Engineering Commons^™

A Study On Effect Of Manufacturing Parameters On Morphology Of A356 Aluminum Foam, Nikhil Nanabhau Mahajan

All Theses

Metal foams have shown an excellent promise for usage as multifunctional material concerning research & development in the last 20 years. They provide remarkable mechanical as well as physical properties being lightweight. Open-cell metal foams have already been used in sound and noise absorption. Open-cell metal foams are outstanding for use in heat exchangers, filters, and many more applications, while closed-cell foams show excellent characteristics in impact energy absorptions. Closed-cell metal foams have higher energy absorption than their solid parent metal as they convert most of the impact energy into deformation energy. Metal foams have been used as prominent safeguard …

Reactive Thin Film Polymers And Thin Film Composite Membranes For The Rapid Screening Of Uranium Isotopes, Abenazer W. Darge

All Dissertations

Traditional radiochemistry approaches for the detection of trace-level alpha-emitting radioisotopes in water require lengthy offsite sample preparations and do not lend themselves to rapid quantification. Therefore, a novel platform is needed that combines onsite purification, concentration, and isotopic screening with a fieldable detection system. My dissertation research objective was to develop novel reactive thin polymer films and thin film composite membranes for the selective separation of uranium from environmental water followed by direct isotopic analysis by alpha spectroscopy. Chapter 1 reviews progress made on uranium separation from aqueous matrices and discusses methods used for the determination of isotopic composition.

Chapter …

Hydration Of High-Alumina Calcium Aluminate Cements With Carbonate And Sulfate Additives, Jonathan Lapeyre, Sai Akshay Ponduru, Monday Uchenna Okoronkwo, Hongyan Ma, Aditya Kumar

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study investigated the influence of limestone (LS) and calcium sulfate (C$) mineral additives on the hydration kinetics of high-α-Al₂O₃ calcium aluminate cement (CAC) utilizing experimental techniques and thermodynamic simulations. Increasing the replacement level of limestone or calcium sulfate increased the cumulative heat of the hydration reaction. The limestone exhibited limited acceleratory effects to the CAC hydration kinetics due to the coarseness of the powder. The coarse particle size distribution limited any heterogenous nucleation that would have occurred with a finer particle size as well as the intrinsic insolubility kinetically limits the formation of monocarboaluminate phases. Conversely, …

Rheological Behavior Of Dspc-, Dbpc-, And Dppc-Oxygen Microbubbles And Their Effectiveness In Improving Survival In A Rat Model Of Lipopolysaccharide-Induced Acute Respiratory Distress Syndrome, Riaz Ur Rehman Mohammed

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Acute respiratory distress syndrome (ARDS) causes 75,000 deaths in the U.S., annually. It is characterized by hypoxemia and damage to the lung alveoli. ARDS Management strategies involve extracorporeal membrane oxygenation (ECMO) and mechanical ventilation, but none of these methods improve the mortality rates. Oxygen microbubbles (OMBs) consist of a lipid shell with an oxygen core and have potential to augment oxygenation to manage ARDS. Previous studies demonstrated significant improvements in systemic oxygenation and mortality upon administering OMBs.

We replicated an ARDS rat model by intratracheal administration of lipopolysaccharide at a 24 mg/kg dose. After inducing the disease in rats, the …

Isolation And Production Of Tandem Collagen Binding Domain From Clostridial Collagenase Colg And Developments In C1q Reagent Production For Future Molecule Characterization Work, Stephanie Beitle

Chemical Engineering Undergraduate Honors Theses

This thesis covers a two part project: the production methods to create a double collagen binding domain molecule with a growth factor for wound healing applications and the development of a new in-house production method for isolating C1q from bovine blood. The wound healing molecule was created using transformation, sonication, and purification before being tested via electrophoresis SDS page and Western blots to confirm the molecule’s presence. The C1q in-house production method utilizes an ultrafiltration flow cell rather than dialysis at a critical point in the process, allowing for researchers to not only be able to use a single small …

Insect Antennae As Bioinspirational Superstrong Fiber-Based Microfluidics, Griffin J. Donley

All Theses

Nature is frequently turned to for inspiration for the creation of new materials. Insect antennae are hollow, blood-filled fibers with complex shape, and are cantilevered at the head. The antenna is muscle-free, but the insect can controllably flex, twist, and maneuver it laterally. To explain this behavior, a comparative study of structural and tensile properties of the antennae of Periplaneta americana (American cockroach), Manduca sexta (Carolina hawkmoth), and Vanessa cardui (painted lady butterfly) was performed. These antennae demonstrate a range of distinguishable tensile properties, responding either as brittle fibers (Manduca sexta) or strain-adaptive fibers that stiffen when stretched (Vanessa cardui …

