Engineering Commons^™

Adaptive Tracking Controller For Real-Time Hybrid Simulation, Alejandro Palacio-Betancur

Theses and Dissertations--Civil Engineering

Real-time hybrid simulation (RTHS) is a versatile and cost-effective testing method for studying the performance of structures subjected to dynamic loading. RTHS decomposes a structure into partitioned physical and numerical sub-structures that are coupled together through actuation systems. The sub-structuring approach is particularly attractive for studying large-scale problems since it allows for setting up large-scale structures with thousands of degrees of freedom in numerical simulations while specific components can be studied experimentally.The actuator dynamics generate an inevitable time delay in the overall system that affects the accuracy and stability of the simulation. Therefore, developing robust tracking control methodologies are necessary …

Variance Decomposition Of Forecasted Water Budget And Sediment Processes Under Changing Climate In Fluvial And Fluviokarst Systems, Nabil Al Aamery

Theses and Dissertations--Civil Engineering

Variance decomposition is the partitioning of different factors affecting the variance structure of a response variable. The present research focuses on future streamflow and sediment transport processes projections as the response variables. The authors propose using numerous climate factors and hydrological modeling factors that can cause any response variable to vary from historic to future conditions in any given watershed system. The climate modeling factors include global climate model, downscaling method, emission scenario, project phase, bias correction. The hydrological modeling factor includes hydrological model parametrization, and meteorological variable inclusion in the analysis. This research uses a wide spectrum of data, …

Fabrication, Characterization And Applications Of Highly Conductive Wet-Spun Pedot:Pss Fibers, Ruben Sarabia Riquelme

Theses and Dissertations--Chemical and Materials Engineering

Smart electronic textiles cross conventional uses to include functionalities such as light emission, health monitoring, climate control, sensing, storage and conversion of energy, etc. New fibers and yarns that are electrically conductive and mechanically robust are needed as fundamental building blocks for these next generation textiles.

Conjugated polymers are promising candidates in the field of electronic textiles because they are made of earth-abundant, inexpensive elements, have good mechanical properties and flexibility, and can be processed using low-cost large-scale solution processing methods. Currently, the main method to fabricate electrically conductive fibers or yarns from conjugated polymers is the deposition of the …

Nanostructured Metal Thin Films As Components Of Composite Membranes For Separations And Catalysis, Michael J. Detisch

Theses and Dissertations--Chemical and Materials Engineering

Novel metallic thin film composite membranes are synthesized and evaluated in this work for improved separations and catalysis capabilities. Advances in technology that allow for improved membrane performance in solvent separations are desirable for low molecular weight organic separation applications such as those in pharmaceutical industries. Additionally, the introduction of catalytic materials into membrane systems allow for optimization of complex processes in a single step. By adding a nanostructured metallic thin film to its surface, a polymer membrane may be modified to exhibit these improved properties. Using magnetron sputtering, thin metal films may be deposited on commercially available membranes to …

Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde

Theses and Dissertations--Chemical and Materials Engineering

Titania (titanium dioxide) is a metal oxide which has recently been investigated as a photocatalyst, most commonly for use in hydrolysis, which absorbs mostly in the UV range. However, the range of absorption can be shifted to fall within the visible light range either by doping or by functionalizing the surface with atomic or molecular adsorbates. Over the course of this research, a series of Density Functional Theory (DFT) calculations are performed to ascertain the effects of these different methods on the photocatalytic performance of titania. While the effects of nitrogen doping and oxygen vacancies are well known, more recent …

A Thermodynamic And Feasibility Study Of Green Solvents For The Fabrication Of Water Treatment Membranes, Xiaobo Dong

Theses and Dissertations--Chemical and Materials Engineering

Nonsolvent induced phase separation (NIPS) has been widely used to fabricate polymeric membranes. In NIPS, a polymer is dissolved in a solvent to form a dope solution, which is then cast on a substrate and immersed in a nonsolvent bath, where phase inversion occurs. Petroleum-derived organic solvents, such as N-Methyl-2-Pyrrolidone (NMP) and Dimethylacetamide (DMAc), have been traditionally used to fabricate polymeric membranes via NIPS. However, these solvents may have negative impacts on environmental and human health; therefore, using greener and less toxic solvents, preferably derived from biomass, is of great interest to make membrane fabrication sustainable. In this dissertation, two …

Understanding And Mitigating The Electrochemical-Mechanical Degradation Of High Capacity Battery Electrodes, Dingying Dang

