Engineering Commons^™

Fractionation And Characterization Of Lignin Streams From Unique High-Lignin Content Endocarp Feedstocks, Wenqi Li, Kirtley Amos, Mi Li, Yunqiao Pu, Seth Debolt, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Background: Lignin is a promising source of building blocks for upgrading to valuable aromatic chemicals and materials. Endocarp biomass represents a non-edible crop residue in an existing agricultural setting which cannot be used as animal feed nor soil amendment. With significantly higher lignin content and bulk energy density, endo-carps have significant advantages to be converted into both biofuel and bioproducts as compared to other biomass resources. Deep eutectic solvent (DES) is highly effective in fractionating lignin from a variety of biomass feedstocks with high yield and purity while at lower cost comparing to certain ionic liquids.

Results: In the present …

Scaling Nonreactive Cross Flow Over A Heated Plate To Simulate Forest Fires, Nikolay Gustenyov, Nelson Akafuah, Ahmad Salaimeh, Mark A. Finney, Sara Mcallister, Kozo Saito

Institute of Research for Technology Development Faculty Publications

The paper reports visualization of the flow of smoke over a flat surface inside of a low-speed wind tunnel. A heating plate flush mounted on the wind tunnel floor simulated a spreading line fire that produces uniform heat flux under constant wind speed condition. A paper-thin cloth was soaked with commercially available Vaseline and placed on top of the heating plate; when it is heated, it produced thick white smoke, ideal for flow visualization. Two sides and top of the wind tunnel were made of a trans- parent acrylic sheet that enabled LED and laser sheet light illumination of the …

Two-Level Surrogate-Assisted Differential Evolution Multi-Objective Optimization Of Electric Machines Using 3-D Fea, Narges Taran, Dan M. Ionel, David G. Dorrell

Power and Energy Institute of Kentucky Faculty Publications

A two-level surrogate-assisted optimization algorithm is proposed for electric machine design using 3-D finite-element analysis (FEA). The algorithm achieves the optima with much fewer FEA evaluations than conventional methods. It is composed of interior and exterior levels. The exploration is performed mainly in the interior level, which evaluates hundreds of designs employing affordable kriging models. Then, the most promising designs are evaluated in the exterior loop with expensive 3-D FEA models. The sample pool is constructed in a self-adjustable and dynamic way. A hybrid stopping criterion is used to avoid unnecessary expensive function evaluations.

Optimal Design Of A Switched Reluctance Motor With Magnetically Disconnected Rotor Modules Using A Design Of Experiments Differential Evolution Fea-Based Method, Vandana Rallabandi, Jie Wu, Ping Zhou, David G. Dorrell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Switched reluctance (SR) machines are attractive because they present relatively high efficiency and torque density in spite of lacking permanent magnets. This paper focuses on a two-objective optimization of an external rotor SR motor with a stator that has concentrated coils and a rotor with magnetically isolated modules. The objectives are minimum loss and mass, and 11 independent dimensionless geometric variables are considered as inputs that affect them. A combined design of experiments (DOE) and differential evolution (DE) approach is proposed. The DOE methodology is used to reduce the search space by eliminating from consideration input variable values, leading to …

Blood Transfusions In Preterm Infants: Changes On Perfusion Index And Intermittent Hypoxemia, Katrina T. Ibonia, Henrietta S. Bada, Philip M. Westgate, Enrique Gomez Pomar, Prasad Bhandary, Abhijit R. Patwardhan, Elie G. Abu Jawdeh

Pediatrics Faculty Publications

BACKGROUND

Red blood cell (RBC) transfusion decreases intermittent hypoxemia (IH) events beyond the first week of life. This benefit may be related to improved perfusion to the respiratory control network. Perfusion index (PI) is a perfusion measure provided by the pulse oximeter. We hypothesized that the benefit in IH after RBC transfusion is associated with an increase in PI. In addition, we assessed the value of PI and clinical measures in predicting the effect of RBC transfusion on IH.

