Bioresource and Agricultural Engineering Commons^™

Experimental And Modelling Evaluation Of Slagging Behaviour Of German Lignite, Martin Kaiser, Alexander Ilyushechkin

Coal Combustion and Gasification Products Journal Archive

The behaviour of mineral matter is important for the characterisation of coal for use in entrained-flow gasification technologies. We investigated four behavioural characteristics—ash fusion temperatures (AFT), slag viscosity versus temperature profiles, temperatures of critical viscosity (TCV), and slag phase compositions—of Rhenish lignite coal ash using laboratory and modelling tools. Our modelling of AFT using coal ash composition provided a wide range of data, with only one (modified) model demonstrating agreement with experimental data. Experimental slag viscosity data were obtained over a temperature range from 1200uC to 1500uC. Where relevant, TCV was also measured. Comparison of these data to the calculated …

Fly Ash As A Potential Scrubber Of Acidic Wastes From The Phosphate Industries In Israel, Roy Nir Lieberman, Eli Lederman, Ithamar Pelly, Haim Cohen

Coal Combustion and Gasification Products Journal Archive

Fly ash (FA) is produced in Israeli utilities via bituminous coal combustion. It is used as a cement additive or in concrete production, and its economic value is low. The FA produced in Israel is very basic (defined as class F) owing to ambient air quality standards that impose low sulfur content in the imported coals. Because the lime content is high (in the South African coal, ,10 wt%), it is a good potential chemical scrubber to acidic wastes. The phosphate industry in Israel produces mainly phosphate fertilizers and water-treatment products as well as phosphoric acid. The production methods rely …

Geochemistry And Mineralogy Of Coal-Fired Circulating Fluidized Bed Combustion Fly Ashes, Luis F.O. Silva, Marcos L.S. Oliveira, Rubens M. Kautzmann, Claudete G. Ramos, Maria Izquierdo, Shifeng Dai, Jennifer Wilcox, Jeremy Hoffman, James C. Hower

Coal Combustion and Gasification Products Journal Archive

The fuel, bed ash, and fly ash were sampled from a circulating fluidized bed combustion (CFBC) unit at two times. The first sampling was a high-sulfur (S) coal-only run, and the second sampling coincided with an experimental burn of up to 10% switchgrass (Panicum virgatum) pressed pellets mixed with a high-S coal. The latter blend had a higher moisture content and a lower heating value than the coal-only fuel. Given the time between the samplings and the special needs for the experimental run, unavoidable changes in the coal and limestone complicate comparisons of the bed ash and fly ash chemistry …

Trends In Coal Utilization And Coal Combustion Product Production In Kentucky: Results Of The 2012 Survey Of Power Plants, James C. Hower, Gerald A. Thomas, Shelley G. Hopps

Coal Combustion and Gasification Products Journal Archive

The University of Kentucky Center for Applied Energy Research has conducted a survey of Kentucky’s utility coal-fired power plants every 5 years since 1992. The survey includes a collection of the feed coal and the coal combustion products (CCPs). The latest collection was in 2012, with the accompanying information survey covering trends in 2011. Overall coal-fired energy production decreased, and the nature of the CCPs changed for a number of reasons, including but not limited to, increased gas production in the Appalachians, a series of warm winters, energy conservation, depletion of Appalachian coal reserves, and utility responses to regulations. From …

Pretreatment Of Scenedesmus Sp. Biomass As A Potential Anaerobic Digestion Substrate, Xinyi E, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algal biomass can be a potential substrate for anaerobic digestion. However, raw algae cells show a resistance to biological degradation, resulting in a slower methane production rate. Varying thermal and chemical pretreatments of algal biomass were investigated in an attempt to increase soluble organic matter (SOM) yield, which would result in enhanced methane production during subsequent anaerobic digestion. Scenedesmus sp. was harvested using three different procedures: with flocculation, with flocculation and drying, and without flocculation or drying. For all pretreatments and algae types, fluorescence micrographs were obtained to visually confirm the degradation of the algal cell walls. A complete 2 …

Effects Of Sodium Hydroxide Pretreatment On Structural Components Of Biomass, Alicia A. Modenbach, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Pretreatment is a unit operation in the conversion of biomass to valuable products that utilizes various combinations of conditions, including chemicals, heat, pressure, and time, to reduce the recalcitrance of lignocellulose. Many such pretreatments have been developed over the years, as the operating conditions can be adapted so that lignocellulose is modified in ways unique to each pretreatment. By tailoring pretreatment conditions to achieve these modifications, the types of final products produced can be controlled. The purpose of this review is to provide a consolidated source of information for sodium hydroxide effects on lignocellulose. The structural characteristics of lignocellulose and …

