Engineering Commons^™

Synthesis, Molecular And Solid State Structures, And Magnetic Properties Of Sandwich Lanthanide Phthalocyanines Lacking C-H Bonds, Wycliffe A. Graham

Dissertations

A new class of sandwich phthalocyanine (Pc) compounds without C-H bonds was synthesized and characterized. They are the bis[octakis(perfluoro i-C₃F₇) octakis(perfluoro)phthalocyaninato(2−)]M(III) complexes, formulated as (F₆₄Pc)₂MH, M = Tb, Dy, Lu, Y. Single molecular magnetic (SMM) behavior in the (F₆₄Pc)₂TbH and (F₆₄Pc)₂DyH complexes was confirmed through slowed relaxation response of their magnetization in an applied time varying magnetic field during alternating current (AC) magnetic testing in the range 2 - 50 K. The energy barrier to magnetic reversal, Δ = 215 cm^-1 and …

Auger-Mediated Processes And Photoluminescence In Group Iv Semiconductor Nanostructures, Nikhil Modi

Dissertations

Group IV semiconductors (Si, Ge) are inefficient light emitting materials due to their indirect bandgap structure. Nanostructures of Si, Ge, and SiGe however, have shown relatively high photoluminescence (PL) quantum efficiency (QE) at low carrier concentrations. At higher carrier concentrations, the PL QE of these nanostructures is drastically reduced due to the onset of a fast non-radiative process attributed to Auger recombination. Moreover, this onset occurs earlier in structures with reduced physical dimensions, than in bulk material. The study of Auger-mediated processes in group IV nanostructures is therefore critical to understanding the physics of carrier recombination and photonic device limitations. …

Rational Design Of Hydrogen-Free Catalytic Active Sites, Andrei Ioan Loas

Dissertations

Materials that are organic-based and exhibit oxidative catalytic activity, including free-radical pathways, while being refractory to the activated oxygen species are not known. The synthesis of several classes of such materials, their electronic and structural characterizations as well as catalytic properties are reported. Their rational molecular design and biologically inspired reactivity are based on enzymatic active sites, which are reengineered into robust metal-organic fluoroalkylated scaffolds that, for the first time, exhibit structural asymmetry and tunable π-π interactions both in solution and solid state. In these complexes, labile C-H bonds are replaced with chemically and thermally resistant C-F bonds to create …

Vector Coprocessor Sharing Techniques For Multicores: Performance And Energy Gains, Spiridon Florin Beldianu

Dissertations

Vector Processors (VPs) created the breakthroughs needed for the emergence of computational science many years ago. All commercial computing architectures on the market today contain some form of vector or SIMD processing.

Many high-performance and embedded applications, often dealing with streams of data, cannot efficiently utilize dedicated vector processors for various reasons: limited percentage of sustained vector code due to substantial flow control; inherent small parallelism or the frequent involvement of operating system tasks; varying vector length across applications or within a single application; data dependencies within short sequences of instructions, a problem further exacerbated without loop unrolling or other …

Design And Automated Operation Of A Condensation-Induced Depressurization System, Fen Du

Dissertations

Typical examples of the use of the vacuum environments in industry include vacuum coating, vacuum drying, vacuum packing, vacuum casting, vacuum heat treatment, vacuum cooling for food storage and leakage detection. Most of these applications require a comparatively small volume of vacuum environment. However, there are also many applications where enormous vacuum chambers are needed. For example, a large vacuum chamber is used to simulate the conditions of space.

This study investigates the design and the automated operation of a vacuum generation system based on the idea of the condensation-induced depressurization with prefilled condensable medium in a confined, adiabatic chamber. …

Desalination Of Brine And Produced Water By Membrane Distillation At Lower As Well As Higher Temperatures And Pressures, Dhananjay Singh

Dissertations

Direct contact membrane distillation (DCMD)-based desalination process is a thermally- driven separation process where a hydrophobic microporous membrane separates a hot brine feed and a cold distillate which condenses the water vapor from the hot brine passing through the membrane pores. So far, DCMD has been explored for hot brines and other aqueous solutions below 100oC. For feed solutions above 100oC, DCMD has an extra advantage over other conventional separation processes like reverse osmosis (RO) which requires cooling of the feed solution costing additional energy; further, RO can not utilize the heat available in the feed solution. Produced water obtained …

