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Articles 31 - 60 of 16791

Full-Text Articles in Engineering

Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber Sep 2026

Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber

Journal of Sustainable Construction Materials and Technologies

This study examines the impact of creating a longitudinal void in high-strength reinforced concrete (RC) beams to decrease concrete volume. Testing involved three groups: solid beams (SB), beams with a 75 mm void (VB), and beams with a void incorporating 1.2% micro-steel fibers (VBSF), across various shear spans (a/d) of 1.8, 2.7, and 3.6. Results indicated that increased a/d led to a 54.2% reduction in peak loads and a 119.2% increase in deflection for solid beams. The void negatively affected load-bearing at a/d = 1.8 with a 25% peak load reduction and brittle failure. At a/d = 2.7, effects were …

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Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu Sep 2026

Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu

Journal of Electrochemistry

High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …

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Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang Sep 2026

Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang

Journal of Electrochemistry

The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …

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Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang Sep 2026

Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang

Journal of Electrochemistry

Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …

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Complementary Thermodynamic Mechanisms Of Boron And Carbon Segregation At Grain Boundaries In Nickel Alloys, Tyler D. Dolezal, Rodrigo Freitas, Ju Li Sep 2026

Complementary Thermodynamic Mechanisms Of Boron And Carbon Segregation At Grain Boundaries In Nickel Alloys, Tyler D. Dolezal, Rodrigo Freitas, Ju Li

Faculty Publications

Grain boundary stabilization by light interstitials is central to the performance of Ni-based superalloys, yet the thermodynamic mechanisms governing their interactions with substitutional chemistry remain poorly resolved. Here, we use hybrid Monte Carlo molecular dynamics simulations to quantify how boron and carbon modify the thermodynamic, structural, and chemical ordering of grain boundaries in Ni-Cr alloys. By analyzing interfacial state variables, site-resolved segregation spectra, local chemical ordering, and structural evolution, we show that boron and carbon stabilize grain boundaries through complementary pathways. Carbon drives saturation-controlled stabilization by recruiting Cr and conditioning boundary chemistry, while suppressing temperature-driven structural transformations of the boundary. …

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Modeling Urban Heat Island Mitigation Strategies In Egyptian Cities Using Envi-Met, Islam M. Gaber, Abbas M. Hassan, Tarek Elkashef, Ola A. Gad, Ahmed M. Abdo, Abdelrazek Elkomy Sep 2026

Modeling Urban Heat Island Mitigation Strategies In Egyptian Cities Using Envi-Met, Islam M. Gaber, Abbas M. Hassan, Tarek Elkashef, Ola A. Gad, Ahmed M. Abdo, Abdelrazek Elkomy

HBRC Journal

Mitigation techniques for urban heat islands (UHI) have emerged as a critical concern for global urban environmental sustainability. Passive cooling employing cool materials and/or urban greening has shown to be the most effective strategy for mitigating the impacts of UHI. This latter method, however, is relatively new in the literature of urban environmental studies, and research on it is still limited, particularly for cities in hot-dry climatic zones. This study aims to investigate the possibility of improving albedo rates and adopting urban greening measures, such as greening building roofs, roadways, and walkways, in several Egyptian cities located in various climatic …

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Improving Mechanical Properties Of Soft Clay By Deep Soil Mixing In North Delta, Egypt Vs. Finite Element Simulation, Ali Gamal Abdel Zaher, Sherif Abdelaziz Mazek, Samir Abdelfattah, Mostafa Merzk Sep 2026

Improving Mechanical Properties Of Soft Clay By Deep Soil Mixing In North Delta, Egypt Vs. Finite Element Simulation, Ali Gamal Abdel Zaher, Sherif Abdelaziz Mazek, Samir Abdelfattah, Mostafa Merzk

HBRC Journal

Soft clay layers in the Northern Nile Delta pose significant geotechnical challenges due to low shear strength, high compressibility, and susceptibility to settlement. This study implements a section of a canal embankment in the field using Deep Soil Mixing (DSM) with a cement content of 165 kg/m3 and aims to evaluate its effectiveness in stabilizing soft clay while providing practical design tools for similar deltaic environments. Long-term field monitoring and laboratory testing, including UCS and permeability measurements, were conducted to support the analysis. A Finite Element Model (FEM) was developed in PLAXIS 2D v21 and calibrated against field data, …

