Engineering Commons^™

Synthesis, Characterization And Applications Of Reduced Graphene Oxide And Composite Membranes For Selective Separations And Removal Of Organic Contaminants, Ashish Aher

Theses and Dissertations--Chemical and Materials Engineering

Among the next generation materials being investigated for membrane development, partially reduced Graphene Oxide (rGO) has received increasing attention from the membrane community. rGO-based nanofiltration membranes have shown promising results in applications such as partial desalination, organic contaminant removal, gas-phase separations, and separations from solvent media. rGO offers a unique platform compared to common polymeric membranes since it can be used for separation applications in both aqueous and organic solvent media. An rGO-based platform could also be utilized to synthesize reactive membranes, giving rGO membranes the additional capability of reactively removing organic contaminants. This research focuses on the synthesis of …

Nanoharvesting And Delivery Of Bioactive Materials Using Engineered Silica Nanoparticles, Md Arif Khan

Theses and Dissertations--Chemical and Materials Engineering

Mesoporous silica nanoparticles (MSNPs) possess large surface areas and ample pore space that can be readily modified with specific functional groups for targeted binding of bioactive materials to be transported through cellular barriers. Engineered silica nanoparticles (ESNP) have been used extensively to deliver bio-active materials to target intracellular sites, including as non-viral vectors for nucleic acid (DNA/RNA) delivery such as for siRNA induced interference. The reverse process guided by the same principles is called “nanoharvesting”, where valuable biomolecules are carried out and separated from living and functioning organisms using nano-carriers. This dissertation focuses on ESNP design principles for both applications. …

The Fabrication And Characterization Of Metal Oxide Nanoparticles Employed In Environmental Toxicity And Polymeric Nanocomposite Applications, Matthew Logan Hancock

Theses and Dissertations--Chemical and Materials Engineering

Ceria (cerium oxide) nanomaterials, or nanoceria, have commercial catalysis and energy storage applications. The cerium atoms on the surface of nanoceria can store or release oxygen, cycling between Ce³⁺ and Ce⁴⁺, and can therefore act as a therapeutic to relieve oxidative stress within living systems. Nanoceria dissolution is present in acidic environments in vivo. In order to accurately define the fate of nanoceria in vivo, nanoceria dissolution or stabilization is observed in vitro using acidic aqueous environments.

Nanoceria stabilization is a known problem even during its synthesis; in fact, a carboxylic acid, citric acid, is …

Scanning Probe Microscopy Measurements On 2d Materials And Iridates, Armin Ansary

Theses and Dissertations--Physics and Astronomy

In the past two decades, there has been a quest to understand and utilize novel materials such as iridates and two-dimensional (2D) materials. These classes of materials show a lot of interesting properties both in theoretical predictions as well as experimental results. Physical properties of some of these materials have been investigated using scanning probe measurements, along with other techniques.

One-dimensional (1D) catalytic etching was investigated in few-layer hexagonal boron nitride (hBN) films. Etching of hBN was shown to share several similarities with that of graphitic films. As in graphitic films, etch tracks in hBN commenced at film edges and …

Numerical Simulations Of Premixed Flames Of Multi Component Fuels/Air Mixtures And Their Applications, Essa Kh I J Salem

Theses and Dissertations--Mechanical and Aerospace Engineering

Combustion has been used for a long time as a means of energy extraction. However, in the recent years there has been further increase in air pollution, through pollutants such as nitrogen oxides, acid rain etc. To solve this problem, there is a need to reduce carbon and nitrogen oxides through lean burning, fuel dilution and usage of bi-product fuel gases. A numerical analysis has been carried out to investigate the effectiveness of several reduced mechanisms, in terms of computational time and accuracy. The cases were tested for the combustion of hydrocarbons diluted with hydrogen, syngas, and bi-product fuel in …

Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito

Mechanical Engineering Faculty Publications

Hydrocarbons as reductants show promising results for replacing NH₃ in SCR technology. Therefore, considerable interest exists for developing low-temperature (< 200 °C) and environmentally friendly HC-SCR catalysts. Hence, C₂H₄ was examined as a reductant using activated-carbon-supported MnOx-based catalyst in low-temperature SCR operation. Its sensitivity to Mn concentration and operating temperature was parametrically studied, the results of which showed that the catalyst activity followed the order of 130 °C > 150 °C > 180 °C with an optimized Mn concentration near 3.0 wt.%. However, rapid deactivation of catalytic activity also occurred when using C₂H₄ as the reductant. The mechanism of deactivation was explored and is …

Lightweight Thermal Management Material For Enhancement Of Through-Thickness Thermal Conductivity, Matthew Collins Weisenberger

Center for Applied Energy Research Faculty Patents

A flexible sheet of aligned carbon nanotubes includes an array of aligned nanotubes held in a polymer matrix material. The carbon nanotubes have an average length of between about 50 microns and about 500 microns. The polymer matrix has an average thickness of between about 10 microns and about 500 microns. The flexible sheet has a density of about 0.2 to about 1.0 glee and includes between about 98 to about 60 weight percent aligned carbon nanotubes and between about 2 and about 40 weight percent polymer. A tape of aligned carbon nanotubes, a method for producing a tape of …

Determination Of Chemical Speciation Of Arsenic And Selenium In High-As Coal Combustion Ash By X-Ray Photoelectron Spectroscopy: Examples From A Kentucky Stoker Ash, Biao Fu, James C. Hower, Shifeng Dai, Sarah M. Mardon, Guijian Liu

Center for Applied Energy Research Faculty and Staff Publications

Knowledge of the chemical speciation of arsenic and selenium in coal fly ash is essential in the evaluation of the environmental behavior of fly ash disposed in a landfill in a natural environment. In this study, a series of high-As coal fly ash from stoker boilers were collected to determine the chemical forms of arsenic and selenium. The ash surface chemical characteristics and the speciation of arsenic and selenium were characterized by X-ray photoelectron spectroscopy and X-ray-induced Auger electron spectroscopy. The results indicate that the surface enrichment ratio for selenium (63.3–309.5) is higher than that of arsenic (1.2–21.2). The Wagner …

Coordinated Unmanned Aircraft System (Uas) And Ground-Based Weather Measurements To Predict Lagrangian Coherent Structures (Lcss), Peter J. Nolan, James Pinto, Javier González-Rocha, Anders Jensen, Christina N. Vezzi, Sean C. C. Bailey, Gijs De Boer, Constantin Diehl, Roger Laurence Iii, Craig W. Powers, Hosein Foroutan, Shane D. Ross, David G. Schmale Iii

Mechanical Engineering Faculty Publications

Concentrations of airborne chemical and biological agents from a hazardous release are not spread uniformly. Instead, there are regions of higher concentration, in part due to local atmospheric flow conditions which can attract agents. We equipped a ground station and two rotary-wing unmanned aircraft systems (UASs) with ultrasonic anemometers. Flights reported here were conducted 10 to 15 m above ground level (AGL) at the Leach Airfield in the San Luis Valley, Colorado as part of the Lower Atmospheric Process Studies at Elevation—a Remotely-Piloted Aircraft Team Experiment (LAPSE-RATE) campaign in 2018. The ultrasonic anemometers were used to collect simultaneous measurements of …

Manganese-Enhanced Magnetic Resonance Imaging: Overview And Central Nervous System Applications With A Focus On Neurodegeneration, Ryan A. Cloyd, Shon A. Koren, Jose F. Abisambra

Physiology Faculty Publications

Manganese-enhanced magnetic resonance imaging (MEMRI) rose to prominence in the 1990s as a sensitive approach to high contrast imaging. Following the discovery of manganese conductance through calcium-permeable channels, MEMRI applications expanded to include functional imaging in the central nervous system (CNS) and other body systems. MEMRI has since been employed in the investigation of physiology in many animal models and in humans. Here, we review historical perspectives that follow the evolution of applied MRI research into MEMRI with particular focus on its potential toxicity. Furthermore, we discuss the more current in vivo investigative uses of MEMRI in CNS investigations and …

