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2023

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Articles 6691 - 6720 of 9778

Full-Text Articles in Engineering

Automated Combustion Model Classification For Char Particle Distributions Using 3-D Morphology Analysis And Pore-Resolving Cfd Simulations, Dongyu Liang, Simcha L. Singer Mar 2023

Automated Combustion Model Classification For Char Particle Distributions Using 3-D Morphology Analysis And Pore-Resolving Cfd Simulations, Dongyu Liang, Simcha L. Singer

Mechanical Engineering Faculty Research and Publications

Combustion of pulverized coal involves millions of particles with a distribution of morphologies. A workflow is presented to characterize, classify, and model distributions of highly porous coal char particles. To understand the impacts of morphology, 3-D pore-resolving combustion simulations for 150 particles imaged with micro-CT are first performed. To facilitate modeling distributions of morphology in reactor-scale CFD, a machine learning algorithm is then trained to classify particles according to their expected combustion behavior and to select an accurate, computationally efficient 1-D particle-scale combustion model. Whereas existing approaches classify particles solely according to morphology and use 2-D measurements, the present approach …


Reinforcement Learning Framework For The Unreal Engine, Justin B. Wheeler Mar 2023

Reinforcement Learning Framework For The Unreal Engine, Justin B. Wheeler

Master's Theses

This dissertation addresses the need for using machine learning-based methods rather than traditional rule-based methods for controlling non-playable characters (NPCs). The goal of the Reinforcement Learning Framework for the Unreal Engine is to enable game development studios to create, train, and more easily implement smarter, more compelling AI characters in major video game releases. The framework contains three distinct software libraries: an Unreal Engine reinforcement learning library whose purpose is to enable Unreal Engine levels to act as reinforcement learning environments, a python library which provides convenient abstractions and implementations to the reinforcement learning process, and a flexible connection system …


Racketframes: A Dataframe Implementation For The Racket Programming Language, Shubham Kahal Mar 2023

Racketframes: A Dataframe Implementation For The Racket Programming Language, Shubham Kahal

Master's Theses

The DataFrame is a powerful table-like data structure used frequently in Data Science, the in-demand and innovative field focused on the extraction of valuable insights from data. Typically, datasets are not perfect upon collection and need to be prepared so that the resulting dataset is useful for statistical analysis. A DataFrame API supports optimized methods such as, selecting, aggregating and filtering rows, columns, and cells as well as renaming row and column labels. It also supports methods for normalizing data, merging data, adding new columns and labelling missing data among numerous other features. An API to work with tabular data …


Analysis And Usage Of Natural Language Features In Success Prediction Of Legislative Testimonies, Marine Cossoul Mar 2023

Analysis And Usage Of Natural Language Features In Success Prediction Of Legislative Testimonies, Marine Cossoul

Master's Theses

Committee meetings are a fundamental part of the legislative process in which
constituents, lobbyists, and legislators alike can speak on proposed bills at the
local and state level. Oftentimes, unspoken “rules” or standards are at play in
political processes that can influence the trajectory of a bill, leaving constituents
without a political background at an inherent disadvantage when engaging with
the legislative process. The work done in this thesis aims to explore the extent to
which the language and phraseology of a general public testimony can influence a
vote, and examine how this information can be used to promote civic …


Trajectory-Tracking Control Of The Ball-And-Plate System, Dominic E. Riccoboni Mar 2023

Trajectory-Tracking Control Of The Ball-And-Plate System, Dominic E. Riccoboni

Master's Theses

The Mechatronics group in the Mechanical Engineering department of Cal Poly is interested in creating a demonstration of a ball-and-plate trajectory tracking controller on hardware. The display piece will serve to inspire engineering students to pursue Mechatronics and control theory as an area of study. The ball-and-plate system is open-loop unstable, underactuated, and has complicated, nonlinear equations of motion. These features present substantial challenges for control - especially if the objective is trajectory tracking. Because the system is underactuated, common nonlinear trajectory tracking control techniques are ineffective. This thesis lays out a theoretical foundation for controlling the hardware.