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Integrated Fire Protection Design In Pharmaceutical Manufacturing Facilities: An Applied Case Study, Eman Osman Mahmoud Osman, Fouad Abdel-Mawgoud Abdel-Halim Qasim, Alaa El-Din El-Sayed Farid Hassan Sep 2026

Integrated Fire Protection Design In Pharmaceutical Manufacturing Facilities: An Applied Case Study, Eman Osman Mahmoud Osman, Fouad Abdel-Mawgoud Abdel-Halim Qasim, Alaa El-Din El-Sayed Farid Hassan

HBRC Journal

The architectural design of pharmaceutical manufacturing facilities presents a complex engineering challenge, requiring simultaneous compliance with Good Manufacturing Practice (GMP) containment standards and life safety egress codes. This research presents an applied methodology for integrated fire protection design in sterile pharmaceutical environments, demonstrated through a case study of a manufacturing complex comprising cleanroom production zones and high-bay storage warehouses with heights reaching 14.8 m. The study reconciles facility classification under the Egyptian Fire Code and NFPA standards by defining Occupancy Hazard Groups W-1 and W-2 (high- and moderate-hazard storage), while utilizing regulatory Code Tables C-1 and C-2 to calculate occupant …

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Physical Modeling To Represent Molten-Slag Entrapment Behavior Into Molten-Steel Under Simultaneous Similitude Condition Of Multiple Dimensionless Numbers, Yuichi Tsukaguchi, Sho Nakano Sep 2026

Physical Modeling To Represent Molten-Slag Entrapment Behavior Into Molten-Steel Under Simultaneous Similitude Condition Of Multiple Dimensionless Numbers, Yuichi Tsukaguchi, Sho Nakano

Progress in Scale Modeling, an International Journal

Physical model construction and experiment are essential for scientific investigations of flow phenomena such as high temperature two phase flow of molten metal and inert gas. It has been a common method to construct a physical model with a convenient scale then proceed experiments under similitude condition of one or two dimensionless number(s) of dominant forces to represent. It is an ideal experimental method to satisfy the simultaneous similitude condition of multiple dimensionless numbers concerned with the objective flow phenomena but has been considered difficult or impossible to realize for many years. Contrarily, the concept of the simultaneous similitude of …

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The Effect Of Transition Metal Oxides On The Performance Of Triboelectric Nanogenerators, Md Arafat Hossain, Abdullah Mohammad Sarjish, Md. Wasikur Rahman, Victoria Padilla, Mohammed Jasim Uddin Sep 2026

The Effect Of Transition Metal Oxides On The Performance Of Triboelectric Nanogenerators, Md Arafat Hossain, Abdullah Mohammad Sarjish, Md. Wasikur Rahman, Victoria Padilla, Mohammed Jasim Uddin

Mechanical Engineering Faculty Publications

Triboelectric nanogenerators (TENGs) are a promising energy-harvesting technique that utilizes contact electrification and electrostatic induction to convert mechanical energy into electrical energy. Contact electrification can occur between any two surfaces that experience periodic physical contact and separation, regardless of the material type. Various materials have been investigated for triboelectrification in TENGs for different applications. Although polymers are used in TENGs, various transition metal oxides (TMOs), including binary, ternary, and doped binary/ternary oxides, have also been widely studied as filler materials to improve TENG performance. Introducing TMOs into the polymer matrix enhances the performance by increasing surface charge density and enabling …

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Aerodynamic Effects Optimisation Of Water-Powered Funicular Car Body Exposed To Headwind And Crosswind, Theodorus Agung Wicaksono, Bagus Wahyudi, Syamsul Hadi, Wirawan Wirawan, Hangga Wicaksono Sep 2026

Aerodynamic Effects Optimisation Of Water-Powered Funicular Car Body Exposed To Headwind And Crosswind, Theodorus Agung Wicaksono, Bagus Wahyudi, Syamsul Hadi, Wirawan Wirawan, Hangga Wicaksono

Journal of Mechanical Engineering Science and Technology (JMEST)

Water-powered funicular railways are an environmentally friendly mode of transport whose efficiency heavily depends on the principle of gravity. However, their operation is vulnerable to natural wind disturbances that can hinder speed or cause a risk of overturning on steep, curved tracks. This study aims to analyse the influence of funicular car model design on the rolling moment exerted on the rails as the car turns to enter a track branch. The research methodology involves aerodynamic simulations using SolidWorks flow simulation, comparing three body models: WAHYUDI, FUNAERO, and AEROFUN. Simulations were conducted with variations in turn angles (10° to 30°) …