STUDY DESIGN AND METHODS

We prospectively enrolled infants less than 30 weeks' gestation age. PI and oxygen saturation (SpO₂) …

Magnetic Ordering In A Vanadium-Organic Coordination Polymer Using A Pyrrolo[2,3-D:5,4-D']Bis(Thiazole)-Based Ligand, Yulia A. Getmanenko, Christopher S. Mullins, Vladimir N. Nesterov, Stephanie Lake, Chad Risko, Ezekiel Johnston-Halperin

Chemistry Faculty Publications

Here we present the synthesis and characterization of a hybrid vanadium-organic coordination polymer with robust magnetic order, a Curie temperature T_C of ∼110 K, a coercive field of ∼5 Oe at 5 K, and a maximum mass magnetization of about half that of the benchmark ferrimagnetic vanadium(tetracyanoethylene)_~2 (V·(TCNE)_~2). This material was prepared using a new tetracyano-substituted quinoidal organic small molecule 7 based on a tricyclic heterocycle 4-hexyl-4H-pyrrolo[2,3-d:5,4-d′]bis(thiazole) (C₆-PBTz). Single crystal X-ray diffraction of the 2,6-diiodo derivative of the parent C₆-PBTz, showed a disordered hexyl chain and …

Photocatalytic Activity: Experimental Features To Report In Heterogeneous Photocatalysis, Md. Ariful Hoque, Marcelo I. Guzman

Chemistry Faculty Publications

Heterogeneous photocatalysis is a prominent area of research with major applications in solar energy conversion, air pollution mitigation, and removal of contaminants from water. A large number of scientific papers related to the photocatalysis field and its environmental applications are published in different journals specializing in materials and nanomaterials. However, many problems exist in the conception of papers by authors unfamiliar with standard characterization methods of photocatalysts as well as with the procedures needed to determine photocatalytic activities based on the determination of “apparent quantum efficiencies” within a wavelength interval or “apparent quantum yields” in the case of using monochromatic …

An Accurate And Efficient Time Delay Estimation Method Of Ultra-High Frequency Signals For Partial Discharge Localization In Substations, Pengfei Li, Kejie Dai, Tong Zhang, Yantao Jin, Yushun Liu, Yuan Liao

Electrical and Computer Engineering Faculty Publications

Partial discharge (PD) localization in substations based on the ultra-high frequency (UHF) method can be used to efficiently assess insulation conditions. Localization accuracy is affected by the accuracy of the time delay (TD) estimation, which is critical for PD localization in substations. A review of existing TD estimation methods indicates that there is a need to develop methods that are both accurate and computationally efficient. In this paper, a novel TD estimation method is proposed to improve both accuracy and efficiency. The TD is calculated using an improved cross-correlation algorithm based on full-wavefronts of array UHF signals, which are extracted …

Highly Thiolated Poly (Beta-Amino Ester) Nanoparticles For Acute Redox Applications, Andrew L. Lakes, David A. Puleo, J. Zach Hilt, Thomas D. Dziubla

Chemical and Materials Engineering Faculty Publications

Disulfides are used extensively in reversible cross-linking because of the ease of reduction into click-reactive thiols. However, the free-radical scavenging properties upon reduction are often under-considered. The free thiols produced upon reduction of this disulfide material mimic the cellular reducing chemistry (glutathione) that serves as a buffer against acute oxidative stress. A nanoparticle formulation producing biologically relevant concentrations of thiols may not only provide ample chemical conjugation sites, but potentially be useful against severe acute oxidative stress exposure, such as in targeted radioprotection. In this work, we describe the synthesis and characterization of highly thiolated poly (β-amino ester) (PBAE) nanoparticles …

