Engineering Commons^™

The Fate Of Hazardous Polluting Substances In An Aqueous Environment, Robert Paul Casani

Theses

The fate of Hazardous Polluting. Substances (HPS) in an aqueous environment has been investigated using ultraviolet light. Chlorobenzene, o-cresol and nitrobenzene were used as model HPS for this study. The kinetics were followed and good first order plots were obtained for all compounds. The temperature of the reaction was shown to effect the rate. Solid insoluble and soluble non-volatile products were formed in the photolytic reaction of the three model systems.

The Preparation Of Cis- And Trans-1,2-Dimethoxyethylene. The Study Of The Cis-Trans-Rearrangement And Evaluation Of Equilibrium Constants, James T. Waldron

Dissertations

Equilibrium constants for the mercuric acetate-catalyzed reaction, cis-CH₃ OCH=CHOCH₃ D trans-CH₃ OCH=CHOCH₃, have been determined in the liquid and vapor phase over the temperature range 30° - 175°C by gas chromatography analysis. A novel synthesis of the cis- and trans-isomers of 1,2-dimethoxyethylene is discussed. From a screening of 29 catalysts, mercuric acetate, mercuric benzoate, and mercuric salicylate were found to be favorable isomerization catalysts. For the liquid phase reaction,

ln K = -779.8/T + 0.6748

with ΔH° = +1.549 ± 0.019 Kcal/mole
and ΔS° = +1.34 ± 0.05 e.u./mole

Similarly, for the vapor phase reaction, …

The Aging Of Sbr Vulcanizates, Arthur Robert Leckart

Theses

A literature survey was conducted on SBR aging, Being vulnerable to attack by the forces of nature (such as ozone, oxygen, heat and light), SBR vulcanizates requires the addition of chemicals to retard aging. Phenylamines were found to be the best type of antiaging additives, The effectiveness of other antiaging additives were examined. Although the mechanisms of aging are not perfectly understood; sane theories and aging reactions are discussed.

Structure And Magnetic Properties Of Rare Earth Garnets, Milan R. Kokta

Dissertations

This study deals with preparation and magnetic properties of garnet compounds containing rare earth ions and scandium ions on two crystallographic sites: the dodecahedral and the octahedral. A number of compounds of the types {R_3-yr_y}[r_x Ga_2-x](Ga₃) O_12' {R₃}[Sc₂](Fe_z Ga_3-x) O_12' {R_3-y Sc_y}[Sc₂] (Fe₃) O_12' and {R_3-y r_y)[r₂ (Fe_z Ga_3-z) O_12' where R stands for large rare earth ions such as Nd³⁺ and Pr³⁺, …

Electromagnetic Wave Propagation In Nonuniform Waveguides With Perfect Conducting Walls, Irwin Share

Dissertations

The analysis of nonuniform waveguides is formulated in terms of non-orthogonal generalized coordinates by utilizing the Hertz vector potentials and the Riemann metric tensor.

When the Hertz potential is expressible as a function of the propagation coordinate times a function of the transverse coordinates, then the nonuniform waveguide may be represented by transverse equations and a set of uncoupled nonuniform transmission lines. This decomposition facilitates studying propagation along the propagation coordinate. Sufficient conditions to achieve this decomposition are investigated. It is demonstrated that these constraints may provide guidelines for selecting a useful coordinate system to describe the nonuniform waveguide. In …

An Investigation Of The Neuromuscular Command In The Control Of Respiration, Nirmal Kumar Mishra

Dissertations

The purpose of the investigation is to study the signals involved in the respiratory system and to obtain a model for the dynamics including the activity of the phrenic nerve as the input and the transpulmonary pressure, air flow and the volume as the response.

Experiments were done on anasthetized dogs under natural breathing, with steady state response to various levels of CO2 in the inspired air, and under electrophrenic stimulation. Bipolar electrodes were used at the phrenic nerve, in the cervical region, either for recording the phrenic neurogram or for supramaximal unilateral (or bilateral) stimulation using pulse frequency modulated …

Methods For Acoustic Holography And Acoustic Measurements, Wolfgang Fischer

Dissertations

In this dissertation, a novel "four-step acoustical holographic imaging system" is described and several means for its implementation are analyzed both theoretically and experimentally. This system is compared with other methods of acoustical holography, (ie. permitting to obtain a visible, 3-D image of an object insonified with supersonic waves) and some of its advantages are indicated.

The use of optical holographic techniques to convert an arbitrary acoustic image to a visible image is investigated and a new method - the "holographic sound image converter" - is introduced and analyzed. This converter consists of the "holographic interferometer" and an appropriate "coupler". …

Computer Simulation Of A Linde "Double Column", John A. Bazan

Theses

The purpose of this thesis is to develop a Fortran Computer Program to simulate the operation of a Linde "Double Column" for the separation of air into oxygen and nitrogen. The model outputs the number of contact stages required, the reflux ratio, the heat loads (condenser and reboiler, and the five profiles of temperature, pressure, vapor flow rate, liquid flow rate, and light component composition. From this data, the proposed design can be evaluated, and the effect of varying operating conditions explored.