Investigating The Effects Of Sic Abrasive Particles On Friction Element Welding, Gaurav Awate

All Theses

The growing demands on reducing the harmful emissions from automobiles have forced automakers to reduce the weight of the vehicle. The increasing demands on improving the fuel economy also has challenged automotive manufacturers to make the vehicle as lightweight as possible. However, the challenge is also to ensure that the vehicle meets safety standards. For the vehicle to meet these standards, it needs to be of adequate strength as well. Automotive manufacturers have adopted a strategy of using multi-material construction to achieve the target. But with multi-material construction comes the requirement of advanced joining techniques that are capable of joining …

Near-Earth Ion Irradiation Effects On Functional Ceramic Materials: A Combined Experimental-Monte Carlo Approach, William J. Sands

All Theses

The near-Earth space radiation environment is a complex system that creates a harmful environment for materials to operate in. Motivated by the search for using optical defects as an indicator of radiation damage, five single-crystal functional ceramic materials were selected to undergo ion irradiation at conditions found in the near-Earth space environment. Due to the complex nature of ion irradiation effects in ceramic materials, a host of calculations and experimental characterization methods were used. Calculations using the 2013 SRIM code were used to evaluate the ion projected range and the type and number of defects (vacancies) created by ion irradiation. …

Preparation, Cure, And Characterization Of Cyanate Ester-Epoxy Blends, Donald A. Klosterman

Chemical and Materials Engineering Faculty Publications

Cyanate ester resins are often blended with lower cost epoxy monomers in order to modify the cost, toughness, and processing characteristics. There are also several choices of catalysts that can be used to improve processing, namely by reducing the cure temperature. This study was undertaken to illustrate how a designed experiment approach can be used to systematically investigate a wide range of material combinations and illuminate the basic cure behavior of some simple cyanate ester – epoxy blend combinations. Two commercial cyanate ester resin products were obtained. Each was blended with a bisphenol F based epoxy resin at two different …

Additive Manufacturing Of Variable Contrast Computed Tomography Anatomical Phantoms Using A Single Feedstock In Fused Filament Fabrication, Cory J. Darling

LSU New Orleans Theses and Dissertations

Anatomical phantoms used in biomedical education and training benefit greatly from Fused filament fabrication’s (FFF) ability to rapidly produce complex and unique models. Current materials and methods used in FFF have limited ability to accurately produce phantoms that can mimic the radiological properties of multiple biological tissues. This research demonstrates that the CT contrast of FFF produced models can be modified by varying the concentration of bismuth oxide in acrylonitrile butadiene styrene (ABS) filaments and a tunable CT contrast that mimics the CT contrast ranging from fatty tissue to cortical bone using a single composite filament without introducing artificial image …

Solid-State Formation Mechanisms Of Core–Shell Microstructures In (Zr,Ta)B2 Ceramics, Anna N. Dorner, Frédéric Monteverde, William Fahrenholtz, Gregory E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

Transition metal diborides with core–shell microstructures have demonstrated excellent mechanical properties at elevated temperatures. Previous studies concluded that core–shell microstructures were formed by liquid-assisted mass transport mechanisms, but in this study, we propose a solid-state formation mechanism for core-shell microstructures in (Zr,Ta)B2 ceramics produced by reaction hot pressing and in ZrB2-TaB2 diffusion couples. Diffusion couple experiments demonstrated that core–shell microstructures developed as a result of Ta diffusion along ZrB2 grain boundaries, which occurred concurrently with lattice diffusion of Ta into ZrB2. These findings suggest that with optimization of batching and processing parameters, core–shell diboride materials may be formed through solid-state …

Preparation Of Concrete Specimen For Internal Sulfate Attack Analysis Using Electron Backscatter Diffraction, R. Sharon Uwanyuze, Lucas Enright, Jiyao Zhang, Stefan Schafföner

Materials Science and Engineering Faculty Research & Creative Works

Concrete cores were obtained from houses in eastern Connecticut, USA, that had varying degrees of crumbling foundations and wall cracking. Electron backscatter diffraction (EBSD) was used simultaneously with energy dispersive X-ray spectroscopy to investigate the degradation of these samples. This combination allowed the precise correlation of elemental composition with mineral crystallography phase mapping. EBSD examination showed the presence of pyrrhotite, pyrite, and marcasite phases in some of the samples, whereas internal sulfate attack (ISA) is triggered by the release of sulfates through the oxidation of such iron sulfides. Secondary expansion products from ISA are associated with foundation cracking, wall bulging, …