A Hierarchical Spectrum Access Scheme For Tv White Space Coexistence In Hetergeneous Networks, Mohammad Zaeri-Amirani, Fatemeh Afghah, Sherali Zeadally

Information Science Faculty Publications

Among current techniques for dynamic access to television (TV) white space (TVWS), geolocation database-based access provides a promising performance in protecting the TV-band incumbents from interference that cannot be efficiently achieved in other license-exempt models. However, in heterogeneous wireless networks, most portable devices do not have such access and may cause interference to TV incumbents. We propose a hierarchical model for spectrum sharing in TVWS that includes a wide range of fixed and portable devices. In the first tier, the TV broadcaster can lease the spectrum bands to local fixed users based on a soft license agreement. The fixed users …

Facepet: Enhancing Bystanders' Facial Privacy With Smart Wearables/Internet Of Things, Alfredo J. Perez, Sherali Zeadally, Luis Y. Matos Garcia, Jaouad A. Mouloud, Scott Griffith

Information Science Faculty Publications

Given the availability of cameras in mobile phones, drones and Internet-connected devices, facial privacy has become an area of major interest in the last few years, especially when photos are captured and can be used to identify bystanders’ faces who may have not given consent for these photos to be taken and be identified. Some solutions to protect facial privacy in photos currently exist. However, many of these solutions do not give a choice to bystanders because they rely on algorithms that de-identify photos or protocols to deactivate devices and systems not controlled by bystanders, thereby being dependent on the …

A Simple And Robust Approach To Reducing Contact Resistance In Organic Transistors, Zachary A. Lamport, Katrina J. Barth, Hyunsu Lee, Eliot Gann, Sebastian Engmann, Hu Chen, Martin Guthold, Iain Mcculloch, John E. Anthony, Lee J. Richter, Dean M. Delongchamp, Oana D. Jurchescu

Chemistry Faculty Publications

Efficient injection of charge carriers from the contacts into the semiconductor layer is crucial for achieving high-performance organic devices. The potential drop necessary to accomplish this process yields a resistance associated with the contacts, namely the contact resistance. A large contact resistance can limit the operation of devices and even lead to inaccuracies in the extraction of the device parameters. Here, we demonstrate a simple and efficient strategy for reducing the contact resistance in organic thin-film transistors by more than an order of magnitude by creating high work function domains at the surface of the injecting electrodes to promote channels …

Integrating Crash, Hospital, And Roadway Data To Investigate The Effect Of Cable Median Barriers On Injury Severity, Michael D. Singleton, Eric R. Green, William Nicholas Staats, I-Chen Chen

Kentucky Transportation Center Research Report

Executive Summary

• In median-involved crashes, the odds of a police-reported injury were estimated to be 42% lower on road segments with a cable median barrier (CMB) than on road segments with a concrete median barrier, and the difference was statistically significant [odds ratio 0.58, 95% confidence interval (0.43, 0.78)].
• In median-involved crashes, the odds of having an injury severity score of 8 or greater were estimated to be 34% higher on road segments with a CMB than on road segments with a concrete median barrier; however, the difference was not statistically significant [odds ratio 1.34, 95% confidence interval (0.67, 2.66). …

Investigation Of Kentucky For-Hire Requirements, Andrew Martin, Valerie J. Keathley, Jennifer R. Walton

Kentucky Transportation Center Research Report

This study analyzes the costs and benefits of the Kentucky For-Hire operating authority, which is issued to all carriers who pick up and drop off freight in Kentucky on a for-hire basis. It reviews current statutory and regulatory requirements, calculates the costs and benefits of administering Kentucky For-Hire, reviews the legal history of trucking regulation and deregulation, reports on a survey of other states about their practices with intrastate operating authority, and proposes three alternatives to current policies. The primary benefit of Kentucky For-Hire is that it enables the Kentucky Transportation Cabinet to verify carriers have commercial liability insurance. Several …

