Engineering Commons^™

Optimization Of A Dynamic Hot Water Pretreatment Of Switchgrass Using Catalysis By Carbonation To Maximize Carbochemical Yields, Rohit Tanaji Dhamdere

Graduate Theses and Dissertations

A bio-refinery is a facility that converts renewable bio-resources into value-added chemicals and products. In this context of a bio-refinery, the production of the carbochemicals such as HMF, furfural and organic acids illustrate that multiple products can be produced from a renewable source such as lignocellulosic biomass (switchgrass). Traditionally, carbochemicals such as furfural and HMF are produced using inorganic acids such as H2SO4, HCL, and H3PO4. The use of such acids requires the application of high cost materials of construction such as Hastelloy-C, titanium etc.

The objective of this study is to develop a semi-continuous process for the conversion of …

Fabrication And Characterization Of Thinner Solid-State Nanopores, Denis Forbi Tita

Graduate Theses and Dissertations

Solid State nanopores that are fabricated by the ion beam sculpting process and electron beam drilling have shown great promise as a sensing device for DNA and protein molecules. Even though biological pores such as the alpha-Haemolysin have been in use for quite some time, the use of solid state Nanopores in single biomolecule detection has been on the rise since the mid 1990s. Solid State nanopores have an advantage over biological pores in that they are more robust, stable, and can be sculpted to any desired size for use in translocation experiments. One of the major challenges in Nanopore …

Delay Insensitive Ternary Logic Utilizing Cmos And Cntfet, Ravi Sankar Parameswaran Nair

Graduate Theses and Dissertations

As digital circuit design continues to evolve due to progress of semiconductor processes well into the sub 100nm range, clocked architectures face limitations in a number of cases where clockless asynchronous architectures require substantially less power, generate less noise, and produce less electromagnetic interference (EMI). This dissertation develops the Delay Insensitive Ternary Logic (DITL) asynchronous design paradigm that combines the designs aspects of similar Dual-Rail asynchronous paradigms and Boolean logic to create a single wire per bit, three voltage signaling and logic scheme.

DITL is designed at the transistor level using multi-threshold CMOS and carbon nanotube (CNT) FETs to develop …

Semiconductor Nanocrystals: From Quantum Dots To Quantum Disks, Zheng Li

Graduate Theses and Dissertations

The bottom-up colloidal synthesis opened up the possibility of finely tuning and tailoring the semiconductor nanocrystals. Numerous recipes were developed for the preparation of colloidal semiconductor nanocrystals, especially the traditional quantum dots. However, due to the lack of thorough understanding to those systems, the synthesis chemistry is still on the empirical level. CdS quantum dots synthesis in non-coordinating solvent were taken as a model system to investigate its molecular mechanism and formation process, ODE was identified as the reducing agent for the preparation of CdS nanocrystals, non-injection and low-temperature synthesis methods developed. In this model system, we not only proved …

A Silicon Carbide Linear Voltage Regulator For High Temperature Applications, Javier Antonio Valle Mayorga

Graduate Theses and Dissertations

Current market demands have pushed the capabilities of silicon to the edge. High temperature and high power applications require a semiconductor device to operate reliably in very harsh environments. This situation has awakened interests in other types of semiconductors, usually with a higher bandgap than silicon's, as the next venue for the fabrication of integrated circuits (IC) and power devices. Silicon Carbide (SiC) has so far proven to be one of the best options in the power devices field.