Theses and Dissertations--Chemical and Materials Engineering

Lithium-ion batteries (LIBs) with high energy density and cycling stability play a critical role in developing electric vehicle (EV) and grid energy storage techniques. The electrochemical performance of LIBs can be improved by using high capacity positive (e.g., LiNi_1/3Mn_1/3Co_1/3O₂, i.e., NMC111) and negative (e.g., silicon) electrodes; both, however, experience severe electrochemical-mechanical degradation caused by the lithiation/delithiation induced volume changes. Understanding mechanical degradation mechanisms and their relationships with the capacity fading of electrodes is important for improving the cycling stability of electrodes as well as optimizing the design of electrodes with high capacity …

Knee Joint Loading Following Anterior Cruciate Ligament Reconstruction: Link To Patient Reported Outcomes And A Novel Method To Monitor With Wearable Sensors, Alex Spencer

Theses and Dissertations--Kinesiology and Health Promotion

Recovery from anterior cruciate ligament reconstruction (ACLR) commonly results in undesirable physical and patient-reported outcomes (PROs). Identification of modifiable factors such as knee contact force (KCF) early in rehabilitation that can improve these outcomes is important due to the rapid decrease in function, quality of life, and joint health in this population. Additionally, if noninvasive measurement of KCFs outside of a traditional laboratory were possible, clinicians could optimize patient treatment with personalized care. Therefore, there are two primary aims to this thesis: 1) quantify the link between KCF and PROs which measure pain, ability to perform activities of daily living, …

Investigation Of Host Nanotube Parameters For Enhancing The Performance Of Nanostructured Cds-Cdte Solar Cells, Deepak Kumar

Theses and Dissertations--Electrical and Computer Engineering

Numerical simulations are performed to investigate the effects of host nanotube parameters (pore diameter and pitch for different CdS coverages) and CdTe doping density on device performance in nanowire CdS/ CdTe solar cells using SCAPS-1D. This research finds the optimum values for these parameters in order to achieve the highest efficiency. Experimentally the effect of anodization voltage and fluoride ion concentration on the pore diameter and the pitch are studied for the Titania nanotubes host. It is observed that in the range of 0.3 mL to 2 mL of ammonium fluoride content, pore diameter and the pitch of the Titania …

Mispronunciation Detection And Diagnosis In Mandarin Accented English Speech, Subash Khanal

Theses and Dissertations--Electrical and Computer Engineering

This work presents the development, implementation, and evaluation of a Mispronunciation Detection and Diagnosis (MDD) system, with application to pronunciation evaluation of Mandarin-accented English speech. A comprehensive detection and diagnosis of errors in the Electromagnetic Articulography corpus of Mandarin-Accented English (EMA-MAE) was performed by using the expert phonetic transcripts and an Automatic Speech Recognition (ASR) system. Articulatory features derived from the parallel kinematic data available in the EMA-MAE corpus were used to identify the most significant articulatory error patterns seen in L2 speakers during common mispronunciations. Using both acoustic and articulatory information, an ASR based Mispronunciation Detection and Diagnosis (MDD) …

Articulatory-Wavenet: Deep Autoregressive Model For Acoustic-To-Articulatory Inversion, Narjes Alsadat Agha Seyed Mirza Bozorg

Theses and Dissertations--Electrical and Computer Engineering

Acoustic-to-Articulatory Inversion, the estimation of articulatory kinematics from speech, is an important problem which has received significant attention in recent years. Estimated articulatory movements from such models can be used for many applications, including speech synthesis, automatic speech recognition, and facial kinematics for talking-head animation devices. Knowledge about the position of the articulators can also be extremely useful in speech therapy systems and Computer-Aided Language Learning (CALL) and Computer-Aided Pronunciation Training (CAPT) systems for second language learners. Acoustic-to-Articulatory Inversion is a challenging problem due to the complexity of articulation patterns and significant inter-speaker differences. This is even more challenging when …

Integration Of Large Pv Power Plants And Batteries In The Electric Power System, Oluwaseun M. Akeyo

Theses and Dissertations--Electrical and Computer Engineering

The declining cost of renewables, the need for cleaner sources of energy, and environmental protection policies have led to the growing penetration of inverter-based resources such as solar photovoltaics (PV), wind, and battery energy storage systems (BESS) into the electric power system. The intermittent nature of these resources poses multiple challenges to the power grid and substantial changes in the conventional generation and electrical power delivery practices will be required to accommodate the large penetration of these renewable power plants. The impact of large solar PV penetration on both generation and transmission systems, and the use of BESS to mitigate …

A Comparative Analysis Of Reinforcement Learning Applied To Task-Space Reaching With A Robotic Manipulator With And Without Gravity Compensation, Jonathan Fugal

Theses and Dissertations--Electrical and Computer Engineering

Advances in computing power in recent years have facilitated developments in autonomous robotic systems. These robotic systems can be used in prosthetic limbs, wearhouse packaging and sorting, assembly line production, as well as many other applications. Designing these autonomous systems typically requires robotic system and world models (for classical control based strategies) or time consuming and computationally expensive training (for learning based strategies). Often these requirements are difficult to fulfill. There are ways to combine classical control and learning based strategies that can mitigate both requirements. One of these ways is to use a gravity compensated torque control with reinforcement …