Power Utility Tests For Multi-Mw High Energy Batteries, Oluwaseun M. Akeyo, Huangjie Gong, Vandana Rallabandi, Nicholas Jewell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper reviews the procedures, layouts and metrics described in the new test manual issued by the Electric Power Research Institute (EPRI), in order to determine the performance and functionality of a utility scale battery energy storage system (BESS). In this approach, the large battery unit is connected to the dc-link of a bidirectional power conversion system (PCS), which may be interfaced with either the utility grid or a load bank for the purpose of estimating the BESS operation and performance characteristics, some of which includes; available charge/discharge energy at rated power, continuous charge/discharge duration, battery ramp rate, and ac …

Simulation Studies For A Multi-Mw Hybrid Wind-Solar Pv System For Desalination Plants, Vandana Rallabandi, Nasser Alawhali, Oluwaseun M. Akeyo, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper presents a power system configuration and control schemes for a Multi-MW wind-solar hybrid system, which includes multiple wind turbines and solar panels to support a desalination plant. The wind and solar systems are sized such that the desalination plant obtains, as far as possible, its power from the renewable sources, to minimize the dependence on the utility grid. Each section of the wind turbine system includes a variable speed permanent magnet synchronous generator connected to the grid via a back-to-back voltage source converter. The rectifier operates the wind system at the maximum power point, and the inverter provides …

Tncs & Congestion, Joe Castiglione, Drew Cooper, Bhargava Sana, Dan Tischler, Tilly Chang, Gregory D. Erhardt, Sneha Roy, Mei Chen, Alex Mucci

Civil Engineering Reports

From the executive summary:

This document:

• Identifies common measures of roadway congestion;
• Discusses factors that contribute to roadway to congestion; and
• Quantifies the relative contributions of different factors, including population, employment, road network changes and TNCs, to observed changes in congestion in San Francisco between 2010 and 2016, by location and time of day.

The report utilizes a unique TNC trip dataset provided to the Transportation Authority by researchers from Northeastern University in late 2016, as well as INRIX data, a commercial dataset which combines several real-time GPS monitoring sources with data from highway performance monitoring systems. These data are …

Real Time Operation Of Smart Homes With Pv And Battery Systems Under Variable Electricity Rate Schedules And Transactive Power Flow, Huangjie Gong, Oluwaseun M. Akeyo, Vandana Rallabandi, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

According to some utility schedules, the electricity rate is variable such that homes may be encouraged to buy and store power in a battery when it is inexpensive, and self-consume or sell to the grid during other times. Power arbitrage through a battery energy storage (BES), can help maintain consumer comfort and minimize residential electricity bills. This paper reports the calculated daily energy costs incurred by different types of homes for a given utility electricity rate schedule. The homes exchange power among each other behind a section of the distribution network. A free market system is formed and the electricity …

Sh-Mode Seismic-Reflection Imaging Of Earthfill Dams, Edward W. Woolery

Earth and Environmental Sciences Faculty Publications

Assessing subsurface characteristics and imaging geologic features (e.g., faults, cavities, low-velocity layers, etc.) are typical problems in near-surface geophysics. These questions often have adverse geotechnical engineering implications, and can be especially acute when associated with high-hazard structures such as large earthen flood-control dams. Dam-related issues are becoming more frequent in the United States, because a large part of this major infrastructure was designed and constructed in the early- to mid-twentieth century; these dams are thus passing into the latter stages of their design life, where minute flaws that were overlooked or thought to be insignificant in design/construction are now …

Local Deformation And Texture Of Cold-Rolled Aa6061 Aluminum Alloy, Diaoyu Zhou, Wenwen Du, Xiyu Wen, Junwei Qiao, Wei Liang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Using cold rolling, we plastically deform AA6061 sheets at room temperature and investigate the variations of the microstructures, textures and local deformation of the cold-rolled AA6061 sheets as functions of thickness reduction (Δt/t₀, t₀ and t are the thicknesses of the AA6061 sheet before and after the cold rolling, respectively). The volume fraction of total deformation texture is relatively independent of the thickness reduction for Δt/t₀ ≤ 30%, and becomes an approximately linearly increasing function of the thickness reduction for Δt/t₀ > 30%. Increasing the thickness reduction causes the increase of the Vickers hardness of the …

Ultrafine Mineral Associations In Superhigh-Organic-Sulfur Kentucky Coals, James C. Hower, Debora Berti, Michael F. Hochella Jr.

