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Articles 271 - 300 of 1430
Full-Text Articles in Chemical Engineering
Biofilm Formation Influences The Wettability And Settling Of Microplastics, Amber J. Pete, Philip J. Brahana, Mustapha Bello, Michael G. Benton, Bhuvnesh Bharti
Biofilm Formation Influences The Wettability And Settling Of Microplastics, Amber J. Pete, Philip J. Brahana, Mustapha Bello, Michael G. Benton, Bhuvnesh Bharti
Chemical and Biochemical Engineering Faculty Research & Creative Works
The fate of 99% of the plastics present in oceans is unknown. It is presumed that biofilm formation on plastics leads to their sinking to the ocean floor, thus making them undetectable at the surface. While it is established that biofilms lead to sinking of plastics, it is the mechanism by which biofilms enhance the vertical transport of plastics that remains unknown. It is commonly assumed that biofilms increase the effective mass density of the plastics, which drives their sinking. Here, we show that such an assumption is not always true, and formation of biofilms alone is an insufficient criterion …
Mathematical Modeling Of Microscale Biology: Ion Pairing, Spatially Varying Permittivity, And Born Energy In Glycosaminoglycan Brushes, William J. Ceely, Marina Chugunova, Ali Nadim, James D. Sterling
Mathematical Modeling Of Microscale Biology: Ion Pairing, Spatially Varying Permittivity, And Born Energy In Glycosaminoglycan Brushes, William J. Ceely, Marina Chugunova, Ali Nadim, James D. Sterling
Business and Information Technology Faculty Research & Creative Works
Biological macromolecules including nucleic acids, proteins, and glycosaminoglycans are typically anionic and can span domains of up to hundreds of nanometers and even micron length scales. The structures exist in crowded environments that are dominated by multivalent electrostatic interactions that can be modeled using mean-field continuum approaches that represent underlying molecular nanoscale biophysics. We develop such models for glycosaminoglycan brushes using steady state modified Poisson-Boltzmann models that incorporate important ion-specific (Hofmeister) effects. The results quantify how electroneutrality is attained through ion electrophoresis, spatially varying permittivity hydration forces, and ion-specific pairing. Brush-salt interfacial profiles of the electrostatic potential as well as …
Salt Doping Of Hyaluronic Acid Glycopolymer Biocondensates, James D. Sterling, Lu Fu, Kenisha Pudun, Shenda Baker, Megan Lord, Henry E. Riggs
Salt Doping Of Hyaluronic Acid Glycopolymer Biocondensates, James D. Sterling, Lu Fu, Kenisha Pudun, Shenda Baker, Megan Lord, Henry E. Riggs
Business and Information Technology Faculty Research & Creative Works
Biocondensates are largely studied with regard to intracellular components, while recognition of the formation of extracellular biocondensates are emerging, such as for cell surface heparan sulfate binding with basic fibroblast growth factor. This study analyzed the formation of biocondensates in vitro between the ubiquitous extracellular component, hyaluronan an anionic glycosaminoglycan, and cationic derivitized polyglucosamines known to bind to mucosal interfaces. The effect of molecular weight and net charge ratio was studied using a combination of microscopy, turbidity, laser diffraction particle sizing and zeta potential measurements. These analyses revealed that molecular weight affected the ability to form biocondensates while the surface …
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling excessive water production in mature oil fields has always been a desired objective of the oil and gas industry. This objective calls for planning of more effective water-control gel treatments with optimized designs to obtain more attractive outcomes. Unfortunately, planning such effective treatments remains a dilemma for reservoir engineers due to the lack of methodical design tools in the industry. This paper presents a novel systematic design approach for polyacrylamide-based bulk gel treatments by classifying their field projects according to the gel volume-concentration ratio (VCR) into three design types. In terms of one another, the approach estimates either the …
