Bioresource and Agricultural Engineering | Open Access Articles

Kinetic Desorption And Sorption Of U(Vi) During Reactive Transport In A Contaminated Hanford Sediment, Nikolla P. Qafoku, John M. Zachara, Chongxuan Liu, Paul Gassman, Odeta Qafoku, Steve Smith

United States Department of Energy: Publications

Column experiments were conducted to investigate U(VI) desorption and sorption kinetics in a sand-textured, U(VI)- contaminated (22.7 µmol kg^-1) capillary fringe sediment from the U.S. Department of Energy (DOE) Hanford site. Saturated column experiments were performed under mildly alkaline conditions representative of the Hanford site where uranyl-carbonate and calcium-uranyl-carbonate complexes dominate aqueous speciation. A U(VI)-free solution was used to study contaminant U(VI) desorption in columns where different flow rates were applied. Sorbed, contaminant U(VI) was partially labile (11.8%), and extended leaching times and water volumes were required for complete desorption of the labile fraction. Uranium- (VI) sorption was …

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Cryogenic Laser Induced U(Vi) Fluorescence Studies Of A U(Vi) Substituted Natural Calcite: Implications To U(Vi) Speciation In Contaminated Hanford Sediments, Zheming Wang, John M. Zachara, James Mckinley, Steven Smith

United States Department of Energy: Publications

Time-resolved laser-induced fluorescence spectroscopy (TRLFS) and imaging spectromicroscopy (TRLFISM) were used to examine the chemical speciation of uranyl in contaminated subsurface sediments from the U.S. Department of Energy (U.S. DOE) Hanford Site, Washington. Spectroscopic measurements for contaminant U(VI) were compared to those from a natural, uranyl-bearing calcite (NUC) that had been found via X-ray absorption spectroscopy (XAS) to include uranyl in the same coordination environment as calcium. Spectral deconvolution of TRLFS measurements on the NUC revealed the unexpected presence of two distinct chemical environments consistent with published spectra of U(VI)-substituted synthetic calcite and aragonite. Apparently, some U(VI) substitution sites in …

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Impact Of Highly Basic Solutions On Sorption Of Cs+ To Subsurface Sediments From The Hanford Site, Usa, C.C. Ainsworth, John M. Zachara, K. Wagnon, S. Mckinley, Chongxuan Liu, Steven Smith, H.T. Schaef, Paul Gassman

United States Department of Energy: Publications

The effect of caustic NaNO₃ solutions on the sorption of ¹³⁷Cs to a Hanford site micaceous subsurface sediment was investigated as a function of base exposure time (up to 168 d), temperature (10°C or 50°C), and NaOH concentration (0.1 mol/L to 3 mol/L). At 10°C and 0.1 M NaOH, the slow evolution of [Al]_aq was in stark contrast to the rapid increase and subsequent loss of [Al]_aq observed at 50°C (regardless of base concentration). Exposure to 0.1 M NaOH at 10°C for up to 168 d exhibited little if any measurable effect on sediment mineralogy, Cs …

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Aeration Strategies And Fan Cost Comparisons For Wheat In Mid-South Production Regions, Thomas C. Bridges, Michael D. Montross, Samuel G. Mcneill

Biosystems and Agricultural Engineering Faculty Publications

Numerous factors influence the sizing of aeration fans for summer-harvested crops. Thirty years of weather data for Lexington, Kentucky, were analyzed and the cost of aeration was compared for two axial fans (afan1, afan2) and one centrifugal fan (cfan1). Aeration costs were defined as the sum of the following components: the cost of owning the fan, the cost of electricity for operating the fan, a cost for wheat shrinkage during aeration, and a cost for dry matter loss (DML). The fans were selected to deliver airflow rates of approximately one, two, and three times the recommended aeration rate of 0.11 …

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Streambank Erosion Associated With Grazing Practices In The Humid Region, Carmen T. Agouridis, Dwayne R. Edwards, Stephen R. Workman, José R. Bicudo, Benjamin K. Koostra, Eric S. Vanzant, Joseph L. Taraba

Biosystems and Agricultural Engineering Faculty Publications

The effects of cattle grazing on stream stability have been well documented for the western portion of the U.S., but are lacking for the east. Stream and riparian damage resulting from grazing can include alterations in watershed hydrology, changes to stream morphology, soil compaction and erosion, destruction of vegetation, and water quality impairments. However, few studies have examined the successes of best management practices (BMPs) for mitigating these effects. The objective of this project was to assess the ability of two common BMPs to reduce streambank erosion along a central Kentucky stream. The project site consisted of two replications of …

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Beneficial Reuse And Sustainability: The Fate Of Organic Compounds In The Land-Applied Waste, M. R. Overcash, Ronald C. Sims, J. L. Sims, K. C. Nieman

Biological Engineering Faculty Publications

Land application systems, also referred to as beneficial reuse systems, are engineered systems that have defined and permitted application areas based on site and waste characteristics to determine the land area size requirement. These terrestrial systems have orders of magnitude greater microbial capability and residence time to achieve decomposition and assimilation compared with aquatic systems. In this paper we focus on current information and information needs related to terrestrial fate pathways in land treatment systems. Attention is given to conventional organic chemicals as well as new estrogenic and pharmaceutical chemicals of commerce. Specific terrestrial fate pathways addressed include: decomposition, bound …

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Modeling Sediment Trapping In A Vegetative Filter Accounting For Converging Overland Flow, M. J. Helmers, D. E. Eisenhauer, Thomas G. Franti, Michael G. Dosskey