Mechanical Properties Of Fusion Welded Ceramics In The Sic-Zrb2 And Sic-Zrb2-Zrc Systems, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Derek S. King

Materials Science and Engineering Faculty Research & Creative Works

Mechanical properties of welded SiC-ZrB2 and SiC-ZrB2-ZrC ceramics were measured up to 1700 °C. Commercial powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics using either tungsten inert gas welding or plasma arc welding. Toughness of the parent materials was 3–4 MPa*m1/2 which decreased after welding to 2–2.5 MPa*m1/2. Strength of the SiC-ZrB2-ZrC parent material was ~700 MPa at 25 °C, ~300 MPa at 1700 °C, and retained 40–60% of this strength once welded. Strength of the SiC-ZrB2 parent material was ~600 MPa at 25 °C and 1700 °C and retained 20–30% of …

Investigating The Effect Of Polymer Hydrogels On The Antimicrobial Properties Of Activated Carbon Through The Utilization Of Bacterial, Viral, And Parasitic Microorganisms, Zoe Gunter

Honors Theses

Activated carbon (AC) has long been utilized in biomedical applications due to its innate antimicrobial characteristics. However, little is understood about the mechanism of action that allows AC to prohibit the propagation of different pathogen species. To further ascertain these characteristics and how they affect the propagation of pathogens, procedures were designed with bacterial, viral, and parasitic agents which were utilized in conjunction with varying concentrations of polymer hydrogels to examine the antimicrobial efficacy of AC. The studies performed for this thesis were conducted employing coconut-based AC and Noveon^® AA-1 Polycarbophil USP or Carbopol^® 974P NF hydrogels which, …

Properties Of 25cr7ni Stainless Steel Fabricated Through Laser-Powder Bed Fusion., Arulselvan Arumugham Akilan

Electronic Theses and Dissertations

Stainless steel is a low carbon high alloyed system with higher concentrations of Cr& Ni, which impart high corrosion resistance to them. Alloys with approximately 25% Cr & 7% Ni in their chemical composition are commercially referred to as ‘Super Duplex Stainless Steel’. They have a unique phase composition of approximately 50% ferrite & 50% austenite, yielding a robust combination of high mechanical strength & corrosion resistance. They find extensive interest & application in the fields which demand a longer service life under intense mechanical / corrosive environment such as offshore oil rigs & pipelines in nuclear power plants. Traditional …

Structural, Charge Transport, Gas Sensing, Magnetic, Pseudocapacitive, And Electrocatalytic Properties Of Perovskite Oxides., Surendra Bahadur Karki

Electronic Theses and Dissertations

Perovskites are functional materials with the general formula ABO₃ (A = alkali, alkaline earth or lanthanoid cations and B = transition metal or main group cations). These materials are marked by a variety of crystal structures and interesting properties such as colossal magnetoresistance, ferroelectricity, multiferroicity, superconductivity, pseudocapacitance, gas sensing, charge transport, and electrocatalytic properties. The formula of perovskite can be written as AA’BB’O₆, when there is ordering between two cations over A and B-sites. Such compounds are called double perovskite oxides. Some amount of oxygen could be lost from crystal structure without decomposition of the phase. Such …

Simulation Of Li Dendrite Inhibition In Lithium Battery By Phase-Field Method, Yao Ren

Material Science and Engineering Dissertations - Archive

Lithium (Li) dendrite growth poses serious challenges for the development of Li metal batteries which also stops the footsteps of human utilizing the environment-friendly new power source. Replacing liquid electrolyte with solid electrolyte can not only inhibit the dendrite growth by mechanical suppression, but also introduce more possibilities to the electrochemistry of battery. However, the underlying mechanism is still not fully understood, and most theoretical works focus on pure liquid electrolyte, ignoring the mechanical strain effects. Here we developed a phase-field model which simulates the Li dendrite growth to study the competition between diffusion and deposition rates, the pure elastic …

Porous Silicon Photonics For Label-Free Interferometric Biosensing And Flat Optics, Tahmid Hassan Talukdar

