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Articles 2641 - 2670 of 3294
Full-Text Articles in Engineering
Large-Scale Inverse Ku-Band Backscatter Modeling Of Sea Ice, David G. Long, Quinn P. Remund
Large-Scale Inverse Ku-Band Backscatter Modeling Of Sea Ice, David G. Long, Quinn P. Remund
Faculty Publications
Polar sea ice characteristics provide important inputs to models of several geophysical processes. Microwave scatterometers are ideal for monitoring these regions due to their sensitivity to ice properties and insensitivity to atmospheric distortions. Many forward electromagnetic scattering models have been proposed to predict the normalized radar cross section (σ˚) from sea ice characteristics. These models are based on very small scale ice features and generally assume that the region of interest is spatially homogeneous. Unfortunately, spaceborne scatterometer footprints are very large (5-50 km) and usually contain very heterogeneous mixtures of sea ice surface parameters. In this paper, we use scatterometer …
Learning Real-Time A* Path Planner For Sensing Closely-Spaced Targets From An Aircraft, Jason K. Howlett, Michael A. Goodrich, Timothy W. Mclain
Learning Real-Time A* Path Planner For Sensing Closely-Spaced Targets From An Aircraft, Jason K. Howlett, Michael A. Goodrich, Timothy W. Mclain
Faculty Publications
This work develops an any-time path planner, based on the learning real-time A* (LRTA*) search, for generating flyable paths that allow an aircraft with a specified sensor footprint to sense a group of closely-spaced targets. The LRTA* algorithm searches a tree of flyable paths for the branch that accomplishes the desired objectives in the shortest distance. The tree of paths is created by assembling primitive turn and straight sections of a specified step size. The operating parameters for the LRTA* search directly influence the running time and path-length performance of the search. A modified LRTA* search is presented that terminates …
Micro-Genetic Algorithm Design Of Hybrid Conventional Waveguide And Photonic Crystal Structures, J. Cai, S. Kim, Gregory P. Nordin, J. Jiang
Micro-Genetic Algorithm Design Of Hybrid Conventional Waveguide And Photonic Crystal Structures, J. Cai, S. Kim, Gregory P. Nordin, J. Jiang
Faculty Publications
We previously proposed the hybrid integration of photonic crystals (PhCs) and conventional index-guided waveguides (CWGs) as a potentially attractive method of realizing compact waveguide elements for large-scale planar lightwave circuits (PLCs). We now examine 90-deg bends and beamsplitters in PhC/CWG structures in which the waveguide core has a high refractive index (3.25) and yet a low refractive index contrast (1.54%) with the clad material. A PhC structure composed of a triangular or square array of air holes is placed at the intersection of input and output waveguides to obtain high efficiency 90-deg bends. We find that diffraction from the boundary …
Design Of A Multiband Internal Antenna For Third Generation Mobile Phone Handsets, Mohammod Ali, Gerard James Hayes, Huan-Sheng Hwang, Robert A. Sadler
Design Of A Multiband Internal Antenna For Third Generation Mobile Phone Handsets, Mohammod Ali, Gerard James Hayes, Huan-Sheng Hwang, Robert A. Sadler
Faculty Publications
A multiband internal antenna is introduced. The antenna consists of a driven meander-line element and two parasitic elements. The design is particularly unique since it supports the third generation mobile phone handsets where multiband operation is greatly desired. The proposed antenna operates effectively in the aMPS 800 (824-894 MHz), GSM 900 (880-960 MHz), and GSM 1900 (1850-1990 MHz) bands within 2.5:1 (voltage standing wave ratio (VSWR). Detail design criteria with respect to geometrical parameter variation are given. Experimental data (VSWR and pattern) obtained from a laboratory prototype are also presented.
Design And Testing Of Spacecraft Power Systems Using Vtb, Zhenhua Jiang, Shengyi Liu, Roger A. Dougal
Design And Testing Of Spacecraft Power Systems Using Vtb, Zhenhua Jiang, Shengyi Liu, Roger A. Dougal
Faculty Publications
A study is presented on the design and testing of spacecraft power systems using the virtual test bed (VTB). The interdisciplinary components such as solar array and battery systems were first modeled in native VTB format and validated by experiment data. The shunt regulator and battery charge controller were designed in Simulink according to the system requirements and imported to VTB. Two spacecraft power systems were then designed and tested together with the control systems.