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Parametric Study On The Plastic Hinge Length Of Precast Concrete Columns With Grouted Sleeve Connections, Rizky Tri Amalia, Harun Alrasyid Sep 2026

Parametric Study On The Plastic Hinge Length Of Precast Concrete Columns With Grouted Sleeve Connections, Rizky Tri Amalia, Harun Alrasyid

Journal of Sustainable Construction Materials and Technologies

The use of precast concrete structures with grouted sleeve (GS) connections has gained significant traction in the acceleration of bridge construction. The plastic hinge length (Lp) is a critical parameter for assessing the seismic performance and deformation capacity of such structural members. The previous study has proposed empirical equations for Lp in monolithic columns; however, a comprehensive understanding of the influential parameters on Lp in precast concrete columns with GS connections remains limited. This study presents a detailed parametric investigation to evaluate the effects of key design parameters on the plastic hinge length of a precast concrete columns with GS …

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In Silico Analysis Of Momordica Charantia Triterpenoids As Adenosine Monophosphate-Activated Protein Kinase Ligands For Type 2 Diabetes Mellitus Therapy, Anita Dwi Puspitasari Sep 2026

In Silico Analysis Of Momordica Charantia Triterpenoids As Adenosine Monophosphate-Activated Protein Kinase Ligands For Type 2 Diabetes Mellitus Therapy, Anita Dwi Puspitasari

Chimica et Natura Acta

Type 2 diabetes mellitus continues to rise and calls for safe therapeutic leads. This study assessed the potential of triterpenoids from bitter melon (Momordica charantia) as AMP-activated protein kinase (AMPK) ligands at the ATP-binding site through an in silico approach. AMPK (PDB ID: 4QFG) was prepared in YASARA; nine M. charantia triterpenoids and metformin were docked in PLANTS. Redocking of staurosporine validated the protocol (RMSD 0.2376 Å; ≤2.0 Å). Kuguacin J (-89.9934), Karavilagenin B ( 86.4084), and Kuguacin R (-85.8514) yielded lower (more favorable) docking scores than metformin (-56.5325) and interacted with hinge residues (Val96 and Glu94/Glu100). As expected, the …

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Sla Elastic Resin Curing Test Data, Richard Amesimenu, Johnson Nwogu, Haijun Gong Sep 2026

Sla Elastic Resin Curing Test Data, Richard Amesimenu, Johnson Nwogu, Haijun Gong

Datasets

3D printing via stereolithography (SLA) enables high-resolution polymer components, but as-printed parts may exhibit incomplete polymerization and reduced mechanical performance. This study investigates the effects of UV post-curing time on SLA-printed elastic photopolymer resin. Specimens were evaluated using Differential Scanning Calorimetry (DSC), uniaxial tensile testing (ASTM D412 Type C), and Durometer Type M hardness testing. Results show that increased post-curing enhances crosslink density, tensile strength, elastic modulus, and hardness, while extended curing may reduce ductility. An optimal post-curing window balancing stiffness and flexibility was identified. Testing datasets include DSC (dsc/), tensile testing (tensile/), and hardness testing (hardness/) results for uncured …

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Ecofriendly Synthesis Of Silver Nanoparticles As Antimicrobial Active Agents From Its Cationic Precursors, Abdul Haris Watoni Watoni Sep 2026

Ecofriendly Synthesis Of Silver Nanoparticles As Antimicrobial Active Agents From Its Cationic Precursors, Abdul Haris Watoni Watoni

Chimica et Natura Acta

This review presents a comprehensive survey on the green synthesis of silver nanoparticles from silver nitrate precursor using plant extracts along with their characterization and antimicrobial activity assessment. The synthesis of silver nanoparticles through a green chemistry approach is increasingly in demand because it is environmentally friendly, easy to do, and efficient, especially for the purpose of antimicrobial active ingredients in disinfectant and antiseptic formulas. Green synthesis of silver nanoparticles can be carried out using silver nitrate as a silver precursor and plant extracts as a source of bioreductants and capping agents. The synthesis products are then characterized using UV-Vis …

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Key Strategies Enabling The Contribution Of Social Infrastructure In Climate-Proofing Cities: An Explorative Case Study Of Rotterdam, The Netherlands, Sara Elgamal, Alaa El.Eashy, Sherif Sheta Sep 2026

Key Strategies Enabling The Contribution Of Social Infrastructure In Climate-Proofing Cities: An Explorative Case Study Of Rotterdam, The Netherlands, Sara Elgamal, Alaa El.Eashy, Sherif Sheta