This dissertation presents the first attempt to fabricate a SiC linear voltage regulator. This circuit would provide a power management option …

Plasmonic Pervaporation Via Gold Nanoparticle-Functionalized Nanocomposite Membranes, Aaron Russell

Graduate Theses and Dissertations

Butanol derived from biological feedstocks has significant potential as a liquid fuel source, but the separation methods used in its production can be prohibitively expensive and are therefore currently the subject of extensive research. Pervaporation is a promising membrane process that is effective in butanol separations, but involves a large energy demand. This study examines the possibility of increasing flux and energy efficiency in pervaporation via plasmonic heating of gold nanoparticle-functionalized, polymer nanocomposite membranes (AuNCMs) in lieu of conventional feed heating. An economic analysis demonstrated that plasmonic pervaporation could achieve significant reductions in energy usage and utility cost in butanol …

Optimization Models And Algorithms For Truckload Relay Network Design, Hector Andres Vergara Arteaga

Graduate Theses and Dissertations

Driver turnover is a significant problem for full truckload (TL) carriers that operate using point-to-point (PtP) dispatching. The low quality of life of drivers due to the long periods of time they spend away from home is usually identified as one of the main reasons for the high turnover. In contrast, driver turnover is not as significant for less-than-truckload (LTL) carriers that use hub-and-spoke transportation networks which allow drivers to return home more frequently. Based on the differences between TL and LTL, the use of a relay network (RN) has been proposed as an alternative dispatching method for TL transportation …

Slope Stability Monitoring Using Remote Sensing Techniques, Omar Alberto Conte Robles

Graduate Theses and Dissertations

During the past six years the Arkansas State Highway and Transportation Department (AHTD) has spent over nine million dollars repairing slope failures that have occurred in the state of Arkansas. Specifically, higher than average precipitation in 2004 and 2008 led to large quantities of slides, all of which were repaired. Two highways, within the state of Arkansas, with known historical movements along or across the highways are being monitored using traditional surveying techniques and advanced remote sensing techniques. These slides, both of which are located in fill slopes. One a 500-foot long slide located north of Chester, Arkansas, within the …

Cross-Linked Pdms Expansion Due To Submersion In Liquid And Supercritical Co2, Teng Yang

Graduate Theses and Dissertations

Characterization of micro/nano-copper particles impregnated Polydimethylsiloxane (PDMS) submersed in supercritical carbon dioxide (scCO2) was studied. The purpose of this investigation was to advance micro-corrosion sensor technology utilizing PDMS and micro-metal particle composite as the sensing element currently under-development. One of the key challenges encountered was the removal of the native oxides inherently existing on the metal particles. Numerous techniques were experimented with to counter this problem at the UA Engineered Micro/Nano Systems Laboratory (EMNSL), with swell-based protocols being identified as the most promising solution. In terms of compatibility to Micro-electro-mechanical Systems (MEMS) fabrication, CO2 is often used in the release …

Energy Consumption And Greenhouse Gas Emissions From Commercial And Manufacturing Sectors Specific Studies On Hvac Equipment And Dairy Processing, Aik Jong Tan

Graduate Theses and Dissertations

Commercial and manufacturing sectors in United States consumed approximately 50% of the total End use energy in 2010. In 2009, 81.5% of the greenhouse gas (GHG) emitted in the United States was energy related. From the broad aspects of commercial and manufacturing sectors; two relatively narrow and specific topics, commercial building's HVAC equipment and dairy processing were chosen to increase the understanding of the energy use and GHG emission in these two sectors. Few published studies related to these two specific areas are available. The first study in this thesis discussed the energy use and GHG emissions by HVAC equipment …

Molecular Dynamics Study Of Diffusion Of O2 Penetrates In Uncrosslinked Polydimethysiloxane (Pdms), Crosslinked Pdms, And Pdms-Based Nanocomposites, Varun Ullal

Graduate Theses and Dissertations

Molecular dynamics simulations are used to study diffusion of O₂ molecules in pure polydimethysiloxane (PDMS), crosslinked PDMS, and PDMS-based nanocomposites. The PDMS chains and penetrates are modeled using a hybrid interatomic potential which treats the Si-O atoms along the chain backbone explicitly while coarse-graining the methyl side groups and penetrates. By tracking the diffusion of penetrates in the system and subsequently computing their mean-squared displacement, diffusion coefficients are obtained. In pure PDMS models of varying molecular weight, diffusivity of the O₂2 penetrates is found to have an inverse relationship with chain length. Simulation models with longer chains …

