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Building Services Engineering

No abstract provided.

A Bilayer Self-Assembled Membrane Electrode For Fluorescence And Its Electrochemical Characterization, Xiang-Ying Sun, Bin Liu, Yun-Bao Jiang

Journal of Electrochemistry

The bilayer membrane was assemblied on Au electrode by the electrostatic interaction between the fluorescence regent 1-naphthylamine diacetate acid (NADA) and DL-Cysteine. The SAMs electrode NADA/Cys/Au can be used as fluorescence and electrochemical sensor for metal ions. This paper states the electrochemical characterization of NADA/Cys/Au and SAMs' application in continous determination for Cu²⁺ and Ni²⁺.

The Electrochemical Behaviors Of A Novel Ferrocene Alkylthiol Sams On Au Electrode, Xiao-Gang Zhang, Yan-Li Shi, Hu-Lin Li

Journal of Electrochemistry

A novel alkylthiol molecule containing ferrocene and pyridium moieties and its hydrogenated products were synthesized and subsequently assembled on Au electrode as SAMs. Cyclic voltammogram(CV) was used to investigate the structure-dependent electrochemical response of the SAMs in 0.1 mol/L HClO₄ aqueous solution.

Oxidation Behavior Of Zr-Cu-Al-Ni Amorphous Alloys In Air At 300～500℃, H. H. Hsieh, W. Kai, T. G. Neih, Y. Kawamura

Journal of Electrochemistry

The oxidation behavior of the Zr- based bulk amorphous alloy (BMG; Zr-30Cu-10Al-5Ni in at.%) was studied in dry air over the temperature range 300～500 ℃. The kinetic results indicated that the amorphous alloy oxidized linearly at 300 ℃, while the parabolic oxidation was observed at 350～425 ℃, and the oxidation behavior at 500 ℃ was irregular and complicated. In general, the scales formed on the surface of the amorphous alloy were temperature-dependent, consisting of tetragonal-ZrO₂ at 300 ℃, and of mostly tetragonal-ZrO₂ as well as minor amounts of monoclinic-ZrO₂ and CuO at T ≥ 350 ℃.

Electrochemical Monitoring On The Deactivation Of A Metallic Oxide Anode, Li-Kun Xu, Shi-Zhe Song, Ting-Yong Wang, Guang-Zhang Chen

Journal of Electrochemistry

The process of accelerated life test of an IrO₂/Ta₂O₅ coated titanium anode was monitored using cyclic voltammetry and electrochemical impedance spectroscopy. The vatiation with electrolysis time of anodic voltammetric charge Q^*, the double layer capacitance C_dl,the oxide film resistance R_f and the charge transfer resistance R_ct for oxygen evolution was measured. A deactivation mechanism was proposed based on the observation results.

Synthesis And Electrochemical Characteristics Of Nickel-Based Complex Oxide LiANi0.78Co0.2Cd0.02O2, Rong-Zhong Yuan, Mei-Zhen Qu, Zuo-Long Yu

Journal of Electrochemistry

The nickel-based complex oxide Li_aNi_0.78Co_0.02O₂ cathode materials for lithium-ion rechargeable batteries was synthesized by the improved solid-state reaction method with LiOH·H₂O, ball-like Cd-doped Ni(OH)₂ and Co₂O₃ as raw materials. The analysis ICP-AES proved that the as-prepared compounds were near the stoichiometric form. The XRD, SEM and electrochemical characteristics testing were also carried out. The results showed that the complex cathode material Li_aNi_0.78Co_0.2Cd_0.02O₂ has layered structure, homogeneous surface distributions,uniform particles with good crystal morphology as well as stable electrochemical …

Conductance Properties For Electrolyte Of Lithium Ion Battery At Low Temperature, Jing-Li Han, Yan-Mei Yu, Jian Chen, Chun-Tong Wang

Journal of Electrochemistry

The system of LiPF₆-ethylene carbonate (EC)-methy1 acetate (MA) was studied. The conductivities of this system were measured under various composition and various salt concentrations at temperature range of 20～-50 ℃. The optimum composition of this system was selected. The tests of cyclic voltammography and charge-discharge were carried out. This system was compared with commercial electrolyte solution.

Effect Of Scn- On The Transition Current Of Zn During The Electrodeposition Zn-Co Alloys, Ren-He Yin, Wei-Min Cao, Zheng-Hua Fang

Journal of Electrochemistry

For co-deposition of Zn-Co alloys at sufphate baths with micro-concentration of SCN^- the transition current of Zn was found with the deposition process changing from normal Co-deposition to anomalous co-deposition, and the value of transition current increased with increasing SCN^- concentration, but decreased with increasing value of pH. The existence of SCN^- decreases the evolution overpotential of Co metal, but has no effects on the evolution overpotential of Zn metal and H₂.

