Engineering Commons^™

Investigation Of The Dynamics Of Photocarriers During Photoelectrochemical Water Splitting By Combination Of Photoelectrochemistry And Transient Absorption Spectroscopy, Wen-Hua Leng

Journal of Electrochemistry

Semiconductor photoelectrochemical hydrogen production is an important and promising technology for utilizing solar energy. The efficiency of hydrogen production depends on the efficiencies of separation and transport of photo-generated carriers. A deep understanding of the behavior of these processes has guiding significance for designing efficient solar hydrogen device. photoelectrochemical and transient absorption spectroscopy methods are powerful tool for studying the microscopic dynamics and mechanism of photocatalytic reaction. This review describes the part of the latest results of the author regarding the semiconductor photoelectrochemical hydrogen production obtained by these methods,and the problems and future research priorities in this field are proposed.

Recent Progress In The Mechanistic Understanding Of Formic Acid Oxidation On Pt Electrode, Jie Xu, Dao-Chuan Jiang, Dong Mei, Zheng-Da He, Yan-Xia Chen

Journal of Electrochemistry

This article reviews the recent progress in understanding of the mechanisms for formic acid oxidation on Pt electrode. There are two pathways for formic acid oxidation on Pt electrode: (1) Indirect Pathway through which HCOOH is oxidized to CO₂ through CO_ad intermediate. This pathway contributes only 1% of the total current; (2) Direct Pathway where HCOOH is oxidized directly to CO₂. The results from IR Spectroscopy, single-crystal electrochemistry and DFT calculation all support that the bridge-bonded formate is neither the intermediate of direct pathway nor the precursor for CO_ad formation in indirect pathway. Possible mechanism …

Electrocatalytic Oxidation Of Formate On Pd-Cu/C - Effect Of Dealloying Pretreatment, Kun Jiang, Ye Wang, Tao Lin, Wen-Bin Cai

Journal of Electrochemistry

Carbon supported highly dispersed Pd-Cu nanoalloy catalyst toward formate electrooxidation is prepared via one-pot synthesis by using ethylene glycol as the reducing agent and sodium citrate as the stabilizer. The as-prepared catalyst is structurally characterized by TEM and XRD. The Cu dealloyment is carried out through repetitive potential cycling of the Pd-Cu/C catalyst in an acidic solution. The dealloying effect on the performance of the Pd-Cu/C is investigated by using cyclic voltammetry and chronoamperometry, and the surface structural change of Pd-Cu/C is probed by in situ ATR-IR measurement. The results show that the as-prepared Pd-Cu/C processes a better long-term stability …

Preparation And Lithium Storage Performance Of Sn-Snsb Nanoparticles, Yao Xiao, Jiao-Hong Wu, Qi Wang, Ling Huang, Jun-Tao Li, Shi-Gang Sun

Journal of Electrochemistry

Tin was widely studied as alternative anode material to carbon for lithium-ion batteries thanks to its much higher theoretical capacity. However, a pure tin electrode suffers severely from its poor cycleability due to mechanical fatigue caused by volume change during lithium insertion and extraction processes. Tin-based alloy may improve the cycleability property of tin electrode. In this article, we report facile synthesis of spherical Sn-SnSb nanopartciles using a simple solvent-thermal approach. It is amazing to find that the spherical Sn-SnSb nanoparticles can circumvent volume changes effectively during charge-discharge process. Electrochemical discharge/charge results show that the spherical Sn-SnSb nanoparticles electrode exhibits …

Electrochemical Fabrication Of Two-Dimensional Flower-Like Pt Nanostructures For Methanol Electrocatalytic Oxidation, Xia Wang, Jun Hu, Yong-Jun Li

Journal of Electrochemistry

Two-dimensional flower-like Pt nanostructures (2D FPNs) were fabricated on glassy carbon substrates by galvanostatical electrochemical technique. The electrolyte was the HAuCl₄ + HClO₄ aqueous solution without addition of any structure-directing organic reagent, which made as-prepared Pt nanostructures cleaner, exhibiting much higher reactivity. Scanning electron microscopic images revealed that 2D FPNs were spherical Pt nano-flowers constructed by the smallest building blocks, nano-leaves. The number density of spherical Pt nano-flowers can be tuned by controlling the electrodeposition time. High resolution transmission electron microscopic images indicated that each nano-leaf was formed by growing along Pt(111) direction. Electrocatalytic activities of as-prepared 2D …

Preparation Of Pt-Tio2/Graphene Composites With High Catalytic Activity Towards Methanol Oxidation And Oxygen Reduction Reaction, Li Qi, Ying Yin, Wen-Guang Tu, Bing-Bing Wu, Zhao-Sheng Wang, Jian-Guo Liu, Jun Gu, Zhi-Gang Zou