A Solid State Kinetic Study Of Potassium Permanganate In Alkali Halide Disks, Joseph Paul Cusumano

Theses

The stoichiometry and the kinetics of the reactions of KMnO₄ in KCl and KIO₄ in KCl were studied. The kinetics of the reactions were studied at three different temperatures to obtain the thermodynamic parameters. In addition, these reactions were studied in KBr and RbI matrices. The data was obtained using infrared spectrophotometer measurements.

The reactions all appeared to be first order with respect to the permanganate ion. The stoichiometric studies indicate that the Mn₄^- is converted to Mn⁺⁺ and the Mn⁺⁺ ion apparently catalyzes the reduction of KI₄. The results indicate the …

Analysis Of Decomposition Gases And Leach Water From Controlled Sanitary Landfill, Robert Gargano

Theses

A sanitary landfill was simulated by placing "refuse" between two layers of soil in 6" by 24" cylinders. Canine nutriment was used to simulate the refuse. Once the refuse began to decompose, the decomposition gases were collected in a gas cell and analyzed in an Infrared Spectrophotometer. When gas samples were not taken, the decomposition gases were vented through a water trap (to prevent air from backing up into the system) into the atmosphere. Distilled water was added and withdrawn at two week intervals to leach out the pollutants.

From the Infrared analysis, the decomposition gases were determined to be …

Separations Via Semicontinuous Parametric Pumping, Edward H. Reiss

Theses

A semicontinuous parametric pump with batch operation during one half-cycle and continuous operation in the other half-cycle was experimentally investigated in the model system, toluene-n-heptane on silica gel adsorbent. Comparison was made with analytical results obtained by the equilibrium theory. It was shown that when the penetration distance for the cold cycle was less than or equal to that of the hot cycle and the height of the column, the rate of production of pure solvent in the semicontinuous pump may become quite large relative to that in the continuous pump.

Predictions Of Catalyst Utilization With Continuous Replacement In Multistage Continuous Reactors From Batch Reactor Data, Norman M. Feinberg

Theses

This thesis presents a new equation for predicting catalyst utilization with continuous replacement in multistage continuous reactors from batch reactor data.

An equation is derived from experimental data for a. no-replacement system which predicts catalyst activity as a function of time. The assumption of constant inventory, constant replacement rate and perfect mixing permit the calculation of catalyst age distribution. By combining age distribution with a measure of catalyst productivity, as determined from activity as a function of time, an equation for catalyst utilization was derived. The case used to prepare this equation was where the activity decline curve appears as …

Computerized Computation Of Counter-Current Extraction Problems For Ternary Liquid Systems, Albert Warren Patterson

Theses

A Fortran computer program has been developed that will calculate the number of theoretical equilibrium stages required for a countercurrent liquid-liquid extraction design problem. It also furnishes a complete stagewise material balance. Further utility can be found by using it for optimization studies. The program can be utilized for three-component systems that form one pair of partially miscible liquids, the most frequently occuring situation. The program was written for the General Electric Mark I Time-Sharing System.

The program has a practical advantage in that isothermal liquid equilibria data are used directly for calculation purposes. No use is made of theoretically …

Manpower And Productivity In The Construction Industry, John A. Purciello

Theses

The relationship between manpower and productivity is an important factor in the area of increasing construction costs. Manpower supply is affected by worker mobility, influx of minority workers, work accidents, and training and apprenticeship programs.

A survey was conducted in the state of New Jersey to determine if a manpower shortage existed. The survey was conducted by submitting questionnaires to contractors, unions, owners, and architect-engineers.

The results of the survey indicated that a manpower shortage does exist, and that the shortage has influ enced construction costs, Furthermore, as a result of the increasing costs, indications of a decline in new …

Vibration And Buckling Of Elastic Plates With Shear And Rotatory Inertia, Bomi Batiwalla

Dissertations

The effects of shear, rotatory inertia and inplane forces on the transverse vibration of thin plates are studied. In addition, the effect of shear on the buckling of thin plates is examined. A general differential equation of motion is derived for an isotropic thin plate subjected to normal and inplane forces with the consideration of shear and rotatory inertia. The method of internal constraints and Hamilton's principle are utilized.

The resulting fourth order differential equation is solved for simply supported plates of various shapes by employing a finite difference technique. The shapes examined are a square, a circle, a circular …

Effectiveness Of Training Programs For Graduate Engineers, V.C. Rajashekar

Theses

This thesis represents an investigation of effectiveness as a result of engineering training. The basic elements of effectiveness and its learning process are explained and said that the effectiveness could be learnt and improved.