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling excessive water production in mature oil fields has always been a desired objective of the oil and gas industry. This objective calls for planning of more effective water-control gel treatments with optimized designs to obtain more attractive outcomes. Unfortunately, planning such effective treatments remains a dilemma for reservoir engineers due to the lack of methodical design tools in the industry. This paper presents a novel systematic design approach for polyacrylamide-Based bulk gel treatments by classifying their field projects according to the gel volume-concentration ratio (VCR) into three design types. in terms of one another, the approach estimates either the …
Design And Applications Of Fmoc-Histidine And Aspartic Acid Tripeptides As Proton Conductive Materials, Shejla S. Pollozi
Design And Applications Of Fmoc-Histidine And Aspartic Acid Tripeptides As Proton Conductive Materials, Shejla S. Pollozi
Dissertations, Theses, and Capstone Projects
The increasing demand for clean and sustainable energy has driven forward rapid improvements in polymer-electrolyte fuel cells and the use of ion-conducting polymers (ionomers) as proton exchange membranes and catalyst binders. While perfluorinated electrolytes have been commercially used as conductive membranes for nearly four decades, a new class of sustainable, conductive materials has emerged, inspired by the efficiency of charge transport processes in biological systems. These molecules, knows as peptide amphiphiles (PAs), have gained popularity as building blocks for the bottom-up fabrication of nanomaterials through supramolecular self-assembly. Supramolecular nanostructures, often in the form of hydrogels, are held together via non-covalent …
Local Il-10 Delivery Modulates The Immune Response And Enhances Repair Of Volumetric Muscle Loss Muscle Injury, Tai Huynh, Cassandra Reed, Zain Blackwell, Peyton Phelps, Luis Carlos Pinzon-Herrera, Jorge Almodovar, David A. Zaharoff, Jeffery Wolchok
Local Il-10 Delivery Modulates The Immune Response And Enhances Repair Of Volumetric Muscle Loss Muscle Injury, Tai Huynh, Cassandra Reed, Zain Blackwell, Peyton Phelps, Luis Carlos Pinzon-Herrera, Jorge Almodovar, David A. Zaharoff, Jeffery Wolchok
Biomedical Engineering Faculty Publications and Presentations
This study was designed to test the hypothesis that in addition to repairing the architectural and cellular cues via regenerative medicine, the delivery of immune cues (immunotherapy) may be needed to enhance regeneration following volumetric muscle loss (VML) injury. We identified IL-10 signaling as a promising immunotherapeutic target. To explore the impact of targeting IL-10 signaling, tibialis anterior (TA) VML injuries were created and then treated in rats using autologous minced muscle (MM). Animals received either recombinant rat IL-10 or phosphate buffered saline (PBS) controls injections at the site of VML repair beginning 7 days post injury (DPI) and continuing …
Effect Of Class C And Class F Fly Ash On Early-Age And Mature-Age Properties Of Calcium Sulfoaluminate Cement Paste, Sukanta K. Mondal, Carrie Clinton, Hongyan Ma, Aditya Kumar, Monday Uchenna Okoronkwo
Effect Of Class C And Class F Fly Ash On Early-Age And Mature-Age Properties Of Calcium Sulfoaluminate Cement Paste, Sukanta K. Mondal, Carrie Clinton, Hongyan Ma, Aditya Kumar, Monday Uchenna Okoronkwo
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
To Promote the Sustainable Development of Eco-Efficient Calcium Sulfoaluminate (CSA) Cements through the Partial Replacement of the CSA Clinker with Supplementary Cementitious Waste Products, the Effects of Coal Fly Ashes on the Early-Age and Mature-Age Properties of a Calcium Sulfoaluminate (CSA)-Based Cement Paste Were Investigated. the Impacts of Both Class C and Class F Fly Ashes on the Rheological Properties, Hydration Kinetics, and Compressive Strength Development of CSA Cement Paste Were Studied. Rheology-Based Workability Parameters, Representing the Rate of Loss of Flowability, the Rate of Hardening, and the Placement Limit, Were Characterized for the Pastes Prepared with Fixed Water-To-Cement (W/c) …