Journal of Electrochemistry

A series of graphene-supported TiO₂ nanoparticles (TiO₂/G) with different TiO₂ contents were prepared by a facile hydrothermal method, and then the Pt-TiO₂/G catalysts were successfully prepared by reducing Pt-precursor with microwave technique. Compared with Pt-G catalysts, the catalytic performance toward oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) of Pt-TiO₂/G catalysts was improved due to the addition of TiO₂. However, the excessive TiO₂ would lead to a poor catalytic performance of Pt-TiO₂/G catalysts because of the low electrical conductivity of TiO₂.

Effecting Of Dissolved Oxygen On Microbial Fuel Cells Based On Pseudomonas Aeruginosa, Chang-Li Cao, Li-Xiang Chen, Ran-Ran Wu, Ken-Lin Chang, Feng Zhao

Journal of Electrochemistry

In this work, the reaction between the electron shuttle secreted by Pseudomonas aeruginosa and anode was studied by measuring cyclic voltammogram and open circuit potential. The effect of dissolved oxygen on the oxidation reaction of anode was explored. It was demonstrated that the reaction was a diffusion-controlled and reversible process. The anode was a little affected when the dissolved oxygen of inocula was low (0 ~ 1.6 mg·L^-1). The polarization curves showed that the current output of microbial fuel cells decreased 7% with the impact of dissolved oxygen.

Msu Xtreme: Minnesota State University, Mankato's Entry Into The "Clean Snowmobile Challenge 2001", Scott Betcher, Allen Caldwell, Nathan Lindeman, Brian Mandelkow, Dave Maniak, Randy Rohlf, James Skuya, Dennis Swanson, Aaron Wolff, Mark Brandl, Dan Dobesh, Ryan Erickson, Jeff Gillen, Jan Smith, Jason Wilkie

Journal of Undergraduate Research at Minnesota State University, Mankato

Minnesota State University, Mankato’s Automotive Engineering Technology program formed a team to enter the Clean Snowmobile Challenge 2001. Selections for the organization’s machine included a 2001 Polaris Edge Chassis specially outfitted with a 2000 500 cc two-stroke Polaris engine. Modifications to the snowmobile were made specifically for Clean Snowmobile Challenge 2001 events. Acceleration, emissions, cold start, noise, fuel economy/range, handling/drivability, hill climb, and static display made up the list of events featured in the competition. MSU Xtreme has modified the snowmobile in every area with special emphasis on emissions and handling. Testing and analysis of the sled’s systems brought the …

Formula-Sae Wireless Data Logger, Eric Holland

Journal of Undergraduate Research at Minnesota State University, Mankato

The Formula-SAE (Society of Automotive Engineers) race car requires an onboard data logger to obtain and record the performance information received from the Fuel Injection Controller. This data is needed for analyzing the engine performance of the race car. It is advantageous to have this unit transmit the data via a wireless link to a handheld monitoring tool. Having user interface, like a LCD screen and a keypad, would make the monitoring tool easy to use. Also making the monitoring tool communicate with a PC would offer the beneficial features of saving and printing data. By having the PC connectivity, …

Health Risks Caused By Wireless Technologies, Durreeshahwar Zafarahmed, Qurrat-Ul-Ain Zafarahmed

Journal of Undergraduate Research at Minnesota State University, Mankato

There are many health issues related to the use of cellular phones, wireless local area networks, and other devices that emit electromagnetic radiation (EMR). Some of these systems have become a part of our daily lives and many of us are in direct or indirect contact for extended period of times with these devices. However, the general public is unaware of the health risks associated with the use of these devices. Our research covers studies done by individuals as well as organizations on the harmful effects on the health of people from these devices and their claims. We also present …

Rad Car: Restructuring Of The Chassis And Body, Chris Hadfield, Dale Larue

Journal of Undergraduate Research at Minnesota State University, Mankato

This paper covers the project of designing and constructing the RAD Car chassis as part of the requirement for a senior design class. This paper discusses methods of redesigning and constructing a new mold section, complete chassis, and jig fixtures. Also discussed are the steps that were taken to accomplish such a project which included the feasibility of different designs, the choices for these designs, and the costs associated with manufacturing and production.

