Engineering Commons^™

Study Of Static And Dynamical Properties Of Complex Antiferroelectrics Materials, Kinnary Yogeshbhai Patel

Graduate Theses and Dissertations

The aim of this dissertation is the investigation of the static and dynamical properties of the complex antiferroelectric materials using Effective Hamiltonian method and First principles calculations. In chapter 3, a novel elemental interatomic coupling in perovskite materials which bilinearly couples the antiferroelectric displacements of cations with the rotations of the oxygen octahedra. This new coupling explains a very complex crystal structure of prototypical antiferroelectric PbZrO3. My explanation provides a unified description of many other complex antipolar crystal structures in variety of perovskite materials, including the occurrence of incommensurate phases in some of them. In chapter 4, results and analysis …

Biopolymeric Materials For Tissue Regeneration, Cell Manufacturing, And Drug Delivery, David Alfonso Castilla-Casadiego

Graduate Theses and Dissertations

The development of materials for tissue regeneration, cell manufacturing, and drug delivery is possible by the manipulation of polymer properties and the use of three different techniques including layer-by-layer, electrospinning, and molding technique.

By applying the layer-by-layer technique over biomaterials, it is possible to develop polymeric multilayers that promote a more favorable environment for cellular functionality, increasing the possibility of improving their acceptance in the area of implantation. IRVASE demonstrated being a powerful technique that allows for a reliable characterization of the physical-chemical and thermal properties of the fabricated surfaces. This opens the possibility to monitor the design of surfaces …

Memory Module Design For High-Temperature Applications In Sic Cmos Technology, Affan Abbasi

Graduate Theses and Dissertations

The wide bandgap (WBG) characteristics of SiC play a significant and disruptive role in the power electronics industry. The same characteristics make this material a viable choice for high-temperature electronics systems. Leveraging the high-temperature capability of SiC is crucial to automotive, space exploration, aerospace, deep well drilling, and gas turbines. A significant issue with the high-temperature operation is the exponential increase in leakage current. The lower intrinsic carrier concentration of SiC (10-9 cm-3) compared to Si (1010 cm-3) leads to lower leakage over temperature. Several researchers have demonstrated analog and digital circuits designed in SiC. However, a memory module is …

Statistical Machine Learning For Breast Cancer Detection With Terahertz Imaging, Tanny Andrea Chavez Esparza

Graduate Theses and Dissertations

Breast conserving surgery (BCS) is a common breast cancer treatment option, in which the cancerous tissue is excised while leaving most of the healthy breast tissue intact. The lack of in-situ margin evaluation unfortunately results in a re-excision rate of 20-30% for this type of procedure. This study aims to design statistical and machine learning segmentation algorithms for the detection of breast cancer in BCS by using terahertz (THz) imaging. Given the material characterization properties of the non-ionizing radiation in the THz range, we intend to employ the responses from the THz system to identify healthy and cancerous breast tissue …

Development Of Biomaterials For Drug Delivery, Raquel De Castro

Graduate Theses and Dissertations

Drug delivery systems (DDS) have highly evolved in the last decades with the development of hydrogels and nanoparticles. However, high systemic uptake, side effects, low bioavailability, and encapsulation efficiency continue to be a major hurdle faced by such DDSs.

Nanoparticles and hydrogels can be specifically designed for targeted DDSs to mitigate some of the problems. This dissertation aimed to design two DDSs for ocular drug delivery and one for cancer treatment. The first project sought to develop chitosan nanoparticles (Cs-NP) using PEGDA as a copolymer to encapsulate gentamicin (GtS) for ocular drug delivery. Cs-NPs contain positive charges that can interact …

Improvement Of Stability Of A Grid-Connected Inverter With An Lcl Filter By Robust Strong Active Damping And Model Predictive Control, Seungyong Lee

Graduate Theses and Dissertations

This study addresses development and implementation of robust control methods for a three-phase grid-connected voltage source inverter (VSI) accompanied by an inductive-capacitive-inductive (LCL) filter. A challenge of current control for the VSI is LCL filter resonance near to the control stability boundary, which interacts with the inverter control switching actions and creates the possibility of instability. In general, active damping is needed to stabilize the system and ensure robust performance in steady-state and dynamic responses. While many active damping methods have been proposed to resolve this issue, capacitor-current-feedback active damping has been most widely used for its simple implementation.

