Engineering Commons^™

High Temperature Oxidation Of Nickel, Virgil R. Friebel

Masters Theses

"Using a sensitive volumetric technique, a study was made of the kinetics of oxidation of nickel at 1200° C. and 1300° C. Three purities of nickel were used for the investigation which was limited to the initial three hours of reaction.

The rate of oxidation of nickel followed the parabolic rate law after an initial period of deviation which lasted up to 40 minutes. No direct correlation was found between the oxide thickness and the end of the period of deviation from the parabolic rate law.

The purity of the nickel was found to have a marked effect on the …

The Constitution Of Magnesium-Rich Magnesium-Zirconium Alloys, Kenneth Allen Fowler

Masters Theses

"The magnesium-zirconium system has been studied to 0.8 per cent zirconium which represents the limit of solubility of zirconium in liquid magnesium at 950°C. Alloys have been prepared by two methods of alloy additions, and the results compared. Microstructural studies have been made of the alloys in the cast, extruded, and heat-treated conditions. The limit of solid solubility has been determined on the basis of resistivity and temperature coefficient of resistivity measurements, as well as by metallographic examination, with good agreement. A secondary structure resulting from precipitation of a second phase within cored regions of the alloy has been studied …

The Effect Of The Rare Earth Elements On The Hot Workability Of Ingot Iron, L. A. Neumeier

Masters Theses

"The effect of mischmetal and rare earth oxides on the hot workability of ingot iron in the hot-short region was studied. Thirteen heats were melted in air in a basic-lined induction furnace. All heats were thoroughly deoxidized with aluminum prior to the rare earth additions. Mischmetal was added in amounts of 0.1, 0.3 and 0.5 per cent. Rare earth oxides were added in amounts of 0.1 and 0.2 per cent. Temperatures were maintained at approximately 2900°F and holding intervals between mischmetal additions and pouring at two minutes. Bars were hot rolled and swaged for hot twisting in the hot-short region. …

Determination Of Vapor-Liquid Equilibrium Data By Continuous Distillation, David William Bunch

Masters Theses

"The procuring of experimental vapor-liquid equilibrium data has been a problem of considerable importance to chemical engineers for a number of years. Modern distillation theory and practice have made accurate vapor-liquid equilibrium data practically a necessity.

Using conventional methods for determining vapor-liquid equilibrium data, an experimenter can obtain only a single vapor-liquid equilibrium composition per trial. Ramalho working with Tiller has developed a new method which makes possible the determination of all values of the vapor and liquid concentrations in a single experiment.

The work done by Ramalho indicated that the necessity for very precise temperature measurements presented a serious …

Segregation Method As Possible Process To Beneficiate Oxidized Lead Ores, Jose Molfino Tomasio

Masters Theses

"In this investigation it has been demonstrated that the Segregation Process has merit for treating oxidized lead ores.

The process comprises heating the crushed ore with salt and coal at about 750° C. to produce metallic lead attached to the carbon particles, which then is recovered by conventional flotation methods.

The quantities of sodium chloride and coal required for the best segregation of lead obtained in this work was 1.0 percent of coal and 1.0 percent of salt by weight.

Good segregation was obtained by using salt and coal as fine as 65 or 48 mesh. Segregation varied with the …

An Experimental Investigation Of Receiver System Sensitivity, James Henry Johnson

Masters Theses

"A method of determining the minimum detectable power density incident at the receiving antenna of a UHF receiver is proposed. The minimum detectable power density is the power density required to produce a signal-to-noise ratio of unity in the output of the receiver. The proposed method includes the receiving antenna impedance, the necessary connecting transmission lines, and the receiver impedance.

It is shown that an error in the antenna directivity will produce a significant error in the overall sensitivity of a receiving system. Since the directivity is the most difficult system variable to determine experimentally, it is probably the limiting …

Physical Property Tests Of Rock, Centrifugal Tests And The Design Of Underground Mine Openings, Samuel Shu Mou Chan

Masters Theses

"Proper design of stable underground mine openings is important to the mining industry today. Various methods have been utilized by investigators to approach this goal.

