Engineering Commons^™

An Acoustic-Based Microfluidic Platform For Active Separation And Mixing, Myeong Chan Jo

USF Tampa Graduate Theses and Dissertations

Particle separation is of great interest to many biological and biomedical applications. Flow-based methods have been used to sort particles and cells. However, the main challenge with flow based particle separation systems is the need for a sheath flow for successful operation. Existence of the sheath liquid dilutes the analyte, necessitates precise flow control between sample and sheath flow, requires a complicated design to create sheath flow and separation efficiency depends on the sheath liquid composition. In addition, current gold standard active separation techniques are only capable of separation based on particle size; hence, separation cannot be achieved for same-size …

Fabricating And Characterizing Physical Properties Of Electrospun Polypeptide-Based Nanofibers, Dhan Bahadur Khadka

USF Tampa Graduate Theses and Dissertations

This dissertation has aimed to fabricate polypeptide based biomaterial and characterize physical properties. Electrospinning is used as a tool for the sample fabrication. Project focused on determining the feasibility of electrospinning of certain synthetic polypeptides and certain elastin-like peptides from aqueous feedstocks and to characterize physical properties of polymer aqueous solution, cast film and spun fibers and fiber mats. The research involves peptide design, polymer electrospinning, fibers crosslinking, determining the extent of crosslinking, fibers protease degradation study, fibers stability and self-organization analysis, structure and composition determination by various spectroscopy and microscopy techniques and characterization of mechanical properties of individual suspended …

Continuous Electrowetting In Passivating And Non-Passivating Systems, Mehdi Khodayari

USF Tampa Graduate Theses and Dissertations

Electrowetting is an electromechanical response that can be used to change the equilibrium

shape of droplets on a surface through the application of an electric potential. By applying this potential asymmetrically to a droplet, the droplet can be moved. Typical electrowetting devices use an electrode covered by a dielectric to reduce electrochemical interactions. Successful electrowetting requires electrodes and dielectric layers that can resist damage through many cycles of voltage.

Continuous Electrowetting (CEW) is performed on high resistivity silicon wafers. In this process, when an electric potential difference is applied between the substrate ends, the droplet on the substrate moves towards …

Biomechanics Of Patient Handling Slings Associated With Spinal Cord Injuries, Julie Kahn

USF Tampa Graduate Theses and Dissertations

Pressure ulcers and related skin integrity threats are a significant problem in current transfer/transport systems used for spinal cord injury patients. To understand this problem twenty-three different slings with varying type, material, and features were analyzed in hopes to identify at-risk areas for skin integrity threats such as pressure ulcers. Population samples included non-disabled (otherwise referred to as "healthy") volunteers as well as SCI patients from the James A. Haley Veterans Hospital. High resolution pressure interface mapping was utilized to directly measure the interface pressures between the patient and sling interface. Overall results provide relevant feedback on the systems used …

Optimized Correlation Of Geophysical And Geotechnical Methods In Sinkhole Investigations: Emphasizing On Spatial Variations In West-Central Florida, Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

Abstract

Sinkholes and sinkhole-related features in West-Central Florida (WCF) are commonly identified using geotechnical investigations such as standard penetration test (SPT) borings and geophysical methods such as ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Geophysical investigation results can be used to locate drilling and field testing sites while geotechnical investigation can be used to ground truth geophysical results. Both methods can yield complementary information. Geotechnical investigations give important information about the type of soil, groundwater level and presence of low-density soils or voids at the test location, while geophysical investigations like GPR surveys have better spatial coverage and …

Modeling Nitrogen Transformations In A Pilot Scale Marine Integrated Aquaculture System, Brian Mccarthy

USF Tampa Graduate Theses and Dissertations

Integrated aquaculture systems (IAS) are a type of recirculating aquaculture systems (RAS) where the wastewater is treated and returned to the fish tanks. The important difference between the two is that in an IAS, wastes from the aquaculture component are recovered as fertilizer to produce an agricultural product whereas in an RAS, waste organics, nutrients and solids are treated and discharged. A pilot marine IAS at Mote Aquaculture Research Park in Sarasota, FL was studied for this project. Water quality monitoring, measurements of fish health and growth rates of fish and plants were performed over a two-year period to determine …