There …

An Accurate And Efficient Electro-Thermal Compact Model Of Sic Power Mosfet Including Third Quadrant Behavior, Arman Ur Rashid

Graduate Theses and Dissertations

Due to narrower bandgap and lower critical electric field, silicon (Si) power devices have reached their limit in terms of the maximum blocking voltage capability. Exploiting this limitation, wide bandgap devices, namely silicon carbide (SiC) and gallium nitride (GaN) devices, are increasingly encroaching on the lucrative power electronics market. Unlike GaN, SiC devices can exploit most of the established fabrication techniques of Si power devices. Having substrate of the same material, vertical device structures with higher breakdown capabilities are feasible in SiC, unlike their GaN counterpart. Also, the excellent thermal conductivity of SiC, compared to GaN and Si, let SiC …

Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore

Graduate Theses and Dissertations

Cellulose nanomaterials (CNMs) are derived from plant matter and are comprised of nanoscopic cellulose crystals and fibers. They have a diverse set of applications, from cosmetics to oil recovery. This study focuses on the properties of Oxone® mediated TEMPO-oxidized cellulose nanomaterials (OTO-CNMs) and their use in controlling the transport properties of polymeric substrates. Synthesis and characterization of cellulosic nanoparticles have resulted in the creation of OTO-CNMs with properties that increase hydrophilicity. With added hydrophilicity, OTO-CNMs possess lower fouling propensity, making them ideal membrane additive for transport limited separations such as hemodialysis.

To utilize the material and unique properties thereof, this …

Analog Spiking Neural Network Implementing Spike Timing-Dependent Plasticity On 65 Nm Cmos, Luke Vincent

Graduate Theses and Dissertations

Machine learning is a rapidly accelerating tool and technology used for countless applications in the modern world. There are many digital algorithms to deploy a machine learning program, but the most advanced and well-known algorithm is the artificial neural network (ANN). While ANNs demonstrate impressive reinforcement learning behaviors, they require large power consumption to operate. Therefore, an analog spiking neural network (SNN) implementing spike timing-dependent plasticity is proposed, developed, and tested to demonstrate equivalent learning abilities with fractional power consumption compared to its digital adversary.

Peptoid-Based Microsphere Coatings For Biomaterial Applications, Jesse Leland Roberts

Graduate Theses and Dissertations

Peptoids are peptidomimetic oligomers that predominantly harness similarities to peptides for biomimetic functionality. The incorporation of chiral, aromatic side chains in the peptoid sequence allows for the formation of distinct secondary structures and self-assembly into supramolecular assemblies, including microspheres. Peptoid microspheres can be coated onto substrates for potential use in biosensor technologies, tissue engineering platforms, and drug-delivery systems. They have the potential for use in biomedical applications due to their resistance to proteolytic degradation and low immunogenicity. This dissertation focuses on the physical characteristics and robustness of the peptoid microsphere coatings in various physiological conditions, along with their ability to …

Investigative Study Of Microalgal And Electrochemical Wastewater Treatment Systems And Modeling Of The Wafer-Enhanced Electrodeionization Using Supervised Learning, Humeyra Betul Ulusoy Erol

Graduate Theses and Dissertations

Wastewater has a serious impact on environment and public health due to its high concentration of nutrients and toxic contaminants. Without proper treatment, excess nutrients discharged in wastewater can cause a damage to the ecosystem such as undesirable pH shifts, cyanotoxin production, and low dissolved oxygen concentrations.

Main objectives of this dissertation work were to investigate i) the biofuel potential of P. cruentum when grown in swine wastewater, ii) the influence of four most commonly used ion exchange resins on the system efficiency and selectivity for the removal of sodium, calcium, and magnesium ions, and iii) the modeling of wafer-enhanced …

When It Rains, It Pours: A Case Study Of Spatio-Temporal Variations In High-Intensity Precipitation Events In Arkansas, Deanna Mantooth-Hendrix

Graduate Theses and Dissertations

Climate change is having an impact on weather systems and ecosystems worldwide. Glaciers are receding, oceans are acidifying, hurricanes are stronger, and extreme precipitation is increasing in frequency. Even with the wealth of data and knowledge about the threat of climate change, some places are slow to adapt because they think that the impact to their ecosystem will not be severe. The goal of this project was to determine if climate change is having an impact on extreme precipitation in the top urban areas of Arkansas. The major concern with an increase in extreme events in urban areas is flooding. …