HBRC Journal

Social infrastructure, as the physical medium for social life in cities, is increasingly being acknowledged for its ability to offer climate-proofing benefits both in times of climate stability and climate disturbances. However, more evidence is needed on how social infrastructure can be deliberately shaped to contribute to climate-proofing cities. Our study addresses this gap through exploring the key strategies which ensure the effective engagement of social infrastructure (SI) in climate proofing cities (CPC). An explorative case study of Rotterdam city is performed, as the city is well recognized as a pioneer in climate resilience through spatial planning. Data sources for …

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Synthesis Of Fe-Doped Porous Carbon Catalyst Derived From Coconut Shell Waste Using Ferric Nitrate Nonahydrate (Fe(No3)3.9h2o) As An Iron Precursor, Ilham Lestadi Putra, Sukarni Sukarni, Heru Suryanto Sep 2026

Synthesis Of Fe-Doped Porous Carbon Catalyst Derived From Coconut Shell Waste Using Ferric Nitrate Nonahydrate (Fe(No3)3.9h2o) As An Iron Precursor, Ilham Lestadi Putra, Sukarni Sukarni, Heru Suryanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Renewable energy from lignocellulosic biomass is a promising alternative to fossil fuels. Coconut shell (CS) waste is a favorable precursor for porous carbon due to its high carbon content, abundance, and non-food nature. However, conventional biochar often has limited surface area and catalytic active sites, hindering its effectiveness as a catalyst. While Fe-based modifications are promising, the use of ferric nitrate-assisted activation of coconut-shell-derived porous carbon remains underexplored. This research focused on developing an Fe-doped porous carbon catalyst from CS via ultrasound-assisted impregnation, followed by activation in a tube furnace. CS biochar was produced through pyrolysis at 550 °C and …

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Which Factors Are Most Important For Understanding Neighborhood-Scale Electrification Transitions In New York City, And How Do These Factors Interact Within Urban Energy Systems?, Aaryan Nair Sep 2026

Which Factors Are Most Important For Understanding Neighborhood-Scale Electrification Transitions In New York City, And How Do These Factors Interact Within Urban Energy Systems?, Aaryan Nair

Publications and Research

Building electrification has emerged as a central strategy for reducing greenhouse gas emissions from urban areas, yet its implementation remains uneven across cities due to differences in buildings, infrastructure, and local conditions. This literature review examines the factors that influence neighborhood-scale electrification transitions in New York City and explores how these factors interact within urban energy systems. Drawing on research from building science, energy systems, infrastructure planning, and sustainability transitions, the paper identifies five recurring categories of influence: building characteristics, demand characteristics, infrastructure conditions, planning and investment capacity, and socioeconomic conditions. The review finds that building age, typology, density, and …

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The Instability And Unsustainability Of Our Planned, Or Imagined Media Future, Thom Gencarelli Sep 2026

The Instability And Unsustainability Of Our Planned, Or Imagined Media Future, Thom Gencarelli

Proceedings of the New York State Communication Association

In the face of the growth and planned growth of industrial developments in artificial intelligence, embodied AI, immersive media/virtual reality, and the fintech industry and cryptocurrencies – and the energy requirements for each of these and all of them together – this paper examines the question of whether the plans for growth and future development in these areas is probable, possible, problematic, or impossible.  Additionally, the examination is situated atop both state-based and criminal threats to use the Internet and mobile Internet to wreak havoc and instability.

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Thermal And Electrical Properties Of (Cr,Mo,Ta,V,W)C High-Entropy Carbide Ceramics, Ali Sarikhani, Steven M. Smith, Suzana Filipovic, William G. Fahrenholtz, Gregory E. Hilmas Sep 2026

Thermal And Electrical Properties Of (Cr,Mo,Ta,V,W)C High-Entropy Carbide Ceramics, Ali Sarikhani, Steven M. Smith, Suzana Filipovic, William G. Fahrenholtz, Gregory E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

The synthesis and characterization along with the resulting properties of fully dense (Cr,Mo,Ta,V,W)C high entropy carbide ceramics were studied. The ceramics were synthesized from metal oxide and carbon powders by carbothermal reduction, followed by spark plasma sintering at various temperatures for densification. Increasing the densification temperature resulted in grain growth and an increase in the lattice parameter. Thermal diffusivity increased linearly with testing temperature, resulting in thermal conductivity values ranging from ∼7 W/m•K at room temperature to ∼12 W/m•K at 200 °C. Measured heat capacity values matched theoretical estimates calculated using the Neumann-Kopp rule. Room temperature electrical resistivity decreased from …