Several important …


Simple Open-Source Formal Verification Of Industrial Programs, Christopher Disney Peterson Mar 2023

Simple Open-Source Formal Verification Of Industrial Programs, Christopher Disney Peterson

Master's Theses

Industrial programs written on Programmable Logic Controllers (PLCs) have become an essential component of many modern industries, including automotive, aerospace, manufacturing, infrastructure, and even amusement parks. As these safety-critical systems become larger and more complex, ensuring their continuous error-free operation has become a significant and important challenge. Formal methods are a potential solution to this issue but have traditionally required substantial time and expertise to deploy. This usability issue is compounded by the fact that PLCs are highly proprietary and have substantial licensing costs, making it difficult to learn about or deploy formal methods on them.

This thesis presents the …


A Biochemical Necroptosis Model Explains Cell-Type-Specific Responses To Cell Death Cues, Geena V. Ildefonso, Marie Oliver Metzig, Alexander Hoffmann, Leonard A. Harris, Carlos F. Lopez Mar 2023

A Biochemical Necroptosis Model Explains Cell-Type-Specific Responses To Cell Death Cues, Geena V. Ildefonso, Marie Oliver Metzig, Alexander Hoffmann, Leonard A. Harris, Carlos F. Lopez

Biomedical Engineering Faculty Publications and Presentations

Necroptosis is a form of regulated cell death associated with degenerative disorders, autoimmune and inflammatory diseases, and cancer. To better understand the biochemical mechanisms regulating necroptosis, we constructed a detailed computational model of tumor necrosis factor-induced necroptosis based on known molecular interactions from the literature. Intracellular protein levels, used as model inputs, were quantified using label-free mass spectrometry, and the model was calibrated using Bayesian parameter inference to experimental protein time course data from a well-established necroptosis-executing cell line. The calibrated model reproduced the dynamics of phosphorylated mixed lineage kinase domain-like protein, an established necroptosis reporter. A subsequent dynamical systems …


Adsorption Of Methylene Blue On Papaya Bark Fiber: Equilibrium, Isotherm And Kinetic Perspectives, Sumaya Tarannum Nipa, Nawrin Rahman Shefa, Shahanaz Parvin, Most Afroza Khatun, Md Jahangir Alam, Sujan Chowdhury, M. Azizur R. Khan, Sk Md Ali Zaker Shawon, Biplob K. Biswas, Md. Wasikur Rahman Mar 2023

Adsorption Of Methylene Blue On Papaya Bark Fiber: Equilibrium, Isotherm And Kinetic Perspectives, Sumaya Tarannum Nipa, Nawrin Rahman Shefa, Shahanaz Parvin, Most Afroza Khatun, Md Jahangir Alam, Sujan Chowdhury, M. Azizur R. Khan, Sk Md Ali Zaker Shawon, Biplob K. Biswas, Md. Wasikur Rahman

Mechanical Engineering Faculty Publications

Rapid population growth and industrial expansion lead us to be habitat of a polluted planet. One of the major pollutants that badly affect the ecosystem being organic dyes released from various chemical industries where cleaner production concept is straightway adopted. Papaya (Carica papaya) bark fiber (PBF) is a natural product used for Methylene Blue (MB) dye removal as a cost–effective adsorbent from aqueous solution by batch method. Several parameters as the effect of pH, initial dye concentration, contact time, and adsorbent dosage were studied and optimized for maximum dye recovery. Reaction kinetics of the process and Langmuir and Freundlich adsorption …


Approach To Problem Solving And Use Of Intuition By Engineering Technology Students, Meher R. Taleyarkhan, Anne M. Lucietto, Natalie L. F. Hobson, Therese M. Azevedo Mar 2023

Approach To Problem Solving And Use Of Intuition By Engineering Technology Students, Meher R. Taleyarkhan, Anne M. Lucietto, Natalie L. F. Hobson, Therese M. Azevedo

Journal of Global Education and Research

Engineering technology students often forgo a methodical approach of solving or answering questions on assignments or exams in favor of an intuition-based approach, emphasizing educated guessing (Broberg et al., 2008). Faculty observations have noted these student solutions often provide explanations, usually sans calculations, to support answers the students believe to be reasonable when in reality deviated from the correct answer. An extensive study was developed to assess several distinctions between student intuition and use of cognition in problem solving, as related to a generalized student population. The study was comprised of a survey and interview. The survey utilized two instruments, …