Design And Assembly Of High-Temperature Signal Conditioning System On Ltcc With Silicon Carbide Cmos Circuits, Sajib Roy

Graduate Theses and Dissertations

The objective of the work described in this dissertation paper is to develop a prototype electronic module on a low-temperature co-fired ceramic (LTCC) material. The electronic module would perform signal conditioning of sensor signals (thermocouples) operating under extreme conditions for applications like gas turbines to collect data on the health of the turbine blades during operation so that the turbines do not require shutdown for inspection to determine if maintenance is required. The collected data can indicate when such shutdowns, which cost $1M per day, should be scheduled and maintenance actually performed. The circuits for the signal conditioning system within …

Securing Fog Federation From Behavior Of Rogue Nodes, Mohammed Saleh H. Alshehri

Graduate Theses and Dissertations

As the technological revolution advanced information security evolved with an increased need for confidential data protection on the internet. Individuals and organizations typically prefer outsourcing their confidential data to the cloud for processing and storage. As promising as the cloud computing paradigm is, it creates challenges; everything from data security to time latency issues with data computation and delivery to end-users. In response to these challenges CISCO introduced the fog computing paradigm in 2012. The intent was to overcome issues such as time latency and communication overhead and to bring computing and storage resources close to the ground and the …

Photothermal Response Induced By Nanocage-Coated Artificial Extracellular Matrix Promotes Neural Stem Cell Differentiation, Seunghyun Jung, Nathaniel Harris, Isabelle I. Niyonshuti, Samir V. Jenkins, Abdallah M. Hayar, Fumiya Watanabe, Azemat Jamshidi-Parsian, Jingyi Chen, Michael J. Borrelli, Robert J. Griffin

Mechanical Engineering Faculty Publications and Presentations

Strategies to increase the proportion of neural stem cells that differentiate into neurons are vital for therapy of neurodegenerative disorders. In vitro, the extracellular matrix composition and topography have been found to be important factors in stem cell differentiation. We have developed a novel artificial extracellular matrix (aECM) formed by attaching gold nanocages (AuNCs) to glass coverslips. After culturing rat neural stem cells (rNSCs) on these gold nanocage-coated surfaces (AuNC-aECMs), we observed that 44.6% of rNSCs differentiated into neurons compared to only 27.9% for cells grown on laminin-coated glass coverslips. We applied laser irradiation to the AuNC-aECMs to introduce precise …

Surface Modified Polypropylene Membranes For Treating Hydraulic Fracturing Produced Waters By Membrane Distillation, Tharaka Hawpe Gamage

Graduate Theses and Dissertations

Membrane distillation is an emerging technology for treating hydraulic fracturing flowback and produced waters. Suppression of membrane fouling by inorganic and polar and non-polar organic compounds is a challenge. Here polyhydroxyethyl methacrylate, polyacrylic acid, polvinylallyl imidazolium bromide and polyvinylhexyl imidazolium bromide chains have been grafted from the membrane surface. Fouling is initially due to adsorption of organic compounds followed by scale formation. When challenged with produced water, membranes modified with polvinylallyl imidazolium bromide chains provided the greatest resistance to fouling. For EC pretreated produced water and synthetic produced water that contained mainly inorganic species, the flux decline was much less.

Remote Performance Modulation Of Ultrafiltration Membranes By Magnetically And Thermally Responsive Polymer Chains, Arijit Sengupta, Anh Vu, Xianghong Qian, Sumith R. Wickramasinghe

Chemical Engineering Faculty Publications and Presentations

Ultrafiltration membranes, that respond to an external magnetic field and local temperature have been developed. Surface-initiated activator-generated electron transfer (AGET) atom transfer radical polymerization (ATRP) has been used to graft poly(N-isopropylacrylamide) (PNIPAm) from the surface of 300 kDa regenerated cellulose membranes. The polymerization initiator was selectively attached to the entire membrane surface, only the outer membrane surface or only the inner pore surface. A superparamagnetic nanoparticle was attached to the end of the polymer chain. The DI water flux as well as the flux and rejection of bovine serum albumin were investigated in the absence and presence of a 20 …