A review of previous investigations of each of the phases of underground mine opening stress analysis is presented.

An approximate method of designing underground mine structures based on estimation of the initial stress field, rock physical property tests, and model tests, together with preliminary field data, is presented, and a specific example given"--Forward, page i.

Construction Of A Pulsed Perforated-Plate Extraction Unit, Clarence James Vetter Jr.

Masters Theses

"Liquid-liquid extraction is an important operation in the production and reprocessing of nuclear fuels. In the purification of uranium by liquid-liquid extraction, uranyl nitrate is separated from impurities by extraction into an organic solvent, followed by re-extraction into an aqueous phase. Further processing of the aqueous uranyl nitrate solution is tailored to yield uranium metal or any desired uranium compound.

In order that students in nuclear and chemical engineering may have an understanding of the practical as well as theoretical aspects of liquid-liquid extraction, a model of a uranium purification plant was designed and built in the Unit Operations Laboratory …

Design Of An Intermediate Frequency Amplifier And Variable Frequency Oscillator, Robert Charles Mcintyre

Masters Theses

"Since the advent of the transistor in 1948 many technological barriers have been overcome in the field of semiconductors. Unfortunately, however, there is a considerable period of time between the discovery of a scientific phenomena and its widespread use and understanding by practicing engineers. The motivating factor which prompted this investigation was primarily the lack of knowledge which the author possessed concerning transistors. The selection of the amplifier and oscillator design confined the study primarily to the transistor. Considerable time, however, had to be spent in the study of basic transistor theory before any phase of the design could be …

Effect Of Boundry Layer Control, Through Surface Holes, On The Film Coefficient Of Convective Heat Transfer, Jainti Prasad

Masters Theses

"This thesis has as its objective, the effect of some boundary layer control on the convective heat transfer film coefficient, metal to liquid. The boundary layer control was produced by drilling 1/16 inch diameter holes on the tube surface.

In this modern world of atoms and the current development of large quantities of its energy at low cost, the subject of designing heat exchange devices of higher efficiency is receiving considerable attention. In a reactor, or any type of heat exchange device, there are limits for the temperatures of a heat exchange surface because of corrosion, strength of metals etc. …

A Thermodynamic Study Of The System Pbo-Pbs, John P. Hager

Masters Theses

"An experimental investigation was conducted in order to determine the thermodynamic and kinetic behavior of the system PbO-PbS.

The thermodynamic behavior of the system PbO-PbS was studied by measuring the P_SO₂ in argon-SO₂ mixtures equilibrated with various PbO-PbS mixtures in a recirculating-type equilibrium apparatus, and analyzing the condensed phases by means of X-ray diffraction.

The effect of temperature and PbO/PbS ratio on the rate of SO₂ evolution was investigated in order to determine the reaction mechanisms involved in the approach to equilibrium.

A sodium hydroxide, hydrogen peroxide titration technique was employed in the analysis of SO_{2 …}

Construction Of Distillation Solvent Recovery System, Joseph Richard Aid Iii

Masters Theses

"When a nuclear fuel is “burnt” in an atomic reactor it is not possible to completely utilize the fissionable material present due to build-up of fission products (which act as poisons), depletion of the fissionable material, and radiation damage to the fuel elements. Chemical processing of nuclear fuels is concerned with the recovery of the fissionable materials, specifically uranium, plutonium, and thorium, from the spent fuel elements. There are two general methods of reprocessing nuclear fuels: aqueous and non-aqueous. The aqueous methods include solvent extraction, ion exchange, and precipitation. Comprising the non-aqueous methods are fluoride volatility and pyrometallurgy. At the …

Effect Of A Lime-Cement Additive On The Physical Properties Of A Podzolic Clay Soil, Raymond H. Frankenberg

Masters Theses

"The object of this research is to obtain data and information from laboratory tests concerning the effect of combined lime and cement additives on the physical properties of illitic clay soils"--Introduction, page 3.

