Engineering Commons^™

Influence Of Precursor Preparation On The Synthesis Of Boron Carbide From Glutinous Rice Flour, Kannigar Dateraksa, Sujarinee Sinchai

Journal of Metals, Materials and Minerals

Boron carbide is a promising candidate for a variety of applications, including blasting nozzles, neutron moderators, and lightweight armor. Using of inexpensive and readily available starting materials which can react with boric acid to form B-O-C bonds, e.g., glutinous rice flour, is one of alternative means to produce high purity boron carbide powder at low temperature. In this study, boric acid and glutinous rice flour, boron and carbon sources, were used for synthesizing B4C powder by the carbothermic reduction. The mole ratios of boric acid to glutinous rice flour ranging from 1:1 to 2.5:1 were formulated and mixed by continuous …

Effect Of Zinc-Hydroxo Species On The Growth Of One-Dimensional Zno Nanostructures, Nontakoch Siriphongsapak, Somyod Denchitcharoen

Journal of Metals, Materials and Minerals

One-dimensional ZnO nanostructures were grown on ZnO seed layer by hydrothermal method using zinc nitrate (Zn(NO3)2) and sodium hydroxide (NaOH) as precursors. The concentrations of NaOH and Zn(NO3)2 were varied from 40 mM to 680 mM and kept constant, respectively. Effects of increasing the hydroxide ions on the concentration of zinc-hydroxo species in the solution were studied using thermodynamic simulation software. The simulated results showed that Zn(OH)2 and Zn(OH)3- concentrations tended to decrease but Zn(OH)42- was non-linearly increased when the concentration of NaOH at room temperature was increased. After the growth of ZnO, the samples were characterized by FESEM and …

Experimental And Numerical Characterization Of Fatigue Crack Propagation In High-Speed Railway Wheel Er8 Steel, Chaichayo Suetrong, Vitoon Uthaisangsuk

Journal of Metals, Materials and Minerals

In this work, characteristics of fatigue crack growth in the Paris regime of the rail wheel steel grade ER8 were investigated. Experimental crack growth tests under different cyclic loads of a compact tension (CT) specimen and corresponding FE simulations were carried out. The extended FE method (XFEM) coupled with damage evolution based on the strain energy release rate or the Paris law was applied to describe the crack propagation mechanism in the tested CT samples. Hereby, the fatigue fracture model parameters were firstly determined from the experimental data. It was found that the predicted crack growth rates agreed well with …

Effect Of Cladding Of Stellite-6 Filler Wire On The Surface Of Ss316l Alloy Through Cold Metal Arc Transfer Process, Thinesh Babu Thiagarajan, Sengottuvel Ponnusamy

Journal of Metals, Materials and Minerals

In this work, Cladding was done on SS316L alloy through the CMT process using Stellite-6 filler wire. 31 experiments were done at different welding conditions as per CCD matrix. The cladding specimens were characterized by macro and micro-study, Vickers microhardness evaluation and corrosion resistance analysis. An optical microscope, SEM-EDAX, and XRD were used to predict the structural characterizations, presence and the distributions of the elements. Based on the study higher voltage & welding speed showed appreciable hardness at the interface & cladding regions. The thickness of the interface was noted at a maximum of 190 μm. The EDS spectra showed …

Development And Characterization Of Sic Fiber Reinforced B4c Composite, Jitendra Kumar Sonber, Sanjib Majumdar, Vivekanand Kain

Journal of Metals, Materials and Minerals

This study is conducted to investigate the effects of silicon carbide short fiber (SiCf) reinforcement on processing and properties of boron carbide ceramic. Studies have been carried out on the hot pressing, mechanical property measurement, microstructure evolution and oxidation study of SiCf reinforced B4C composite. B4C-SiCf composites have been prepared by hot pressing at 1950℃ with varying SiCf content in the range of 10 vol% to 30 vol%. All the composites are densified to near theoretical density. It is noticed that hardness of composite is decreased and fracture toughness of composite is increased by addition of SiC fiber. Hardness of …

Facile Purification Of Locally Mined Gypsum And Its Use For Preparing Nano-Hemihydrates, Luqman Ayodeji Adams, Enobong Essien, Taiwo Aiyeloro, Stella Oseyomon, John Makanjuola

Journal of Metals, Materials and Minerals

Gypsum has a wide range of applications, in interior decorations, building construction, supplements or implants in orthopaedics to mention a few. However, in many developing countries including Nigeria, there is still a large-scale importation despite huge available natural deposits. In this study, a facile method to purify locally-mined gypsum has been explored based on the mineral retrograde solubility in water. The purified gypsum was investigated for its elemental composition in comparison to the crude sample and a commercially obtained medical-grade gypsum using X-ray fluorescence (XRF). The results showed that the purified gypsum contained 94.05% CaSO4 compared with the crude which …

