Engineering Commons^™

Gas Hydrate Inhibition And Its Unique Thermodynamic Behaviors Within The Porous Clay Sediment, Yun-Ho Ahn, Huen Lee

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

The fundamental understanding of gas and water system in geological sediments is necessary for greenhouse gas sequestration and future energy production. Depending on the surrounding environments that water, gas, and other substrate material coexist, several unique phases such as supercritical, dissolved gas, gas oversatu-rated, and hydrate could be formed. Especially, gas hydrates which are composed of water frameworks and several gaseous guest molecules have drawn people’s attention for its application such as methane production with carbon dioxide sequestration. For these reasons, to produce methane from natural gas hydrate and store carbon dioxide by replacement reaction, the thermodynamic behaviors of gas …

Fractional Transport Models For Shale Gas In Tight Porous Media, Nadeem A. Malik, Iftikhar Ali

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

Modelling the flow of fluid through tight porous media, such as unconventional hydrocarbon reservoirs, is very challenging and it is a growing sector and must be addressed. Shale gas is found in such tight porous rocks which are characterized by nano-scale size porous networks with ultra-low permeability [1,2].

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Impact Of Engineered Nanoparticles In Initiating Or Modulating Pathology-Related Inflammation, Diana Boraschi, Yang Li, Emanuele Scala, Victor F. Puntes, Paola Italiani

Nanotechnology in Medicine: From Molecules to Humans

The possibility that nanomaterials could perturb the normal course of an inflammatory response is a key issue when assessing nano-immunosafety. The alteration of the normal progress of an inflammatory response may have pathological consequences, since inflammation is a major defensive mechanism and its efficiency maintains the body’s health. We can thus consider as pathology-related inflammation those inflammatory reactions that, instead of eliminating foreign agents, lack down-regulation and cause tissue damage. To assess the ability of nanoparticles to initiate and modulate inflammatory reactions, an in vitro model was used that recapitulates all the stages of infection-induced inflammation, from initiation to resolution, …

An Experimental Investigation On Effect Of Pores Per Inch In Compact Heat Exchanger With Aluminum Foam, Oronzio Manca, Bernardo Buonomo, Luca Cirillo, Sergio Nardini

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

Metal foams are a new class of materials with low densities and novel thermal and mechanical properties. Aluminum foams combine low weight with good rigidity, strength, damping of vibrations and noise, shock resistance and low thermal conductivity [1]. An experimental investigation on a single row of aluminum tubes, covered with layers of aluminum foams, was carried out by T’joen et al. [2]. A range of foam layer thickness, Reynolds number tube spacing and different type of foam were considered and compared with compact helically finned tube heat exchangers. An experimental investigation was carried out by Sertkaya et al. [3] to …

Exact Solution For Viscous Fluid Flow In Porous Medium With Magnetic Field, Dinesh P. A., Jayalakshmamma D.V., Chandrashekhar D.V.

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

The steady flow of viscous, incompressible, conducting fluid flow past a spherical solid core embedded in another spherical porous medium is considered. The exact solution is obtained for the flow in the presence of transverse magnetic field. The considered fluid flow is governed by Brinkman equation in porous region and by Stokes equation in the fluid region with additional Lorentz’s force due to applied magnetic field. The flows in the two regions are matched across the interface by assuming continuity of velocity and stress across the interface. Further, no-slip condition at the solid surface and uniform velocity far from the …

Stokes Flow Past A Two-Layers Heterogeneous Porous Sphere With The Effect Of Stress Jump Condition: An Exact Solution, Kun Yang, Xin Yan, Kambiz Vafai

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

The flow past a porous sphere has extensive industrial and engineering applications, such as the flow of pulverized coals particulate during combustion, sedimentation of fine particulate suspensions, flow in porous beds etc. Several studies have been done about the flow past a porous body under different models and boundary conditions. The models used in their investigations can be divided into the following categories: (i) Adopting Darcy equation to describe the flow in porous media and Stokes equations to describe the flow in the free fluid with the continuity conditions of velocity and pressure at the interface or the Beavers-Joseph (BJ) …