Image Statistical Frameworks For Digital Image Forensics, Patchara Sutthiwan

Dissertations

The advances of digital cameras, scanners, printers, image editing tools, smartphones, tablet personal computers as well as high-speed networks have made a digital image a conventional medium for visual information. Creation, duplication, distribution, or tampering of such a medium can be easily done, which calls for the necessity to be able to trace back the authenticity or history of the medium. Digital image forensics is an emerging research area that aims to resolve the imposed problem and has grown in popularity over the past decade. On the other hand, anti-forensics has emerged over the past few years as a relatively …

Upper Extremity Rehabilitation Using Interactive Virtual Environments, Qinyin Qiu

Dissertations

Stroke affects more than 700,000 people annually in the U.S. It is the leading cause of major disability. Recovery of upper extremity function remains particularly resistant to intervention, with 80% to 95% of persons demonstrating residual upper extremity impairments lasting beyond six months after the stroke. The NJIT Robot Assistive Virtual Rehabilitation (NJIT-RAVR) system has been developed to study optimal strategies for rehabilitation of arm and hand function. Several commercial available devices, such as HapticMaster™, Cyberglove™, trakSTAR™ and Cybergrasp™, have been integrated and 11 simulations were developed to allow users to interact with virtual environments. Visual interfaces used in these …

Energy-Efficient Multi-Criteria Packet Forwarding In Multi-Hop Wireless Networks, Komlan Egoh

Dissertations

Reliable multi-hop packet forwarding is an important requirement for the implementation of realistic large-scale wireless ad-hoc networks. However, packet forwarding methods based on a single criterion, such as the traditional greedy geographic forwarding, are not sufficient in most realistic wireless settings because perfect-reception-within-rangecannot be assumed. Furthermore, methods where the selection of intermediate relaying nodes is performed at the transmitter-side do not adapt well to rapidly changing network environments. Although a few link-aware geographic forwarding schemes have been reported in the literature, the tradeoffs between multiple decision criteria and their impact on network metrics such as throughput, delay and energy …

Inkjet Printing Of Resistive-Type Humidity Sensor For Harsh Environments, Hamed Kazerani

Dissertations

A flexible resistive-type humidity sensor for harsh environments is successfully designed and fabricated by an inkjet printing method using a Dimatix materials printer (DMP-2800 series from Fujifilm). Construction of the sensors is based on inkjet printed interdigitated silver electrodes on a polyimide flexible substrate along with an inkjet printable polyaniline (PANi) as humidity sensitive material. A copolymer of ethylene and vinyl alcohol (EVOH) is used as sensor protective coating. Double strand water- soluble PANi ink is synthesized by polymerization of aniline monomers with poly(4- styrenesulfonic acid) (PSSA) as a template.

Manufactured devices showed high sensitivity (/% @ 45%RH) to humidity …

Quantifying Prehension In Persons With Stroke Post Rehabilitation, Saumya Sara Puthenveettil

Theses

This study describes the analysis of reaching and grasping abilities of the hemiparetic arm and hand of patients post stroke after a series of interactive virtual reality (VR) simulated training sessions and conventional physical therapy of similar intensity. Six subjects participated in VR training and five subjects in clinical rehabilitation for two weeks. Subjects’ finger joint angles were measured during a kinematic reach to grasp test using CyberGlove® and arm joint angles were measured using the trackSTARTM system prior to training and after training. Downward force applied to the object during grasping was assessed using Nano17TM, a force/torque sensor system …

Analysis Of Tissue Engineering Strategies For Bone-Related Applications, Timothy Buirkle

Theses

Over the past few decades, tissue engineering approaches have pushed their way to the forefront of biotechnological research and development, serving a wide variety of applications. This research utilizes quantitative methods to analyze the outcome of two bone tissue engineering studies. In an in vivo study, the use of Negative Pressure Wound Therapy (NPWT) in combination with stem cell-loaded scaffolds was investigated for the repair of large bone defects. Quantitative histological analysis was performed by determining both the percentage of cells proliferating (BrdU), as well as cells expressing bone-specific markers of alkaline phosphatase (A L P) in the defect. Total …