Center for Applied Energy Research Faculty and Staff Publications

Two high-organic-sulfur Kentucky coals, the eastern Kentucky River Gem coal and the western Kentucky Davis coal, are examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), both including elemental analysis by energy-dispersive spectroscopy (EDS). From the SEM–EDS analysis, it is observed that the western Kentucky coal had areas with Pb and Cd in addition to the expected Fe and S and the eastern Kentucky coal had individual Fe–S-rich areas with La and Ni and with Si, Al, Cr, Ni, and Ti. TEM and selected area electron diffraction (SAED) analyses demonstrate that anglesite with a rim of Pb-bearing amorphous …

Noncontact Speckle Contrast Diffuse Correlation Tomography Of Blood Flow Distributions In Tissues With Arbitrary Geometries, Siavash Mazdeyasna, Chong Huang, Mingjun Zhao, Nneamaka B. Agochukwu, Ahmed A. Bahrani, Lesley Wong, Guoqiang Yu

Biomedical Engineering Faculty Publications

A noncontact electron multiplying charge-coupled-device (EMCCD)-based speckle contrast diffuse correlation tomography (scDCT) technology has been recently developed in our laboratory, allowing for noninvasive three-dimensional measurement of tissue blood flow distributions. One major remaining constraint in the scDCT is the assumption of a semi-infinite tissue volume with a flat surface, which affects the image reconstruction accuracy for tissues with irregular geometries. An advanced photometric stereo technique (PST) was integrated into the scDCT system to obtain the surface geometry in real time for image reconstruction. Computer simulations demonstrated that a priori knowledge of tissue surface geometry is crucial for precisely reconstructing the …

Comparison Of Left Ventricular Strains And Torsion Derived From Feature Tracking And Dense Cmr, Gregory J. Wehner, Linyuan Jing, Christopher M. Haggerty, Jonathan D. Suever, Jing Chen, Sean M. Hamlet, Jared A. Feindt, Walter Dimitri Mojsejenko, Mark A. Fogel, Brandon K. Fornwalt

Biomedical Engineering Faculty Publications

Background: Cardiovascular magnetic resonance (CMR) feature tracking is increasingly used to quantify cardiac mechanics from cine CMR imaging, although validation against reference standard techniques has been limited. Furthermore, studies have suggested that commonly-derived metrics, such as peak global strain (reported in 63% of feature tracking studies), can be quantified using contours from just two frames – end-diastole (ED) and end-systole (ES) – without requiring tracking software. We hypothesized that mechanics derived from feature tracking would not agree with those derived from a reference standard (displacement-encoding with stimulated echoes (DENSE) imaging), and that peak strain from feature tracking would agree with …

In Vivo Brainstem Imaging In Alzheimer’S Disease: Potential For Biomarker Development, David J. Braun, Linda J. Van Eldik

Neuroscience Faculty Publications

The dearth of effective treatments for Alzheimer’s disease (AD) is one of the largest public health issues worldwide, costing hundreds of billions of dollars per year. From a therapeutic standpoint, research efforts to date have met with strikingly little clinical success. One major issue is that trials begin after substantial pathological change has occurred, and it is increasingly clear that the most effective treatment regimens will need to be administered earlier in the disease process. In order to identify individuals within the long preclinical phase of AD who are likely to progress to dementia, improvements are required in biomarker development. …

Self-Cleaning Nanocomposite Membranes With Phosphorene-Based Pore Fillers For Water Treatment, Joyner Eke, Katherine Elder, Isabel Escobar