Experimental Research On Internal Convection Heat Transfer Of Supercritical Pressure Co2 In Porous Media, Le Zhang, Pei-Xue Jiang, Rui-Na Xu, Zhen-Chuan Wang

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

The flow and heat transfer of fluids at supercritical pressure in porous media has attracted much attention due to its extensive applications, such as supercritical water-cooled nuclear reactor, CO₂ gas cooled reactor, transpiration cooling and supercritical CO₂ solar thermal power generation system. There are mainly two theories to describe convection heat transfer in porous media, i.e., the local thermal equilibrium model (LTE) and the local thermal non-equilibrium model (LTNE). Compared with LTE model, the LTNE model is a more detailed model that uses two energy equations to describe heat transport in the solid and fluid. The internal heat …

The Influence Of Cold Rolling On The Pore Morphology And Flow Resistivity Of Porous Aluminum, Nicolas Lippitz, Samir Maudarbocus, Joachim Rösler

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

Materials with an open porosity are used in many applications, such as filters, acoustic absorbers or heat exchangers. For these applications the pore size and shape as well as the depending flow resistivity are important parameters and need to be adjusted for the specific case. The material parameters are usually defined by the manufacturing process and are therefore signature for different types of porous materials. In this study the porosity, pore shape and the depending flow resistivity of a given material are adjusted using a cold rolling process. The material chosen is a porous aluminum with a porosity of about …

Flow Of Shale Gas In Tight Rocks Using A Non-Linear Transport Model With Pressure Dependent Model Parameters, Nadeem A. Malik, Iftikhar Ali, Bilal Chanane, Ryad A. Ghanam

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

A new source of energy has recently been discovered from unconventional hydrocarbon reservoirs, such as shale gas deposits. Shale gas is found in tight porous rocks which are characterised by nano-scale size porous networks with ultra-low permeability [1,2]. The modelling of transport through such tight porous media is very challenging because it is a relatively new discipline and not much is known but transport processes in them, and little data is available; but it is a growing sector and must be addressed. Here, we apply a recently developed non-linear gas transport model [3], to reservoir simulations of single-phase gas through …

Nanotechnology Applications In Medical Diagnosis, Imaging, And Therapy, Mansoor M. Amiji

Nanotechnology in Medicine: From Molecules to Humans

Tremendous advances in molecular and personalized medicine also present challenges for translation of innovative experimental approaches into clinically relevant strategies. To overcome some of these challenges, nanotechnology offers interesting solutions for disease prevention, diagnosis, and treatment. For many systemic diseases, overcoming biological barriers and target specific delivery are the key challenges. Additionally, newer generation of molecular therapies, such as gene therapy, oligonucleotides, and RNA interference (RNAi) require robust and highly specific intracellular delivery strategies for effective and clinically meaningful therapeutic outcomes.

In this presentation, I will cover several of our approaches for development of multifunctional engineered nano-systems for targeted therapies …

Nanotechnologies For The Treatment Of Severe Diseases, Patrick Couvreur

Nanotechnology in Medicine: From Molecules to Humans

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Development Of Biocompatible Small-Molecule Spacers As Metal Oxide Nanoparticles' Stabilizing Agents, Galina Goloverda, Huy Do, Ezinne U. Agwaramgbo, Anastasia Labeaud, Rajesh Komati, Vladimir Kolesnichenko

Nanotechnology in Medicine: From Molecules to Humans

Development and study of the magnetic nanoparticles for biological and clinical applications remains one of the challenging research areas in chemistry and materials science. The performance of these particles as, for example, drug delivery, MRI, hyperthermia or cell tracking agents, depends on their magnetic susceptibility. Their ability to form stable aqueous colloids, the mobility, and diffusion properties in biological media, rely on organic coating, which is usually composed of hydrophilic biocompatible polymers such as dextrans or poly(ethylene glycol)s. Some areas of biomedical imaging, labeling and delivery application can benefit from magnetic nanoparticles with higher mobility and penetration, stronger interaction with …

Conference Program, Kambiz Vafai, Adrian Bejan, Oronzio Manca, Akira Nakayama

Sixth International Conference on Porous Media and Its Applications in Science, Engineering and Industry

No abstract provided.