Sra Inhibition Improves Antitumor Potency Of Antigen-Targeted Chaperone Vaccine, Jie Qian, Xiaofei Yu, Zheng Liu, Jinyang Cai, Masoud H. Manjili, Hu Yang, Chunqing Guo, Xiang Yang Wang
Sra Inhibition Improves Antitumor Potency Of Antigen-Targeted Chaperone Vaccine, Jie Qian, Xiaofei Yu, Zheng Liu, Jinyang Cai, Masoud H. Manjili, Hu Yang, Chunqing Guo, Xiang Yang Wang
Chemical and Biochemical Engineering Faculty Research & Creative Works
We Have Previously Demonstrated that Scavenger Receptor a (SRA) Acts as an Immunosuppressive Regulator of Dendritic Cell (DC) Function in Activating Antitumor T Cells. Here We Investigate the Potential of Inhibiting SRA Activity to Enhance DC-Targeted Chaperone Vaccines Including One that Was Recently Evaluated in Melanoma Patients. We Show that Short Hairpin RNA-Mediated SRA Silencing Significantly Enhances the Immunogenicity of DCs that Have Captured Chaperone Vaccines Designed to Target Melanoma (I.e., Hsp110-Gp100) and Breast Cancer (I.e., Hsp110-HER/Neu-ICD). SRA Downregulation Results in Heightened Activation of Antigen-Specific T Cells and Increased CD8+ T Cell-Dependent Tumor Inhibition. Additionally, Small Interfering RNA (SiRNA) Complexed …
Coupling Atr-Ftir Spectroscopy With Multivariate Analysis For Polymers Manufacturing And Control Of Polymers’ Molecular Weight, Tung Nguyen, Ahmad Arabi Shamsabadi, Mona Bavarian
Coupling Atr-Ftir Spectroscopy With Multivariate Analysis For Polymers Manufacturing And Control Of Polymers’ Molecular Weight, Tung Nguyen, Ahmad Arabi Shamsabadi, Mona Bavarian
Department of Chemical and Biomolecular Engineering: Faculty Publications
Acrylate-based polymers are commonly used in the chemical industry. Consistent manufacturing of these polymers with the help of Process Analytical Technology (PAT) is very desirable. The capability of monitoring polymers’ molecular weight in real-time reduces operation time and eliminates the frequent samplings needed for quality control. Herein, molecular weight (Mw) of glycidyl methacrylate-co-methyl methacrylate (GMA-co- MMA) copolymer was monitored in real-time using mid-infrared ATR-FTIR spectroscopy. The Principal Component Analysis (PCA) and Partial Least Square (PLS) models were then utilized to examine, improve the latent space, and select high-quality spectra. We show that acquiring highly correlated spectra enhances the …
Coupling Nitrate Capture With Ammonia Production Through Bifunctional Redox-Electrodes, Kwiyong Kim, Alexandra Zagalskaya, Jing Lian Ng, Jaeyoung Hong, Vitaly Alexandrov, Tuan Anh Pham, Xiao Su
Coupling Nitrate Capture With Ammonia Production Through Bifunctional Redox-Electrodes, Kwiyong Kim, Alexandra Zagalskaya, Jing Lian Ng, Jaeyoung Hong, Vitaly Alexandrov, Tuan Anh Pham, Xiao Su
Department of Chemical and Biomolecular Engineering: Faculty Publications
Nitrate is a ubiquitous aqueous pollutant from agricultural and industrial activities. At the same time, conversion of nitrate to ammonia provides an attractive solution for the coupled environmental and energy challenge underlying the nitrogen cycle, by valorizing a pollutant to a carbon-free energy carrier and essential chemical feedstock. Mass transport limitations are a key obstacle to the efficient conversion of nitrate to ammonia from water streams, due to the dilute concentration of nitrate. Here, we develop bifunctional electrodes that couple a nitrate-selective redox-electrosorbent (polyaniline) with an electrocatalyst (cobalt oxide) for nitrate to ammonium conversion. We demonstrate the synergistic reactive separation …
Direct Synthesis Of Ethylene And Hydrogen From Co2 And Ethane Over A Bifunctional Structured Cao/Cr2o3-V2o5/Zsm-5 Adsorbent/Catalyst Monolith, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei
Direct Synthesis Of Ethylene And Hydrogen From Co2 And Ethane Over A Bifunctional Structured Cao/Cr2o3-V2o5/Zsm-5 Adsorbent/Catalyst Monolith, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this study, we synthesized bifunctional adsorbent/catalyst materials (BFMs) consisting of a CaO adsorbent admixed with Cr2O3-V2O5/ZSM-5 catalysts. The obtained BFMs were further formulated, processed, and shaped through additive manufacturing (3D printing) method. The physical and chemical properties of structured CaO/Cr2O3-V2O5/ZSM-5 adsorbent/catalyst monoliths were thoroughly characterized and evaluated. The effects of operating conditions including reaction temperature, ethane composition, and space velocity on single-bed CO2 capture and selective formation of ethylene and hydrogen were systematically investigated. The adsorption-reaction experiments revealed …
Development Opportunities And Technical Challenges Of Industrialization For Hydrogen Production From Bio-Ethanol Reforming, Xue Han, Hong He, Guojun Yue, Hailong Lin, Jinsong Liu, Bin Yu
Development Opportunities And Technical Challenges Of Industrialization For Hydrogen Production From Bio-Ethanol Reforming, Xue Han, Hong He, Guojun Yue, Hailong Lin, Jinsong Liu, Bin Yu
Bulletin of Chinese Academy of Sciences (Chinese Version)
Bio-ethanol reforming for hydrogen production, using renewable raw materials and adopting mature and efficient chemical processes, is an important source of green hydrogen supply to achieve the goals of carbon peaking and carbon neutrality. Bio-ethanol is a widely used substitute for fossil fuels. With the continuous progress of cellulosic ethanol technology in recent years, bio-ethanol will gradually break through the constraints of starch-based raw material supply. Based on the industrialization achievements of hydrogen production and bio-ethanol, bio-ethanol reforming can realize a rapid linkage with the existing hydrogen energy industry. However, the existence of a carbon-carbon signal bond in ethanol poses …
Development, Validation And Implementation Of Multiple Radioactive Particle Tracking Technique, Mehul S. Vesvikar, Thaar M. Aljuwaya, Mahmoud M. Taha, Muthanna H. Al-Dahhan
Development, Validation And Implementation Of Multiple Radioactive Particle Tracking Technique, Mehul S. Vesvikar, Thaar M. Aljuwaya, Mahmoud M. Taha, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Computer Automated Radioactive Particle Tracking (CARPT) technique has been successfully utilized to measure the velocity profiles and mixing parameters in different multiphase flow systems where a single radioactive tracer is used to track the tagged phase. However, many industrial processes use a wide range of particles with different physical properties where solid particles could vary in size, shape and density. For application in such systems, the capability of current single tracer CARPT can be advanced to track more than one particle simultaneously. Tracking multiple particles will thus enable to track the motion of particles of different size shape and density, …
3d-Printed Boron Nitride Catalytic Monoliths For Oxidative Dehydrogenation Of Propane, Theodore Agbi, Wei Shang Lo, Khaled Baamran, Taekyung Ryu, Christine Cheung, Fateme Rezaei, Ive Hermans
3d-Printed Boron Nitride Catalytic Monoliths For Oxidative Dehydrogenation Of Propane, Theodore Agbi, Wei Shang Lo, Khaled Baamran, Taekyung Ryu, Christine Cheung, Fateme Rezaei, Ive Hermans
Chemical and Biochemical Engineering Faculty Research & Creative Works
Boron-containing materials are efficient catalysts for the oxidative dehydrogenation of propane to propylene, proceeding via radical intermediates. The radical mechanism is initiated by the solid surface and propagated in the gas phase. It has been hypothesized that the propylene selectivity could be increased by enhancing the gas-phase contributions by favoring the formation of iso- over n-propyl radical intermediates. Indeed, whereas n-propyl radicals can be converted to both propylene and ethylene, iso-propyl radicals yield exclusively propylene. In this contribution, we explore 3D printing to structure the hexagonal boron nitride (hBN) heterogeneous catalyst with high void space. 3D-printed hBN monoliths were found …