Evaluating Sampling Strategies For Rainfall Simulation Studies And Surface Transport Of Antibiotics From Swine Manure Applied To Fescue Plots, Holly K. Enlow

Theses and Dissertations--Biosystems and Agricultural Engineering

Antibiotics are commonly used in animal agriculture to treat and prevent diseases and promote growth. Unfortunately, large amounts of antibiotics are not metabolized, but instead are excreted in urine and feces. Rainfall simulation studies were used to investigate the transport of the antibiotic oxytetracycline and various constituents in runoff and the ability of alum to reduce pollutant transport. Runoff samples were collected at several points during the simulated storm event from each of four treatments: control (C), manure only (M), manure and antibiotics (MA), and manure, antibiotics and alum (MAA). Flow-weighted composite samples were created and compared to the flow …

Sequential Co-Culture Of Anaerobic Bacteria On Switchgrass In A Continuous Flow-Through Reactor For Biofuel Production, Noelia M. Elia

Theses and Dissertations--Biosystems and Agricultural Engineering

Solid substrate cultivation (SSC) using lignocellulosic non-food feedstock, such as switchgrass, is an alternative for advanced biofuel production. Acetone-Butanol-Ethanol (ABE) fermentation in two stages using a sequential culture of microorganisms from the class Clostridia is an approach proposed to increase the butanol production.

The goal was to test the efficacy of a sequential culture on high solid substrate cultivation in batch and continuous cultivation, and to evaluate conditions to optimize butanol production using switchgrass as substrate.

Initial batch experiments were used to determine particle size effect, choice of solvent producer and pretreatment evaluation: The effect of particle size on gas …

Low Cost Flow Sensing For Field Sprayers, Yue Zhang

Theses and Dissertations--Biosystems and Agricultural Engineering

Precisely measuring the flow rate in sprayers is a key technology to precision agriculture. With the development of advanced technologies, the demand for the ability to measure flow rate of individual nozzle has become more important and urgent.

This paper investigates the possibility of developing a low-cost flow rate measurement technique. The technique is based on analyzing the acoustic signal from a microphone placed near the nozzle tip. A comparison between acoustic signal and vibration signal was made to study the relations between them. Then several possible locations of the microphone for measuring flow rate were tested and compared, and …

Laboratory Scale Concept Validation And Evaluation Of Compromising Plant Nodal Integrity As A Means To Increase Bale Density, Aaron P. Turner

Theses and Dissertations--Biosystems and Agricultural Engineering

Transportation costs represent a significant role in the economics of packaged hay and biomass crops. The material’s low bulk density limits transportation efficiency. Density is currently limited by the ability of the baling twine to withstand the expansion forces generated by the baled material shortly after it is ejected from the bale chamber. It was hypothesized that compromising the structure of the plant, particularly the plant nodes could reduce the amount of energy stored in the material as it is compressed and thereby reduce the material’s elastic response to compression. Literature pertinent to the biomass material’s behavior in compression was …

Field Implementation Of Phanerochaete Chrysosporium Biomass Pretreatment: Fungal Identification And Inoculation Techniques, Bobby D. Carey Jr

Theses and Dissertations--Biosystems and Agricultural Engineering

Scaling biological pretreatment from the bench scale to the production scale may be more economical if unsterilized feedstock are used, however these allow for microbial competition from contaminates. An accurate and rapid method for identifying the desired biological pretreatment organism is necessary to confirm the presence of the desired organism when contaminates are morphologically similar to the target organism. Traditional methods, such as visual identification, sequencing, and selective plating can be time consuming and are sometimes still inconclusive. Based on methods described in the literature, plasmid DNA containing the marker genes gus (�-glucuronidase), LacZ, and gfp (green fluorescence protein) …

Enzymatic Hydrolysis Of Biomass At High-Solids Loadings – A Review, Alicia A. Modenbach, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Enzymatic hydrolysis is the unit operation in the lignocellulose conversion process that utilizes enzymes to depolymerize lignocellulosic biomass. The saccharide components released are the feedstock for fermentation. When performed at high-solids loadings (≥ 15% solids, w/w), enzymatic hydrolysis potentially offers many advantages over conversions performed at low- or moderate-solids loadings, including increased sugar and ethanol concentrations and decreased capital and operating costs.