Penetration Of Plga Nanoparticles Into The Intracranial Rat C6 Glioma: Influence Of Surfactant Coating, Yulia M Alinovskaya, Nadezhda Osipova, Olga Maksimenko, Svetlana Gelperina, Pavel Melnikov, Vladimir Baklaushev

Nanotechnology in Medicine: From Molecules to Humans

As shown by our previous studies, the PLGA nanoparticles (NP) coated with poloxamer 188 (P188) enable brain delivery of doxorubicin and its high anti-tumour effect against the intracranial glioblastoma in rats [1]. The objective of the present study was to evaluate the uptake of the P188-coated PLGA NP in the intracranial C6 glioma in rats. For visualization using scanning laser confocal microscopy (SLCM) and an intravital fluorescence imaging system Ivis^ÒSpectrum CT (Perkin-Elmer), the NP were labeled with DiI (DiI-PLGA NP). The DiI-PLGA NP were administered i.v. into rats with intracranial C6 glioma on day 15 after tumour implantation. …

Conference Program, Lola Eniola-Adefeso, Paolo Decuzzi

Nanotechnology in Medicine: From Molecules to Humans

No abstract provided.

Iron Oxide Nanoparticles With A Variable Size And An Iron Oxidation State For Imaging Applications, Vladimir Kolesnichenko, Galina Goloverda, Pavel Kucheryavy, Leonard Spinu

Nanotechnology in Medicine: From Molecules to Humans

Magnetite nanoparticles in the size range of 3.2-7.5 nm were synthesized with high yields under variable reaction conditions using high temperature hydrolysis of the precursor iron(II) and iron(III) chelated alkoxide complexes in surfactant-free diethylene glycol solutions. The average sizes of the particles were adjusted by changing the reaction temperature and time, and by using sequential growth technique. Reaction products formed as shelf-stable colloids. In order to obtain γ‑iron(III) oxide particles in the same range of sizes, diethylene glycol colloids of magnetite were oxygenated at room temperature. As-obtained colloids were characterized by DLS; powdery products obtained by coagulating them with oleic …

Wet Air Oxidation For Industrial Wastewater And Sludge Treatment: First Results Of A New Research Program In Quebec, Jean-François Vermette, Sophie Girard, Patrick Desjardins

5th International Congress on Green Process Engineering (GPE 2016)

Introduction

Sub-critical water technologies, in particular wet air oxidation (WAO), have been developing across Europe in recent decades. This process is now used at the industrial scale for the effective treatment of wet organic material, mainly sludge from wastewater treatment plants (WWTP), and is done with energy self-sufficiency [1, 2]. In WAO, hot pressurised water (200-350 ˚C, 30-200 bars) is enriched with oxygen or air to initiate exothermic oxidation of organic material, mostly into CO₂ and H₂O. Since the operating temperature is much lower than typical incineration, no gaseous emissions of NO_X, dioxins or furans …

How To Reduce The Energy Costs Of Food And Dairy Products To Spray Drying?, Pierre Schuck, Anne Dolivet, Serge Méjean, Romain Jeantet

5th International Congress on Green Process Engineering (GPE 2016)

The most frequently used technique for dehydration of dairy products is spray drying. This is an effective method to preserve biological products as it does not involve prolong exposure of materials to severe heat treatment. Due to the variety and complexity of the concentrates to be dried, a more rigorous understanding of spray-drying based on physico-chemical and thermodynamic properties is necessary. At the same time, the current state of the art did not allow easy determination of the parameters of spray-drying of dairy products prior to drying, except from performing several complex and expensive experiments with pilot-scale spray-dryer. Nevertheless, recent …

Oxygen/Steam Charcoal Gasification In A Fluidized Alumina Bed, Rui Moreira, Rui Vaz, António Portugal, Noemí Gil-Lalaguna, Fernando Bimbela, José Luis Sánchez

5th International Congress on Green Process Engineering (GPE 2016)