Tolerance Intervals For Time Series Models And Specifying Trimming/Winsorizing Cutoffs, Kedai Cheng

Theses and Dissertations--Statistics

Confidence intervals are used to capture a parameter of interest, usually a mean or a quantile, at a specified confidence level. Prediction intervals are another practical interval that aim at making sound predictions of future values with some confidence. Although these are useful inference tools, neither of them gives people a plausible range of the sampled population. Tolerance intervals are such an inference tool that captures a specified proportion of the sampled population at a predetermined confidence level. In this dissertation, tolerance intervals for an autoregressive process with order p are constructed. In addition, a method of utilizing tolerance interval …

Resource Efficient Design Of Quantum Circuits For Cryptanalysis And Scientific Computing Applications, Edgard Munoz-Coreas

Theses and Dissertations--Electrical and Computer Engineering

Quantum computers offer the potential to extend our abilities to tackle computational problems in fields such as number theory, encryption, search and scientific computation. Up to a superpolynomial speedup has been reported for quantum algorithms in these areas. Motivated by the promise of faster computations, the development of quantum machines has caught the attention of both academics and industry researchers. Quantum machines are now at sizes where implementations of quantum algorithms or their components are now becoming possible. In order to implement quantum algorithms on quantum machines, resource efficient circuits and functional blocks must be designed. In this work, we …

End-To-End Prediction Of Weld Penetration In Real Time Based On Deep Learning, Wenhua Jiao

Theses and Dissertations--Electrical and Computer Engineering

Welding is an important joining technique that has been automated/robotized. In automated/robotic welding applications, however, the parameters are preset and are not adaptively adjusted to overcome unpredicted disturbances, which cause these applications to not be able to meet the standards from welding/manufacturing industry in terms of quality, efficiency, and individuality. Combining information sensing and processing with traditional welding techniques is a significant step toward revolutionizing the welding industry. In practical welding, the weld penetration as measured by the back-side bead width is a critical factor when determining the integrity of the weld produced. However, the back-side bead width is difficult …

Modeling Thin Fluid Film On A Rotary Bell, Mark Doerre

Theses and Dissertations--Mechanical Engineering

A component of the mission in the Institute of Research for Technology Development at the University of Kentucky is advancing research and development and bringing it to the factory floor for continuous improvement. This dissertation delves into the art and science of rotational fluid mechanics in the context of rotary bell atomizers. One outcome proves that an approximation for calculating fluid film thicknesses on high-speed spinning surfaces inferred while working in cylindrical and spherical coordinate systems can be applied to an arbitrary bell profile. However, the analytical limits of this approximation were not investigated. In all cases, a restriction exists …

Electrophoresis In Heterogeneous Hydrogels And Applications In Surface Patterning, Ning Ge

Theses and Dissertations--Mechanical Engineering

The creation of chemical micropatterns on surfaces makes it possible to add unique chemical functionality to surfaces, modifying properties such as wettability, or even adding the ability to selectively bind other molecules. The creation of biochemical surface patterning in particular is useful in a variety of fields including tissue engineering and highthroughput drug screening. There are many existing surface patterning techniques which focus on precise control over the patterned geometry, even down to submicron scale features, but they do not allow local control over chemical concentration. So the results are high resolution patterns with binary concentration. There are also existing …

The Influence Of Cryogenic Machining On Surface Integrity And Functional Performance Of Titanium Alloys For Biomedical And Aerospace Applications, Ying Sun

Theses and Dissertations--Mechanical Engineering

The excellent properties of titanium alloys such as high strength, as well as good corrosion and fatigue resistance are desirable for the biomedical and aerospace industry. However, the same properties that make titanium alloys desirable in high-performance applications also make these space-age materials “difficult-to-machine” materials, as the titanium alloys exhibit high cutting temperatures because of their high strength and low thermal conductivity.