A Self-Retracting Fully Compliant Bistable Micromechanism, Nathan D. Masters, Larry L. Howell
A Self-Retracting Fully Compliant Bistable Micromechanism, Nathan D. Masters, Larry L. Howell
Faculty Publications
A new class of fully compliant bistable mechanisms with the added benefit of integrated self-retraction has been developed (hereafter identified as Self-Retracting Fully compliant Bistable Mechanism or SRFBM). A technique using tensural pivots to manage compressive loading in compliant mechanisms is introduced and implemented in the SRFBM. The elimination of traditional kinematic joints and their associated clearance allows a total displacement between stable positions of 8.5 m, and the mechanism size is less than 300 m square when using 2.0 m minimum line widths. Maximum actuation force is approximately 500 N. The SRFBM's small linear displacement and reasonable actuation force …
In Situ Uv-Visible Assessment Of Extent Of Reduction During Oxidation Reactions On Oxide Catalysts, Morris D. Argyle, Kaidong Chen, Carlo Resini, Catherine Krebs, Alexis T. Bell, Enrique Iglesia
In Situ Uv-Visible Assessment Of Extent Of Reduction During Oxidation Reactions On Oxide Catalysts, Morris D. Argyle, Kaidong Chen, Carlo Resini, Catherine Krebs, Alexis T. Bell, Enrique Iglesia
Faculty Publications
The extent of reduction of active centers during oxidative alkane dehydrogenation on VOx/Al2O3 was measured from pre-edge UV-visible spectral features and found to increase with increasing VOx domain size and propane/O2 ratio.
Effects Of Solvent Model Flexibility On Aqueous Electrolyte Behavior Between Electrodes, Richard L. Rowley, John N. Harb, Clint G. Guymon, Matthew L. Hunsaker, Douglas Henderson
Effects Of Solvent Model Flexibility On Aqueous Electrolyte Behavior Between Electrodes, Richard L. Rowley, John N. Harb, Clint G. Guymon, Matthew L. Hunsaker, Douglas Henderson
Faculty Publications
Molecular dynamics simulations have been carried out for aqueous electrolyte solutions between model electrode surfaces. The effect of solvent model flexibility on bult and double layer properties was observed for electrode surface charge densities of 0, 0.1 and 0.2 and ion concentrations of 0, 0.5 and 1 M. Two flexible models were used to isolate the effects of flexibility from the effects of a change in the condensed-phase dipole moment. Model flexibility increases the pure water self-diffusion coefficient while a larger liquid diple moment substantially decreases it. There is an increase in ion contact adsorption and counter ion affinity with …
Thermal Management Of Algan-Gan Hfets On Sapphire Using Flip-Chip Bonding With Epoxy Underfill, Jie Sun, H. Fatima, Alexei Koudymov, A. Chitnis, X. Hu, H.-M Wang, J. Zhang, Grigory Simin, J. Yang, Asif Khan
Thermal Management Of Algan-Gan Hfets On Sapphire Using Flip-Chip Bonding With Epoxy Underfill, Jie Sun, H. Fatima, Alexei Koudymov, A. Chitnis, X. Hu, H.-M Wang, J. Zhang, Grigory Simin, J. Yang, Asif Khan
Faculty Publications
Self-heating imposes the major limitation on the output power of GaN-based HFETs on sapphire or SiC. SiC substrates allow for a simple device thermal management scheme; however, they are about a factor 20-100 higher in cost than sapphire. Sapphire substrates of diameters exceeding 4 in are easily available but the heat removal through the substrate is inefficient due to its low thermal conductivity. The authors demonstrate that the thermal impedance of GaN based HFETs over sapphire substrates can be significantly reduced by implementing flip-chip bonding with thermal conductive epoxy,underfill. They also show that in sapphire-based flip-chip mounted devices the heat …
Image Segmentation With Ratio Cut, Song Wang, Jeffrey Mark Siskind
Image Segmentation With Ratio Cut, Song Wang, Jeffrey Mark Siskind
Faculty Publications
This paper proposes a new cost function, cut ratio, for segmenting images using graph-based methods. The cut ratio is defined as the ratio of the corresponding sums of two different weights of edges along the cut boundary and models the mean affinity between the segments separated by the boundary per unit boundary length. This new cost function allows the image perimeter to be segmented, guarantees that the segments produced by bipartitioning are connected, and does not introduce a size, shape, smoothness, or boundary-length bias. The latter allows it to produce segmentations where boundaries are aligned with image edges. Furthermore, the …
Cooperative Path Planning For Timing Critical Missions, Timothy W. Mclain, Randal W. Beard
Cooperative Path Planning For Timing Critical Missions, Timothy W. Mclain, Randal W. Beard
Faculty Publications
This paper presents a cooperative path planning approach for teams of vehicles operating under timing constraints. A cooperative control approach based on coordination variables and coordination functions is introduced and applied to cooperative timing problems. Three types of timing constraints are considered: simultaneous arrival, tight sequencing, and loose sequencing. Simulation results demonstrating the approach are presented.