Efficiency Of 2-Dodecylaminopyridine For The Liquid-Liquid Extraction Of Gold(Iii) From Succinic Acid Medium, Umrao Shep, Rucha Pawar, Balasaheb Arbad

Journal of Metals, Materials and Minerals

Extractive recovery of gold(III) from succinic acid solution with high molecular weight amine: 2-dodecylaminopyridine (2-DDAP) as a new extractant in xylene has been investigated. Extraction data indicates that 5 × 10-4 mol⋅L-1 2-DDAP is a very efficient and fast extractant. Gold(III) can be effectively extracted (D = 414.16) with 2-DDAP from 0.04 M succinic acid solution. The equilibrium of gold(III) from aqueous phase of succinic acid with 2-DDAP is achieved within 60 sec. The extraction of gold(III) with 2-DDAP proceed at the interface according to ion pair formation mechanism. The best stripping solution from among the studied ones is the …

Effect Of Dc Power On The Thickness, Hardness And Adhesion Strength Of Ti-51 At% Ni Coated Ti/Tin, Ishiaka Shaibu Arudi, Esah Hamzah, Muhammad Azizi Mat Yajid, Bushroa Abdul Razak

Journal of Metals, Materials and Minerals

The coating of Ti/TiN was successfully deposited on Ti-51 at% Ni substrates by using direct current (DC) magnetron sputtering technique and the effect of different sputtering power on the thickness, surface hardness and adhesion strength of the coatings were studied. The microstructural characterization was carried out using scanning electron microscope (SEM), energy-dispersive X-ray (EDX) and X-ray diffractometer (XRD). The coating thicknesses were detected and measured using SEM. The surface hardness test was performed using microhardness tester, and the adhesion strength was carried out by scratch testing. The results showed that the TiN crystallites growth orientation, thickness, surface hardness and adhesion …

Developments Of Biodegradable Polymer Based On Polylactic Acid (Pla) With Natural Color Extracts For Packaging Film Applications, Worraphol Nansu, Passarawan Chaiwut, Sukunya Ross, Gareth Ross, Nungruthai Suphrom, Sararat Mahasaranon

Journal of Metals, Materials and Minerals

This research was interested in the use of natural colorants to replace hazardous synthetic pigments in the plastic polymer industry. The natural colors were selected from local plants indigenous to southeast Asia, which were Hibiscus sabdariffa roselle calyx (RS) and Caesapinia sappan Linn heartwood (SP). Natural colorant extracts were used as additives in poly(lactic acid ) (PLA). These were manufactured using a twin screws extruder and blow film extruder to obtain biodegradable thin films for use as packaging materials. Biodegradable films were characterized by color index, light barrier properties, water vapor transmission (WVTR), morphology, mechanical and chemical properties. The results …

Effects Of Delay Time And Curing Temperature On Compressive Strength And Porosity Of Ground Bottom Ash Geopolymer Mortar, Nattapong Makaratat, Sumrerng Rukzon, Prinya Chindaprasirt

Journal of Metals, Materials and Minerals

This research investigated development of ground bottom ash (GBA) for a new geopolymer material. The compressive strength and porosity of the geopolymer mortar containing GBA were tested. The GBA-based geopolymer mortar mixtures were designed by control liquid to GBA ratio for all tests. Extra water was also used to maintain the workability of geopolymer mortar. The sodium hydroxide (NaOH) concentrations of 10 M and 15 M were used. Furthermore, sodium silicate (Na2SiO3) to sodium hydroxide (NaOH) ratios by mass such as 0.50, 1.50 and 2.50 were also used as alkali activator solutions. Effects of delay time and no-delay time, heat …

A Review Of Rice Husk Silica As A Heterogeneous Catalyst Support, Izzati Nasir, Nadiah Ameram, Arlina Ali, Siti Roshayu Hassan, Nurul Akmar Che Zaudin, Jamil Mohamed Sapari

Journal of Metals, Materials and Minerals

The yield of amorphous silica has less residue of mineral content in rice husk (RH) and a high specific surface area through the simple alkaline extraction process at first, then acid precipitation of RH. At this time, the leaching process using alkali and calcination of RH is the best method to acquire amorphous silica with a high surface area. The different temperatures were used for the calcination of RH and continue with sodium hydroxide (NaOH) treatment by using different concentration. The sample titrated using hydrochloric acid (HCl) to extract silica. Pretreatment with acid leaching for the RH was also conducted …