Efficacy Of Geosynthetic Separators And Filters: An Evaluation Of Test Sections In Marked Tree, Arkansas, Ashique Ali Boga

Graduate Theses and Dissertations

Field and laboratory tests were conducted on 18 full-scale, geosynthetic reinforced, roadway test sections located in Marked Tree, Arkansas. Base course, geosynthetic, and subgrade samples were collected, and pavement depth, in-situ density and in-situ hydraulic conductivity measurements were obtained during a geotechnical site investigation. The performance of sections containing geotextile products being used for separation and filtration (Carthage Mills FX-66, Mirafi 570, Propex 2006, Propex 2044, and Propex 4553) was investigated.

Moisture content, sieve analysis, Atterberg limits, modified proctor, specific gravity, and hydraulic conductivity tests were performed on the acquired soil samples. Transmissivity and permittivity testing was conducted on the …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Computer Modeling Of The Influence Of Structure Plan Areas On Tornado Forces, Nashmi Hassan M Alrasheedi

Graduate Theses and Dissertations

The study of the conventional Straight Line (SL) wind flow dominates research into wind loads on structures. Most structure design takes into account only research into SL flow. Few researchers have studied tornado forces on buildings and attempted to distinguish between tornadic wind loads and SL flow loads. Using a computer simulation, this research addresses and distinguishes between the tornadic forces and SL forces on structures. In the numerical simulation, tornado forces and SL forces will be compared on large structure plan areas and on thin structure plan areas. Additionally this research investigates how the increase in the vortex strength …

Design And Implementation Of A Small Electric Motor Dynamometer For Mechanical Engineering Undergraduate Laboratory, Aaron Farley

Graduate Theses and Dissertations

This thesis set out to design and implement a new experiment for use in the second lab of the laboratory curriculum in the Mechanical Engineering Department at the University of Arkansas in Fayetteville, AR. The second of three labs typically consists of data acquisition and the real world measurements of concepts learned in the classes at the freshman and sophomore level. This small electric motor dynamometer was designed to be a table top lab setup allowing students to familiarize themselves with forces, torques, angular velocity and the sensors used to measure those quantities, i.e. load cells and optical encoders. The …

Design Of Orbital Maneuvers With Aeroassisted Cubesatellites, Stephanie Clark

Graduate Theses and Dissertations

Recent advances within the field of cube satellite technology has allowed for the possible development of a maneuver that utilizes a satellite's Low Earth Orbit (LEO) and increased atmospheric density to effectively use lift and drag to implement a noncoplanar orbital maneuver. Noncoplanar maneuvers typically require large quantities of propellant due to the large delta-v that is required. However, similar maneuvers using perturbing forces require little or no propellant to create the delta-v required. This research reported here studied on the effects of lift on orbital changes, those of noncoplanar types in particular, for small satellites without orbital maneuvering thrusters. …

Plasma-Assisted Molecular Beam Epitaxial Growth Of Indium Nitride For Future Device Fabrication, Steven Paul Minor

Graduate Theses and Dissertations

The need for energy conservation has heightened the search for new materials that can reduce energy consumption or produce energy by the means of photovoltaic cells. III-nitride alloys show promise for these applications due to their generally good transport properties and ability to withstand high power applications. Along with these, this family of semiconductor alloys has a direct bandgap energy range (0.7-6.2 eV) which spans the entire visible spectrum and encompasses a large portion of the available solar spectrum. Of the three root III-nitride semiconductors, AlN, GaN, and InN, InN has only recently become attainable epitaxially with qualities good enough …

Aptamer-Based Spr Biosensor For Detection Of Avian Influenza Virus, Hua Bai

Graduate Theses and Dissertations

Rapid and specific detection of avian influenza (AI) virus is urgently needed with the concerns over the outbreaks of highly pathogenic H5N1 avian influenza in animal and human infection. Aptamers are artificial oligonucleic acid that can specifically bind to target molecules. They show comparable affinity for target virus and better thermal stability than monoclonal antibodies. Those advantages make aptamers promising candidates in diagnostic and detection applications. The goal of this research was to use DNA&ndashaptamer as the specific recognition element in a portable surface plasmon resonance (SPR) biosensor for detection of AI H5N1 virus in poultry.