Microstructure Sensitive Design Of An Orthotropic Plate Subjected To Tensile Load, Brent L. Adams, Mark Lyons, Joshua R. Houskamp, Surya R. Kalidindi
Microstructure Sensitive Design Of An Orthotropic Plate Subjected To Tensile Load, Brent L. Adams, Mark Lyons, Joshua R. Houskamp, Surya R. Kalidindi
Faculty Publications
Financial support for this work was provided by the Army Research Office, Proposal No. 42566-MS, Dr. David Stepp, Program Director and Army Research Lab, Dr. Scott Schoenfeld, Point of Contact. Microstructure Sensitive Design (MSD) is a newly developed mathematical framework that facilitates rigorous solutions to inverse problems in microstructure design of materials. In this paper, this methodology is applied to an orthotropic thin plate containing a circular hole subjected to an in-plane uniaxial tensile load. The primary design objective is to maximize the load carrying capacity of the plate while avoiding plastic deformation in the plate. Making use of the …
Rapid Prototyping Of Digital Controls For Power Electronics, Antonello Monti, Enrico Santi, Roger A. Dougal, Marco Riva
Rapid Prototyping Of Digital Controls For Power Electronics, Antonello Monti, Enrico Santi, Roger A. Dougal, Marco Riva
Faculty Publications
The process for designing digital controls for power electronics is typically quite convoluted and affords many opportunities for errors to occur. We present here a new and complete, method for rapid prototyping of digital controls that allows rapid realization of new designs. The approach uses a collection of tools that include both software (the virtual test bed (VTB) and Matlab/Simulink) and hardware (dSpace DSP). An example application of the methodology completes the discussion.
Building Solid Models From Boreholes And User-Defined Cross-Sections, Alan M. Lemon, Norman L. Jones
Building Solid Models From Boreholes And User-Defined Cross-Sections, Alan M. Lemon, Norman L. Jones
Faculty Publications
Solid models of geologic structures are useful tools for geologists and engineers. Solid models completely and unambiguously define the stratigraphy for the site being modeled, including complex boundaries and embedded seams. Past research has focused on the “set operations” approach to create solid models. Whereas the set operations approach is flexible, it requires significant user intervention and is therefore difficult to use. A simple approach for generating solid models from borehole data, called the horizons method, is presented. The horizons method can be used to build solids directly from borehole data with minimal user intervention. The user first assigns horizon …
Interaction Energy Surfaces Of Small Hydrocarbon Molecules, Richard L. Rowley, Jukka-Pekka Jalkanen, Tapani A. Pakkanen, Yan Yang
Interaction Energy Surfaces Of Small Hydrocarbon Molecules, Richard L. Rowley, Jukka-Pekka Jalkanen, Tapani A. Pakkanen, Yan Yang
Faculty Publications
Nonbonding interactions of small alkane molecules were studied with ab initio methods. Previously reported energy data for ethane and propane dimers were supplemented with 1747 new configurations of dimers involving slightly larger hydrocarbons. The completed work provides interaction energy surfaces for all combinations of dimer pairs involving ethane, propane, isobutane, and neopentane and thus contains information of all chemical groups found in acyclic alkanes. The strongest attraction of the studied molecule pairs was encountered in isobutane C2h dimer, where an energy minimum of -1.784 kcal mol^-1 at 4.28 Angstroms separation of centermost carbon atoms was observed. The composite data set …
An Advanced Ambiguity Selection Algorithm For Seawinds, David G. Long, David W. Draper
An Advanced Ambiguity Selection Algorithm For Seawinds, David G. Long, David W. Draper
Faculty Publications
SeaWinds on QuikSCAT, a spaceborne Ku-band scatterometer, estimates ocean winds via the relationship between the normalized radar backscatter and the vector wind. Scatterometer wind retrieval generates several possible wind vector solutions or ambiguities at each resolution cell, requiring a separate ambiguity selection step to give a unique solution. In processing SeaWinds on QuikSCAT data, the ambiguity selection is "nudged" or initialized using numerical weather prediction winds. We describe a sophisticated new ambiguity selection approach developed at Brigham Young University (BYU) that does not require nudging. The BYU method utilizes a low-order data-driven Karhunen-Loeve wind field model to promote self-consistency. Ambiguity …