Recent Progress In The Research On Electrodeposition Of Composite Coatings, Xiao-Bing Liu, Xu-Cheng Wang, Yu Chen, Dan-Hong Cheng, Zu-Zhan Yu

Journal of Electrochemistry

Recent progress in the research on composite coatings prepared by electroplating technology is reviewed. The nanoscaled particles, electrocatalytic, photoactive composite coatings are emphatically discussed. The composite coatings prepared by dispersing nanoscaled particles could attain better hardness, wear resistance and corrosion resistance than those of composite coatings which prepared by adding micronscaled particles. As compared with pure metal electrode and alloy electrode, some electrocatalytic composite coatings electrode could markedly reduce the overvoltages of cathodic and anodic electrode reaction. In recent years, the electrocatalytic composite coatings which based on metal oxides and conductive polymer as matrix materials become a newest field of …

Initial Stages Of Pd Deposition Onto Au(111) Electrodes From Pdso4, Jing Tang, Petri M., Kibler L.A., Kolb D.M.

Journal of Electrochemistry

Metal thin films have attracted considerable interest in relation to catalysis, energy, material, corrosion and environmental protection. Pd thin film is capable of proton reduction and strong hydrogen absorption, which has shown electrocatalytic activity to the oxidation of small organic molecules. In this paper, in-situ STM measurements are performed to study the deposition process and the influence of the surface structure and anion adsorption. When Pd is deposited from PdSO₄ solution on Au(111) in the UPD range, a monolayer of Pd with pseudomorphic (1×1) structure was formed on the substrate with induced (3×7) R19° SO₄^2- adsorption. With …

Preparation And Electrochemical Preformance Of Zn-La Alloys, Xian-Ling Meng, Hua-Bin Yang, En-Dong Yang, Xiao-Dan Wang, Hai-Chang Zhang, Jun-Hong Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

Zn-La alloys were prepared by solid phase diffusion method and the effects of La on the electrochemical performance of zinc electrodes were investigated using potentiostatic polarization technique and charging/discharging cycle test. The results showed that adding La to zinc electrode remarkably suppressed the zinc dendrite, the shape of zinc electrode and zinc corrosion, and hence, markedly improved the cycle performance of zinc electrodes. The discharging capacity of the zinc electrode containing 0.5at.% La which was the optimum was still 520 mAh/g after it cycled 80s at the current of 100 mA. The XPS showed that La element mainly adhered on …

Microstructure And Electrochemical Characteristics Of The Anodic Film Formed On Aluminum Surface, Jeng-Kuei Chang, Chi-Min Liao, Chih-Hsiung Chen, Wen-Ta Tsai

Journal of Electrochemistry

The thickness, morphology, chemical composition, and crystallinity of the anodized film formed on aluminum were examined in a transmission electron microscope (TEM). Thin foil for TEM analysis was prepared by ultramicrotomy. The relationship between the microstructure and the electrochemical characteristics of the alumina film forming on the pure aluminum was discussed in this investigation. At the forming voltage less than 100V, the anodized films formed at 85 ℃in aqueous ammonium adipate electrolyte was amorphous in nature. Although the film resistance was increased with the forming voltage, its dielectric constant was not changed significantly. As the forming voltage exceeded 100V, crystalline …

Study Of Marine Biocorrosion Using Afm And Molecular Techniques, Herbert H.P.Fang, Lichong Xu, Tong Zhang

Journal of Electrochemistry

Biofilm is ubiquitous in nature.However,corrosin caused by biofilm is still by and large overlooked. This presentation is to demonstrate the applications of several newly developed analytical techniques in chemisrty and microbiology for the study of marine biocorrosion on steel. AFM(atomic force microscopy) was applied to investigate the initial formation mechanism of biofilm and the degree of corrosion of steel in polluted seawater. DNA/RNA-related molecular techniques were used to analyze the microbial composition corrosive biofilm. Results showed that microbial corrosion began within six days, and the corroded volume in the increased as a power function of time with an index 2.83. …

Selective Corrosion In Duplex Stainless Steel, Wen-Ta Tsai, Kuen-Ming Tsai, Chang-Jian Lin, Yan Fu

Journal of Electrochemistry

In duplex stainless steel, the two constituent phases, namely ferritic (α) and austenitic (γ) phases, have different crystal structure and chemical composition. They may thus exhibit different corrosion resistances in aqueous environment. In this investigation, an electrochemical technique with spatial resolution was employed to measure the potential difference between these two constituent phases in 2205 duplex stainless steel. Image analyzing techniques were also used to examine the preferential corrosion between α and γ phases. The experimental results showed that ferrite had a higher potential than austenite in 0.01 mol/L NaCl solution. In 2 mol/L H₂SO₄+x mol/L …