The goal of this review is to provide a consolidated source of information on studies using high-solids loadings in enzymatic hydrolysis. Included in this review is a brief discussion of the limitations, such as a lack of available …

The Use Of Co-Culturing In Solid Substrate Cultivation And Possible Solutions To Scientific Challenges, Wanying Yao, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

This perspective systematically summarizes the use of solid substrate co‐cultures in agriculture, food, plant, and industrial biotechnology applications. The summarization is organized by organism, i.e. fungus, bacteria, yeast and then co‐cultivation of either two or three organisms. Generally, in solid substrate co‐culture, the organisms synergistically penetrate and degrade the solid substrate, thereby increasing product yield and productivity over a monoculture. Efforts to increase co‐culture performance include optimizing process parameters (pH, temperature, moisture, and oxygen demand) and defining the acceptable types of substrate. Scientific challenges exist in understanding the interactions between microbial stains, such as viability, suite of products, and bio‐transformations. …

Horizontal Pressures In Cylindrical Metal Silos And Comparison With Different International Standards, José W. B. Do Nascimiento, José P. Lopes Neto, Michael D. Montross

Biosystems and Agricultural Engineering Faculty Publications

The focus of this research was to evaluate the horizontal pressures on a cylindrical metal silo of corrugated walls and flat bottom with 1.82m diameter and 5.4m high, and to compare the values with those obtained theoretically by the ISO 11697, EP 433 and AS 3774 standards. The silo was symmetrically filled and constant speed with wheat cv. soft red for two different height/diameter ratios (H/D) and was unloaded through three orifices with a diameter of 71.6mm, one concentric and two eccentrics. Horizontal pressures were measured on the walls of the silo at three positions using hydraulic type pressure cells. …

Influence Of Media Composition On The Growth Rate Of Chlorella Vulgaris And Scenedesmus Acutus Utilized For Co2 Mitigation, Czarena L. Crofcheck, Xinyi E, Aubrey Shea, Michael D. Montross, Mark Crocker, Rodney Andrews

Biosystems and Agricultural Engineering Faculty Publications

Atmospheric carbon dioxide levels have increased since the industrial revolution due to increasing combustion of fossil fuels. One possible CO₂ mitigation strategy is the use of microalgae for mitigation of CO₂. This paper focuses on the influence of media composition on the growth rate of two microalgae strains, Chlorella vulgaris and Scenedesmus actus. A KNO₃ based medium was found to work better for Chlorella, while a urea based equivalent worked better for Scenedesmus. The urea based media investigated here resulted in growth similar to that found with previously reported KNO₃ based media. …

The John Zink Hamworthy Combustion Handbook, 2nd Edition, Volume 1: Fundamentals, Edited By Charles E. Baukal, Jr., Crc Press, Boca Raton, Fl, 2013., Payal A. Chandan

Coal Combustion and Gasification Products Journal Archive

No abstract provided.

Location Of Cerium In Coal-Combustion Fly Ashes: Implications For Recovery Of Lanthanides, James C. Hower, John G. Groppo, Prakash Joshi, Shifeng Dai, David P. Moecher, Michelle N. Johnston

Coal Combustion and Gasification Products Journal Archive

Given the worldwide demand for rare earth elements (REEs) in modern electronics, all potential sources of the REEs should be investigated. Coal-combustion fly ash represents a potential source of REEs. Fly ashes, derived from the combustion of coals from Kentucky in the United States and Jungar in China, were examined by wavelength-dispersive spectrometry electron microprobe analysis of epoxy-bound polished pellets. From previous studies, it was known that the REEs did not show any enrichment relative to flue gas temperature at the point of collection or to the particle size, that is, external surface area, of the particles. Cerium, the most …

Chemical Partitioning And Mobility Of Trace Elements In Dry Disposed Weathered Ash Conditioned With High-Saline Effluents, S.A. Akinyemi, A. Akinlua, W.M. Gitari, R.O. Akinyeye, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

Weinvestigated the mobility of inorganic elements in the ash dump due to chemical interaction of weathered dry disposed ash conditioned with high-saline effluents and ingressed CO2 from atmosphere and percolating rainwater. Drilled ash core samples collected from dry disposed ash dump at a South African coal-burning power station were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses. A modified sequential extraction procedure was selected to determine the mineralogical association of the investigated elements in the 1-year-old drilled ash cores. Major mineral phases are quartz and mullite and other minor phases included hematite, lime, calcite, anorthite, mica, and enstatite. …

Effects Of Coal Combustion By-Product–Encapsulated Ammonium Nitrate On Wheat Yield And Uptake Of Nitrogen And Metals, Eton E. Codling