Density Of States Simulations Of Proteins, Nitin Rathore, Thomas A. Knotts Iv, Juan J. De Pablo
Density Of States Simulations Of Proteins, Nitin Rathore, Thomas A. Knotts Iv, Juan J. De Pablo
Faculty Publications
A modified version of a recently introduced algorithm that calculates density of states by performing a random walk in energy space has been proposed and implemented to study protein folding in a continuum. A united atom representation and the CHARMM19 [B. R. Brooks, R. E. Bruccoleri, B. D. Olafson, D. J. States, S. Swaminathan, and M. Karplus, J. Comput. Chem. 4, 187 (1983)] force field are employed for these simulations. This method permits estimation of the density of states of a protein via a random walk in the energy space, thereby allowing the system to escape from local free-energy minima …
Advances In Experimental Method And Analysis For Estimation Of Geometrically-Necessary Dislocations, Brent L. Adams, Bassem S. El-Dasher, Anthony D. Rollett
Advances In Experimental Method And Analysis For Estimation Of Geometrically-Necessary Dislocations, Brent L. Adams, Bassem S. El-Dasher, Anthony D. Rollett
Faculty Publications
The authors wish to thank The Alcoa Technical Research Center for supplying the specimens and performing the compression tests. This work was supported by the MRSEC program of the National Science Foundation under DMR-0079996 as well as Lawrence Livermore Laboratory DOE/DoD Joint Program. An behavior of grain boundaries of the polycrystalline materials over a wide range of length scales during plastic deformation is considered. Electron backscattering diffraction and orientation imaging microscopy provide automated scanning measurements of the lattice orientation near grain boundaries. These methods are useful to set the necessary length scales. The data are presented for directionally-solidified pure Al …
A Joint Trajectory Generator For Motion Recovery, Edward Red, Wei Li
A Joint Trajectory Generator For Motion Recovery, Edward Red, Wei Li
Faculty Publications
This paper describes an adaptive S-curve used to recover a tool path upon a system crash in the Windows operating system (OS). For a mechanism such as a robot or machine tool, the joint values, being delivered as setpoints to the servo-controller, are dynamically recorded by the real-time operating system also residing on the computer. The real-time OS can control the abort and record pertinent motion data after Windows OS crash.
Experimental Characterization Of The Mimo Wireless Channel: Data Acquisition, Analysis, And Modeling, Michael A. Jensen, Jon W. Wallace, A. Lee Swindlehurst, Brian D. Jeffs
Experimental Characterization Of The Mimo Wireless Channel: Data Acquisition, Analysis, And Modeling, Michael A. Jensen, Jon W. Wallace, A. Lee Swindlehurst, Brian D. Jeffs
Faculty Publications
Detailed performance assessment of space-time coding algorithms in realistic channels is critically dependent upon accurate knowledge of the wireless channel spatial characteristics. This paper presents an experimental measurement platform capable of providing the narrowband channel transfer matrix for wireless communications scenarios. The system is used to directly measure key multiple-input-multiple-output parameters in an indoor environment at 2.45 GHz. Linear antenna arrays of different sizes and construction with up to ten elements at transmit and receive are utilized in the measurement campaign. This data is analyzed to reveal channel properties such as transfer matrix element statistical distributions and temporal and spatial …
High-Resolution Measurements With A Spaceborne Pencil-Beam Scatterometer Using Combined Range/Doppler Discrimination Techniques, David G. Long, Michael W. Spencer, Wu-Yang Tsai
High-Resolution Measurements With A Spaceborne Pencil-Beam Scatterometer Using Combined Range/Doppler Discrimination Techniques, David G. Long, Michael W. Spencer, Wu-Yang Tsai
Faculty Publications
Conically scanning pencil-beam scatterometer systems, such as the SeaWinds radar, constitute an important class of instruments for spaceborne climate observation. In addition to ocean winds, scatterometer data are being applied to a wide range of land and cryospheric applications. A key issue for future scatterometer missions is improved spatial resolution. Pencil-beam scatterometers to date have been real-aperture systems where only range discrimination is used, resulting in a relatively coarse resolution of approximately 25 km. In this paper, the addition of Doppler discrimination techniques is proposed to meet the need for higher resolution. The unique issues associated with the simultaneous application …