Enhanced Mechanical And Thermal Properties Of Fly Ash-Based Geopolymer Composites By Wollastonite Reinforcement, Khanthima Hemra, Takaomi Kobayashi, Pavadee Aungkavattana, Sirithan Jiemsirilers

Journal of Metals, Materials and Minerals

The present study investigated the mechanical and thermal properties of geopolymer composite. The geopolymer composite was prepared by mixing fly ash and wollastonite with the alkaline activator, which was 6 M KOH:K2SiO3 in a mass ratio of 1:1 and a solid:liquid mass ratio of 3:2. The compressive strength at 28 days of geopolymer was 33.3 MPa and possessed the highest strength of 38.3 MPa when 30 wt% wollastonite was added. The flexural strength presented differently whereby it increased from 2.1 MPa to 6.8 MPa. It increased remarkably up to 200% with the addition of 50 wt% wollastonite. The geopolymer composites …

Raman Signal Enhancement Of Low-Cost Metal Sheet Sers With Gold Decoration, Nampueng Pangpaiboon, Kawinphob Phetnam, Sukon Kalasung, Chanunthorn Chananonawathorn, Viyapol Patthanasettakul, Mati Horprathum, Pitak Eiamchai, Noppadon Nuntawong, Saksorn Limwichean

Journal of Metals, Materials and Minerals

Surface Enhance Raman Spectroscopy (SERS) is a sensitive surface creating plasmonic resonance for the Raman scattering. SERS is considered as a powerful technique to enhance the Raman signal, when quantity of sample is limited. Recently, our lab team has discovered a low-cost SERS template fabrication, laser-engraving method, which is suitable with gold nanoparticles decoration. In this work, two different materials, zinc and copper, are used as metal sheet SERS substrate. Gold nanoparticles sputtered with 270 s of sputtering time are used as decorated noble metal. FE-SEM images illustrate the nano-in-microstructure of the engraved metal sheets. The decorated Au nanoparticles are …

Oxidation Behavior Of Sn-1 Wt% Bi Alloy In Air And Deionized Water At Room Temperature, Tanavut Naravuthichai, Patama Visuttipitukul, Sirichai Leelachao, Tachai Luangvaranunt

Journal of Metals, Materials and Minerals

Formation of tin oxides on surface Sn-1 wt% Bi alloy lapping plates causes interactions with protrusions of embedded diamond grits, and reduces the efficiency of the lapping process. The rate and type of oxide formation were investigated to understand the problem. Electrochemical analysis was performed to characterize the oxide film thickness, and x-ray photoelectron spectroscopy was performed to characterize the tin oxide species. Oxidation in air at room temperature reaches a thickness of 23 Å after 72 h. Oxidation in deionized water at room temperature has a faster growth rate, and reaches a thickness of 33 Å after 72 h. …

Mechanical Performance Of Woven Carbon Reinforced Epoxy Composites With Varied Orientation Angle, Sweety Ashish Agrawal, Someshwar Bhattacharya

Journal of Metals, Materials and Minerals

The mechanical properties of woven carbon fibre reinforced epoxy composites laminated with different orientation angle in stacking sequence were investigated. Woven fabric layers with different linear density carbon tow have been produced on modified rigid rapier sample loom and impregnated with epoxy by hand lay-up technique for composite preparation. Curing of composite was carried out at room temperature for 2 h. Five different laminar composites were prepared with different orientation angles [(0/0/0/0), 0/+30/-30/0, 0/+45/-45/0, 0/+60/-60/0 and 0/+90/-90/0]. The mechanical properties like tensile, flexural, and impact test) were analysed in both longitudinal and transverse directions. Physical properties such as density and …

Investigation Of Optimum Parameters For Rotary Friction Welding Of Aluminum Round Bars Using Three-Level Factorial Design Methodology, Tanakorn Jantarasricha, Siridech Kunhirunbawon, Montri Wimol

Journal of Metals, Materials and Minerals

The welding process has been essential to increasing productivity in numerous industries across Thailand. There are several welding processes to choose from, and the welding process to use will be determined by the suitability of the production in that industry. Another important consideration in welding is to keep the mechanical properties of the joint area as close to the parent material workpiece as possible. This research aims to select the optimum parameter for rotary friction welding aluminum round bar AA6063-T5. That is according to the DIN 50125 type B standard test. The optimal condition consists of welding rotational speed, welding …