All Dissertations

This dissertation uses porous silicon as a material platform to explore novel optical effects in three domains: (i) It studies dispersion engineering in integrated waveguides to achieve high performance group index sensing. With proper design parameters, the sensor waveguides can theoretically achieve 6 times larger group index shift compared to the actual bulk effective refractive index shift. We demonstrate the guided mode confinement factor to be a key parameter in design and implementation of these waveguides. (ii) It explores multicolor laser illumination to experimentally demonstrate perceptually enhanced colorimetric sensing, overcoming the limitations faced by many contemporary colorimetric sensors. Our technique …

Synthesis Of Monodisperse Nanoscintillators At High Temperatures For Biomedical Relevant Applications, Eric Zhang

All Dissertations

Luminescent sub-100 nm particulates continuously generate immense research interest in the biomedical field for imaging, theranostics, and optogenetics. Conventionally, upconversion nanoparticles or UV activated semiconductors are studied, however these materials are limited by biological barriers such as the skin which reduces the penetration depth of these excitation sources, tissue's auto- fluorescence, and toxicity. One approach to overcome these challenges is to use nanoscintillators (sub-100 nm materials that can generate visible light using high energy excitation sources such as x-rays) which can generate light locally to the human body. Numerous scintillators have been reported since the discovery of x-rays from the …

Effects Of Sizing Agents On Mechanical Properties Of Carbon Fiber–Polymer Composites Via Fused Filament Fabrication Additive Manufacturing., Benjamin D. Mitchell

Electronic Theses and Dissertations

This study demonstrated the effects of changing the sizing agent parameter during the preparation of carbon fibers on the mechanical properties of composite made with acrylonitrile butadiene styrene (ABS) as the matrix material and carbon fibers as the fiber material. Three types of sizing agents produced by Allnex were used to coat three different batches of carbon fibers that were mixed with a torque rheometer and extruded with a barrel-style melt extruder into continuous spools of 1.75 mm filament for use with commercial 3D printers. Tensile tests were conducted on the filaments and tensile bars printed from the materials. Results …

Development Of Porous Solid Acid Catalysts For Lignocellulose And Plastic Upcycling., Mohammad Shahinur Rahaman

Electronic Theses and Dissertations

My goal is to develop chemical processes for transforming waste to solve environmental problems and enhance sustainability. Environmental problems such as pollution and massive amounts of waste are the main drivers that stimulate my research ideas. I focused on creating novel, efficient catalytic processes for converting polymeric waste "feedstocks" into high-value chemicals by integrating my expertise in catalysis, materials science, and synthetic chemistry to develop porous solid catalytic materials. During my Ph.D., I focused on two polymeric feedstocks, lignocellulose, and discarded plastic.

Early in my Ph.D. journey, I focused on catalytic upcycling of lignocellulose. Lignocellulosic biomass is cost-effective, abundant, and …

Towards Improving The Properties And Furthering Acceptance Of Advanced Technology Nuclear Fuels, Jennifer K. Watkins

Boise State University Theses and Dissertations

To avoid detrimental environmental impacts from climate change, the world community needs to push for the use of clean energy technologies. Development of proposed advanced technology nuclear fuels supports efforts to ensure nuclear energy is included as a non-carbon emitting source of electricity generation. Advanced technology nuclear fuels, also referred to as accident tolerant fuels (ATFs), have received renewed interest for use in the current nuclear reactor fleet as well as in advanced reactor technologies due to their high uranium loading, desirable thermophysical properties, and performance under irradiation as compared to the benchmark oxide fuel. A limiting consideration for the …

Multiphase Layered Transition Metal Oxide Positive Electrodes For Sodium Ion Batteries, Eric Gabriel, Dewen Hou, Eungje Lee, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Multiphase layered transition metal oxides (LTMOs) for sodium ion battery (SIB) positive electrodes with phase interfaces across multiple length scales are a promising avenue toward practical, high-performance SIBs. Combinations of phases can complement each other's strengths and mitigate their weaknesses if their interfaces are carefully controlled. Intra- and interparticle phase interactions from nanoscale to macroscale must be carefully tuned to generate distinct effects on properties and performance. An informed design strategy must be paired with relevant synthesis techniques and complemented by spatially resolved characterization tools to manipulate different length scales and interfaces. This review examines the design, synthesis, and characterization …

Mechanochromic Tunable Emissions Of Hydrogel Encapsulated Radioluminescent Crystalline Colloidal Arrays, Sarah Mell