Automatic Tuning Of A.C. Compensating Networks, Giles C. Sinkewiz

Masters Theses

"The purpose of this thesis is to illustrate the practicality of using an auxiliary servo system to shift parameters in damping networks of the main servo system.

Since amplification is most easily achieved with A.C. amplifiers and since A.C. servo motors are superior in operation to D.C. servo motors, because no brushes or commutators are needed, the A.C. servo system is widely used. However, one major problem is confronted when designing an A.C. servo system. This is the problem of designing damping circuits and compensating circuits which are insensitive to carrier frequency fluctuations. Notch filters provide the desired transfer functions, …

The Evaluation Of The Influence Of Large Aggregate On The Permeability Of Single-Grained Soils, Edward Clayton Grubbs

Masters Theses

"Each year many earth fill structures are designed and built with the primary purpose of impounding water. As these structures are only relatively impervious, engineers must consider the control of seepage in design. In order to predict seepage, the engineer must have knowledge of the potential flow or water through the earthen structure. He is, therefore, faced with the problem of determining a coefficient of permeability for use in design calculations.

The coefficient of permeability is easily enough determined for fine-grained materials. However, in construction it is very rare to find proper fill material which does not include quite a …

Properties Of Air-Entrained Concrete At Early Ages, Ugur Ozoguz

Masters Theses

"This study, entitled "Properties of Air-Entrained Concrete at Early Ages" concerns a group of tests designed to provide quantitative information regarding the effect of entrained air on the strength and durability of concrete before it reaches its 28 day strength.

Experiences in the field and laboratories have demonstrated that the addition of a moderate amount of air to any concrete mix will bring a marked increase in resistance to the disintegrating effects of freezing and thawing.

There have been extensive studies made on the subject of durability of air entrained concrete. Most of these studies were based on the effect …

Preparation Of Casting Slips Containing Ferrous Powders And Alginates, Robert Eugene Newcomer

Masters Theses

"The preparation of casting slips containing ferrous powders dispersed by alginates was studied and an attempt was made to determine the mechanism by which suspension was attained. The colloidal aspects of preparing ceramic casting slips are discussed and an analogy is drawn to preparation of metallic slips suspended by alginates.

Sodium and ammonium alginates were used to suspend stainless steel and iron powders. The effect of NaOH, HC1, and various phosphate additions on the properties of slips and algin solutions was considered.

It was found that colloidal concepts can not be applied to explain observed behavior in the system studied. …

A Study Of The Feasibility Of Stabilizing Putman Soil With Hydrated Lime And Portland Cement In Combination, John Henry Kern

Masters Theses

"This paper is the report of a feasibility study of the combined use of hydrated lime and portland cement to stabilize the troublesome Putnam soil of northern Missouri. In its natural state, this soil is highly plastic, possesses great shrinkage and swell characteristics when the moisture content is changed and is classified as an A-7-5 soil by the A. A. S. H. O. Standards for the Classification of Highway Subgrade Materials.

During the course of this investigation, the following tests were performed: (1) Moisture-Density Relationships for soil with admixtures; (2) Triaxial Compression Test; (3) Unconfined Compression Tests; (4) Freeze-Thaw Tests; …

The Equalization And Optimization Of A Third-Order Type-1 Position Control System, Viswanatha Seshadri

Masters Theses

"While the practice of feedback control dates back to the day when the earliest living organisms began to react to their environmental conditions and the changes therein, it has been only during the past two decades that this technique came to be subjected to a scientific examination. Yet, an astoundingly rapid advancement has resulted in the field of servo-mechanisms, contributing substantially to the development of modern civilized existence and activity to its present standards, and promising to contribute, to an ever-increasing extent, to the accelerated progress of scientific and industrial enterprise in this space age.