Fuel Characteristics Of Processed, High-Fiber Sugarcane, Scott Q. Turn, Charles M. Kinoshita, Lee A. Jakeway, Bryan M. Jenkins, Larry Lin Baxter 8507091, Ben C. Wu, Linda G. Blevins
Fuel Characteristics Of Processed, High-Fiber Sugarcane, Scott Q. Turn, Charles M. Kinoshita, Lee A. Jakeway, Bryan M. Jenkins, Larry Lin Baxter 8507091, Ben C. Wu, Linda G. Blevins
Faculty Publications
A study of treatment methods to improve the fuel characteristics of sugarcane variety B52298 was conducted. Two parent materials, whole cane (WC) and stripped cane (SC), were included in the study. The whole cane material was subjected to three treatments: (1) no treatment, WC-U; (2) a single milling, WC-M; and (3) an initial milling followed by leaching and a secondary milling, WC-MLM. Treatments (1) through (3) are in order of increasing severity. The stripped cane material was subjected to treatment (3) and designated as SC-MLM. Regardless of parent material, milling produced moisture contents of ∼50% wet basis and fiber bulk …
Algan/Gan Heterostructure Field-Effect Transistors On Single-Crystal Bulk Aln, X. Hu, J. Deng, N. Pala, R. Gaska, M. S. Shur, C. Q. Chen, J. Yang, Grigory Simin, M. A. Khan, J. C. Rojo, L. J. Schowalter
Algan/Gan Heterostructure Field-Effect Transistors On Single-Crystal Bulk Aln, X. Hu, J. Deng, N. Pala, R. Gaska, M. S. Shur, C. Q. Chen, J. Yang, Grigory Simin, M. A. Khan, J. C. Rojo, L. J. Schowalter
Faculty Publications
We report on the performance of AlGaN/GaN/AlN heterostructurefield-effect transistors(HFETs) grown over slightly-off c-axis, single-crystal, bulk AlN substrates. Dc and rf characteristics of these devices were comparable to HFETs grown on semi-insulating SiC. The obtained results demonstrate that bulk AlN substrates are suitable for fabricating high-power microwave AlGaN/GaN transistors.
Web Mining For Web Personalization, Magdalini Eirinaki, M. Vazirgiannis
Web Mining For Web Personalization, Magdalini Eirinaki, M. Vazirgiannis
Faculty Publications
Web personalization is the process of customizing a Web site to the needs of specific users, taking advantage of the knowledge acquired from the analysis of the user's navigational behavior (usage data) in correlation with other information collected in the Web context, namely, structure, content, and user profile data. Due to the explosive growth of the Web, the domain of Web personalization has gained great momentum both in the research and commercial areas. In this article we present a survey of the use of Web mining for Web personalization. More specifically, we introduce the modules that comprise a Web personalization …
Algan/Gan Hemts - Operation In The K-Band And Above, Ioulia P. Smorchkova, M. Wojtowicz, Rajinder Sandhu, R. Tsai, M. Barsky, C. Namba, P.-S. Liu, R. Dia, Minhdao Truong, D. Ko, J. Wang, H. Wange, Asif Khan
Algan/Gan Hemts - Operation In The K-Band And Above, Ioulia P. Smorchkova, M. Wojtowicz, Rajinder Sandhu, R. Tsai, M. Barsky, C. Namba, P.-S. Liu, R. Dia, Minhdao Truong, D. Ko, J. Wang, H. Wange, Asif Khan
Faculty Publications
We report on the power and microwave noise performance of AlGan/GaN high electron-mobility transistors (HEMTs) at frequencies f > 18 GHz (K- and Ka-bands). At 20 GHz, a record continuous-wave output power of 1.6 W has been achieved on an eight-finger 500-mum total gate-periphery device. At 29 GHz, a 120-mum gate-periphery device showed a pulsed output density of 1.6 W/mm with an associated gain of 6.7 dB and power-added efficiency of 26%. Minimum noise figure of 1.5 dB has been achieved on a 0.2 mum x 200 mum device at 26 GHz. The data demonstrate the viability of AlGan/GaN HEMTs for …
Real Time Dynamic Trajectory Smoothing For Uninhabited Aerial Vehicles, Erik Anderson, Randal Beard, Timothy W. Mclain
Real Time Dynamic Trajectory Smoothing For Uninhabited Aerial Vehicles, Erik Anderson, Randal Beard, Timothy W. Mclain
Faculty Publications
Sponsorship: AFOSR, DARPA. This paper presents a real-time, feasible trajectory generation algorithm for unmanned air vehicles (UAVs) flying through a sequence of waypoints. The algorithm produces extremal trajectories that transition between straight-line path segments in a time-optimal fashion. In addition, the algorithm can be configured so that the dynamically feasible trajectory has the same path length as the straight-line waypoint path. Implementation issues associated with the algorithm are described in detail. Simulation studies show the effectiveness of the proposed method.