Hydrodynamic Effects Of An Arch-Shaped Fiber Optic Probe In A Dissolution Testing Apparatus 2, Yiran Zhang

Theses

Dissolution testing is widely used in the pharmaceutical industry to evaluate newly developed drug formulations and as a quality control method to insure that solid dosage forms have consistent dissolution property. Typically, samples are manually drawn from the dissolution vessel prior to analysis. An approach to overcome the limitations of manual sampling consists in the use of sampling probes, such as fiber optic probes, permanently inserted in the dissolution medium and continually sampling the drug concentration in it as the solid dosage form dissolves. Despite their advantages, permanently inserted fiber optic probes can alter the normal fluid flow within the …

Alterations In Brain Connectivity After Spinal Cord Injury Using Functional Mri, Yamin Ahmed Noor

Theses

Every year, approximately 50 people per million of inhabitants are inflicted by Spinal Cord Injury (SCI). The long-term impairment of the SCI patients has led researchers to investigate different rehabilitation and treatment efforts that require careful observations to be made on reliable markers. Presently, a number of neuropsychological assessments are used for SCI rehabilitation and research purposes. However, there is a need for the discovery of sensitive biomarkers that can be used to characterize SCI. Altered functional connectivity in the brain has been observed in a number of neurological patient populations. Hence, it was hypothesized that such alterations in brain …

Magnetic Targeted Drug Delivery System In Gene Therapy, Weilong Lu

Theses

Drug delivery system is a method to transport the drug of the required amount accurately to the targeted diseased part. Recently, the concept of Magnetic Targeted Drug Delivery System (MTDDS), based upon magnetic particles under the action of an external magnetic field, exhibits considerable potential for a wide range of medical applications. Gene therapy is the insertion of genes into an individual's cells and tissues to treat diseases. As the recombinant virus vector has many limits and problems, more studies turn to the nonvirus vectors, which have transfection efficiency and low cytotoxicity. PLLA(poly(L lactic acid)) can be biodegradable and has …

Moxon Based Rfid Tag Reader And Gps Antenna, Haojiong Liu

Theses

Modern communication applications at UHF frequencies require antennas with wide band, high forward gain, low backward radiation, high cross-polarization, small size and low manufacture cost. The Moxon antenna based on a two element Yagi-Uda antenna over the ground reflector is one of the most favorite antennas for HAM operators which can produce outstanding front to back ratio of radiated power, good match over the desired band and relatively low elevation height.

A sequence of topologies has been proposed from a single vertical element to two vertical elements of the Moxon arms, until the lately patented Broadband Circularly Polarized Moxon Based …

High-Performance Matrix Multiplication On Intel And Fgpa Platforms, Gang Li

Theses

Matrix multiplication is at the core of high-performance numerical computation. Software methods of accelerating matrix multiplication fall into two categories. One is based on calculation simplification. The other one is based on increasing the memory access efficiency. Also matrix multiplication can be accelerated using vector processors. In this investigation, various matrix multiplication algorithms and the vector-based hardware acceleration method are analyzed and compared in terms of performance and memory requirements. Results are shown for Intel and Xilinx FPGA platforms. They show that when the CPU is fast, Goto's algorithm runs faster than Strassen's algorithm because the data access speed is …

Magnetic Iron Oxide Nanoparticles: Synthesis, Characteristics, Magnetic Behavior, And Biomedical Applications, Chengyin Fu

Theses

Magnetic iron oxide nanoparticles are attracting increasing attention due to their interesting properties that can be applied in a great number of applications such as catalysis and biomedicine. This thesis focuses on the synthesis, characteristics, and biomedical applications of iron oxide nanoparticles. The two most common iron oxides, including magnetite and maghemite, are discussed in this thesis.