Analytical Methods For Determining Connectivity Leakage In Collaboration With Meissner Filtration Products, Ennis Cuhadaroglu, Finn Mccarthy, Alvin Ng Mar 2023

Analytical Methods For Determining Connectivity Leakage In Collaboration With Meissner Filtration Products, Ennis Cuhadaroglu, Finn Mccarthy, Alvin Ng

Biomedical Engineering

The scope of our project involved choosing existing testing procedures and determining a viable sample size to determine an accurate leakage rate of single-use system connections (SUS). Another goal was to assess the effects of gamma irradiation on the material integrity of the hose barb to tubing connections.

Our key customer requirements included: being able to determine an overall leakage rate and making a repeatable testing process. The importance of these requirements was determined through our house of quality and Pugh charts. To achieve the requirements, we tested the leakage in low-pressure and high-pressure scenarios with a large enough sample …


Development Of Fibroblast/Endothelial Cell-Seeded Collagen Scaffolds For In Vitro Prevascularization, Daniela S. Masson-Meyers, Fahimeh Tabatabaei, Lane Steinhaus, Jeffrey M. Toth, Lobat Tayebi Mar 2023

Development Of Fibroblast/Endothelial Cell-Seeded Collagen Scaffolds For In Vitro Prevascularization, Daniela S. Masson-Meyers, Fahimeh Tabatabaei, Lane Steinhaus, Jeffrey M. Toth, Lobat Tayebi

Biomedical Engineering Faculty Research and Publications

The development of vascularized scaffolds remains one of the major challenges in tissue engineering, and co-culturing with endothelial cells is known as one of the possible approaches for this purpose. In this approach, optimization of cell culture conditions, scaffolds, and fabrication techniques is needed to develop tissue equivalents that will enable in vitro formation of a capillary network. Prevascularized equivalents will be more physiologically comparable to the native tissues and potentially prevent insufficient vascularization after implantation. This study aimed to culture human umbilical vein endothelial cells (HUVECs), alone or in co-culture with fibroblasts, on collagen scaffolds prepared by simple fabrication …


Response Of The Metastable Pitting Corrosion Of Laser Powder Bed Fusion Produced Ti–6al–4v To H+ Concentration Changes, Yuwei Cui, Liangyu Chen, Liqiang Wang, Jun Cheng, Laichang Zhang Mar 2023

Response Of The Metastable Pitting Corrosion Of Laser Powder Bed Fusion Produced Ti–6al–4v To H+ Concentration Changes, Yuwei Cui, Liangyu Chen, Liqiang Wang, Jun Cheng, Laichang Zhang

Research outputs 2022 to 2026

There is limited research on metastable pitting corrosion in an acidic environment, and acid is a major challenge for material corrosion. Therefore, this work investigated the metastable pitting corrosion of laser powder bed fusion (LPBF)-produced Ti–6Al–4V, in Hank’s solution, at different pH values (pH = 3, 5, and 7). This work investigated the effect of acid on the characteristics of passive films, as well as the change in metastable pitting behavior. Based on the results of electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS), the passive film will be inhibited and dissolved under the influence of H+. The higher …


Moisture Sources Of Precipitation In The Great Lakes Region: Climatology And Recent Changes, Zhao Yang, Yun Qian, Pengfei Xue, Jiali Wang, T. C. Chakraborty, William J. Pringle, Jianfeng Li, Xiaodong Chen Mar 2023

Moisture Sources Of Precipitation In The Great Lakes Region: Climatology And Recent Changes, Zhao Yang, Yun Qian, Pengfei Xue, Jiali Wang, T. C. Chakraborty, William J. Pringle, Jianfeng Li, Xiaodong Chen

Michigan Tech Publications, Part 1

Given the critical role of precipitation on hydroclimate, we quantified the contributions of moisture source regions to precipitation in the Great Lakes Region (GLR) using multiple reanalysis data sets. Results show that the Great Plains (GPs) and the GLR itself are the primary sources of moisture. The moisture sources for the double peaks in the GLR precipitation that occur in June and September are identified, which is caused by a shift in the peak timing of moisture contribution from the GLR and GPs. In particular, moisture from the GPs contributes more to the heavy precipitation, while moisture from the GLR …