Evaluating The Effects Of Wood Source On The Physicochemical Properties Of Crosslinked Cellulose Nanocrystals, Helena Tchoungang Nkeumen

Graduate Theses and Dissertations

Cellulose is an abundant and naturally occurring biopolymer that has been used by humans for food, shelter, and clothing for about two centuries now. Highly crystalline nanoparticles derived from cellulose, called cellulose nanocrystals (CNCs), show great potential to meet the rising need for sustainable and nontoxic materials for biomedical applications. However, multiple biomedical applications of CNCs, such as those involving their use in tissue engineering scaffolds, require CNC-based structures to be stable in aqueous environments, a property that native CNCs do not possess due to their inherent hydrophilicity. Chemical crosslinking of CNCs addresses this issue by providing aqueous stability to …

Quantifying The Effect Of Intrinsic Aging On Skin Microstructure And Mechanical Function Using Multiphoton Microscopy, Alan Edward Woessner

Graduate Theses and Dissertations

Over the next couple of decades, the number of elderly individuals is expected to double, bringing increased healthcare spending due to seemingly minor injuries to skin. In skin, the 3D dermal collagen fiber network, which is the primary load-bearing structure, undergoes changes in organization and composition due to intrinsic aging. However, the relationships between altered microstructure and mechanical function is not well understood. Quantitative imaging techniques have been used in the past to link skin structure to mechanical function, but previous analysis has been limited to 2D assessments. Multiphoton microscopy (MPM) is a non-destructive imaging technique with intrinsic depth-sectioning capabilities, …

Estimating Irrigation In Rice Fields With A Water Balance Approach, Kristen Trinh

Biological and Agricultural Engineering Undergraduate Honors Theses

Global food production must increase to meet the demand associated with increased population growth, so irrigation water use will continue to rise. Therefore, it is important to monitor water usage particularly when an irrigation flowmeter is unavailable. A field water balance was created for a selection of rice fields in East-central Arkansas under observation in 2018 and 2019. From those, irrigation inputs are deduced from the water balance alone. First, each field had sensors that collected water table level (WTL) data. Next, other water inputs and outputs such as precipitation and evapotranspiration (ET) were collected from two modeled sources. The …

Low Impact Development: Low-Maintenance Design To Encourage Residential Adoption Of Sustainable Systems, Haley Ellis

Biological and Agricultural Engineering Undergraduate Honors Theses

Residential adoption of low-impact development (LID) technology can positively impact downstream watershed hydrology by reducing total volumetric discharge from the residential site. This reduction can provide economic, environmental, and social benefits for the residents as well as the community at large. Additionally, homeowners are often affected by stormwater related issues, like flooding or washout, that could be easily mitigated with a sustainably engineered LID structure or network. Engineering for sustainability often includes the blending of several objectives to provide greater overall benefit. This thesis compares the outflow characteristics of three low-maintenance residential LID design scenarios differing in rain garden soil …

Design Of Control Logic And The Human-Machine Interface For A Demonstration Plant Growth Chamber Implemented On A Programmable Logic Controller, Rachael Koehler

Biological and Agricultural Engineering Undergraduate Honors Theses

This honors thesis covers the planning, development, and implementation of system controls and human-machine interface (HMI) for a demonstration plant growth chamber. The work is a continuation of an ongoing project to be used as an educational and recruiting tool manifesting the skills acquired from the Biological and Agricultural Engineering Department at the University of Arkansas’ College of Engineering. This work includes emergency controls, overall design interface, and controls for both the aeration and lighting subsystems of the growth chamber. Overall design interface controls established included development of two user modes, Administrator and Visitor. The Administrator user will have full …

Performance And Economics Of Solar Inverters And Module Level Power Electronics In A 1 Mw Photovoltaic System, Maxwell Criswell

Biological and Agricultural Engineering Undergraduate Honors Theses

Photovoltaic solar panels convert sunlight to electricity in the form of direct current; therefore, a necessary component of every photovoltaic system is an inverter to convert the electricity to usable alternating current. There are various commercially available inverter technologies manufactured today such as microinverters, string inverters, and central inverters, as well as module level power electronic devices such as DC optimizers that are capable of improving system performance in string and central inverter systems. This thesis compares the performance and economics of five different inverter and module level power electronic systems through model simulation using Helioscope software. The five alternatives …