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The Role Of Mxene In The Process Of Sintering Hpcs To Ceramic, Jianyu Dai, Congjie Wei, Jeremy Watts, Chenglin Wu Sep 2026

The Role Of Mxene In The Process Of Sintering Hpcs To Ceramic, Jianyu Dai, Congjie Wei, Jeremy Watts, Chenglin Wu

Materials Science and Engineering Faculty Research & Creative Works

This work presents a detailed investigation of the pyrolysis and sintering processes of hydridopolycarbosilane (HPCS) polymers, focusing on the formation of β-silicon carbide (β-SiC) and the influence of Ti3C2–Ox in this process. Due to the computational limitations of density functional theory (DFT), molecular dynamics methods with appropriate potentials are necessary for simulating large-scale systems, however, the available potentials are limited when the modeling process evolves relatively more element types or complex chemical-mechanical processes are studied. In this work, a machine learning based MACE (Multi-body ACE) model is adopted and trained to accurately capture the polymer's transformation …

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Manufacturing Routes For Oxide Dispersion Strengthened Alloys, Ertugrul Demir, Seung Min Ha, Alexander Killips, Guan Cheng Chen, Yitian Chi, Dileepa Maddumage, Dalong Zhang, Xiaochun Li, Haiming Wen, Enrique Lavernia Sep 2026

Manufacturing Routes For Oxide Dispersion Strengthened Alloys, Ertugrul Demir, Seung Min Ha, Alexander Killips, Guan Cheng Chen, Yitian Chi, Dileepa Maddumage, Dalong Zhang, Xiaochun Li, Haiming Wen, Enrique Lavernia

Materials Science and Engineering Faculty Research & Creative Works

Oxide dispersion strengthened alloys are promising structural materials for high temperature, irradiation, and mechanically demanding environments because their performance depends on fine and stable oxide dispersoids distributed within a metallic matrix. However, reliable fabrication remains challenging because precursor oxide nanoparticles or oxide forming species must be transformed into stable oxide dispersoids without excessive agglomeration, coarsening, contamination, or loss during processing. This review critically compares powder metallurgy, additive manufacturing, and liquid metallurgy routes for ODS alloy fabrication, with emphasis on oxide evolution, microstructure control, mechanical performance, scalability, and industrial maturity. Powder metallurgy remains the most reliable route for producing fine and …

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Flexural Performance Of Deficient Rc Beams Repaired With Gfrp Composite, Zena Aljazaeri, Hayder Alghazali, Zuhair Al-Jaberi, John J. Myers Sep 2026

Flexural Performance Of Deficient Rc Beams Repaired With Gfrp Composite, Zena Aljazaeri, Hayder Alghazali, Zuhair Al-Jaberi, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Fiber-reinforced polymer composite materials have been improved for use in repairing and strengthening existing infrastructure over the past few decades. This case study focuses on the effect of confinement with GFRP strips on the structural performance of out-of-service beams in bridge applications due to the impact of over-height vehicles or inadequate lap-spliced reinforcements. In this study, beams with inadequate lap splices in the tension zone were utilized to mimic the damaged area in out-of-service RC beams. The proposed repair technique is a glass fiber-reinforced polymer (GFRP) composite in the form of longitudinal sheets and U-wrapped strips. The experimental study determined …

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Engineered Porous Structures For Propellants Using Additive Manufacturing, Elbert Caravaca Aug 2026

Engineered Porous Structures For Propellants Using Additive Manufacturing, Elbert Caravaca

Dissertations

Foamed polymers are widely used today for shock absorption and packaging materials to prevent damage to their contents. Typical foamed densities vary from 0.1 g/cm3 to 0.4 g/cm3 depending on the polymeric materials used. There is a need to explore foaming densities above 0.4 g/cm3 for propellants with highly engineered surface area progression for increased combustion performance. One way to achieve this is through highly controlled and engineered graded foam structures. To further exploit this approach, additive manufacturing coupled with a tunable means to generate foamed structures is the target of this work. To generate foam structures …

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Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao Aug 2026

Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao

Journal of Electrochemistry

Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …

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Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang Aug 2026

Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang

Journal of Electrochemistry

Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …

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In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li Aug 2026