Optimal Configuration Of Extreme Fast Charging Stations Integrated With Energy Storage System And Photovoltaic Panels In Distribution Networks, Zhouquan Wu, Pradeep Bhat, Bo Chen Mar 2023

Optimal Configuration Of Extreme Fast Charging Stations Integrated With Energy Storage System And Photovoltaic Panels In Distribution Networks, Zhouquan Wu, Pradeep Bhat, Bo Chen

Michigan Tech Publications, Part 1

Extreme fast charging (XFC) for electric vehicles (EVs) has emerged recently because of the short charging period. However, the extreme high charging power of EVs at XFC stations may severely impact distribution networks. This paper addresses the estimation of the charging power demand of XFC stations and the design of multiple XFC stations with renewable energy resources in current distribution networks. First, a Monte Carlo (MC) simulation tool was created utilizing the EV arrival time and state-of-charge (SOC) distributions obtained from the dataset of vehicle travel surveys. Various impact factors are considered to obtain a realistic estimation of the charging …


Austenite Formation And Manganese Partitioning During Double Soaking Of An Ultralow Carbon Medium-Manganese Steel, Josh J. Mueller, Alexandra G. Glover, David K. Matlock, John G. Speer, Emmanuel De Moor Mar 2023

Austenite Formation And Manganese Partitioning During Double Soaking Of An Ultralow Carbon Medium-Manganese Steel, Josh J. Mueller, Alexandra G. Glover, David K. Matlock, John G. Speer, Emmanuel De Moor

Michigan Tech Publications, Part 1

Double soaking (DS) is a thermal processing route intended to produce austenite–martensite microstructures in steels containing austenite-stabilizing additions and consists of intercritical annealing (primary soaking), followed by heating and brief isothermal holding at an increased temperature (secondary soaking), and quenching. Herein, experimental dilatometry during DS of a medium-manganese (Mn) steel with nominally 7 wt% Mn and an ultralow residual carbon concentration, in combination with phase-field simulations of austenite formation during secondary soaking, is presented. The feasibility of maintaining heterogeneous Mn distributions during DS is demonstrated and insight is provided on the effects of the secondary soaking temperature and prior Mn …


Early Introduction Of 3d Modeling Modules Promotes The Development Of Simulation Skills In Downstream Biomedical Engineering Curricula, Mary S. Jia, Raj R. Rao, Mostafa Elsaadany Mar 2023

Early Introduction Of 3d Modeling Modules Promotes The Development Of Simulation Skills In Downstream Biomedical Engineering Curricula, Mary S. Jia, Raj R. Rao, Mostafa Elsaadany

Biomedical Engineering Faculty Publications and Presentations

Background

Recent advancements in additive manufacturing have made 3D design a desirable skill in combating the historically slow development of biomedical products. Due to the broad applicability of additive manufacturing to biomedical engineering, 3D design and 3D printing are attractive educational tools for biomedical engineering students. However, due to the multidisciplinary nature of biomedical engineering, finding a suitable spot in the curriculum to teach students basic and application-based skills for 3D manufacturing is difficult. Furthermore, prior training in fundamental 3D design skills may be needed to support the use of application-based supplementary content.

Results

We designed a SolidWorks Simulations toolkit …


Evaluating Automated Truck Platoon (Atp) Deployment For The Los Angeles–Inland Empire Trade Corridor Enhancement, Shailesh Chandra, Aastha Chaudhary, Prakhar Srivastava, Jose Torres-Aguilera Mar 2023

Evaluating Automated Truck Platoon (Atp) Deployment For The Los Angeles–Inland Empire Trade Corridor Enhancement, Shailesh Chandra, Aastha Chaudhary, Prakhar Srivastava, Jose Torres-Aguilera