A SPR biosensor was …

Investigation Of Negative Differential Resistance Phenomena In Quantum Well Heterostructures, Nazariy Andrushchak

Graduate Theses and Dissertations

Increasing interest in entirely new possibilities for quantum mechanical description of carriers transport is becoming more evident with the developing advancements in epitaxial growth technique. Consequently, molecular beam epitaxy (MBE) technique is considered to be the most precise technique that allows the growth of ultra-thin layers of different compositions.

Those structures can be designed to investigate the wave-nature of carriers, which broadens the possibilities in device design and fabrication for a specific area. In this thesis the fundamental study of the real space charge transfer (RST) mechanism that took place in quantum well heterostructures and led to the negative differential …

Experimental Study Of Novel Materials And Module For Cryogenic (4k) Superconducting Multi-Chip Modules, Ranjith John

Graduate Theses and Dissertations

The objectives of this proposal are to understand the science and technology of interfaces in the packaging of superconducting electronic (SCE) multichip modules (MCMs) at 4 K. The thermal management issue of the current SCE-MCMs was examined and the package assembly was optimized. A novel thermally conducting and electrically insulating nano-engineered polymer was developed for the thermal management of SCE-MCMs for 4 K cryogenic packaging. Finally, the nano-engineered polymer was integrated as underfill in a SCE-MCM and the thermal and electrical performance of SCE-MCM was demonstrated at 4 K.

Niobium based superconducting electronics (SCE) are the fastest known digital logic …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …

Silicon Germanium Sram And Rom Designs For Wide Temperature Range Space Applications, Matthew Barlow

Graduate Theses and Dissertations

This thesis presents a design flow from specifications and feature requirements to embeddable blocks of SRAM and ROM designs from 64 bytes to 1 kilobyte that are suitable for lunar environments. The design uses the IBM SiGe 5AM BiCMOS 0.5 micron process for a synchronous memory system capable of operating at a clock frequency of 25 MHz. Radiation mitigation techniques are discussed and implemented to harden the design against total ionizing dose (TID), single-event upset (SEU), and single-event latch-up (SEL). The memory arrays are also designed to operate over the wide temperature range of -180 °C to 125 °C. Design, …

Electrospun Polycaprolactone Nanofiber Scaffolds For Tissue Engineering, Andreas Haukas

Graduate Theses and Dissertations

Stem cell and tissue engineering offer us with a unique opportunity to research and develop new therapies for treating various diseases that are otherwise incurable using traditional medicines. However, development of these new therapies replies upon the establishment of in vitro cell culture and differentiation systems that mimic in vivo microenvironments required for cell-cell and cell-ECM interaction. The development of these cell culture systems depends upon the identification of appropriate biomaterials and cell sources. Biomaterials should be carefully selected and fabricated into scaffolds for supporting cell growth and differentiation. In this study, we explored the fabrication of 3D electrospun nanofiber …

Development Of A Microfluidic Device Coupled To Microdialysis Sampling For The Pre-Concentration Of Cytokines, Randy Francisco Espinal Cabrera

Graduate Theses and Dissertations

A proof-of-concept microfluidic device combined with heparin-immobilized magnetic beads was created to concentrate cytokine proteins collected from microdialysis samples. Cytokines are known to be related to several diseases such as cancer, and Parkinson's diseases, so to be able to develop more effective diseases treatments their interactions have to be well understood. Amine-functionalized polystyrene and carboxyl-functionalized magnetic microspheres of ~6.0 ìm in diameter were used to immobilize heparin. The amount of heparin immobilized on polystyrene beads was 5.82 x 10-8 ± 0.36 x 10-8 M per 1.0 x 106 beads and for magnetic beads was 0.64 x 10-8 ± 0.01 x …