Comparison Of Optimization Techniques In Large Scale Transportation Problems, Tapojit Kumar

Journal of Undergraduate Research at Minnesota State University, Mankato

The Transportation Problem is a classic Operations Research problem where the objective is to determine the schedule for transporting goods from source to destination in a way that minimizes the shipping cost while satisfying supply and demand constraints. Although it can be solved as a Linear Programming problem, other methods exist. Linear Programming makes use of the Simplex Method, an algorithm invented to solve a linear program by progressing from one extreme point of the feasible polyhedron to an adjacent one. The algorithm contains tactics like pricing and pivoting. For a Transportation Problem, a simplified version of the regular Simplex …

An Economic Analysis Of Small-Scale Biodiesel Production: Implementation Of Ethyl Ester Production In A Job Shop Setting, Scott Haase, Benjamin Craig

Journal of Undergraduate Research at Minnesota State University, Mankato

Biodiesel is becoming a demanded consumer automotive alternative fuel used in diesel vehicles today. An emerging trend is toward small-scale biodiesel production performed by the final consumer. A limited source of commercially available production systems exists and has resulted in many systems being designed and built by the user. Preliminary research conducted by the authors has shown biodiesel to be the least-cost alternative to petroleum diesel after as few as 8 months of system use. This study examines the economic viability of building and producing biodiesel using a small-scale production system versus buying consumer petroleum diesel. During production, measurements were …

Applied Energy Systems - Rudimentary Thermodynamics, Jim Mcgovern

Book/Book Chapters

This is a compact textbook for a module addressing rudimentary thermodynamics within the context of applied energy systems. It is at an introductory level for engineers or technologists. The book does not attempt to cover the principles of thermodynamics comprehensively. Rather, it provides a practical but theoretically sound foundation, linked to some key areas. Energy, heat and work are all introduced, as are units and dimensions. Ideal gases and properties of liquids and vapours are treated. Non-flow and steady flow processes are described. Simple theory is provided for pumps and for the reciprocating compressor. Rudimentary steam and refrigeration or heat …

20140827.5: Engineering Office, 1952-1971, College Of Information Technology And Engineering

Guides to University Archives

These items include materials from the College of Information Technology and Engineering at Marshall University from 1952-1971. Items were received in 2014 and include notable materials about the history of Engineering at Marshall, including training for engineering students, library holdings, the Engineering curriculum report from 1962, samples of student work within Engineering, and the Citizens Committee for presentation and improvement of Engineering from 1972. This is not an exhaustive list. Please download the finding aid for a full list of contents.

Increasing Participation In The Pilot Weather Reporting (Pirep) System Through User Interface Design, Stephen M. Casner

Journal of Aviation Technology and Engineering

Although pilots regard pilot weather reports (PIREPs) as valuable flight planning resources, the number of PIREPs that pilots submit is relatively small. In a previous survey, pilots indicated that submitting PIREPs sometimes requires too much effort, and that they are often unable to recall the information fields required to complete a report. Pilots also indicated that the idea of submitting a PIREP often does not occur to them, and that they feel that other pilots are mainly interested in receiving reports about severe weather. In this study the authors attempt to address obstacles to submitting PIREPs by proposing two alternative …

Validation Of New Technology Using Legacy Metrics: Examination Of Surf-Ia Alerting For Runway Incursion Incidents, Robert Joslin

Journal of Aviation Technology and Engineering

This study demonstrated an innovative method of utilizing expert raters and actual high-risk incidents to identify shortcomings of using legacy metrics to measure the effectiveness of new technology designed to mitigate hazardous incidents. Expert raters were used to validate the Enhanced Traffic Situational Awareness on the Airport Surface with Indications and Alerts (SURF-IA) model for providing alerts to pilots to reduce the occurrence of pilot deviation type runway incursion incidents categorized as serious (Category A or B) by the legacy FAA/ICAO Runway Incursion Severity Classification (RISC) model. The study concluded that the SURF-IA model did not yield an outcome of …

Hybrid Photomultiplier Tube And Photodiode Parallel Detection Array For Wideband Optical Spectroscopy Of The Breast Guided By Magnetic Resonance Imaging, Fadi El-Ghussein, Michael A. Mastanduno, Shudong Jiang, Brian W. Pogue, Keith D. Paulsen

Dartmouth Scholarship

A new optical parallel detection system of hybrid frequency and continuous-wave domains was developed to improve the data quality and accuracy in recovery of all breast optical properties. This new system was deployed in a previously existing system for magnetic resonance imaging (MRI)-guided spectroscopy, and allows incorporation of additional near-infrared wavelengths beyond 850 nm, with interlaced channels of photomultiplier tubes (PMTs) and silicon photodiodes (PDs). The acquisition time for obtaining frequency-domain data at six wavelengths (660, 735, 785, 808, 826, and 849 nm) and continuous-wave data at three wavelengths (903, 912, and 948 nm) is 12 min. The dynamic ranges …