A Wearable Motion Analysis System To Evaluate Gait Deviations, Amanda Lynn Martori

USF Tampa Graduate Theses and Dissertations

A Wearable Motion Analysis System (WMAS) was developed to evaluate gait, particularly parameters that are indicative of mild traumatic brain injury. The WMAS consisted on six Opal IMUs attached on the sternum, waist, left and right thigh and left and right shank. Algorithms were developed to calculate the knee flexion angle, stride length and cadence parameters during slow, normal and fast gait speeds. The WMAS was validated for repeatability using a robotic arm and accuracy using the Vicon motion capture system, the gold standard for gait analysis. The WMAS calculated the gait parameters to within a clinically acceptable range and …

Design, Manufacturing, And Assembly Of A Flexible Thermoelectric Device, Christopher Anthony Martinez

USF Tampa Graduate Theses and Dissertations

This thesis documents the design, manufacturing, and assembly of a flexible thermoelectric device. Such a device has immediate use in haptics, medical, and athletic applications. The governing theory behind the device is explained and a one dimensional heat transfer model is developed to estimate performance. This model and consideration for the manufacturing and assembly possibilities are the drivers behind the decisions made in design choices. Once the design was finalized, manufacturing methods for the various components were explored. The system was created by etching copper patterns on a copper/polyimide laminate and screen printing solder paste onto the circuits. Thermoelectric elements …

Quantifying The Ergonomic Impact On Healthcare Workers Using A Needle-Free Injector Device, Humberto Jose Olivero Lara

USF Tampa Graduate Theses and Dissertations

Background: Jet injectors are advantageous over needle injectors by eliminating sharps hazards. The Government Accountability Office estimates 29% preventable sharp injuries with an estimated direct cost of more than $500 million out of the CDC's reported incidence of 385,000 needle stick injuries per year among US hospital healthcare workers. Yet the forces required to set and trigger devices using spring mechanisms for medication delivery have not been explored. This laboratory experiment measured forces exerted by healthcare workers (HCWs) using a particular jet injector approved by FDA in 2011.

Objectives: In order to quantify the ergonomic impact on HCWs using a …

Theoretical Studies Of Co Based Catalysts On Co Hydrogenation And Oxidation, Nianthrini Balakrishnan

USF Tampa Graduate Theses and Dissertations

CO hydrogenation and CO oxidation are two important processes addressing the energy and environmental issues of great interest. Both processes are carried out using metallic catalysts. The objective of this dissertation is to study the catalytic processes that govern these two reactions from a molecular perspective using quantum mechanical calculations. Density Functional Theory (DFT) has proven to be a valuable tool to study adsorption, dissociation, chain growth, reaction pathways etc., on well-defined surfaces. DFT was used to study the CO reduction reactions on promoted cobalt catalyst surfaces and CO oxidation mechanisms on cobalt surfaces.

CO hydrogenation via Fischer-Tropsch Synthesis (FTS) …

Evaluation Of A Pilot Land-Based Marine Integrated Aquaculture System, Suzanne Boxman

USF Tampa Graduate Theses and Dissertations

Recirculating aquaculture systems (RAS) produce aquaculture products on land with minimal discharge of waste products and minimal water loss. High costs associated with waste treatment for RAS have triggered the growth of integrated aquaculture systems (IAS) which incorporate macrophytes (aquatic plants) into the treatment train. The objective of this research was to examine a pilot scale inland marine IAS with three different methods for solids treatment: a sand filter followed by a plant bed, only a plant bed, and geotextile bags. Florida Pompano (Trachinotus carolinus) were grown along with Smooth Cordgrass (Spartina alterniflora), Black Needle Rush …

Synthesis And Investigations Of Type I And Ii Clathrates Of Group 14, Michael Blosser