Exploring Ph Gradient Phenomena In Non-Linear Electrokinetic Microfluidic Devices, Azade Tahmasebi
Exploring Ph Gradient Phenomena In Non-Linear Electrokinetic Microfluidic Devices, Azade Tahmasebi
Dissertations, Master's Theses and Master's Reports
Electrokinetic microfluidics is a versatile technology utilized within lab on a chip (LOC) devices for diagnostic and analytical applications; advantages include reduced resource demands, flexibility, and simplicity of use. Dielectrophoresis (DEP) is a precision nonlinear electrokinetic tool utilized within microfluidic microdevices to induce polarization and control bioparticle motions for applications that range from hemoglobin separations to cancer cell isolation and detection. Despite promising results, undesired side phenomena can occur in electrokinetic systems which impede reproducibility and accuracy. These unfavorable phenomena have not been comprehensively explored in the literature. Prior preliminary research suggests the fundamental phenomena originate from microelectrodes utilized in …
The Success Story Of First Ever Polymer Flood Field Pilot To Enhance The Recovery Of Heavy Oils On Alaska's North Slope, Abhijit Dandekar, Baojun Bai, John Barnes, Dave Cercone, Reid Edwards, Samson Ning, Randy Seright, Brent Sheets, Dongmei Wang, Yin Zhang
The Success Story Of First Ever Polymer Flood Field Pilot To Enhance The Recovery Of Heavy Oils On Alaska's North Slope, Abhijit Dandekar, Baojun Bai, John Barnes, Dave Cercone, Reid Edwards, Samson Ning, Randy Seright, Brent Sheets, Dongmei Wang, Yin Zhang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The primary goal of the first ever polymer flood field pilot at Milne Point is to validate the use of polymers for heavy oil Enhanced Oil Recovery (EOR) on Alaska North Slope (ANS). The specific objectives are systematic evaluation of advanced technology that integrates polymer flooding, low salinity water flooding, horizontal wells, and numerical simulation based on polymer flood performance data. Accordingly, under the co-sponsorship of the US Department of Energy and Hilcorp Alaska LLC the first ever polymer field pilot commenced on August 28, 2018 in the Schrader Bluff heavy oil reservoir at the Milne Point Unit (MPU) on …
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers, Xiaojing Ge, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai, Yuwei Zhang
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers, Xiaojing Ge, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai, Yuwei Zhang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High viscosity friction reducers (HVFRs) are widely used as friction-reducing agents and proppant carriers during hydraulic fracturing. The reuse of produced water has gained popularity due to environmental and economic benefits. Currently, the field's most commonly used friction reducers are anionic and cationic HVFRs. Anionic HVFRs are typically pumped with freshwater, while cationic HVFRs are used with high Total Dissolved Solids (TDS) produced water. Cationic friction reducers are believed to have better TDS tolerance, friction reduction performance, and proppant transport capabilities compared to anionic friction reducers under high TDS conditions due to their superior viscoelastic properties. In addition, the impact …
Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water, Xiaojing Ge, Abdulmohsin Imqam, Baojun Bai
Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water, Xiaojing Ge, Abdulmohsin Imqam, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High viscosity friction reducers (HVFRs) have been gaining more attention and increasing in use as proppant carriers. Reusing of produced water has also been driven by both environmental and economic benefits. However, high total dissolved solids (TDS) of produced water and high reservoir temperature significantly decrease the viscoelastic properties of HVFRs even for the cationic ones, which further reduce their proppant transport capabilities. Increasing loadings of HVFRs also has very limited effects on improving their proppant transport performances under high-TDS and high-Temperature conditions. The ultimate objective of this experimental study is to investigate the injection rate effects on the proppant …