For most of their applications, the magnetic behavior of iron oxide nanoparticles in a fluid is very important, especially, the high gradient magnetic separation of the particles from a nonmagnetic liquid medium, such as blood in the human body. A 2D model, which …

Experimental Evaluation Of Near Infrared Light Penetration Into Neural Tissue, Ujwal Anil Parikh

Theses

Near infrared (NIR) lasers find applications in medicine both for diagnostic and treatment purposes. Penetration depth into the tissue is a critical parameter to be considered in these NIR laser applications. Published data on the optical properties of rodent neural tissue are rare, despite the frequent use of rats as animal models. The aim of this study was to directly measure the light intensity profile inside the rat brain gray matter that is illuminated by an NIR laser beam. The local light intensities were sampled using an optical fiber inserted into the brain. The intensity profile in the axial direction …

Simulation Of Polymer Solar Cell Characteristics By Amps-1d, Lu Zhang

Theses

Simulation of polymer solar cell characteristics is presented in this study. The solar cells are made of materials such as the following: Poly (3-hexylthiophene): [6, 6]-phenyl C61- butyric acid methylester (P3HT: PCBM) and poly[2,1,3-benzothiadiazole-4,7-diyl[4,4- bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2,6-diyl]]: [6, 6]-phenyl C₆₁- butyric acid methylester (PCPDTBT: PCBM) are used as active layer materials. Analysis of Microelectronic and Photonic Structures One Dimension (AMPS-1D) is a computer simulation tool for solar cell device characteristics. The first part of this study focuses on the performance and comparison of current-voltage (I-V) simulations of indium oxide (In₂O₃) and tin oxide (SnO₂) …

Fmri Assessment Of Ischemic Stroke In Humans, Rui Yuan

Theses

Cerebral ischemia, or brain ischemia is a kind of stroke where the blood flow is insufficient to the metabolic demand of brain. The lack of oxygen supply will directly lead to the death of brain tissue. There are two major injury regions: the infarct and penumbra. Mostly, since the infarct regions became dead tissues rapidly after stroke, there is a tiny possibility to rescue them in time. But penumbra parts are different. Tissues there will be viable for hours after ischemia. Hence, both theoretically and practically, it is possible to salvage those cells in the penumbra region. Diffusion weighted image …

Three-Dimensional Magnetic Field Sensor In Ibm 0.18Μm Cmos Technology, Gang Wang

Theses

This work presents a compact three-dimensional Magnetic Field Sensor (MFS) designed in standard Complementary Metal-Oxide-Semiconductor (CMOS) technology. A circular Vertical Hall Device (VHD) for horizontal magnetic field detection and a split- drain Horizontal Hall Device (HHD) for the vertical magnetic field detection are integrated to implement the three-dimensional M FS. This merged design has the advantage of smaller area and lower power consumption. The sensitivity of the vertical hall device (ring-shaped magneto-resistor) and the horizontal hall device (Split-Drain Magnetic Field-Effect Transistor (SD-MAGFET)) is estimated as 0.11V/T and 2.88V/T respectively. The vertical direction of the magnetic field detection demonstrates a higher …

Cerebral Spasticity Modeled As Disorded Equilibrium Point Control, Darnell Simon

Dissertations

Spasticity is a highly complex phenomenon, which has not been defined in precise and quantifiable terms. Although the muscle stretch reflex is thought to play an important role in spasticity generation, the pathophysiologic basis of spasticity is not completely understood. A valid measure of spasticity is one that is chosen within the context of a theory describing the physiological mechanisms underlying the control of posture and movement in healthy individuals and possible impairments of these mechanisms leading to motor disorders. This research’s goal was to determine the role of stretch reflex threshold in the regulation of impaired motor control through …

Source Localization Via Time Difference Of Arrival, Ciprian Romeo Comsa

Dissertations

Accurate localization of a signal source, based on the signals collected by a number of receiving sensors deployed in the source surrounding area is a problem of interest in various fields. This dissertation aims at exploring different techniques to improve the localization accuracy of non-cooperative sources, i.e., sources for which the specific transmitted symbols and the time of the transmitted signal are unknown to the receiving sensors. With the localization of non-cooperative sources, time difference of arrival (TDOA) of the signals received at pairs of sensors is typically employed.