Corrosion Behavior Of Reinforcing Steel In Concrete Subjected To Chloride Contamination By Eis, Rong-Gang Hu, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS) was employed to study the influence of chloride on the corrosion behavior of reinforcing steel in concrete. In Nyquist plot, the spectrum consists of two semicircles, indicating that the reinforced concrete system contained two time constants,one derived from electrical double layer of reinforcing steel and the other from the deposition film of concrete layer. The depressed semicircle in lower frequency featured the non-faradic behavior of the electrical double layer (EDL) deviated from idea capacitor due to diffusive effect which was attributed to the surface roughness of rebar and the inhomogenity of concrete layer. Then the EDL was …

Corrosion Behavior Of Mg1.85Mm0.15Ni Hydrogen Storage Alloy Modified By Electroless Cu In Ch3Ohâ·H2O Solutions, Hua-Bin Yang, Hai-Chang Zhang, Hua Sun, Xiao-Dan Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

The corrosion behavior of the Mg_1.85Mm_0.15Ni (Mm:Ce-rich mischmetal) alloy modified by electroless Cu coating in different CH₃OH-H₂O solutions has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy. These results showed that the corrosion behavior was improved after electroless Cu. The potentiodynamic polarization and electrochemical impedance spectroscopy results showed that the alloy electrode had more promising anti-corrosion behavior after coated in a 40%CH₃OH-H₂O solution. The values of corrosion current density and electrode reaction resistance were 5.6 mA·cm^-2 (11.7 mA·cm^-2 for uncoated alloy electrode) and 22.25 Ω·cm …

Perfluorinated Sulfonic Acid Lithium Conductivity Humidity Sensor, Hong-Feng Xu, Jing Liu, Li Wan

Journal of Electrochemistry

Treat carbon paper with 3% PTFE solution and dried in 340 ℃ for 40 minutes to enhance its intension, and level off the surface of the carbon paper with a mixture of XC-72 carbon black and PTFE solution. With those treated carbon paper as electrodes, recast Nafion thin film from 5% Nafion solution as humidity sensitive material, a solid polymer electrolyte humidity sensor was prepared on a thin PET film. Take the relative humidity data from several saturated salt solutions, the relationship between conductivity response and relative humidity was studied at different relative humidies .The results showed: when the polymer …

Corrosion Prediction Of Carbon Steel In Concentrated Lithium Bromide Solutions At High Temperature Using Bp Neural Network, Nai-Bao Huang, Cheng-Hao Liang

Journal of Electrochemistry

Neutral network model has been developed for the computation of corrosion rate of carbon steel in LiBr solutions.The results indicate that the model is capable of reproducing the effects of changes in alkalinity, temperatures, LiBr and Na₂MoO₄ concentrations on the rates of general corrsion and good agreement between calculated and experimental corrosion rate is obtained. The model can be used to satisfactorily predict the corrosion rate of carbon steel in different concentrations of LiBr solutions containing different inhibitors at different temperatures. It also provides a novel method for corrosion monitoring of metals used in LiBr absorption chiller.

Security Watch: No-Fly Zones And Flying Blind, Ibpp Editor

International Bulletin of Political Psychology

The article evaluates the gain in security from no-fly zones from a security perspective.

Risk Perception Regarding Energy Production: Factor Structure In A French Sample, Etienne Mullet, Anne Bertrand, Cécilia Lazreg, Sheila Rivière Shafighi

The University of New Hampshire Law Review

[Excerpt] "Considering that energy production is a key factor in the development of nations, it is important to have detailed information on the risks attributed by lay people to the different types of energy as well as the different stages of energy production. This study reports on the structure of risk perception with regard to energy production found among French participants. There have already been many investigations of risk perception related to energy production. . . .

The present study is a direct extension of the Mullet study. A similar, although more complete, set of items was used. These items …

Co-Operation In Health And Safety: A Game Theory Analysis, Sylvie Nadeau

The University of New Hampshire Law Review

[Excerpt] “Health and safety managers face complex challenges in today’s production environments. They are confronted with increasingly flexible, autonomous and polyvalent contexts. Asymmetry of information on the workplace is widespread because various intervening parties rely on information lacking conformity. Social partners generate and use information which supports or benefits their pursuit of differing goals. Ascertaining and controlling this information can prove both difficult and costly. When addressing health and safety issues, one intervening partner alters or changes behavior in response to changes introduced by the other side. Strategic behaviors result, based on post-contract opportunism (moral hazard) and alliances with partners …

Bs News

Building Services Engineering

No abstract provided.

Trends. Aviation Security: Thinking About Capps, Capps Ii, And Beyond, Ibpp Editor

International Bulletin of Political Psychology

This Trends article discusses computer assisted passenger prescreening systems (CAPPS) and aviation security.

Bs News

Building Services Engineering

No abstract provided.