Study Of Legionella Pneumophila Treatment With Copper In Drinking Water By Single Cell-Icp-Ms, Lei Xu, Austin Sigler, Anna Chernatynskaya, Lindsey Rasmussen, Jingrang Lu, Endalkachew Sahle-Demessie, David J. Westenberg, Hu Yang, Honglan Shi
Study Of Legionella Pneumophila Treatment With Copper In Drinking Water By Single Cell-Icp-Ms, Lei Xu, Austin Sigler, Anna Chernatynskaya, Lindsey Rasmussen, Jingrang Lu, Endalkachew Sahle-Demessie, David J. Westenberg, Hu Yang, Honglan Shi
Biological Sciences Faculty Research & Creative Works
Legionella pneumophila is a persistent opportunistic pathogen that poses a significant threat to domestic water systems. Previous studies suggest that copper (Cu) is an effective antimicrobial in water systems. A rapid and sensitive quantification method is desired to optimize the conditions of L. pneumophila treatment by Cu and to better understand the interaction mechanisms between Cu and cells. In this study, we developed a highly sensitive single cell (SC)-ICP-MS method to monitor L. pneumophila cell concentration and track their uptake of Cu. The SC-ICP-MS method showed excellent sensitivity (with a cell concentration detection limit of 1000 cells/mL), accuracy (good agreement …
Influence Of Interfering Ions And Adsorption Temperature On Radioactive Iodine Removal Efficiency And Stability Of Ni-Mof-74 And Zr-Uio-66, Turki Alghamdi, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Influence Of Interfering Ions And Adsorption Temperature On Radioactive Iodine Removal Efficiency And Stability Of Ni-Mof-74 And Zr-Uio-66, Turki Alghamdi, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Metal-organic frameworks (MOFs) often exhibit an exceptional adsorption-based separation performance for a variety of gases, ions, and liquids. While most radioactive iodine removal studies focus on the capture of radioactive iodine from off-gas streams, few studies have systematically investigated the effect of structure-property relationships of MOFs on iodine removal performance in the presence of interfering ions in liquid solutions. Herein, we investigated the iodide ion (I-) adsorption performance of two model MOFs (e.g., Ni-MOF-74 and Zr-UiO-66) in liquid phase as a function of iodine concentration (e.g., 0.125 to 0.25 and 0.50 mmol/L) and adsorption temperature (e.g., 25 to …
A Comprehensive Review Of The Influence Of Heat Exchange Tubes On Hydrodynamic, Heat, And Mass Transfer In Bubble And Slurry Bubble Columns, Dalia S. Makki, Hasan Sh Majdi, Amer A. Abdulrahman, Abbas J. Sultan, Zahraa W. Hasan, Laith S. Sabri, Bashar J. Kadhim, Muthanna H. Al-Dahhan
A Comprehensive Review Of The Influence Of Heat Exchange Tubes On Hydrodynamic, Heat, And Mass Transfer In Bubble And Slurry Bubble Columns, Dalia S. Makki, Hasan Sh Majdi, Amer A. Abdulrahman, Abbas J. Sultan, Zahraa W. Hasan, Laith S. Sabri, Bashar J. Kadhim, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Bubble and slurry bubble column reactors (BCRs/SBCRs) are used for various chemical, biochemical, and petrochemical applications. They have several operational and maintenance advantages, including excellent heat and mass transfer rates, simplicity, and low operating and maintenance cost. Typically, a catalyst is present in addition to biochemical processes where microorganisms are used to produce industrially valuable bio-products. Since most applications involve complicated gas-liquid, gas-liquid-solid, and exothermic processes, the BCR/SBCR must be equipped with heat-exchanging tubes to dissipate heat and control the reactor's overall performance. In this review, past and very recent experimental and numerical investigations on such systems are critically discussed. …
Demonstration Of High Detoxification Efficiency Of Glassy Polymer-Metal Hydroxide Composites Toward Chemical Warfare Agent Simulants, Peter O. Aina, Sukanta K. Mondal, Joshua Costain, Ali A. Rownaghi, Fateme Rezaei