A two-stage localization method in multipath environments is proposed. During the …

Target Localization In Passive And Active Systems : Performance Bonds, Vlad Mihai Chiriac

Dissertations

The main goal of this dissertation is to improve the understanding and to develop ways to predict the performance of localization techniques as a function of signal-to-noise ratio (SNR) and of system parameters. To this end, lower bounds on the maximum likelihood estimator (MLE) performance are studied. The Cramer-Rao lower bound (CRLB) for coherent passive localization of a near-field source is derived. It is shown through the Cramer-Rao bound that, the coherent localization systems can provide high accuracies in localization, to the order of carrier frequency of the observed signal. High accuracies come to a price of having a highly …

High Rate Space Time Code With Linear Decoding Complexity For Multiple Transmitting Antennas, Amir Laufer

Dissertations

The multipath nature of the wireless channel, results in a superposition of the signals of each path at the receiver. This can lead to either constructive or destructive interference. Strong destructive interference is frequently referred to as deep fade and may result in temporary failure of communication due to the severe drop in the channel's signal-to-noise ratio (SNR). To avoid this situation, signal diversity might be introduced. When having more than one antenna at the transmitter and / or receiver, forming a Multiple-Input Multiple-Output (MIMO) channel, spatial diversity can be employed to overcome the fading problem. Space time block codes …

Single And Multiphase Mixing In Partially Filled Stirred Vessels, Shilan Motamedvaziri

Dissertations

In many industrial applications, mixing vessels have a liquid height-to-tank diameter ratio, H/T, equal to, or larger than 1. However, there are many instances where this ratio is lower than 1, as in all those cases in which the vessel is either emptied or filled. Even when H/T<1, sufficient agitation must still be provided in order to attain the desired process objectives. When the impeller submergence is reduced as a result of lowering the liquid level, the fluid dynamics of even a single-phase stirred liquid can become quite complex, with different regimes possibly existing depending on the geometric characteristics of the system (such as impeller clearance, liquid height, or liquid submergence above the impeller). The objectives of this work were to study in detail the hydrodynamic changes that occur when H/T is decreased, and to determine the minimum liquid levels and the critical impeller submergence for different impeller off-bottom distances, impeller diameters and agitation speeds where adequate mixing process can still be achieved, both in a single liquid phase and in solid-liquid suspensions.

Flat-bottomed, baffled vessels (5L, 12L, 20L and 170L) equipped with a single disk turbine (DT) of four different sizes placed at five different impeller off-bottom clearances were used here to study the system's hydrodynamics and related mixing phenomena. A number of experimental tools were used to analyze the systems under investigation, including: …

Influence Of Defects And Impurities On Solar Cell Performance, Vinay Budhraja

Dissertations

Multicrystalline silicon (mc-Si) solar cells exhibit high impurity content and higher density of crystal defects such as grain boundaries, dislocations, stacking faults and impurity precipitates. Even though the effect of dislocations on mc-Si solar cell performance has been studied, a severe lack of understanding of the quantitative effects of dislocations on cell parameters still exists. Some correlation has been reported under the assumption of a uniform distribution of dislocation density and a negligible effect of front and back surface recombination velocity. This assumption can cause a significant error as the current mc-Si technology provides good surface passivation by SiN:H and …

Wireless Sensor Network For Health Monitoring, Jin Soo Choi

Dissertations

Wireless Sensor Network (WSN) is becoming a significant enabling technology for a wide variety of applications. Recent advances in WSN have facilitated the realization of pervasive health monitoring for both homecare and hospital environments. Current technological advances in sensors, power-efficient integrated circuits, and wireless communication have allowed the development of miniature, lightweight, low-cost, and smart physiological sensor nodes. These nodes are capable of sensing, processing, and communicating one or more vital signs. Furthermore, they can be used in wireless personal area networks (WPANs) or wireless body sensor networks (WBSNs) for health monitoring. Many studies were performed and/or are under way …

Analysis Of A Composite Dielectric-Ferrite Loaded Resonator Using The Transmission Line Model With Application To A Tunable Dual Mode Bandpass Filter, Charlotte Blair

Dissertations

A magnetically tuned filter is presented in this dissertation. Filter tuning of a dielectric ceramic resonator is accomplished using by using two oppositely biased ferrites. Specifically, a change in the applied magnetic field is used to alter the permeability of the ferrite so as to achieve maximum tuning range. Through electromagnetic (EM) simulations and laboratory experiments, tuning of the filter passband by 20 MHz is demonstrated.

This investigation focuses on the design of a bandpass resonator using a combination of dielectric-ferrite material layers. An initial simplification of the geometry of the structure is used as the basis for a program …