Comprehensive Model Of Alkali-Salt Deposition In Recovery Boilers, Richard A. Wessel, Larry Lin Baxter 8507091
Comprehensive Model Of Alkali-Salt Deposition In Recovery Boilers, Richard A. Wessel, Larry Lin Baxter 8507091
Faculty Publications
Algorithms for alkali-salt deposition have been implemented into a comprehensive model for recovery boilers. The model includes (a) mechanisms for particle formation and chemistry, (b) particle deposition and adhesion, and (c) deposit thermal properties. These algorithms are fully coupled with models for turbulent flow, black liquor combustion, and heat transfer in the boiler. Model predictions for particle deposition in the convection pass are presented for a Babcock & Wilcox recovery boiler. This work is part of an ongoing project sponsored by the U.S. Department of Energy to demonstrate an improved ability to anticipate ash behavior with changes in fuel composition, …
Time-Resolved Electroluminescence Of Algan-Based Light-Emitting Diodes With Emission At 285 Nm, M. Shatalov, A. Chitnis, V. Mandavilli, R. Pachipulusu, J. P. Zhang, V. Adivarahan, S. Wu, Grigory Simin, M. Asif Khan, G. Tamulaitis, A. Sereika, I. Yilmaz, M. S. Shur, R. Gaska
Time-Resolved Electroluminescence Of Algan-Based Light-Emitting Diodes With Emission At 285 Nm, M. Shatalov, A. Chitnis, V. Mandavilli, R. Pachipulusu, J. P. Zhang, V. Adivarahan, S. Wu, Grigory Simin, M. Asif Khan, G. Tamulaitis, A. Sereika, I. Yilmaz, M. S. Shur, R. Gaska
Faculty Publications
We present a study on the time evolution of the electroluminescence(EL)spectra of AlGaN-based deep ultraviolet light-emitting diodes(LEDs) under pulsed current pumping. The ELspectra peaks at 285 nm and 330 nm are found to result from recombination involving band-to-band and free carriers to deep acceptor level transitions. The 330 nm long-wavelength transitions to deep acceptor levels in the p-AlGaN layer as well as the nonradiative processes significantly influence the LED internal quantum efficiency.
From Learning To Talk To Learning Engineering; Drawing Connections Across The Disciplines, Nikos J. Mourtos
From Learning To Talk To Learning Engineering; Drawing Connections Across The Disciplines, Nikos J. Mourtos
Faculty Publications
This paper introduces eight so-called conditions of learning (immersion, demonstration, engagement, expectations, responsibility, approximation, employment and response), which have been previously established for the learning of literacy. It is stipulated that these conditions are universal in nature; in other words, they must be present for any learning to occur. When these conditions are met, students learn more efficiently and are able to enjoy and appreciate their subject matter. The article discusses briefly how these conditions were established and their relevance in the study of engineering. More importantly, the article also presents examples of how these conditions can be satisfied in …
Study Of Ionic Conductivity Profiles Of The Air Cathode Of A Pemfc By Ac Impedance Spectroscopy, Qingzhi Guo, Maria Cayetana, Yu-Min Tsou, Emory S. De Castro, Ralph E. White
Study Of Ionic Conductivity Profiles Of The Air Cathode Of A Pemfc By Ac Impedance Spectroscopy, Qingzhi Guo, Maria Cayetana, Yu-Min Tsou, Emory S. De Castro, Ralph E. White
Faculty Publications
A characterization of the ionic conduction of the active layer of a polymer electrolyte membrane fuel cell (PEMFC) cathode by ac impedance measurement at open-circuit potential conditions was conducted. Porous electrode theory was used to derive a compact equation, ∂2Φ̑2/∂y2+∂lnf(y)/∂y×∂Φ̑2/∂y−R/f(y)(1+jΩ)Φ̑2=0, to solve for the impedance response of a cathode at open-circuit potential conditions. This equation includes a parameter R, the ratio of an ionic resistance (evaluated at the active layer/membrane interface), to the total charge-transfer resistance of the active layer. The influence of an assumed ionic conductivity distribution profile f(y) on the error in the estimation of total double-layer …