Improving The Quality Of Traffic Records For Traffic Incident Management, Reginald R. Souleyrette, Mei Chen, Xu Zhang, Eric R. Green, Shraddha Sagar

Kentucky Transportation Center Research Report

Traffic incidents in US roadways cause 25 percent of all delays experienced by users. The resulting congestion may lead to secondary crashes, increasing economic costs and further risking the lives of travelers. Traffic Incident Management is a process that detects, responds to, and clears traffic incidents as quickly as possible so that traffic flow is restored safely. This project analyzes the three TIM performance measures: Roadway Clearance Time, Incident Clearance Time and Secondary Crashes of Kentucky to identify a baseline for performance which may indicate potential for improvement. The study pinpoints different data sources, tools and technologies that can be …

Thermal Comfort In Heated-And-Ventilated-Only Warehouses, Christian Taber, Donald G. Colliver

Biosystems and Agricultural Engineering Faculty Publications

Building energy codes and standards contain minimum requirements that provide a path to energy efficient buildings and building systems. ASHRAE/IES Standard 90.1 and the International Energy Conservation Code (IECC) are the main national building code models in the United States. Both Standard 90.1 and the IECC are updated on three-year cycles with the goal of reducing building energy consumption.

Concentrically Loaded Circular Rc Columns Partially Confined With Frp, Sahar Y. Ghanem, Issam E. Harik

Civil Engineering Faculty Publications

Wrapping reinforced concrete (RC) columns with fiber reinforced polymer (FRP) composites is effective in increasing their capacity. The current state of the art concentrates primarily on fully wrapped columns and few studies dealt with partially wrapped ones. The objective herein is to evaluate the effectiveness of partial wraps (or strips) and to develop a confined concrete compressive stress–strain (f_c − ε_c) model that accounts for partial wrapping. Three-dimensional finite element (FE) models are generated to evaluate the influence of different parameters on the behavior of concentrically loaded RC circular columns that are partially and fully wrapped …

Determining The Degree Of [001] Preferred Growth Of Ni(Oh)2 Nanoplates, Taotao Li, Ning Dang, Wanggang Zhang, Wei Liang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Determining the degree of preferred growth of low-dimensional materials is of practical importance for the improvement of the synthesis methods and applications of low-dimensional materials. In this work, three different methods are used to analyze the degree of preferred growth of the Ni(OH)₂ nanoplates synthesized without the use of a complex anion. The results suggest that the preferred growth degree of the Ni(OH)₂ nanoplates calculated by the March parameter and the expression given by Zolotoyabko, which are based on the analysis and texture refinement of the X-ray diffraction pattern, are in good accordance with the results measured by …

Cellulose-Specific Type B Carbohydrate Binding Modules: Understanding Oligomeric And Non-Crystalline Substrate Recognition Mechanisms, Abhishek A. Kognole, Christina M. Payne

Chemical and Materials Engineering Faculty Publications

Background: Effective enzymatic degradation of crystalline polysaccharides requires a synergistic cocktail of hydrolytic enzymes tailored to the wide-ranging degree of substrate crystallinity. To accomplish this type of targeted carbohydrate recognition, nature produces multi-modular enzymes, having at least one catalytic domain appended to one or more carbohydrate binding modules (CBMs). The Type B CBM categorization encompasses several families (i.e., protein folds) of CBMs that are generally thought to selectively bind oligomeric polysaccharides; however, a subset of cellulose-specific CBM families (17 and 28) appear to bind non-crystalline cellulose more tightly than oligomers and in a manner that discriminates between surface topology.