USF Tampa Graduate Theses and Dissertations

Clathrates are a class of new materials that have an open-framework structure that allows guest atoms or molecules to be enclosed inside of their polyhedral framework. Varying the number, weight, and size of the guest species in a particular framework allows one to alter the physical properties of the clathrate. This relationship enables one to further the fundamental understanding of the physics and chemistry of the clathrate structure and use this knowledge to "tune" certain properties. This "tunability" of inorganic clathrates is of great interest as it allows one to optimize their physical properties; making them promising candidates for a …

Prediction Of The Performance Of A Flexible Footing On A Stone-Column Modified Subgrade, Justin Callahan

USF Tampa Graduate Theses and Dissertations

When foundations are designed on weak clay layers, it is a common practice to modify the subgrade by installing stone columns. Currently used methods for determining the level of ground modification, represented by the percentage of soil replaced (replacement ratio), assume a rigid foundation. These analytical methods provide the designer with the potential settlement reduction based on the compressibility parameters of the subgrade and the replacement ratio. The deficiencies of these methods are the assumption of rigidity of the foundation and the consideration of the settlement reduction as the only design criterion. Furthermore, they do not consider the effects that …

Effect Of Cement Chemistry And Properties On Activation Energy, Andre J. Bien-Aime

USF Tampa Graduate Theses and Dissertations

The objective of this work is to examine the effect of cement chemistry and physical properties on activation energy. Research efforts indicated that time dependent concrete properties such as strength, heat evolution, and thermal cracking are predictable through the concept of activation energy. Equivalent age concept, which uses the activation energy is key to such predictions. Furthermore, research has shown that Portland cement concrete properties are affected by particles size distribution, Blaine fineness, mineralogy and chemical composition. In this study, four Portland cements were used to evaluate different methods of activation energy determination based on strength and heat of hydration …

Socioeconomic Factors' And Water Source Features' Effect On Household Water Supply Choices In Uganda And The Associated Environmental Impacts, Christine M. Prouty

USF Tampa Graduate Theses and Dissertations

Over the last twenty years or more, Uganda has benefitted from significant strides in water and sanitation initiated by the United Nations' Millennium Development Goals. While the rapid progress towards development has been vastly beneficial, it is also important that it does not occur at the expense of the environment. The environmental impacts of these water sources must be evaluated and understood. However, to develop a robust understanding of the impact requires inclusion of the community members who use these sources and their perceptions of them. Consequently, the goal of this research is to investigate the interrelationships between socioeconomic factors, …

Community And Household Management Strategies For Water Supply And Treatment In Rural And Peri-Urban Areas In The Developing World, Ryan William Schweitzer

USF Tampa Graduate Theses and Dissertations

Eighty percent of the 780 million people worldwide that access water from an unimproved source live in rural areas. In rural areas, water systems are often managed by community based organizations and many of these systems do not provide service at the designed levels. The Sustainability Analysis Tool developed in Chapter 2 can inform decision making, characterize specific needs of rural communities in the management of their water systems, and identify weaknesses in training regimes or support mechanisms. The framework was tested on 61 statistically representative geographically stratified sample communities with rural water systems in the Dominican Republic. The results …

Spatial Transferability Of Activity-Based Travel Forecasting Models, Sujan Sikder

USF Tampa Graduate Theses and Dissertations

Spatial transferability of travel forecasting models, or the ability to transfer models from one geographical region to another, can potentially help in significant cost and time savings for regions that cannot invest in extensive data-collection and model-development procedures. This issue is particularly important in the context of tour-based/activity-based models whose development typically involves significant data inputs, skilled staff, and long production times. However, most literature on model transferability has been in the context of traditionally used trip-based models, particularly for linear regression-based trip generation and logit-based mode choice models, with little evidence on the transferability of activity-based models and that …

Aspect Ratio Effect On Melting And Solidification During Thermal Energy Storage, Prashanth Sridharan

USF Tampa Graduate Theses and Dissertations

The present work investigates, numerically, the process of melting and solidification in hollow vertical cylinders, filled with air and phase change material (PCM). The PCM used is sodium nitrate, which expands upon melting. Therefore, a void must be present within the cylinder, which is filled with air. The influence of cylinder shape on melting time is determined. The numerical model takes both conductive and convective heat transfer into account during the melting process. The Volume-of-Fluid (VOF) model is used to track the interface between the PCM and air as the PCM melts. Three dimensionless numbers represent the characteristics of the …