The principal concerns of the …

A Study Of The Reaction Of Hydrated Lime With Pure Clay (Kaolin) In Clay Stabilization, Chiyyarath Velayudhan Girijavallabhan

Masters Theses

"The work presented is the investigation of the reaction of pure Kaolinite clay with hydrated lime in clay stabilization. Pure Kaolin clay, ranging from one micron to five microns in size, was mixed with calcium hydroxide in the form of a paste. These mixtures were permitted to react for varying periods of time. An attempt was made to separate the lime from clay lime mixture by density separation using a mixed solution of carbon tetrachloride and tetrabromoethane. Since the above method failed because of the formation of a yellow gelatinous suspension, the lime was removed by washing the clay lime …

The Lattice Constants Of Chromium And Vanadium Containing Dissolved Gases, Paluri Bhimeswara Rao

Masters Theses

"The physical properties of chromium and vanadium are so important that a study of their lattice constants and their coefficients of thermal expansion, requires special consideration.

A number of research workers, over a period of about forty years, have done considerable work in determining the above constants. Some of the previous investigators found an anomaly in the thermal expansion, electrical resistivity and other physical properties of chromium. They observed that at about 37°C, chromium showed a discontinuity in the above physical properties. However it is not known what causes the discontinuity in the expansivity curve of chromium. The discontinuity may …

A Method For The Prediction Of Detection Ranges For Pulsed Doppler Radar, Phillip Orlan Brown

Masters Theses

"Modern radar systems must provide greater detection ranges both against high and low altitude targets because of the significant advances in weapon speed and range. Extended range indicates that the power transmitted by the radar must be increased. It follows, that ground return becomes a problem even at high altitudes.

There are at present three basic types of radars which are (1) pulsed, (2) continuous wave, and (3) pulsed doppler radar. The conventional pulsed radar now closely approaches the theoretical optimum performance; however, it does not have the inherent ability to distinguish between ground return and moving targets. The continuous …

A Dissolution Rate Study In Hydrofluoric Acid Of Titanium And The Alpha Solid Solutions Of Oxygen In Titanium, John L. Ratliff

Masters Theses

"The dissolution mechanism of titanium in hydrofluoric acid was studied by collecting the hydrogen evolved during the dissolution reaction. A concentration range of 0.05 N to 0.50 N and a temperature range of 15°C to 45°C were employed for the determination. Values of the reaction order and energy of activation were determined for both pure titanium and the alpha solid solutions of oxygen in titanium and found to be the same within experimental limits. This indicated that the reaction giving rise to hydrogen evolution on the surfaces of both pure titanium and the TiO_x alloys was the same. The …

Designing Fine Bituminous Mixtures For High Skid Resistance, Jack E. Stephens, William Harner Goetz

JTRP Technical Reports

No abstract provided.

Locating Slippery Highway Sites By Accident Analysis : Technical Paper, Vergil G. Stover, Harold L. Michael

JTRP Technical Reports

No abstract provided.

Strength And Volume Change Characteristics Of A Bituminous Mixture Under Triaxial Testing, James Hamilton Schaub

JTRP Technical Reports

No abstract provided.

Evaluation Of Major Urban Intersections, William Walter Schenler

JTRP Technical Reports

No abstract provided.

Photogrammetric Measurement Of Final Pay Quantities In Highway Construction : Technical Paper, Russel R. Johnson, Robert Douglas Miles

JTRP Technical Reports

No abstract provided.

Design Of A Pressure Sensitive Cell And Model Studies Of Pressures In The Subgrade Of A Flexible Pavement System : Technical Paper, Thurmul Francis Mcmahon, Eldon J. Yoder

JTRP Technical Reports

No abstract provided.

Design And Construction Of Hydraulic Flume And Backwater Effects Of Semi-Circular Constrictions In A Smooth Rectangular Channel : Progress Report No. 2, H. J. Owen

JTRP Technical Reports

No abstract provided.