Results: …

Distinct White Matter Changes Associated With Cerebrospinal Fluid Amyloid-Β1-42 And Hypertension, Omar M. Al-Janabi, Christopher A. Brown, Ahmed A. Bahrani, Erin L. Abner, Justin M. Barber, Brian T. Gold, Larry B. Goldstein, Richard R. Murphy, Peter T. Nelson, Nathan F. Johnson, Leslie M. Shaw, Charles D. Smith, John Q. Trojanowski, Donna M. Wilcock, Gregory A. Jicha

Sanders-Brown Center on Aging Faculty Publications

BACKGROUND: Alzheimer's disease (AD) pathology and hypertension (HTN) are risk factors for development of white matter (WM) alterations and might be independently associated with these alterations in older adults.

OBJECTIVE: To evaluate the independent and synergistic effects of HTN and AD pathology on WM alterations.

METHODS: Clinical measures of cerebrovascular disease risk were collected from 62 participants in University of Kentucky Alzheimer's Disease Center studies who also had cerebrospinal fluid (CSF) sampling and MRI brain scans. CSF Aβ_1-42 levels were measured as a marker of AD, and fluid-attenuated inversion recovery imaging and diffusion tensor imaging were obtained to assess …

Water Processable N-Type Organic Semiconductor, Ruben S. Riquelme, Matthew Collins Weisenberger, Camila F. Gomez

Center for Applied Energy Research Faculty Patents

The present invention concerns a water-processable n-type semiconductor comprised of polyvinylpyrrolidone (PVP), carbon nanotubes (CNTs) and poly(ethyleneimine) (PEI). The semiconductors are prepared by providing PVP and CNTs in a hydrophilic slurry and dispersing therein small amounts of PEI.

Linking Lignin Source With Structural And Electrochemical Properties Of Lignin-Derived Carbon Materials, Wenqi Li, Yan Zhang, Lalitendu Das, Yikai Wang, Mi Li, Namal Wanninayake, Yunqiao Pu, Doo Young Kim, Yang-Tse Cheng, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Valorization of lignin to high-value chemicals and products along with biofuel production is generally acknowledged as a technology platform that could significantly improve the economic viability of biorefinery operations. With a growing demand for electrical energy storage materials, lignin-derived activated carbon (AC) materials have received increasing attention in recent years. However, there is an apparent gap in our understanding of the impact of the lignin precursors (i.e., lignin structure, composition and inter-unit linkages) on the structural and electrochemical properties of the derived ACs. In the present study, lignin-derived ACs were prepared under identical conditions from two different lignin …

Advances In Automotive Conversion Coatings During Pretreatment Of The Body Structure: A Review, Mark Doerre, Larry Hibbitts, Gabriela Patrick, Nelson K. Akafuah

Institute of Research for Technology Development Faculty Publications

Automotive conversion coatings consist of layers of materials that are chemically applied to the body structures of vehicles before painting to improve corrosion protection and paint adhesion. These coatings are a consequence of surface-based chemical reactions and are sandwiched between paint layers and the base metal; the chemical reactions involved distinctly classify conversion coatings from other coating technologies. Although the tri-cationic conversion coating bath chemistry that was developed around the end of the 20th century remains persistent, environmental, health, and cost issues favor a new generation of greener methods and materials such as zirconium. Environmental forces driving lightweight material selection …

X-Search: An Open Access Interface For Cross-Cohort Exploration Of The National Sleep Research Resource, Licong Cui, Ningzhou Zeng, Matthew Kim, Remo Mueller, Emily Ruth Hankosky, Susan Redline, Guo-Qiang Zhang

Computer Science Faculty Publications

Background: The National Sleep Research Resource (NSRR) is a large-scale, openly shared, data repository of de-identified, highly curated clinical sleep data from multiple NIH-funded epidemiological studies. Although many data repositories allow users to browse their content, few support fine-grained, cross-cohort query and exploration at study-subject level. We introduce a cross-cohort query and exploration system, called X-search, to enable researchers to query patient cohort counts across a growing number of completed, NIH-funded studies in NSRR and explore the feasibility or likelihood of reusing the data for research studies.