Coal Combustion and Gasification Products Journal Archive

Ammonium nitrate (AN) is an essential plant nutrient for plant growth. Ammonium nitrate is also an ingredient in explosives. Research is being conducted on reducing the explosiveness of AN by encapsulating it with the use of coal by-products. The objective of this greenhouse pot study was to determine the effects of class C and F fly ash and flue gas desulfurization-gypsum-encapsulated AN on biomass, grain, and straw yield and nitrogen and metals uptake by wheat. Encapsulated AN was mixed with a low-nitrogen soil at 56 and 112 kg N ha^-1^, as well as unencapsulated AN as a control, and planted …

Geotechnical Characterization Of Clinker-Stabilized Fly Ash–Coal Mine Overburden Mixes For Subbase Of Mine Haul Road, Soumya Ranjan Mallick, Manoj Kumar Mishra

Coal Combustion and Gasification Products Journal Archive

Fly ash is a major by-product of thermal power plants that adversely affects land, water, and air. Its gainful utilization in many areas is being continuously explored. Use of fly ash in opencast coal mine haul road construction is one such option. This article reports detailed laboratory investigations carried out on clinker-stabilized fly ash–mine overburden mixes to evaluate their suitability for subbase of mine haul roads. Composite materials were prepared from fly ash, mine overburden, and clinker at different proportions. Proctor compaction test, unconfined compressive strength (UCS), and ultrasonic pulse velocity tests were carried out at different curing periods. UCS …

Increases In Rops Pricing From 2006-2012 And The Impact On Rops Demand, Julie A. Sorensen, Paul L. Jenkins, Barbara Bayes, Erin Madden, Mark Purschwitz, John J. May

Biosystems and Agricultural Engineering Faculty Publications

In 2006, a social marketing campaign was developed to increase the installation of rollover protective structures (ROPS) on unprotected New York tractors. Using data gathered from the program's hotline, the impact of price increases on farmers' interest in ROPS is examined. Pricing data were obtained for all rigid ROPS kits commercially available in the U.S. since 2006. These data were stratified into two groups of ROPS suppliers: (1) tractor manufacturers that sell ROPS for their own tractors, referred to in this study as original equipment manufacturers (OEMs), and (2) aftermarket (AM) ROPS suppliers. The trend in price increases was contrasted …

Development Of A Semi-Automated Tobacco Stripping Machine Utilizing String Trimmers, Robert George Sperry, John H. Wilhoit, George A. Duncan

Biosystems and Agricultural Engineering Faculty Publications

Conventional stripping of burley tobacco is labor intensive and typically requires 50 to 75 worker hours per acre (wkr•h/acre). The goal of the project was to reduce labor by optimizing leaf removal by string trimmer heads using combinations of strings lengths and motor speeds. In tests conducted on a single grade, all leaves outside the grade were removed by hand. Plants were run through the machine for string lengths of 13, 18, and 23 cm (5, 7, and 9 in.) and associated motor speeds which were monitored and recorded. Stripping efficiencies were calculated for each plant and collectively for each …

Designing Contour Weep Berms To Reduce Agricultural Nonpoint Source Pollution, Richard C. Warner, Carmen T. Agouridis, Ross L. Guffey

Biosystems and Agricultural Engineering Faculty Publications

Nonpoint source pollution (NPS) of surface waters is a significant issue in agricultural lands, and best management practices (BMPs) are often used to reduce these impacts. Since the effectiveness of a BMP depends on a large number of widely varying factors, it is important to continue to develop BMPs in order to provide designers with more tools to use to maximize NPS removal. The contour weep berm is a new structural BMP constructed out of earth and subsequently vegetated. It is a linear BMP that is used in combination with a down-gradient vegetated filter strip or forested riparian buffer. Preliminary …

Influence Of Flue Gas Components On The Growth Rate Of Chlorella Vulgaris And Scenedesmus Acutus, Czarena Crofcheck, Aubrey Shea, Michael D. Montross, Mark Crocker, Rodney Andrews

Biosystems and Agricultural Engineering Faculty Publications

Atmospheric carbon dioxide levels have increased since the industrial revolution due to the increase in combustion of fossil fuels. One possible alternative strategy is the use of microalgae for CO₂ capture and recycling. Major components in coal-derived flue gas that may accumulate and effect algae growth include both sulfur oxides and fly ash. However, in practical application, sulfur oxides will be converted quickly to the acid product (H₂SO₄) in the aerobic aqueous conditions of algae cultivation. In this article, the influence of elevated H₂SO₄ levels and the presence of coal-derived fly ash …