Peptoid Microsphere Coatings To Improve Performance In Sandwich Elisa Microarrays, Jesse L. Roberts, German R. Perez Bakovic, Shannon L. Servoss

Chemical Engineering Faculty Publications and Presentations

Enzyme-linked immunosorbent assay (ELISA) microarray performance is limited by low assay sensitivity and dynamic range. Increasing the surface area for reagent binding can help to improve performance, but standard techniques such as roughening the surface or adding a polymer coating lead to increased non-specific fluorescence and do not have reproducibly improved performance. Another approach to increase surface area is adding a microsphere coating on the surface. Poly-N-substituted glycine (peptoid) microspheres are ideal for this application due to low immunogenicity, protease-resistance, and biocompatibility. Peptoids are polymers with a backbone similar to peptides, but with the side chains appended to nitrogen rather …

Lecture 08: Partial Eigen Decomposition Of Large Symmetric Matrices Via Thick-Restart Lanczos With Explicit External Deflation And Its Communication-Avoiding Variant, Zhaojun Bai

Mathematical Sciences Spring Lecture Series

There are continual and compelling needs for computing many eigenpairs of very large Hermitian matrix in physical simulations and data analysis. Though the Lanczos method is effective for computing a few eigenvalues, it can be expensive for computing a large number of eigenvalues. To improve the performance of the Lanczos method, in this talk, we will present a combination of explicit external deflation (EED) with an s-step variant of thick-restart Lanczos (s-step TRLan). The s-step Lanczos method can achieve an order of s reduction in data movement while the EED enables to compute eigenpairs in batches along with a number …

Lecture 00: Opening Remarks: 46th Spring Lecture Series, Tulin Kaman

Mathematical Sciences Spring Lecture Series

Opening remarks for the 46th Annual Mathematical Sciences Spring Lecture Series at the University of Arkansas, Fayetteville.

Do Your Projects Support Your Strategy? Applying Benefits Realization Management, Phil Jones

Operations Management Presentations

In this webinar, foundational concepts of Benefits Realization Management will be presented and discussed. Benefits Realization Management (BRM) is a both a discipline and a process used to align projects undertaken by an organization with the organization’s strategy and culture.

Blood Driven Biopower Cells: Acquiring Energy From Reverse Electrodialysis Using Sodium Concentrations From The Flow Of Human Blood, Efecan Pakkaner, Chase Smith, Christina Trexler, Jamie Hestekin, Christa Hestekin

Chemical Engineering Faculty Publications and Presentations

With the growth of the healthcare industry, small scale power sources are needed to support advancements in medical implants, artificial organs, and sensors throughout the body. However, it remains a challenge to find safe, reliable, and stable power sources for these devices. In this study, a miniaturized reverse electrodialysis (RED) biopower cell design using physiological salinity concentration differences between renal bloodstreams is explored for its potential to be used as a power supply for implantable medical devices. Two small scale RED devices produced consistent power for up to three to ten days, depending on the device design. A two-fold decrease …

Agile Thinking And Innovative Technology Development, Rocky Gay

Operations Management Presentations

Agile Project Management approaches have grown beyond software development and are being incorporated in many industries at a rapid pace. This expansion has created a need for a common language and methodology that fosters self-organized collaboration and an innate desire to deliver products that maximize customer satisfaction. There are a broad range of tools and techniques nested in a framework that facilitate a flexible and steady cadence of product delivery. Organizations have options in managing projects. Shifting to an agile mindset, values and principles may necessitate a culture change in project teams.

Quantitative Set-Based Design To Inform Design Teams, Eric Specking, Nicholas Shallcross, Gregory S. Parnell, Edward Pohl

Industrial Engineering Faculty Publications and Presentations

System designers, analysts, and engineers use various techniques to develop complex systems. A traditional design approach, point-based design (PBD), uses system decomposition and modeling, simulation, optimization, and analysis to find and compare discrete design alternatives. Set-based design (SBD) is a concurrent engineering technique that compares a large number of design alternatives grouped into sets. The existing SBD literature discusses the qualitative team-based characteristics of SBD, but lacks insights into how to quantitatively perform SBD in a team environment. This paper proposes a qualitative SBD conceptual framework for system design, proposes a team-based, quantitative SBD approach for early system design and …