Mineta Transportation Institute

The California Freight Mobility Plan 2020 lists the Los Angeles-Inland Empire trade corridor region as a prominent industrial hub experiencing an increase in freight flows. The California Freight Mobility Plan also regards automated truck platoon (ATP) as an emerging opportunity to minimize congestion on the trade corridor routes. Percentage change in accessibility from 2022 (“without” ATP) to 2040 (“with” ATP) is calculated for the eighteen industry sectors of the Los Angeles-Inland Empire trade corridor. The application of the accessibility formulation was carried out with data on travel time from I-710 and I-10 within Los Angeles County. The findings suggest that …


Highway To The Comfort Zone: History Of The Psychrometric Chart, Eric Teitelbaum, Clayton Miller, Forrest Meggers Mar 2023

Highway To The Comfort Zone: History Of The Psychrometric Chart, Eric Teitelbaum, Clayton Miller, Forrest Meggers

Research Collection College of Integrative Studies

The psychrometric chart is the most common data visualization technique for the designers of thermal comfort systems worldwide. From its humble roots as means of expressing the characteristics of air in building systems design, the use of the chart has grown to include the representation of the zones of human thermal comfort according to both conventional and adaptive models. In this paper, we present an extensive history of this development and the fallacies with representing comfort simply as a box that sometimes moves on the chart. The origins of the link between refrigeration control and comfort control are examined through …


Optimization Of Co2 Huff-N-Puff In Unconventional Reservoirs With A Focus On Pore Confinement Effects, Fluid Types, And Completion Parameters, Aaditya Khanal, Md Fahim Shahriar Feb 2023

Optimization Of Co2 Huff-N-Puff In Unconventional Reservoirs With A Focus On Pore Confinement Effects, Fluid Types, And Completion Parameters, Aaditya Khanal, Md Fahim Shahriar

Jasper Department of Chemical Engineering Faculty Publications and Presentations

The cyclic injection of CO2, referred to as the huff-n-puff (HnP) method, is an attractive option to improve oil recovery from unconventional reservoirs. This study evaluates the optimization of the CO2 HnP method and provides insight into the aspects of CO2 sequestration for unconventional reservoirs. Furthermore, this study also examines the impact of nanopore confinement, fluid composition, injection solvent, diffusivity parameters, and fracture properties on the long-term recovery factor. The results from over 500 independent simulations showed that the optimal recovery is obtained for the puff-to-huff ratio of around 2.73 with a soak period of fewer than 2.7 days. After …


Separation Axioms In Neutrosophic Topological Spaces, Sudeep Dey, Gautam Chandra Ray Feb 2023

Separation Axioms In Neutrosophic Topological Spaces, Sudeep Dey, Gautam Chandra Ray

Neutrosophic Systems with Applications

In this article, we first establish some results based on single-valued neutrosophic sets. Next, we define a subspace topology in a neutrosophic topological space and investigate some properties. We then define the neutrosophic T0, T1, T2-spaces and study their various properties, offering adequate examples.


Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva Feb 2023

Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva

Chemical Technology, Control and Management

The requirements of high operational reliability are most fully met by automated monitoring and control systems, the elements of which are magnetoelastic sensors. Such sensors, due to their metrological characteristics, have found application in electrified railway transport, in the metallurgical, metalworking, mining and other industries. The principle of operation of such sensors is based on the fact that in the process of influencing the magnetic core of the sensor by force, there is a change in the magnetic permeability of the material, a change in the magnetic resistance of the circuit, a change in the mutual inductance coefficient of the …


Model For Calculating The Static Characteristics Of Hydraulic Systems Of Hydro Technical Buildings, Mirkhalil Ismailov, Dong Zhang, Farkhod Kasimov Feb 2023

Model For Calculating The Static Characteristics Of Hydraulic Systems Of Hydro Technical Buildings, Mirkhalil Ismailov, Dong Zhang, Farkhod Kasimov

Chemical Technology, Control and Management

Hydraulic mechanisms that actuate flat gates, widely used in hydraulic structures, are studied as hydraulic actuators of the system. Their static mathematical models are developed using an integrated methodology with a hydraulic pump, inlet and suction pipes, and internal and external resistance factors. Unlike existing mathematical models, the model developed in this paper allows a detailed description of the characteristics of hydraulic drives due to the fact that pressure losses in the throttle, regulator, and power amplifier, as well as local resistances in hydraulic pipelines, are taken into account.


Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov Feb 2023

Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov

Chemical Technology, Control and Management

The article reveals the meaning and essence of the modeling method in the study of complex technological processes based on the problematic aspects of building multifactorial relationships and the principles for their elimination. In the case of non-linearity of multifactorial connections of a complex system, the expediency of approximating such functions by polynomials is substantiated. The authors' ideas about the increasing importance of interpolation methods in practice against the background of the possibility of simplification based on the use of modern mathematical hardware and software for integration into the process of modeling and optimizing technological processes due to the complexity …


Synchronization Of The Training Of Specialists In The Automation Of Technological Processes In Accordance With The Dynamics Of The Taxonomy Of Learning Goals, Yusuf Shodievich Avazov, Kamola Abdullaeva Feb 2023

Synchronization Of The Training Of Specialists In The Automation Of Technological Processes In Accordance With The Dynamics Of The Taxonomy Of Learning Goals, Yusuf Shodievich Avazov, Kamola Abdullaeva

Chemical Technology, Control and Management

Changes in the characteristics of modern ones, reflecting them as the "digital generation", inevitably necessitate electronic interactive, mobile and mixed, machine learning, especially in the field of automation and control of technological processes and production. As a consequence of reflecting these realities, there have been parallel changes in the taxonomy of learning objectives - from the classical to the revised rethought and digital.

In order to study the problem of synchronizing the training of future specialists in the field of automation and control of technological processes and production and funny knowledge in accordance with the dynamics of the taxonomy of …


Procedural Model Of The Monitoring System, Fayzullajon Botirov Feb 2023

Procedural Model Of The Monitoring System, Fayzullajon Botirov

Chemical Technology, Control and Management

This article discusses the process of monitoring information security incidents and factors affecting the effectiveness of monitoring. A procedural model of the functioning of the information security incident monitoring system is constructed, based on the study of its structure, the principles of operation of individual components and literature data, the analysis of individual stages.


Analysis Of Vegetable Oil Refining Technology, Elyor Samadov Feb 2023

Analysis Of Vegetable Oil Refining Technology, Elyor Samadov

Chemical Technology, Control and Management

Innovative technologies for refining vegetable oils are presented, as well as the qualitative characteristics of raw vegetable oils obtained by extraction and mechanical methods. A general review of the chemical composition and impurities of vegetable oils resulting from the reaction between glycerol and fatty acids is carried out, and a brief review of the study to determine the effect of refining on biologically active components.

The analytical review is devoted to a comparative comparison of two types of refining - chemical and physical refining.


Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov Feb 2023

Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov

Chemical Technology, Control and Management

In the article given materials of developing of three-phase electromagnetic current transducers of reactive power, using with asynchronous motor, methods connecting of two sensing element, series, parallel and differential and loops suitable for each phase, dynamic characteristics of output signals of three-phase electromagnetic current transducers asynchronous motor.

On the basis of modern calculation and design complexes are of great importance in the research variable sizes of three-phase current electromagnetic transducers of filter-compensation devices of reactive power of asynchronous motors. Presented mathematical model of research of electrical, electromagnetic and magnetic elements of electromagnetic current transducers in the …


Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li Feb 2023

Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li

Journal of Electrochemistry

Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li2O2 is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li2O2. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li2O2, …


Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang Feb 2023

Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO2 …


Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen Feb 2023

Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen

Journal of Electrochemistry

Electrolytic hydrogen production is heavily restricted by high-energy consumption majorly due to the relatively high potential of anodic oxygen evolution reaction (OER). Development of OER-alternative reaction at the anode has been recently proposed as a promising pathway to address the associated issues. In this work, we report a hybrid acid/alkali dual-electrolyte electrolyzer by coupling acidic hydrogen evolution reaction (HER) using commercial Pt/C cathode with alkaline Electrocatalytic glycerol oxidation (GOR) which is implemented by developing a nickel foam (NF) supporting Co3O4 nanosheets anode that shows low overpotential and high selectivity toward GOR for formate production. The hybrid acid/alkali …