Study About High Influence Doping To Base Resistance And Bandgap Narrowing At Si/Si1-Xgex/Si Heterojunction Bipolar Transistor, Achmad Fadhol

Makara Journal of Technology

Study About High Influence Doping to Base Resistance and Bandgap Narrowing at Si/Si1-xGex/Si Heterojunction Bipolar Transistor. Heterojunction is a link formed bedween two semiconductor materials and differend bandgap which has thinness under 50nm and grow the mixture of plate SiGe as bases. The link is an abrupt link or graded one. In this research learnt formulation of doping concentration influence to basis resistance and bandgap narrowing through Si/Si1-xGex/Si Heterojunction Bipolar Transistor with abrupt emitter-basis link, besides taking care to mobility and basis wide to basis resistance, it is also influence of mole fraction to bandgap power. From the result shows …

Photocatalytic Treatment Of Heavy Metal Waste Cr(Vi) Withtio2 Photocatalyst, Slamet Slamet, Riyadi Syakur, Wahyu Danumulyo

Makara Journal of Technology

Photocatalytic Treatment of Heavy Metal Waste Cr(VI) with TiO2 Photocatalyst. The photocatalytic reduction of hexavalent chromium/Cr(VI) using TiO2 and copper-doped TiO2 as photocatalysts have been studied in stirred tank and circulating photoreactors. All photocatalysts were characterized with FTIR (Fourier Transform Infra Red), BET (Brunauer-Emmett-Teller), XRD (X-Ray Diffraction) and SEM (Scanning Electron Microscope). TiO2 Merck and Degussa P-25 are the commercial photocatalysts used to compare the photocatalytic activity of all the prepared catalysts. Blank test experiments as well as the effect of dopants, EDTA (ethylenediaminetetraacetic acid) and activated carbon addition were studied. Cr(VI) reduction on various pH and initial Cr(VI) concentration …

Development And Analysis Of Geographic Information System For Electricity Network (Case Study: Surabaya Industrial Estate Rungkut In Surabaya)., Lilik Jamilatul Awalin, Bangun Muljo Sukojo

Makara Journal of Technology

Development and Analysis of Geographic Information System for Electricity Network (Case Study: Surabaya Industrial Estate Rungkut in Surabaya). Geographic Information System (GIS) is a system of data which has spatial base. This may be cause has ability to process and analysis data quickly. The ability of GIS will be able to process the alternative in decision making. The need of electric power grows until recent time along with the existence of industrial sector expansion and land use expansion claim better service, large and balance stock of electric power. GIS is a solution for planning and managing data base system, for …

Application Of Remote Sensing And Geographic Information System Methods For Land Using Difference, Bangun Muljo Sukojo, Diah Susilowati

Makara Journal of Technology

Application of Remote Sensing and Geographic Information System Methods for Land Using Difference. Land using difference analysis has been done using remote sensing and Geographic Information System (GIS) methods. Identification of land using difference was conducted using map overlaying process of 1990s (digitized scalling 1:50.000) and 1997s land using map (interpreted from Landsat TM (Thematic Mapper) Image 1997) with UTM (Universal Transverse Mercator) coordinate. Image enhancement was done through histogram equalization with supervised classification devided into 7 classes: rice field, settlement, dry field, industry, pond, sport field and bush. Land using difference and river pollution BOD (Biological Oxygen Demand), COD …

Phase Composition Analysis Using Rietveld Methode And It's Influence To The Hardness Of Ti-Si-N Nanocomposites, Keba Moto, Lia Setiarini, Zufar Abubakar

Makara Journal of Technology

Phase composition analysis using rietveld methode and it’s influence to the hardness of Ti-Si-N nanocomposites. XRD data of nanocomposites Ti-Si-N have been analysed using GSAS based on Rietveld Method in order to identify phases and their composition as well as its influence on the hardness of these nanocomposites. Several new phases have been found in the sample beside the nc-TiN/a-Si3N4& a-/nc-TiSi2 that have been known widely. From the obtained crystalline phase, after the calculation of amorf Si3N4 and TiSi2 phase fraction, it is found that the optimum hardness can be reached when the fraction of a-Si3N4 phase around 8 wt.%

Influence Of Strain Rate And Temperature Of Hot Tension Testing On Mechanical Properties Of Medium Carbon Steel S48c, Dedi Priadi, Iwan Setyadi, Eddy S. Siradj

Makara Journal of Technology

Influence of Strain Rate and Temperature of Hot Tension Testing on Mechanical Properties of Medium Carbon Steel S48C. The characterization of S48C by hot tension testing was done to understanding the influence of temperature and strain rate for S48C flow stress, that close relationship with its forge ability. The hot tension testing was performed on temperatures and strain rates variation (T 850, 900, 950 0C and έ 0,01;1 s-1). The result of hot tension testing showed that increasing temperature decreases ultimate tensile strength (UTS) and flow stress of S48C. The higher decreasing of UTS is on 950 0C about 85% …