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Vegetative filters (VF) are used to remove sediment and other pollutants from overland flow. When modeling the hydrology of VF, it is often assumed that overland flow is planar, but our research indicates that it can be two-dimensional with converging and diverging pathways. Our hypothesis is that flow convergence will negatively influence the sediment trapping capability of VF. The objectives were to develop a two-dimensional modeling approach for estimating sediment trapping in VF and to investigate the impact of converging overland flow on sediment trapping by VF. In this study, the performance of a VF that has field-scale flow path …

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Evaluation Of Toxic Agent Effects On Lung Cells By Fiber Evanescent Wave Spectroscopy, Pierre Lucas, David Lee Coq, Christophe Juncker, Jayne Collier, Dianne E. Boesewetter, Catherine Boussard-Pledel, Bruno Bureau, Mark R. Riley

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Biochemical changes in living cells are detected using a fiber probe system composed of a single chalcogenide fiber acting as both the sensor and transmission line for infrared optical signals. The signal is collected via evanescent wave absorption along the tapered sensing zone of the fiber. We spectroscopically monitored the effects of the surfactant Triton X-lOO, which serves as a toxic agent simulant on a transformed human lung carcinoma type II epithelial cell line (A549). We observe spectral changes between 2800-3000 cm-1 in four absorptions bands, which are assigned to hydrocarbon vibrations of methylene and methyl groups in membrane lipids. …

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Evaluation Of Methods For Estimating Daily Reference Crop Evapotranspiration At A Site In The Humid Southeast United States, R. E. Yoder, Lameck O. Odhiambo, Wesley C. Wright

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Estimated daily reference crop evapotranspiration (ET_o) is normally used to determine the water requirement of crops using the crop factor method. Many ET_o estimation methods have been developed for different types of climatic data, and the accuracy of these methods varies with climatic conditions. In this study, pair−wise comparisons were made between daily ET_o estimated from eight different ET_o equations and ET_o measured by lysimeter to provide information helpful in selecting an appropriate ET_o equation for the Cumberland Plateau located in the humid Southeast United States. Based on the standard error of the …

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Remote Estimation Of Canopy Chlorophyll Content In Crops, Anatoly A. Gitelson, Andrés Viña, Veronica Ciganda, Donald Rundquist, Timothy J. Arkebauer

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Accurate estimation of spatially distributed chlorophyll content (Chl) in crops is of great importance for regional and global studies of carbon balance and responses to fertilizer (e.g., nitrogen) application. In this paper a recently developed conceptual model was applied for remotely estimating Chl in maize and soybean canopies. We tuned the spectral regions to be included in the model, according to the optical characteristics of the crops studied, and showed that the developed technique allowed accurate estimation of total Chl in both crops, explaining more than 92% of Chl variation. This new technique shows great potential for remotely tracking the …

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Full-Text Articles in Bioresource and Agricultural Engineering

Kinetic Desorption And Sorption Of U(Vi) During Reactive Transport In A Contaminated Hanford Sediment, Nikolla P. Qafoku, John M. Zachara, Chongxuan Liu, Paul Gassman, Odeta Qafoku, Steve Smith

United States Department of Energy: Publications

Cryogenic Laser Induced U(Vi) Fluorescence Studies Of A U(Vi) Substituted Natural Calcite: Implications To U(Vi) Speciation In Contaminated Hanford Sediments, Zheming Wang, John M. Zachara, James Mckinley, Steven Smith

United States Department of Energy: Publications

Impact Of Highly Basic Solutions On Sorption Of Cs+ To Subsurface Sediments From The Hanford Site, Usa, C.C. Ainsworth, John M. Zachara, K. Wagnon, S. Mckinley, Chongxuan Liu, Steven Smith, H.T. Schaef, Paul Gassman

United States Department of Energy: Publications

Aeration Strategies And Fan Cost Comparisons For Wheat In Mid-South Production Regions, Thomas C. Bridges, Michael D. Montross, Samuel G. Mcneill

Biosystems and Agricultural Engineering Faculty Publications

Streambank Erosion Associated With Grazing Practices In The Humid Region, Carmen T. Agouridis, Dwayne R. Edwards, Stephen R. Workman, José R. Bicudo, Benjamin K. Koostra, Eric S. Vanzant, Joseph L. Taraba

Biosystems and Agricultural Engineering Faculty Publications

Beneficial Reuse And Sustainability: The Fate Of Organic Compounds In The Land-Applied Waste, M. R. Overcash, Ronald C. Sims, J. L. Sims, K. C. Nieman

Biological Engineering Faculty Publications

Modeling Sediment Trapping In A Vegetative Filter Accounting For Converging Overland Flow, M. J. Helmers, D. E. Eisenhauer, Thomas G. Franti, Michael G. Dosskey

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Evaluation Of Toxic Agent Effects On Lung Cells By Fiber Evanescent Wave Spectroscopy, Pierre Lucas, David Lee Coq, Christophe Juncker, Jayne Collier, Dianne E. Boesewetter, Catherine Boussard-Pledel, Bruno Bureau, Mark R. Riley

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Evaluation Of Methods For Estimating Daily Reference Crop Evapotranspiration At A Site In The Humid Southeast United States, R. E. Yoder, Lameck O. Odhiambo, Wesley C. Wright

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Remote Estimation Of Canopy Chlorophyll Content In Crops, Anatoly A. Gitelson, Andrés Viña, Veronica Ciganda, Donald Rundquist, Timothy J. Arkebauer

Department of Agricultural and Biological Systems Engineering: Faculty Publications