A Correlation-Based Optical Flowmeter For Enclosed Flows, Naiqian Zhang, Joseph S. Dvorak, Yali Zhang

Biosystems and Agricultural Engineering Faculty Publications

A low-cost flowmeter would be very useful in a wide variety of monitoring situations. This article discusses the development of such a flowmeter based on optical components and its testing with water in an enclosed flow system. The sensor consisted of two sets of LEDs and phototransistors spaced 4 cm apart, monitoring the optical properties of the fluid at upstream and downstream locations, respectively. A small amount of dye was injected into the flow, which caused a change in the optical properties of the fluid at both locations. The time required for this change to move from the upstream to …

2013-2014 Kentucky & Tennessee Tobacco Production Guide, Kenneth W. Seebold, Robert C. Pearce, William A. Bailey, Lowell P. Bush, Jonathan D. Green, Robert D. Miller, Laura A. Powers, William M. Snell, Lee H. Townsend, Mark Purschwitz, Larry G. Wells, John H. Wilhoit, Margarita Velandia, Steve Bost, Gene Burgess, Frank Hale, Darrell Hensley, Paul Denton, Neil Rhodes

Agriculture and Natural Resources Publications

Tobacco growers in Kentucky and Tennessee have faced many challenges during the past two years, including weather, labor availability, and rising production costs. However, there have been opportunities as well. Some buying stations have closed or moved, but new buyers have come into the market and contract volumes have been stable overall. Good quality burley tobacco is in relatively short supply, and this has offered opportunities to those who have been able to overcome weather and labor challenges and produce good crops. These changes have had different impacts in different regions of both states, based largely on where buying stations …

A Note On The Occurrence Of Yttrium And Rare Earth Elements In Coal Combustion Products, James C. Hower, Shifeng Dai, Vladimir V. Seredin, Lei Zhao, Irena J. Kostova, Luis F.O. Silva, Sarah M. Mardon, Gulbin Gurdal

Coal Combustion and Gasification Products Journal Archive

There is an international need for a variety of lanthanide elements (rare earth elements, or REEs) in modern electronic and related components. This has led to a desire to broaden production from both previously productive locations and to expand production to new sources, possibly including coal-derived fly ash. The concentration of lanthanides in coal-combustion fly ash depends on a number of factors, one of the most important being the concentration of the elements in the feed coal. Unlike some elements, such as Zn and As, the REE concentration is largely not a function of element volatility. In this study, we …

Fouling Intensity Of Three Indian Coals, S. Balakrishnan, R. Nagarajan

Coal Combustion and Gasification Products Journal Archive

Ash particles can arrive at heat-transfer surfaces either in solid (solidified) state or in molten state, depending on the factors such as location inside the boiler, temperature, and residence time. In this study, arrival of ash particles in solid state, which can occur in the convective section of the boiler, was considered. Apart from the inertial force that drives particles .10 mmto the surface, the low-melting inorganic alkali vapors play a vital role in deposit formation by promoting sticking. Chemical equilibrium calculations were performed to calculate the equilibrium composition of flue gas, as well as the amount of condensable inorganic …

Chemical Weathering And Mobility Of Inorganic Species In Dry Disposed Ash: An Insight From Geochemical Fractionation And Physicochemical Analysis, S.A. Akinyemi, W.M. Gitari, A. Akinlua, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

The burning of low-grade coal produces vast amounts of ash and other solid by-products. In South Africa, coal combustion by-products undergo disposal on land as dry heaps or slurried to dams. In this study, the geochemical partitioning, transport, and mobility of elements in dry disposed ash dumps were investigated using a modified sequential extraction scheme. The chemical and mineralogical compositions of 50 drilled core samples were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry. Ternary plots of major elements as determined by XRF showed that the 15-year-old and 2-week-old dry disposed ashes are sialic, …

Evaluation Of Chemical Additives For The Separation And Recovery Of Bacteria From Food Matrices, Jennifer Leanne Frederick, Stephen P. Walker, Czarena L. Crofcheck, Melissa Newman, Frederick Payne

Biosystems and Agricultural Engineering Faculty Publications

The microbiological testing of foods is a well-established science. Due to the severity of foodborne pathogen illnesses, the widespread use and implementation of rapid detection methods in food testing labs is increasingly important. The first step for successful testing is sampling. Surfactants have been widely used in food microbiology, but there is not much, if any, published research about the use of fatty alcohols and chemical dispersants as aids in microbial separation and recovery. The microbial extraction efficiency of Escherichia coli K12 and Listeria innocua from three representative food matrices (hot dogs, spinach, and milk) was measured using chemical additives …