Mixtures of oxygen and steam were used as gasifying agents to produce a gas stream with high hydrogen content. The effects of the equivalence ratio (ER) and steam to carbon ratio (S/C) on gasification performance were studied at 900 ºC. The highest hydrogen yield (0.412 Nm³/kg charcoal) and apparent energy efficiency (33.43%) were achieved using a mixture that had a S/C ratio of 0.625 and an ER equal to 0.3 (pure oxygen). The results showed that the carbon conversion improved when the ER and the S/C ratio were augmented, and that the production of tars increased when the …

Bio-Oils From Microwave Assisted Pyrolysis Of Cellulose Using A Multi Mode Batch Reactor, Marco Frediani, Piero Frediani, Luca Rosi, Mattia Bartoli

5th International Congress on Green Process Engineering (GPE 2016)

The end of fossil fuels era is becoming day by day [1] however the request of raw materials and fuels from industry is growing every year [2]. As a consequence research for renewable resource to supply oil is became very attractive [3]. Biomasses are very promising sources to satisfy the growing request of energy and raw materials [4-6] and in the same time to reduce the environmental impact due to their production [7]. Cellulose is particular interesting among different available biomasses because it is not interfere with the availability of …

Development Of A Mobile 100 Kg/H Plant For Pyrolysis Using A Mechanically Fluidized Reactor, Dhiraj Kankariya, Stefano Tacchino, Dominic Pjontek, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Current pyrolysis processes perform the thermal decomposition of biomass into a liquid bio-oil, bio-char and non-condensable gases, at around 500 °C, without the addition of oxygen gas. The bio-oil is a complex mixture of many components that is used either as a substitute for fuel oil or for applications such as liquid smoke and bio-phenol resins that do not require pure chemicals.

The large-scale mechanical fluidized reactor (MFR) is a new technology for the pyrolysis of biomass developed by ICFAR, which does not require a sand bed and, thus, provides an undiluted solid char residue, which is essential to realize …

Technological Breakthrough And Innovation In The Production Of Whey Powders, With 30-40% Reduction In Energy Costs, Pierre Schuck, Anne Dolivet, Serge Méjean, Gaelle Tanguy, Daniel Garreau, Corrado Vezzani, Romain Jeantet

5th International Congress on Green Process Engineering (GPE 2016)

There are two essential stages in the elimination of water for the production of whey and permeate powders: concentration by vacuum evaporation followed by spray drying. These two operations alone represent 25% of the energy consumed by the French dairy industry, the major part of which is due to the drying stage. Indeed, 96.7% of the whey water is removed during the vacuum evaporation/concentration stage, whereas drying, which removes only 3.3% of the water, requires 31% of the total energy used over the entire process.

One possible way to reduce energy consumption would be for the product to enter the …

Integrating Batch Pyrolysis And Fractional Condensation (2d Mfr) To Get High-Value Products From Biomass, Mohammad Hossain, Chiara Barbiero, Ian Scott, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Agricultural crop residues are a source of inexpensive biomass to convert into bioproducts. The recovery of valuable chemicals from plant waste would partly solve the disposal issue and offer a more environmentally friendly alternative to synthetic chemical production. One approach to separate and concentrate valuable chemicals from biomass is pyrolysis using a batch reactor process. A mechanically fluidized reactor (MFR) was developed to pyrolyze biomass from ambient to temperatures near 600 °C, forming gases that are then condensed in an ice-chilled condenser to form a bio-oil. The bio-oil produced by the MFR can be separated within temperature ranges, termed one-dimensional …

Microwave Assisted Pyrolysis Of Kraft Lignin At Reduce Pressure In A Multimode Oven, Mattia Bartoli, Marco Frediani, Luca Rosi, Piero Frediani

5th International Congress on Green Process Engineering (GPE 2016)

Lignin is the third-most abundant natural polymer after cellulose and hemicellulose[1] and the only renewable source of aromatics in nature. Moreover lignin is the most relevant waste from industry of paper and bioethanol[2]. Nowadays the common way to dispose it is combustion but the possibility to recovery aromatic moiety from thermochemical conversion of lignin has been received a grown attention. In this field the most promising approach is pyrolysis[3] and particularly interesting is use of microwave (MW) like heating source[4]. Microwave assisted pyrolysis (MAP) was successfully applied in the treatment of plastic …