The term training, is basically the process of education and training. But training cannot be performed as an individual, but is performed as a group. Therefore training a group with having so many individuals needs careful consideration in designing a training program.

In order to get the broadest possible picture of current thinking and current activity in the area of company training programs for graduate engineers, …

The Effect Of Ultrasonic Vibration On Mass Transfer In A Packed Column, Joseph Walter Stanecki

Theses

The object of this research was to investigate the possibility of using externally supplied ultrasonic vibration to surface of a packed distillation column operating at total reflux to improve the separation. The apparatus used for this experimentation consisted of a 2 inch ID Pyrex column having three pairs of ultrasonic transducers epoxied equidistance along the external surface of the column. Each pair of transducers was driven separately by a 50 watt amplifier! power supply and a sine/square wave generator.

There were three types of binary mixtures covered during experimentation: minimum boiling azeotropes, maximum boiling azeotropes and full range mixtures. In …

The Creep And Stress Relaxation Behavior Of Silver Bearing Copper Wire, Alfred Fox

Theses

Creep and stress-relaxation experiments were performed on silverless and silver bearing copper in the temperature range 73F to 250F. The creep experiments were conducted at constant load and temperature, the stress-relaxation tests at constant total strain and temperature for a total time period of 1000 hours. The effect of silver addition of up to 0.2 percent w/o (60oz per ton) on the creep and stress-relaxation behavior of spectrographically pure copper (99.999+ Cu) as well as on that of tough pitch and oxygen free coppers of lesser purity was studied. Spectrographically pure copper was found to be much more susceptible to …

The Reaction Of P-Nitrophenyl Acetate With Lysine Hydrochloride And Poly-1-Lysine Hydrobromide, Emmanuel Plange Matteer

Theses

The reactions of p-nitrophenylacetate with L-lysine hydrochloride and poly-L-lysine hydrobromide as a function of pH were investigated.

The results indicate that both compounds react with the substrate in the pH range 7.0-10.0 with an apparent optimum pH in the region near 9.65.

Poly-L-lysine reacts more rapidly over the entire pH range investigated than does L-lysine.

A Study Of The Optimization Of Ethylene Production In A Tubular Reactor, Richard W. J. Robertson

Theses

The pyrolysis of ethane is a complex reaction involving six individual reactions in a reactant mixture of thirteen components. It is further complicated by the deposition of carbon along the reactor walls. The carbon buildup eventually necessitates reactor shutdown, During the intermediate stages the reactor experiences a gradual increase in inlet pressure which affects the reaction conditions, Optimum temperature profiles exist because the yield goes up with increasing temperature, but, consequently, the reactor must be shut down and cleaned out with increasing frequency. The combined effect causes the yearly production of ethylene to go through an optimum.

To find this …

A Study Of The Effect Of A Dielectric Field On The Solvolysis Rate Of Tert-Butyl Bromide In A Recycle Reactor, Rolf L. Ball

Theses

Previous experiments at Newark College of Engineering have shown that a dielectric field can effect the rate of a chemical reaction. A theory was developed in this thesis to postulate how a dielectric field can increase the rate of a first order reaction whose rate determining step is an ionization. An experimental procedure was developed to measure the reaction rate constant of a tertiary alkyl halide with a solvent to test this theory. The solvolysis of tortbutyl bromide in aqueous ethanol (80%), aqueous dioxane (75%) and aqueous acetone (75%) solvent systems were the reactions selected for study. A total of …

The Development Of Langmuir's Adsorption Isotherms For Glucose And Fructose And The Separation Via Continuous Parametric Pumping, Jafir Abbas Jaferi

Theses

The adsorption equilibria and adsorption rates of fructose and of glucose on aqueous suspensions of fullers earth were determined at various temperatures. The Langmuir adsorption equations were fitted to the equilibrium data and the Langmuir constants were determined so that isotherms could be developed for any pair of parametric pumping operating temperatures.

This glucose+fructose+water system was then subjected to continuous thermal parametric pumping for the separation of glucose and fructose. The operating conditions required for the separation were determined from the experimental adsorption rates and equilibrium isotherms. Samples taken from the continuous top and bottom streams were analyzed by polarimetry …

Equilibrium Calculations Via The Benedict-Webb-Rubin Equation Of State, Steven L. Sincoff

Theses

The performance of various vapor-liquid equilibrium calculations requires phase equilibrium data. One of the most versatile sources of this data is an equation of state, re-lating the pressure, temperature, and phase compositions it a single expression. The equation under study herewith is the eight constant Benedict-Webb-Rubin Equation of State.

This paper provides a computer program which evaluates the following types of phase equilibria: bubble-points, dew-points, and two phase flash calculations. Also included in this paper is the theoretical backround of the Benedict-Webb-Rubin Equation of State, calculational techniques, and the data used in the program.