Demonstration Of High Detoxification Efficiency Of Glassy Polymer-Metal Hydroxide Composites Toward Chemical Warfare Agent Simulants, Peter O. Aina, Sukanta K. Mondal, Joshua Costain, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
The design and development of polymeric composites that can effectively capture and destruct toxic chemicals with a fast detoxification rate is of high importance for protecting the military, first responders, and civilians. Here we report the synthesis and assessment of zirconium hydroxide (Zr (OH)4)-incorporated Ultem, Matrimid, and PIM-1 composites for detoxification of dimethyl 4-nitrophenylphosphonate (DMNP), as a type G toxic nerve agent simulant. Maintaining homogeneity, three different loadings (8, 20, 30 wt %) of Zr (OH)4 were incorporated into the polymers, and the thin films of composite materials were developed for subsequent hydrolysis tests. Our results indicated that increasing the …
Hydrothermal Stability Of Na-Lta Shaped With Clay Binder, Jimmy D.L. Moreno, Daniele Da S. Pereira, Thalita M. Azevedo, Dárley C. De Melo, Debora A.S. Maia, Fateme Rezaei, Moisés Bastos-Neto, Diana C.S. De Azevedo
Hydrothermal Stability Of Na-Lta Shaped With Clay Binder, Jimmy D.L. Moreno, Daniele Da S. Pereira, Thalita M. Azevedo, Dárley C. De Melo, Debora A.S. Maia, Fateme Rezaei, Moisés Bastos-Neto, Diana C.S. De Azevedo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Gas drying by adsorption on molecular sieves is one of the first unit operations in natural gas processing. Nevertheless, the thermal swings during regeneration combined with the presence of a complex gas mixture may lead to early adsorbent fouling. The shaping of adsorbent materials is crucial not only to reduce pressure drop in columns, but also for enhanced thermal and mechanical properties. In this work, synthesized sodium-based zeolite Linde Type A (Na-LTA) in powder was shaped by extrusion into cylindrical pellets using a clay binder followed by calcination at 673 K for 24 h. The produced 2-mm pellets had binder …
Effect Of Alkali Metal Functionalization On Hydrogen Storage Performance Of Highly Porous Activated Carbons, Ruthradharshini Murugavel, Ali A. Rownaghi, Fateme Rezaei
Effect Of Alkali Metal Functionalization On Hydrogen Storage Performance Of Highly Porous Activated Carbons, Ruthradharshini Murugavel, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
With increasing energy demand and fast-paced decarbonization methods adopted to curb the adverse effects of greenhouse gas emissions, hydrogen (H2) is considered a sustainable, clean, and potential renewable energy carrier for the future. To substitute the energy needs required for the physical methods of H2 storage, adsorbed gas storage (AGS) is the next viable option that provides the opportunity to adsorb and desorb gases under mild conditions. In this work, we studied the effect of light alkali metal functionalization comprising Li and K on the H2 storage performance of porous graphitic carbon adsorbents. The effect of metal doping on the …
Effect Of Eggshell Powder And Nano-Hydroxyapatite On The Surface Roughness And Microhardness Of Bleached Enamel, Shahinaz Hassan, Lamiaa Moharam
Effect Of Eggshell Powder And Nano-Hydroxyapatite On The Surface Roughness And Microhardness Of Bleached Enamel, Shahinaz Hassan, Lamiaa Moharam
Chemical and Biochemical Engineering Faculty Research & Creative Works
Background: The aim of the study was to evaluate the remineralizing potential of prepared solutions of eggshell powder (ESP) and nano-hydroxyapatite (nHA) on the surface roughness and microhardness of bleached enamel. Materials and Methods: Fifty bovine anterior teeth were selected and cleaned then bleached using a chemically activated in-office bleaching agent then the teeth were randomly allocated into five groups (n = 10) according to the tested remineralizing agents (10% ESP solution, 10% nHA solution, and MI Paste Plus) into; control, bleached, bleached + ESP solution, bleached + nHA solution, and bleached + MI Paste Plus groups. Then, the teeth …