Chemical and Materials Engineering Faculty Publications

Phosphorene is a two-dimensional material exfoliated from bulk phosphorus and it possesses a band gap. Specifically, relevant to the field of membrane science, the band gap of phosphorene provides it with potential photocatalytic properties, which could be explored in making reactive membranes that can self-clean. The goal of this study was to develop an innovative and robust membrane that is able to control and reverse fouling with minimal changes in membrane performance. To this end, for the first time, membranes have been embedded with phosphorene. Membrane modification was verified by the presence of phosphorus on membranes, along with changes in …

Individualized Clinical Practice Guidelines For Pressure Injury Management: Development Of An Integrated Multi-Modal Biomedical Information Resource, Kathie M. Bogie, Guo-Qiang Zhang, Steven K. Roggenkamp, Ningzhou Zeng, Jacinta Seton, Shiqiang Tao, Arielle L. Bloostein, Jiayang Sun

Institute for Biomedical Informatics Faculty Publications

Background: Pressure ulcers (PU) and deep tissue injuries (DTI), collectively known as pressure injuries are serious complications causing staggering costs and human suffering with over 200 reported risk factors from many domains. Primary pressure injury prevention seeks to prevent the first incidence, while secondary PU/DTI prevention aims to decrease chronic recurrence. Clinical practice guidelines (CPG) combine evidence-based practice and expert opinion to aid clinicians in the goal of achieving best practices for primary and secondary prevention. The correction of all risk factors can be both overwhelming and impractical to implement in clinical practice. There is a need to develop practical …

Gold-Catalyzed Conversion Of Lignin To Low Molecular Weight Aromatics, Yang Song, Justin K. Mobley, Ali Hussain Motagamwala, Mark Isaacs, James E. Dumesic, John Ralph, Adam F. Lee, Karen Wilson, Mark Crocker

Chemistry Faculty Publications

A heterogeneous catalyst system, employing Au nanoparticles (NPs) and Li–Al (1 : 2) layered double hydroxide (LDH) as support, showed excellent activity in aerobic oxidation of the benzylic alcohol group in β-O-4 linked lignin model dimers to the corresponding carbonyl products using molecular oxygen under atmospheric pressure. The synergistic effect between Au NPs and the basic Li–Al LDH support induces further reaction of the oxidized model compounds, facilitating facile cleavage of the β-O-4 linkage. Extension to oxidation of γ-valerolactone (GVL) extracted lignin and kraft lignin using Au/Li–Al LDH under similar conditions produced a range of aromatic monomers in high yield. …

Exploring The Efficiency And Cost Limits Of Fractional Hp Axial Flux Pm Machine Designs, Narges Taran, Vandana Rallabandi, Greg Heins, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Optimizing the design of electric machines is a vital step in ensuring the economical use of active materials. The three-dimensional flux paths in axial flux PM (AFPM) machines necessitate the use of computationally expensive 3D electromagnetic analysis. Furthermore, a large number of design evaluations is required to find the optimum, causing the total computation time to be excessively long. In view of this, a two-level surrogate assisted algorithm capable of handling such expensive optimization problems is introduced, which substantially reduces the number of FEA evaluations. The proposed algorithm is employed to optimally design an AFPM machine within a specified envelope, …

Waterproofing Options For Bridge Decks, Danny Wells, Sudhir Palle, Theodore Hopwood Ii

Kentucky Transportation Center Research Report

Due to the increasing use of deicing chemicals and the subsequent intrusion of chlorides into bridge decks, it is necessary to expand the use of available protective measures, including waterproofing materials. Waterproofing options that fall into three categories; 1) membranes (liquid and sheet systems), 2) friction polymers (laminates), and 3) polymer asphalts. This study assessed the waterproofing characteristics of these products. Prior to this study, no common test had been established to compare the performance of waterproofing products. A test method was developed that closely follows ASTM D5084, “Standard Test Methods for Measurement of Hydraulic Conductivity of Saturated Porous Materials …