Extending The Hybridthread Smp Model For Distributed Memory Systems, Eugene Anthony Cartwright Iii

Graduate Theses and Dissertations

Memory Hierarchy is of growing importance in system design today. As Moore's Law allows system designers to include more processors within their designs, data locality becomes a priority. Traditional multiprocessor systems on chip (MPSoC) experience difficulty scaling as the quantity of processors increases. This challenge is common behavior of memory accesses in a shared memory environment and causes a decrease in memory bandwidth as processor numbers increase. In order to provide the necessary levels of scalability, the computer architecture community has sought to decentralize memory accesses by distributing memory throughout the system. Distributed memory offers greater bandwidth due to decoupled …

Patient And Nurse Considerations In Home Health Routing With Remote Monitoring Devices, Jessica Spicer

Graduate Theses and Dissertations

We build on the current consistent vehicle routing problem literature by formulating a novel multi- objective mathematical model of the home health scheduling and routing problem that includes the option of assigning some patient visits to remote monitoring devices, with the objectives of mini- mizing total cost, achieving nurse consistency and creating balanced nurse workloads. A heuristic solution approach that approximates the efficient frontier of this multiobjective problem is pre- sented and validated, and the results of using this methodology to solve several realistic instances are included. We also analyze the assignment of patients to devices and present some managerial …

Physiochemical And Nanomanipulation Studies Of Carbon Nanomaterials, Siva Naga Sandeep Chalamalasetty

Graduate Theses and Dissertations

Carbon nanomaterials are, without a doubt, one of man's wonder creations. Though these nanomaterials are a very recent trend, extraordinary electromechanical properties and the light weightiness of these nanomaterials attracted the attention of researchers. Although vast research has been done since the start of the US nanotechnology initiative, much effort was in the area of synthesis and characterization of the nanomaterials. However, most of the traditional macroscopic material's theories fail at the nanoscale level, and since the material properties are dependent on size and structure at nanoscale level, the behavior of the carbon nanomaterials in different environments needs attention. High …

Design Of A High Dynamic Range Cmos Variable Gain Amplifier For Wireless Sensor Networks, Yue Yu

Graduate Theses and Dissertations

This thesis presents the design, simulation, layout and testing results for a dB-linear, high dynamic gain range CMOS variable gain amplifier (VGA). The design adopts a new approximated exponential equation called the pseudo exponential equation to implement the dB-linear function. The proposed VGA is designed to have an extremely wide gain variation, small chip area, low supply voltage, and controllable dynamic gain range. The gain variation of the 3-stage VGA is implemented by a voltage to current converter. It controls the bias currents of each VGA cell, so that the output gain of each cell can be controlled. In order …

Characterization And Modeling Of 4h-Sic Low Voltage Mosfets And Power Mosfets, Mihir Mudholkar

Graduate Theses and Dissertations

The integration of low voltage and high voltage circuits on SiC has profound applications. SiC power devices have proved their superiority in terms of high temperature operation, faster switching frequencies and larger power densities when compared with Si power devices. The control of SiC power devices however, lies in the hands of low voltage circuits built on Si. Thus, there exists a separation in the overall system between the low voltage and high voltage side, which increases system cost, weight and reduces efficiency. With the advancement in low voltage SiC processing technology, low voltage control circuits can be made on …

Mott Transition And Electronic Structure In Complex Oxide Heterostructures, Jian Liu

Graduate Theses and Dissertations

Strongly correlated electron systems, particularly transition metal oxides, have been a focus of condensed matter physics for more than two decades since the discovery of high-temperature superconducting cuprates. Diverse competing phases emerge, spanning from exotic magnetism to unconventional superconductivity, in proximity to the localized-itinerant transition of Mott insulators. While studies were concentrated on bulk crystals, the recent rapid advance in synthesis has enabled fabrication of high-quality oxide heterostructures, offering a new route to create novel artificial quantum materials.

This dissertation details the investigation on ultrathin films and heterostructures of 3d⁷(t_2g⁶e_g¹) systems with …