All Theses

Crystalline colloidal arrays (CCAs) are periodic dielectric arrays composed of monodisperse, negatively charged nanoparticles with unique optical characteristics. Poly(styrene-co-propargyl acrylate) (PS-PA) based copolymer nanoparticles synthesized via an emulsion polymerization form the basis of the CCAs in this work. The negatively charged surfaces result in the colloidal nanoparticles self-assembling into a face-centered cubic (fcc) crystal-like structure. The long-range order and spatial periodicity of the array result in a rejection wavelength, characteristic of CCAs, in which a specific wavelength of light is forbidden from propagating throughout the optical system. The CCAs exhibit mechanochromism through a rejection wavelength shift corresponding to a change …

Synthesis And Molecular Processes Governing Self-Healing Polymeric Materials, Siyang Wang

All Dissertations

Self-healing polymers capable of recovering from physical damages are promising materials for advanced technologies. In these studies, we developed routes to achieve self-healable properties in acrylic-based copolymers that rely on non-covalent dipolar interactions present in essentially all polymeric materials. Using a combination of spectroscopic tools, thermo-mechanical analysis, and molecular dynamic (MD) simulations, these studies have shown that dipolar interactions lead to conformational changes of macromolecular segments which, in turn, result in self-healing without external intervention. This dissertation also describes the development of novel self-healable acrylic-based covalent adaptable networks (CANs) that combine reprocessing and self-healing properties. The utilization of dipolar interactions …

Synthesis And Phase Transition Characterization Of Liquid Crystal Membranes With Slit-Like Pores, Isaac Hopwood

Chemical Engineering Undergraduate Honors Theses

Membranes with slit-like pores have been of interest for some time due to their ability to reject smaller particles than traditional cylindrical-pored membranes at the same fluid flux. However, using liquid crystals as a template for this sort of membrane has not been thoroughly investigated. In this study, the liquid crystal mixture of RM257 (2-Methyl-1,4-phenylene bis(4-(3-(acryloyloxy)propoxy)benzoate)) and 5CB (4-Cyano-4'-pentylbiphenyl) for the purpose of manufacturing membranes with slit-like pores, the phase transition behavior of this LC mixture at various mole fractions of RM257, and the impact of mole fraction of RM257 in the liquid crystal (LC) mixture and membrane manufacturing conditions …

Evaluating The Effects Of Curing Methods On Bcsa Cement Concrete, Hannah Allen

Civil Engineering Undergraduate Honors Theses

BCSA cement is a type of cement that makes concrete set up much quicker than typical portland cement concrete. BCSA cement concrete also has a much higher compressive strength than that of portland cement concrete. This study was conducted to determine the effect of different curing conditions on the compressive strength of BCSA cement concrete.

Extractive Membranes For The Detection And Screening Of Waterborne Plutonium, James Foster

All Dissertations

The development of rapid screening tools for special nuclear materials remains a crucial focus for nonproliferation efforts. Traditional approaches for the analysis of trace-level Pu isotopes in water requires tedious and time-consuming sample preparation steps that do not lend well to expeditious screening. Therefore, a novel analytical method that combines both Pu concentration and source preparation into a single detection system would make for an invaluable tool for nuclear security applications. Extractive membranes absorbers can help to fulfill this role as they are capable of concentrating Pu to detectable limits while subsequently serving as alpha spectrometry sample sources. In Chapter …

Sustainable Composites From Agricultural And Petroleum Waste, Menisha S. Karunarathna

All Dissertations

Green gas emission has been a pervasive and persistent subject of debate for a prolonged period. The soaring number of industries and vehicle fuel emissions presage a concomitant rise in global CO₂ emissions. Global cement production is responsible for 8% of the total CO₂ release, yet, the production continues due to the surging demand. Hence, there is an ongoing quest to find alternatives for cement and building materials produced with zero to lower CO₂ emissions. The work presented in this dissertation focuses on finding recyclable, zero CO₂ gas-producing high sulfur biocomposites materials, which can compete with …

Graphene Oxide-Thermoplastic Nanocomposites: Fabrication And Properties, Seyedeh Mastooreh Seyedi Ghezghapan

All Dissertations

Polymer nanocomposites are used for a wide variety of applications. These nanocomposites can have a number of important characteristics depending on the nature of the nanomaterial, its size, volume fraction, its distribution, and interactions within the host polymer. Mechanical strength, thermal and electrical conductivity are some of these materials' most focused and studied features. Besides the positive influences of the reinforcements, nanomaterials also might have some adverse impacts on the polymer matrix. These issues could arise from the aggregation of the fillers and the poor interfacial interactions of the components. Several approaches are introduced to modify the nanofillers and enhance …