Synthesis And Optical Properties Of Forsterite Ceramic Pigments Using Mirror Wastes As A Flux, Niti Yongvanich, Natchaya Lithira, Nitchakarn Nuniead, Wanchalerm Chauyarsa

Journal of Metals, Materials and Minerals

Cobalt-doped forsterite ceramic pigments based on the formula (Mg2-2xCo2x)SiO4 (x = 0, 0.05, 0.1, 0.2) were synthesized using mirror wastes as a flux. Addition of this flux enhanced forsterite phase formation at lower temperature by as much as 200℃. The resulting pigment particles were in a micron range which is suitable for use in a ceramic glaze. The host structure (Mg2SiO4) could accommodate cobalt cations up to 20 at%. Investigation on the chemical distribution revealed that no chemical species from the flux reacted with pigment grains. Optical properties were examined by UV-vis spectroscopy and colorimetry. Technical performance of the obtained …

Improving Employees’ Compliance With Password Policies, Enas Albataineh

CCAC Theses and Dissertations

Employees’ lack of compliance with password policies increases password susceptibility, which leads to financial damages to the organizations as a result of information disclosure, fraud, and unauthorized transactions. However, few studies have examined what motivates employees to comply with password policies.

The purpose of this quantitative cross-sectional study was to examine what factors influence employees’ compliance with password policies. A theoretical model was developed based on Protection Motivation Theory (PMT), General Deterrence Theory (GDT), Theory of Reasoned Action (TRA), and Psychological Ownership Theory to explain employees’ compliance with password policies.

A non-probability convenience sample was employed. The sample consisted of …

Development Of Chemical Methods For Oligonucleotide Purification, Paramagnetic Labeling And Synthesis Of Dna-Based Advanced Materials, Muhan He

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes a chemical method for alternative oligonucleotide purification that is non-chromatographic and gel-free and allows to routinely synthesize and purify long functional RNA strands. The purification of long RNAs is based on the bio-orthogonal inverse electron demand Diels-Alder (IEDDA) chemistry between trans-cyclooctene (TCO) and tetrazine (Tz). Target oligonucleotide strands are selectively tagged with Tz and can be captured and purified from the failure sequences with immobilized TCO. RNA strands are synthesized on solid support through a photolabile linker to avoid the loss of Tz tag. Purity of the isolated oligonucleotides was evaluated using gel electrophoresis, HPLC and mass …

Mixed Carrier Communication For Sixth-Generation Networks :, Ahmed Fahmy Mahmoud Hussein

Legacy Theses & Dissertations (2009 - 2024)

Recently, research on sixth-generation (6G) wireless networks has gained significant interest. By 2030, it is expected that 6G will introduce revolutionary applications and services. Thus, 6G is likely to expand across all available spectrum, including terahertz (THz) and optical frequency bands. Although 5G will offer a massive upgrade to the spectrum, the technology does not provide solutions to support a vast multitude of services and devices simultaneously.Motivated by the heterogeneity of wireless technologies, devices, and services, the Mixed Carrier Communication (MCC) concept is introduced for the first time. MCC is a novel concept that supports the 6G vision by enabling …

Intrabodies Reveal Critical Steps Involved In Ricin's Interactions With The Ribosome, Timothy Francis Czajka

Legacy Theses & Dissertations (2009 - 2024)

Ricin is a highly lethal protein toxin derived from the seeds of the castor plant, Ricinus communis. It is a Type II ribosome inactivating protein (RIP), meaning it is a heterodimer with one subunit, ricin toxin B (RTB), that mediates cell surface attachment and intracellular trafficking and a second subunit, ricin toxin A (RTA), that irreversibly shuts down protein synthesis in the cytosol. During trafficking, RTA and RTB necessarily separate in the endoplasmic reticulum, wherein RTA unfolds and translocates into the cytosol where it refolds into an enzymatically active conformation. RTA is remarkably fast acting and efficient, with few molecules …

Mapping Of Auditory Cortical Functions Using Electrocorticography, James Robert Swift

Legacy Theses & Dissertations (2009 - 2024)

Communication is a dynamic process through which we translate our inner thoughts in such a way that they can be shared with another person. This complex neurological phenomenon is a key predictor of our productivity and health. When our ability to communicate is compromised, our quality of life suffers. Although numerous methods to investigate the neuroscientific underpinnings of human language exist, our understanding of this process remains incomplete. Improving our understanding of where, when, and how auditory cortical activity occurs can enhance diagnostic techniques and improve treatment methods for neurological conditions that can impact auditory processing, such as epilepsy, or …

Deformation Manifold Learning Model For Multi Walled Carbon Nanotubes, Shashank S. Pathrudkar