Net Zero Energy Houses With Dispatchable Solar Pv Power Supported By Electric Water Heater And Battery Energy Storage, Huangjie Gong, Vandana Rallabandi, Dan M. Ionel, Donald G. Colliver, Shaun Duerr, Cristinel Ababei

Power and Energy Institute of Kentucky Faculty Publications

Over a year, net zero energy (NZE) houses produce and feed zero net metered electrical energy to the grid. Technical challenges, notably the `duck curve' arise due to the fact that peak solar generation and load demand are seldom coincident. Common approaches to mitigate this limitation include the curtailment of solar power, and the use of storage. Surplus solar energy may be stored in a battery, which can subsequently be discharged to supply the home electricity needs when demand is in excess. In addition to batteries, less expensive electric water heaters, which are ubiquitous, can be modified as energy storage …

What You Don’T See, Brent Sturlaugson

Architecture Faculty Publications

Follow the supply chains of architecture and you’ll find not just product manufacturers but also environmental polluters and elusive networks of financial power and political influence.

Analysis Of Traffic Crash Data In Kentucky (2013-2017), Eric R. Green, Kenneth R. Agent, Jerry G. Pigman, Paul A. Ross

Kentucky Transportation Center Research Report

Executive Summary

This report documents an analysis of traffic crash data in Kentucky for the years of 2013-2017. A primary objective of this study was to determine average crash statistics for Kentucky highways. Rates were calculated for various types of highways and for counties and cities. Difference criteria were used for exposure.

Average and critical numbers and rates of crashes were calculated for various types of highways in rural and urban areas. These rates used crashes identified on highways where traffic volumes were available. Improved methods of identifying crash locations have resulted in higher rates for the last couple of …

Torque Production Capability Of Axial Flux Machines With Single And Double Rotor Configurations, Narges Taran, Greg Heins, Vandana Rallabandi, Dean Patterson, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Axial flux PM (AFPM) machines are used particularly in applications requiring a compact structure. Their disc shape topology and axial air-gap have lead to a variety of configurations including two popular ones: the yokeless and segmented armature (YASA), and the single-stator single-rotor or single sided machine. In this study, a comprehensive comparative analysis of these configurations is conducted at different magnetic and electric loadings. It is found that at lower loadings, typically employed for air-cooled machines, the torque/ampere characteristics of the YASA machine are almost identical to those of a single sided machine constructed with half the magnet volume. On …

Transistor-Clamped Multilevel H-Bridge Inverter In Si And Sic Hybrid Configuration For High-Efficiency Photovoltaic Applications, Yibin Zhang, Jiangbiao He, Sanjeevikumar Padmanaban, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Using wide bandgap (WBG) devices has been a promising solution to improve the efficiency of power inverters for photovoltaic (PV) applications. However, for multilevel inverters, using WBG devices to improve the inverter efficiency can increase the system cost dramatically due to the high price of WBG devices in the present market as well as the large number of power devices typically required in multilevel inverter topologies. In this paper, a five-level transistor clamped H-bridge (TCHB) inverter will be further investigated. This inverter requires much lower number of semiconductor switches and fewer isolated dc sources than the conventional cascaded H-bridge inverter. …

Improvement Of Fatal Crash Analysis And Follow-Up, William Nicholas Staats, Jerry G. Pigman, Kenneth R. Agent, Paul A. Ross

Kentucky Transportation Center Research Report

Executive Summary

Fatalities resulting from traffic crashes in Kentucky increased from a low of 638 in 2013 to 834 in 2016 (a 31% increase), and there is not a full understanding of the underlying causes for this trend. This study analyzes fatal crashes using data from both Kentucky’s crash reports and the National Highway Traffic Safety Administration’s (NHTSA) Fatal Accident Reporting System (FARS) to identify countermeasures to combat increasing fatal crash rates. In addition, this study compares Kentucky’s crash reports to the fatal crash data in FARS to identify data inconsistencies and recommend procedures to eliminate these inconsistencies.

Emphasis was …