Time Scale Of Groundwater Recharge: A Generalized Modeling Technique, Makhan Virdi

USF Tampa Graduate Theses and Dissertations

Estimating the quantity of water that reaches the water table following an infiltration event is vital for modeling and management of water resources. Estimating the time scale of groundwater recharge after a rainfall event is difficult because of the dependence on nonlinear soil characteristics and variability in antecedent conditions. Modeling the flow of water through the variably saturated zone is computationally intensive since it requires simulation of Richards' equation, a nonlinear partial differential equation without a closed-form analytical solution, with parametric relationships that are difficult to approximate. Hence, regional scale coupled (surface water - groundwater) hydrological models make simplistic assumptions …

Effect Of Bolted Joint Preload On Structural Damping, Weiwei Xu

USF Tampa Graduate Theses and Dissertations

Bolted joints are integral parts of mechanical systems, and bolt preload loss is one of the major failure modes for bolted joint structures. Understanding the damping and frequency response to a varying preload in a single-bolted lap-joint structure can be very helpful in predicting and analyzing more complicated structures connected by these joints.

In this thesis, the relationship between the bolt preload and the natural frequency, and the relationship between the bolt preload and the structural damping, have both been investigated through impact hammer testing on a single-bolted lap-joint structure. The test data revealed that the bolt preload has nonlinear …

The Effects Of Drilling Slurry On Reinforcement In Drilled Shaft Construction, Justin Bowen

USF Tampa Graduate Theses and Dissertations

Drilled shafts are cast-in-place concrete, deep foundation elements that require high levels of quality control to ensure the borehole does not become unstable either during excavation or during concreting. Bentonite slurry is a popular choice among state DOT officials nationwide to maintain borehole stability as it has a long history with reasonable load carrying performance. However, specifications developed to replicate successful shaft construction are largely based on empirical data. Further, as slurry construction is a blind process, the final as-built shaft is rarely visually inspected and much of the perceived concrete flow and slurry interaction with rebar and the soil …

The Biomechanics Of The Tendu In Closing To The Traditional Position, Pli#233; And Relev#233;, Nyssa Catherine Masters

USF Tampa Graduate Theses and Dissertations

Dancers spend many years practicing repetitive movements in order for their bodies to gain flexibility, strength and muscle memory. This thesis investigated the biomechanics of a dance student's knee motion during a tendu to the front in first, third, and fifth positions. A dancer will often perform 75 or more tendu closing actions during one technique class - particularly in ballet technique. During a tendu the moving foot moves along the floor but the toes never leave the floor. The tendu is used to strengthen the leg muscles, particularly the quadriceps and gluteal muscles. Flexion/extension, abduction/adduction, and rotation angles of …

Understanding Pedestrian And Bicyclist Compliance And Safety Impacts Of Different Walk Modes At Signalized Intersections For A Livable Community, Jacob Allen Mirabella

USF Tampa Graduate Theses and Dissertations

With increasing energy costs as well as rampant congestion in major U.S. cities, the popularity of walk and bike mode choices have increased in recent years. Thus, the obtainment of a comprehensive knowledge of pedestrian and bicyclist behaviors is of great importance.

The National Highway Traffic Safety Administration estimates that 11.1%#37; of pedestrian fatalities and 18.5%#37; of bicyclist fatalities in the U.S. occurred in Florida in 2011, which accounts for just 6.1%#37; of the nation's population. Additionally, intersections are hotspots for vehicle-pedestrian conflicts, which is confirmed by the Federal Highway Administration's estimate that nearly one in five pedestrian fatalities occur …

Assessing Appropriate Technology Handwashing Stations In Mali, West Africa, Colleen Claire Naughton

USF Tampa Graduate Theses and Dissertations

Proper hand hygiene is the most effective and efficient method to prevent over 1.3 million deaths annually from diarrheal disease and Acute Respiratory Infections (ARIs). Hand hygiene is also indispensable in achieving the fourth Millennium Development Goal (MDG) to reduce the childhood mortality rate by 2/3rds between 1990 and 2015. Handwashing has been found in a systematic review of studies to reduce diarrhea by 47%#37; and is, thus, capable of preventing a million deaths (Curtis et. al., 2003). Despite this evidence, hand washing rates remain seriously low in the developing world (Scott et al., 2008).