Production Of Glycerol 1,2-Carbonate From Glycerol With Aid Of Ionic Liquid As Catalyst, Nor Asrina Sairi, Zati Ismah, Yatimah Alias, Rozita Yusoff, Mohamed Kheireddine Taieb Aroua,

5th International Congress on Green Process Engineering (GPE 2016)

The surplus formation of glycerol (glycerine or 1,2,3-propanetriol) during biodiesel production has led to a major concern. Glycerol price has dropped and it exerts a great impact on the refined glycerol market. This has triggered an extensive research focus to find an innovative way to revalorize glycerol and transform to value-added chemicals. Yet, it is undeniably a necessary move towards achieving greener and sustainable processes. For instance, glycerol 1,2-carbonate (4-hydroxymethyl-1, 3-dioxolan-2-one) is currently one of the most celebrated glycerol derivatives that captured arising scientific and industrial attentions due to its extensive potential applicability. This cyclic ester of glycerol with carbonic …

Development And Industrial Application Of Novel Non-Cr Passivity For Electrolytic Manganese, Siming Chen, Dongping Duan, E Zhou, Ting Li

5th International Congress on Green Process Engineering (GPE 2016)

No abstract provided.

Sox Trapping Performances Of Cuo Based Silica Mesoporous Adsorbents For Desulfurization Of Industrial Flue Gas Stream, Sophie Dorge, Marc Berger, Habiba Nouali, Laure Michelin, Ludovic Josien, Matthieu Vierling, Michel Molière, Emmanuel Fiani, David Habermacher, Joël Patarin, Jean-François Brilhac, Pierrick Gaudin

5th International Congress on Green Process Engineering (GPE 2016)

In the present work, CuO/SBA-15 SOx regenerable adsorbents were elaborated. Synthesis conditions were controlled in order to obtain highly dispersed Cu²⁺ species assumed to be Cu-O-Si species. Materials were evaluated as SOx adsorbents through multicycle adsorption/regeneration experiments. Their performances decrease along cycles due to copper species sintering and there is an optimal copper loading for a maximal SOx adsorption efficiency.

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Catalytic Property Of Olivine For Bio-Oil Gasification, Mohammad Latifi, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Introduction

Biomass is an attractive renewable source of fuel and energy. Thermochemical processes can convert biomass to a liquid bio-oil or to a syngas. The advantage of using bio-oil as an intermediate is that, in contrast with both raw biomass and gas, it can easily be produced in small distributed units, stored and transported. Not only can platform chemicals and clean fuels be produced from syngas, but hydrogen is itself an alternative fuel. A high hydrogen production is usually desired: for example, methanol production requires a syngas with a molar H₂/CO ratio of 2. Therefore, maximum hydrogen production …

Influence Of Pre-Treatment On Grass Pyrolysis For High Value Products, Chiara Barbiero, Charles Greenhalf, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Pyrolysis of biomass is a process which yields high quality, clean, and green products like bio-oil and bio-char. Bio-oil has a wide range of applications and also includes liquid fuels and raw chemical products. Therefore, it will be attractive to tailor the bio-oil properties to improve the yields of specific compounds that are economically interesting. In particular, pyrolytic sugar can be used for fermentation while phenolic compounds have an array of industrial applications such as adhesives; moreover, they can substitute petroleum-based phenols. However, it is difficult to achieve high yields of specific chemicals in the bio-oil without adequate biomass pre-treatments. …

Pyrolysis Of Residues From Well-Established Biochemical Processes For Biomass Conversion Into Liquid Fuel, Devon Barry, Cedric Briens, Franco Berruti

5th International Congress on Green Process Engineering (GPE 2016)

This project focuses on the pyrolysis of residues from well-established biochemical processes into liquid fuel. The residues examined come from two major conversion processes; wastewater treatment facilities, and biogas digesters. These processes produce low value, unconverted residues that are refractory to further biochemical conversion. Pyrolysis is an aggressive thermochemical conversion process that is ideally suited to such residues.

Currently, these residues are viewed as a low-value or waste products that must be disposed of. The environmentally friendly disposal of wastewater sludge is a common problem for many municipalities, where the sludge is often incinerated or disposed of in landfills. Anaerobic …