In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li

Journal of Electrochemistry

Electrocatalytic nitrate reduction to ammonia (NitRR) represents a sustainable pathway that integrates environmental remediation with the production of high-value ammonia. However, the activity and selectivity of this process are limited by the generation, consumption, and dynamic equilibrium of the key transient intermediate—active hydrogen (*H). Precise modulation of *H necessitates a comprehensive understanding of its behavior, which relies fundamentally on advanced in situ electrochemical characterization techniques. However, a systematic review dedicated to the rational selection and application of in situ electrochemical techniques for the specific characterization of *H in NitRR, with clear definitions of each technique's "detectable targets, quantitative accuracy, and …

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Field-Like- And Self-Spin-Orbit Torques In Magnetic Multilayer Films, Kyle Jeffrey Peterson Aug 2026

Field-Like- And Self-Spin-Orbit Torques In Magnetic Multilayer Films, Kyle Jeffrey Peterson

Electronic Theses and Dissertations

Spin-orbit torques (SOTs) have been realized as an energy efficient mechanism to manipulate and drive magnetization dynamics in magnetic multilayer films. Their damping-like and field-like components provide distinct pathways for controlling the magnetization, enabling switching, sustaining magneto-oscillations, and driving domain-wall motion with potential applications in nonvolatile memory, spin-based logic, and microwave signal generation. However, the accurate quantification and interpretation of these torques remains complicated by experimental sensitivity, the co-symmetry of the Oersted field and the effective field due to the field-like torque, and assumptions regarding the material layers from which the torques originate. The body of work set forth in …

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Synergistic Reinforcement Of Lignin–Chitosan Hydrogels Using Vanillin As A Sustainable Green Crosslinker, Moses Ayitey-Adjin Jr., Mohammad Jahid Hasan, Jeremy Erb, Kishore Chand, Garry S. Crosson, Kenya Crosson, Esteban Ureña-Benavides, Erick Salvador Vasquez-Guardado Aug 2026

Synergistic Reinforcement Of Lignin–Chitosan Hydrogels Using Vanillin As A Sustainable Green Crosslinker, Moses Ayitey-Adjin Jr., Mohammad Jahid Hasan, Jeremy Erb, Kishore Chand, Garry S. Crosson, Kenya Crosson, Esteban Ureña-Benavides, Erick Salvador Vasquez-Guardado

Chemical and Materials Engineering Faculty Publications

While bio-based hydrogels derived from lignin and chitosan are promising sustainable adsorbents, their practical application is hindered by poor mechanical stability. This study addresses this limitation by synthesizing lignin-chitosan hydrogels using vanillin as a green, bio-derived crosslinker via a facile solution-casting method. The formation of imine (Schiff base) linkages between the aldehyde groups of vanillin and the primary amines of chitosan was confirmed by FTIR spectroscopy (C = N stretching at ~ 1602 cm− 1). SEM and TGA results demonstrated a reduction in the pore size of the crosslinked hydrogel and an enhanced residual thermal mass. Rheological and …

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Exploring Red Palm Oil As A Sustainable Plasticizer For Carbon Black-Filled Ssbr/Br Tire Tread Compounds: A Comparative Evaluation Of Commercial Alternatives, Norma Arisanti Kinasih, Mohamad Irfan Fathurrohman, Santi Puspitasari, Dewi Kusuma Arti, Abdulhakim Masa Aug 2026

Exploring Red Palm Oil As A Sustainable Plasticizer For Carbon Black-Filled Ssbr/Br Tire Tread Compounds: A Comparative Evaluation Of Commercial Alternatives, Norma Arisanti Kinasih, Mohamad Irfan Fathurrohman, Santi Puspitasari, Dewi Kusuma Arti, Abdulhakim Masa

Journal of Materials Exploration and Findings

This study investigates the application of red palm oil (RPO) as an alternative vegetable oil resource to substitute petroleum-based plasticizers, which have environmental and health concerns, in carbon black (CB)-filled SSBR/BR tire tread compounds. The plasticizing effects of RPO were thoroughly evaluated by comparing them with a commercial bio-based plasticizer, Epoxidized Soybean Oil (ESBO), and two safer petroleum-based oils, Naphthenic Oil (NYNAS) and Treated Distillate Aromatic Extract (TDAE). The initial investigation shows that fatty acid composition is imposing regarding the plasticizing effect. The higher unsaturated fatty acid content in RPO than in ESBO improved tensile strength and degraded rolling resistance …

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