Studies Of Rare Earth Compounds, Rostam Mondegarian

Theses

The work reported herein has consisted of miscellaneous studies of rare earth compounds.

1. The Pr—As system was studied with a view to obtaining a ferromagnetic composition.
2. Attempts were made to prepare ternary compounds by solid state reaction of PrAs, GdAs or YbAs with MnAs, CrAs or FeAs, and PrP, GdP, or YbP with MnP, CrP or FeP.
3. Attempts were made to prepare quaternary compounds by solid state reaction of YbAs, YbP and GdAs with CdI2 in various molar ratios. In many cases new compouns appeared to be formed but because of complexity of the X—ray patterns it was not possible …

Flow Behavior Of Molten Polymer Blends, Kryspin Pawel Maciejewski

Theses

An experimental study of molten polymer blends was made using the Instron Capillary Rheometer. The materials investigated were two phase blends of non-crystalline polymers (poIymethylmethacrystate-low Mw-polyvinylacetate, polyvinylacetate-polystyrene, polymethylmethacrylate-low Mw-polystyrene, polymethylmethacrylate-high Mw-polystyrene), crystalline polymers (polyethylene-polypropylene) and combinations of non-crystalline-crystalline polymers (polyethylene-polystyrene). Two methods of sample preparation were used, blending of a polymer pair in a molten state by the use of Brabender blender, and a simple manual blending of pellets in desired proportion. The Brabender blended polymer pairs show lower viscosities, this is interpreted molecularly as a result of a reduction of the amount of chain entanglement on shearing of the …

Continuous Interfacial Polycondensation Of Nylon 6-6, Chandrakant A. Patel

Theses

Nylon 6-6 has been prepared by continuous interfacial polycondensation from hexamethylene diamine and adipyl chloride in a stirred system. The effect of monomer concentration and stirring on the intrinsic viscosity of polyamide 6-6 solution in formic acid (90%) was determined.

As stirring rate and monomer ratio increased, the intrinsic viscosity and polymer yield went through a maximum. Diffusion coefficient (D_AB) for hexamethylene diamine was calculated and from that J_D and mass transfer coefficient /D_AB were calculated. A relation between Reynolds number and J_D factor was established by correlation curve.

The Effect Of Variable Properties On The Laminar Flow Of Gases, Norman Shilling

Dissertations

The problem of heat transfer in laminar flow of a gas through a constant diameter cylindrical tube is treated. The gas is cooled by the tube walls held at constant temperature. Two tube inlet conditions are considered: (1) fully developed velocity and uniform temperature profiles (Graetz boundary condition) and (2) uniform velocity and temperature (UTV) profiles. Results of the theoretical and experimental phases of the work are presented.

The theoretical solution is based on the compressible boundary layer equations with varying transport and thermodynamic property terms retained. For the Graetz condition, an existing finite difference solution scheme is modified for …

Dielectric Properties Of Atactic And Isotactic Polystyrene, Thaddeus F. Kroplinski

Theses

The purpose of this investigation was to determine the dielectric constant and dissipation factor of atactic and isotactic polystyrene at 25°C and at frequencies of 0.1, 1.0, 10, and 100 kilocycles per second. In addition, the effects of molecular weight and crystallinity on the dielectric properties of polystyrene mos also studied.

Polystyrene slabs of uniform thickness mere prepared by molding the polymer under heat and pressure. The isotactic polystyrene slabs Imre annealed at 175°g for various lengths of time to achieve varying degrees of crystallinity.

The molded polystyrene slabs were fitted with circular aluminum foil electrodes to form a three …

The Oxidation Of Carbon Monoxide By Magnesium Aluminate, James A. Whelan

Dissertations

In this research the catalytic oxidation of carbon monoxide was investigated on magnesium aluminate catalysts, MgO:xAl₂O₃, with five different compositions, x, ranging from 1.0 to 3.0. The reaction was run at temperatures ranging from 500 to 600 °C. with radioactive carbon monoxide as the tracer. An experimental technique has been devised for the analysis of unreacted CO which takes into account a correction for the solubility of CO in CO₂.

Four mathematical models were postulated to explain the mechanism of reaction. The models were examined against experimental data by means of non-linear least squares …

A Simple Method For Liquid Enthalpy Departure Calculations, Ching-Lin Chien

Theses

The reduced equation of state for gases and liquids developed by Benson and Golding in 1951 is modified and used to calculate liquid enthalpy departures for saturated pure substances and mixtures. The temperature-independent coefficients in the modified equation are determined from critical properties and experimental liquid enthalpies at the boiling point and at the critical point. The results of the proposed method are compared with those predicted with the modified Redlich-Kwong equation of state by Joffe and Zudkevitch.