Cryogenic machining is a severe plastic deformation (SPD) processes which uses liquid nitrogen as the coolant to take away the heat generated during machining in a relatively short time. Cryogenic machining can significantly reduce the cutting temperatures at …

Filtered-Dynamic-Inversion Control For Unknown Minimum-Phase Systems With Unknown Relative Degree, Sumit Suryakant Kamat

Theses and Dissertations--Mechanical Engineering

We present filtered-dynamic-inversion (FDI) control for unknown linear time-invariant systems that are multi-input multi-output and minimum phase with unknown-but-bounded relative degree. This FDI controller requires limited model information, specifically, knowledge of an upper bound on the relative degree and knowledge of the first nonzero Markov parameter. The FDI controller is a single-parameter high-parameter-stabilizing controller that is robust to uncertainty in the relative degree. We characterize the stability of the closed-loop system. We present numerical examples, where the FDI controller is implemented in feedback with mathematical and physical systems. The numerical examples demonstrate that the FDI controller for unknown relative degree …

Safety Concepts For Every Ride: A Statistical Ensemble Simulation To Mitigate Rotational Falls In Eventing Cross Country, Shannon Wood

Theses and Dissertations--Mechanical Engineering

Rotational falls are the leading cause of death and serious injury in the equestrian sport of eventing. Previous studies to develop safety devices used physical models representing one or at most several physical situations leading to different designs and no common understanding. In this thesis, a statistical ensemble model is developed and applied to generate and evaluate 10,000 different situations that might potentially lead to rotational falls. For accurate statistical representation of the horse and rider inertia distributions, measurements of over 400 training or competing horses and riders were recorded and incorporated. Video was recorded of 218 total competitors approaching …

Development Of Micro-Scale High Aspect Ratio Patterned Features With Electroless Nickel Plating, Lorli Smith

Theses and Dissertations--Mechanical Engineering

This thesis describes a novel method designed to pattern high aspect ratio metallic microscale features using a modified photolithography and electroless nickel plating process. This method utilizes modified photolithography techniques to create a polymer mold that is used to control the location of metal deposition on substrate during electroless nickel plating. In order to generate high aspect ratio mold features, a multiple spin-step process was developed to deposit thick layers of SU-8 photoresist, and inclined lithography was also used to generate tapered sidewalls that could help aid mold removal after plating. Results from electroplating experiments were evaluated using a Zygo …

Bacterial Cell Wall Characterization Via Atomic Force And Confocal Microscopy, Joree Sandin

Theses and Dissertations--Mechanical Engineering

Poor oral hygiene is a severe global health issue, with about 44% of the Earth’s population suffering from untreated tooth decay, accounting for over $100 billion dollars spent on dental services per year in the United States, alone. Manual treatments, such as brushing, flossing, or swishing with antiseptic rinse are the main ways to alleviate harmful bacteria that cause these oral health problems. Streptococcus mutans (S. mutans) is a group of highly antibiotic, Gram-positive bacteria that heavily contribute to oral cavities, plaque build-up, and potential loosening or loss of dental implants if a biofilm develops. Currently, the mechanism …

Synthesis Of Metal Oxide Surface And Interface Arrays By A Combined Solid-Liquid- Vapor/Vapor-Liquid-Solid Approach, Alexandra J. Riddle

Theses and Dissertations--Chemistry

This project was motivated by an in situ heating experiment in the transmission electron microscope (TEM) in which gold (Au) nanoparticles were observed to dissolve tin dioxide (SnO2) nanowires (NWs) under vacuum. The explanation for this observation was that the high-temperature and low-pressure environment of the TEM caused the reverse reaction of the well-known vapor-liquid-solid (VLS) method commonly used to grow NWs. In the VLS process, a metal catalyst absorbs reactant vapor until it becomes supersaturated. The precipitation of the NW occurs at the liquid-solid interface, which ceases when there is no longer reactant vapor, and the diameter of the …

Applications Of Drones In Atmospheric Chemistry, Travis J. Schuyler

Theses and Dissertations--Chemistry

The emission of greenhouse gases (GHGs) has changed the composition of the atmosphere during the Anthropocene. A major technical and scientific challenge is quantifying the resulting fugitive trace gas fluxes under variable meteorological conditions. Accurately documenting the sources and magnitude of GHGs emission is an important undertaking for discriminating contributions of different processes to radiative forcing. Therefore, the adverse environmental and health effects of undetected gas leaks motivates new methods of detecting, characterizing, and quantifying plumes of fugitive trace gases. Currently, there is no mobile platform able to quantify trace gases at altitudes(UASs), or drones, can be deployed on-site in …

Interfaces In Lead-Free Tin Perovskite Photovoltaics: An Investigation Of Energetics, Ion Mobility, Surface Modification, And Performance, Alex Boehm

Theses and Dissertations--Chemistry

Halide perovskites have generated tremendous interest as low-cost semiconductors for optoelectronics, such as photovoltaics, lasers, and light emitting diodes due to their extraordinary optical and transport properties. Perovskite photovoltaics in particular have demonstrated a meteoric rise in power conversion efficiencies and drawn considerable interest as a next-generation solar energy technology. The rapid development has centered around lead-based derivatives, and concerns regarding the toxicity of lead has sparked interest in low toxicity and more environmentally friendly perovskite derivatives. In this regime tin (Sn) is regarded as a prominent alternative owing to the ideal bandgap and reduced toxicity exhibited by Sn-halide perovskites. …