Humic Substances-Based Polymer System, Gerard R. Thiel

Patents (University of Northern Iowa)

A system for use in forming polymer compositions, including as a replacement for phenolic based resin systems, for instance, in preparing foundry molds. In a preferred embodiment, the system includes the use of a) a polyermizable hydroxyl-containing component comprising a humic substance (as can be provided by lignite), b) an isocyanate component, and c) a catalyst, and preferably amine catalyst, component adapted to catalyze the polymerization of a) and b). The system is optionally used as binder system in the presence of a filler, such as, in combination with a foundry aggregate such as sand. A polymer system of this …

Designing An Articulation-Agreement Database For The College Of Science And Engineering And Technology Advising Center, Stephanie Fasen, Susan Hendley, Tim Pham, Danish Zaman

Journal of Undergraduate Research at Minnesota State University, Mankato

During their academic careers, some college students transfer to different universities. To allow students to transfer seamlessly to other colleges, advisors at Minnesota universities create articulation agreements that list the classes that transfer between two universities. To use these documents, students and advisors must search through binders to find the correct articulation agreement and then manually review it. This is a time-consuming process for both students and advisors. To make this information more accessible, we created a web-based database that instantly produces a list of equivalent classes for majors offered at Minnesota St ate University, Mankato (MSU) and other Minnesota …

Effects Of Thermal Boundary Conditions During Finite Element Modeling Of Physical Vapor Transport, Wade Luhman

Journal of Undergraduate Research at Minnesota State University, Mankato

Physical vapor transport (PVT) is a material processing method commonly used to produce different types of semiconductor materials. Computer modeling of PVT is important to understand the fundamentals of the processing method. Due to the large amount of computer processing power and storage needed to solve the computer models many of the previously solved simulations have been simplified to efficiently utilize computer usage. Previous PVT computer simulations of mercurous chloride (Hg2Cl2) have assumed constant temperature profiles on the source and crystal substrate for simplicity. These simulations were performed using the FIDAP computational fluid dynamics software package. In this research the …

Cama Newsletter - August, 2014, Civil Aviation Medical Association

Browse all Civil Aviation Medical Association Newsletters

A twelve page newsletter of the Civil Aviation Medical Association. The newsletter provided news about civil aviation medicine and information related to the organization.

Applying Accelerator Mass Spectrometry For Low-Level Detection Of Complex Engineered Nanoparticles In Biological Media, Binghui Wang, George S. Jackson, Robert A. Yokel, Eric A. Grulke

Pharmaceutical Sciences Faculty Publications

Complex engineered nanoparticles (CENPs), which have different core and surface components, are being developed for medicinal, pharmaceutical and industrial applications. One of the key challenges for environmental health and safety assessments of CENPs is to identify and quantity their transformations in biological environments. This study reports the effects of in vivo exposure of citrate-coated nanoalumina with different rare isotope labels on each component. This CENP was dosed to the rat and accelerator mass spectrometry (AMS) was used to quantify ²⁶Al, ¹⁴C, and their ratio in the dosing material and tissue samples. For CENPs detected in the liver, the …

Compliant Joints Suitable For Use As Surrogate Folds, Isaac L. Delimont

Theses and Dissertations

Origami-inspired design is an emerging field capable of producing compact and efficient designs. The object of a surrogate fold is to provide a fold-like motion in a non-paper material without undergoing yielding. Compliant mechanisms provide a means to achieve these objectives as large deflections are achieved. The purpose of this thesis is to present a summary of existing compliant joints suitable for use as surrogate folds. In doing so, motions are characterized which no existing compliant joint provides. A series of compliant joints is proposed which provides many of these motions. The possibility of patterning compliant joints to form an …

Information Technology News, Georgia Southern University

Information Technology: News & Publications (2012-2023)

• 3rd Annual RSI Hackathon- The Most Stellar Hackathon in the Galaxy! – Augusta

Bridge And Ship Collision Risk Assessment And Safety Management Countermeasures In Shanghai Port Waters, Jianlei Yin

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

The Risk Analysis Of Dangerous Cargo Docks Of Zhenjiang Section Of Yangtze River, Ting Zhu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Analysis On The Issue Of Ship Sewage In Terms Of Pollution, Discharge And Reception In The Minjiang Inland Port With Countermeasures, Binsong Zheng

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Research On Ship's Routeing And Reporting System Of The Malacca And Singapore, Xianwei Zhang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

The Selecting And Risk Analysis Of Temporary Anchor Positions In The Port Area Of Qinhuangdao, Shangying Zhang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.