Methods: X-search has been designed as a general framework with two loosely-coupled components: …

Cfd Modeling On Hydrodynamic Characteristics Of Multiphase Counter-Current Flow In A Structured Packed Bed For Post-Combustion Co2 Capture, Li Yang, Fang Liu, Kozo Saito, Kunlei Liu

Mechanical Engineering Faculty Publications

Solvent-based post combustion CO₂ capture is a promising technology for industrial application. Gas-liquid interfaces and interactions in the packed bed are considered one of the key factors affecting the overall CO₂ absorption rate. Understanding the hydrodynamic characterizations within packed beds is essential to identify the appropriate enhanced mass transfer technique. However, multiphase counter-current flows in the structured packing typically used in these processes are complicated to visualize and optimize experimentally. In this paper, we aim to develop a comprehensive 3D multiphase, counter-current flow model to study the liquid/gas behavior on the surface of structured packing. The output from …

Fractionation And Characterization Of Lignin Streams From Unique High-Lignin Content Endocarp Feedstocks, Wenqi Li, Kirtley Amos, Mi Li, Yunqiao Pu, Seth Debolt, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Background: Lignin is a promising source of building blocks for upgrading to valuable aromatic chemicals and materials. Endocarp biomass represents a non-edible crop residue in an existing agricultural setting which cannot be used as animal feed nor soil amendment. With significantly higher lignin content and bulk energy density, endo-carps have significant advantages to be converted into both biofuel and bioproducts as compared to other biomass resources. Deep eutectic solvent (DES) is highly effective in fractionating lignin from a variety of biomass feedstocks with high yield and purity while at lower cost comparing to certain ionic liquids.

Results: In the present …

Scaling Nonreactive Cross Flow Over A Heated Plate To Simulate Forest Fires, Nikolay Gustenyov, Nelson Akafuah, Ahmad Salaimeh, Mark A. Finney, Sara Mcallister, Kozo Saito

Institute of Research for Technology Development Faculty Publications

The paper reports visualization of the flow of smoke over a flat surface inside of a low-speed wind tunnel. A heating plate flush mounted on the wind tunnel floor simulated a spreading line fire that produces uniform heat flux under constant wind speed condition. A paper-thin cloth was soaked with commercially available Vaseline and placed on top of the heating plate; when it is heated, it produced thick white smoke, ideal for flow visualization. Two sides and top of the wind tunnel were made of a trans- parent acrylic sheet that enabled LED and laser sheet light illumination of the …

Two-Level Surrogate-Assisted Differential Evolution Multi-Objective Optimization Of Electric Machines Using 3-D Fea, Narges Taran, Dan M. Ionel, David G. Dorrell

Power and Energy Institute of Kentucky Faculty Publications

A two-level surrogate-assisted optimization algorithm is proposed for electric machine design using 3-D finite-element analysis (FEA). The algorithm achieves the optima with much fewer FEA evaluations than conventional methods. It is composed of interior and exterior levels. The exploration is performed mainly in the interior level, which evaluates hundreds of designs employing affordable kriging models. Then, the most promising designs are evaluated in the exterior loop with expensive 3-D FEA models. The sample pool is constructed in a self-adjustable and dynamic way. A hybrid stopping criterion is used to avoid unnecessary expensive function evaluations.

Optimal Design Of A Switched Reluctance Motor With Magnetically Disconnected Rotor Modules Using A Design Of Experiments Differential Evolution Fea-Based Method, Vandana Rallabandi, Jie Wu, Ping Zhou, David G. Dorrell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Switched reluctance (SR) machines are attractive because they present relatively high efficiency and torque density in spite of lacking permanent magnets. This paper focuses on a two-objective optimization of an external rotor SR motor with a stator that has concentrated coils and a rotor with magnetically isolated modules. The objectives are minimum loss and mass, and 11 independent dimensionless geometric variables are considered as inputs that affect them. A combined design of experiments (DOE) and differential evolution (DE) approach is proposed. The DOE methodology is used to reduce the search space by eliminating from consideration input variable values, leading to …