This study developed and implemented …

Evaluating Cfrp-Masonry Bond Using Thermal Imaging, Joseph Christopher Ross

USF Tampa Graduate Theses and Dissertations

This study presents results from non-destructive testing to evaluate the degradation of the CFRP-masonry bond using thermal imaging. The goal of the research was to identify locations where there was evidence of bond deterioration that could subsequently be verified through destructive pull-off testing.

Four full-scale masonry walls were built outdoors at the University of South Florida in 1995 to evaluate the effectiveness of CFRP for repairing settlement damage. Two of the settlement-damaged walls were repaired using single layer, commercially available unidirectional CFRP systems that used Tonen (wall 3) and Henkel (wall 2) epoxies. These two walls were the subject of …

Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh

USF Tampa Graduate Theses and Dissertations

The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was …

Development Of Nanostructured Graphene/Conducting Polymer Composite Materials For Supercapacitor Applications, Punya A. Basnayaka

USF Tampa Graduate Theses and Dissertations

The developments in mobile/portable electronics and alternative energy vehicles prompted engineers and researchers to develop electrochemical energy storage devices called supercapacitors, as the third generation type capacitors. Most of the research and development on supercapacitors focus on electrode materials, electrolytes and hybridization. Some attempts have been directed towards increasing the energy density by employing electroactive materials, such as metal oxides and conducting polymers (CPs). However, the high cost and toxicity of applicable metal oxides and poor long term stability of CPs paved the way to alternative electrode materials. The electroactive materials with carbon particles in composites have been used substantially …

Effect Of Localized Corrosion Of Steel On Chloride-Induced Concrete Cover Cracking In Reinforced Concrete Structures, Ezeddin Rafaa Busba

USF Tampa Graduate Theses and Dissertations

Abstract: Concrete cover cracking due to reinforcement corrosion is widely accepted as a limit-state indicator in defining the end of functional service life for existing reinforced concrete (RC) structures undergoing corrosion. Many of the currently available durability prediction models are incapable of providing realistic estimates of remaining service lives of RC structures beyond the corrosion initiation point. Therefore, the need to incorporate the length of the corrosion propagation stage in a comprehensive durability prediction approach has recently received much research attention. Previous research focus however was mostly limited to the case of uniformly corroding reinforcement with only few studies addressing …

Application And Characterization Of Self-Assembled Monolayers In Hybrid Electronic Systems, Michael Enoch Celesin

USF Tampa Graduate Theses and Dissertations

In this study, we explore ultra-thin insulators of organic and inorganic composition and their potential role as high-speed rectifiers. Typical applications for these structures include IR sensing, chemical detection, high speed logic circuits, and MEMS enhancements. While there are many elements in the functional group required to create a rectifying antenna (rectenna), the primary thrust of this work is on the rectifier element itself.

To achieve these research goals, a very good understanding of quantum tunneling was required to model the underlying phenomenon of charge conduction. The development of a multi-variable optimization routine for tunneling prediction was required. MATLAB was …

Magnetization Dynamics And Related Phenomena In Nanostructures, Sayan Chandra

USF Tampa Graduate Theses and Dissertations

Collective magnetic behavior in nanostructures is a phenomenon commonly observed in various magnetic systems. It arises due to competing inter/intra–particle interactions and size distribution and can manifest in phenomena like magnetic freezing, magnetic aging, and exchange bias (EB) effect. In order to probe these rather complex phenomena, conventional DC and AC magnetic measurements have been performed along with radio–frequency transverse susceptibility (TS) measurements. We also demonstrate the magnetic entropy change as a parameter sensitive to subtle changes in the magnetization dynamics of nanostructures. The focus of this dissertation is to study the collective magnetic behavior in core-shell nanostructures of Fe/γ–Fe …