Dissertations, Master's Theses and Master's Reports

Two-Dimensional (2D) materials are being studied widely by researchers due to their superior material properties over the bulk materials. Since the isolation of graphene in 2004, graphene has gained popularity amongst the 2D materials community. Graphene when rolled into sheets form Carbon Nanotubes (CNTs) which possess excellent mechanical and electrical properties. Concentric stacks of CNTs yield Multi-walled Carbon Nanotubes (MWCNTs) which are superior to CNTs in certain aspects. It has been well established that the deformation of CNTs and MWCNTs change their mechanical and electrical properties significantly. This has opened doors for CNTs into numerous applications and also piqued the …

A Combustion Model For Multi-Component Fuels Based On Relative Reactivity And Molecular Structure, Arash Jamali

Dissertations, Master's Theses and Master's Reports

A reliable multi-component surrogate fuel model needs to be able to represent both physical properties and chemical kinetics of a real fuel. However, enhancing the fidelity of a model with detailed description of physical and chemical behavior of all fuel components found in real fuels is limited by the prohibitive computational load to calculate the combustion chemistry of the fuel. Hence, it is desirable to achieve computational efficiency by reducing the number of chemical surrogates at the minimum expense of prediction accuracy. The objective of this work is to develop a model that can simulate the oxidation of multi-component fuels …

Base Vibration Effects On Additive Manufactured Part Quality: A Study Of 3d Printing Onboard U.S. Navy Ships, Nick Jensen

Dissertations, Master's Theses and Master's Reports

The current landscape of manufacturing is evolving because of technology like additive manufacturing (AM). The mobility and compactness of AM are what make it desirable for many industry sectors. The U.S. Navy has shown interest in deploying AM on ships as it could alleviate their dependency on off-route docking to recharge supplies. However, the U.S. Navy's aspiration is currently hindered due to harsh ship-borne environments that degrade AM part quality.

This thesis focuses on vertical base vibration effects on AM part quality. An introduction is first given in Chapter 1 to familiarize the reader with the U.S. Navy's predicament. The …

Understanding The Weather- And Soil-Related Variability In Agricultural Water Footprints: Case Study Of Maize And Soybeans Grown In The St. Joseph Watershed, Karleigh M. Krieg

Dissertations, Master's Theses and Master's Reports

Introduced in 2002, the water footprint is a valuable tool for understanding the consumption of freshwater resources. The traditional approach to quantifying the water footprint is to sum the green, blue, and gray water footprint components. The green water footprint is the volume of water that comes from precipitation, is stored in the soil, and used by vegetation. The blue water footprint is the volume of surface or ground water that is withdrawn and applied to cultivated lands via irrigation. These components are based on the evapotranspiration of green and blue water resources, respectively. The gray water footprint is the …

Design And Implementation Of An Oxidation Catalyst For A Spark Ignited Two Stroke Snowmobile Engine, Noah Squires

Dissertations, Master's Theses and Master's Reports

Spark ignited two stroke engines are under increasing pressure as emissions standards become stricter, making them a perfect candidate for a catalytic aftertreatment system. Yet several significant challenges to catalysis exist. Namely two stroke exhaust systems are very sensitive to back pressure changes and high emissions concentrations can make controlling the temperature of the catalytic reaction difficult. Therefore, it is imperative that a two stroke specific catalyst design process be developed. This project focused on beginning to develop such a design process. Key results of this work include finding a location for the catalyst in the exhaust system that offers …

Test 2246: Fendt 1162 Vario Mt, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Identifying Origin-Destination Trips From Gps Data – Application In Travel Time Reliability Of Dedicated Trucks, Li Zhao, Ying Li

Mid-America Transportation Center: Final Reports and Technical Briefs

The advancement of data collection technologies has brought an upsurge in GPS applications. For example, travel behaviour research has benefited from the integration of multiple sources of Global Positioning System (GPS) data. However, the effective use of such data is still impeded by the challenge in data processing. For instance, GPS data, despite providing detailed spatial movement information, do not label the starting and finishing points of a trip, especially for commercial trucks. Hence, there is a critical need to develop a trip identification method to effectively use the trajectory data provided by GPS without additional information. This paper focused …

Mcnair Scholars Research Journal 2021, Calyha Brown, Caroline Carter, Kalvry Cooper, Perla Rodriguez, Huu Trung Tran, Jose A. Cortes, Orion Wynne, Johnathan Alexander Andres, Joshua Perez, Allison Fenske, Chasidah Fried, Giles Fitzwilliams

McNair Scholars Research Journal-Archive

No abstract provided.