki Nagao, Ahmad Salihin Samsudin

Makara Journal of Technology

The blended carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped with various compositions of ammonium bromide (NH4Br)-based solid biopolymer electrolytes (SBEs) were prepared by using the casting method. In this present work, CMC/PVA–NH4Br SBE thin film was used to investigate the electrical conductivity via electrical impedance spectroscopy. The maximum conductivity obtained was 3.21 X 10−4 S cm−1 for sample AB20 at ambient temperature (303 K), and this result might be due to the increased number of charge carrier. A dielectric study was conducted to understand the conductivity behavior. The electrical properties have been measured as a function of frequency of …

Transition Metal Dichalcogenide For High-Performance Electrode Of Supercapacitor, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin, Bouchta Sahraoui

Makara Journal of Technology

Molybdenum dichalcogenides have been reviewed from the perspectives of bandgap, conductivity, and oxidation states of transition metal. Researchers have concluded that a narrow-bandgap transition metal dichalcogenide with high conductivity could be achieved for the high-performance electrode of a supercapacitor.

The Importance Of Usability Aspect In M-Commerce Application For Satisfaction And Continuance Intention, Yassierli Yassierli, Vinsensius Vinsensius, M. S. Syed Mohamed

Makara Journal of Technology

There has been a rapid growing of m-commerce application in recent years due to the development of mobile communication technology and e-commerce business. However, only about 30% of online users, who conduct online searching, make online purchases. The low conversion rate seems to be correlated with poor usability aspect of most m-commerce applications and poor satisfaction reported by users. Research has reported that satisfaction and continuance intention in using m-commerce applications have relationships with service quality and information quality. In this study, a new model of user satisfaction and continuance intention in the context of mobile application was proposed by …

A 2.3/3.3-Ghz Dual Band Low Noise Amplifier Using Switchable Load Inductor In 0.18-Um Cmos Technology, Taufiq Alif Kurniawan, Hsiao-Chin Chen

Makara Journal of Technology

In this paper, the dual band low noise amplifier is designed in 0.18-μm CMOS technology. By combining the proposed switchable load inductor for gain controlling and the conventional inductive source degeneration topology, narrow band gain and good impedance matching are achieved at 2.3/3.3-GHz frequency bands. The new mathematical analysis of low noise amplifier design is derived to define the component parameters of the proposed circuits. The proposed low noise amplifier exhibits gain of 17.18 dB and 15.5 dB, and noise figure of 2.67 dB and 2.52 dB at the two frequency bands, respectively.