Assessment Of The Dimensionless Groups-Based Scale-Up Of Gas–Solid Fluidized Beds, Faraj M. Zaid, Haider Al-Rubaye, Thaar M. Aljuwaya, Muthanna H. Al-Dahhan
Assessment Of The Dimensionless Groups-Based Scale-Up Of Gas–Solid Fluidized Beds, Faraj M. Zaid, Haider Al-Rubaye, Thaar M. Aljuwaya, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
The most common scale-up approach for gas–solids fluidized beds is based on matching the governing dimensionless parameters. In the literature, this approach has been validated only by means of measuring global parameters between different sizes of fluidized beds. However, such global measurements are not sufficient to depict all the interplaying hydrodynamic phenomena and hence verify the scale-up relationships. Therefore, to assess this approach, an advanced gas–solids optical probe and pressure transducer measurement techniques have been applied to quantify local hydrodynamic parameters in two different sized fluidized beds. Four different sets of experimental conditions were designed and conducted to examine the …
Review Of The Fluid Dynamics And Heat Transport Phenomena In Packed Pebble Bed Nuclear Reactors, Rahman S. Almusafir, Ahmed A. Jasim, Muthanna H. Al-Dahhan
Review Of The Fluid Dynamics And Heat Transport Phenomena In Packed Pebble Bed Nuclear Reactors, Rahman S. Almusafir, Ahmed A. Jasim, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Knowledge and proper safety analyses of the gas coolant and heat transport mechanism in the dynamic core of packed pebble bed nuclear reactors pose challenges to the reliable design and efficient operation of these reactors. Therefore, this paper carefully reviews most of the gas coolant mixing and heat transport studies performed for the fluid flow and heat transfer processes in packed pebble bed reactors (PBRs). It begins with a brief introduction and description of nuclear PBRs. The second section summarizes the physical characteristics of packed bed reactors in terms of the bed structure (porosity) and its radial and axial distributions. …
Development And Assessment Of Magnetic Fe2o3@Mof-74 Composite Sorbents For Ethylene/Ethane Separation, Khaled Baamran, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Development And Assessment Of Magnetic Fe2o3@Mof-74 Composite Sorbents For Ethylene/Ethane Separation, Khaled Baamran, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Development of smart sorbents that can be regenerated when triggered by external stimuli such as magnetic field can overcome the poor energy utilization of the current sorbents investigated for light olefins/paraffins separation. In this work, we report the development of novel magnetic sorbents comprising of MOF-74 crystals and superparamagnetic Fe2O3 particles in a core–shell structure, and assessment of their C2H4/C2H6 separation performance. The electromagnetic properties of the materials were tuned by varying the Fe2O3 (Fex) loading (x = 1–20 wt%), and their effects on adsorption …
Techno-Economic And Life Cycle Analyses For A Supercritical Biodiesel Production Process From Waste Cooking Oil For A Plant Located In The Midwest United States, Prashant Nagapurkar, Joseph D. Smith
Techno-Economic And Life Cycle Analyses For A Supercritical Biodiesel Production Process From Waste Cooking Oil For A Plant Located In The Midwest United States, Prashant Nagapurkar, Joseph D. Smith
Chemical and Biochemical Engineering Faculty Research & Creative Works
Existing Literature Lacks Detailed Techno-Economic and Environmental Life Cycle Analyses (TEA-LCA) Focused on Supercritical Biodiesel Production Pathways Produced Via Waste Products. Therefore, in This Work, the TEA-LCA Was Conducted to Generate Supercritical Biodiesel from Waste Cooking Oil for Plants Located in the Midwest Region of USA Having Annual Production Capacities of 10,600 and 128,000 T using Aspen Plus and GREET Software. Two Plant Production Capacities Were Chosen to Capture the Economies of Scale Impact on Biodiesel Manufacture Cost. in the Supercritical Process, Methanol and Propane Were Used as a Cosolvent to Synthesize Biodiesel from Waste Cooking Oil (WCO) at 280 …