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Articles 2701 - 2730 of 16703
Full-Text Articles in Engineering
Investigating The Influence Of Surface Finishing Methods On Corrosion Of Additively Manufactured Ss316l, Joshua R. Fadeley
Investigating The Influence Of Surface Finishing Methods On Corrosion Of Additively Manufactured Ss316l, Joshua R. Fadeley
Boise State University Theses and Dissertations
Additive Manufacturing (AM), namely with metal, has seen a surge in growth and interest over recent years. A wide array of industries is developing new products to take advantage of this budding technology. In order to enable adoption of this technology, understanding of the differences of AM versus traditional manufacturing on the resultant materials properties of printed components is important. The work done for this study fell into two separate categories of work.
The first effort of this work involved the installation, certification, and operation of the first laser powder bed fusion (LPBF) printer at the Center for Advanced Energy …
Additive Manufacturing Of Microelectronic Devices For Extreme Environments, Nicholas Mckibben
Additive Manufacturing Of Microelectronic Devices For Extreme Environments, Nicholas Mckibben
Boise State University Theses and Dissertations
This work encompasses a comprehensive exploration of advanced manufacturing techniques for fabricating microelectronic devices compatible with extreme environments. The research integrates the fields of chemistry, nanomaterials, and additive manufacturing to achieve remarkable progress in sensor development, with a particular emphasis on aerosol jet printing (AJP), surface acoustic wave (SAW) devices, patterned graphene growth, and surface functionalization. The investigation begins with the AJP process development of a commercial silver nanoparticle ink, culminating in the fabrication of a piezoelectric SAW transducer that was prototyped as a high-temperature thermometer, showing excellent linearity when validated to 200°C. Next, the investigation continued with the development …
3d Printed Microdialysis-Based Microsampling Probes, Patrick Pysz
3d Printed Microdialysis-Based Microsampling Probes, Patrick Pysz
Graduate Theses and Dissertations
This work will show the development of a fully 3D printed device platform in which a complex microsampling probe geometry is fabricated in a simple two-step process. This process includes the combination of 2-photon polymerization (2PP) and masked-stereolithography (MSLA). The cutting edge neurotechnology needed to monitor brain internal communication and will require multiple sensing modalities including temperature, pressure, electrophysiological, and optogenetics. Microsampling is an integrally important function for any future biosensing device platform as it allows for chemical delivery and unparalleled specificity through offline analysis of collection samples. Stereolithography (SLA) 3D printing has emerged as a powerful fabrication method capable …
Study On Effect Of 3d Printing Parameters On Surface Roughness And Tensile Strength Using Analysis Of Variance, Faqih Fadillah, Heru Suryanto, Suprayitno Suprayitno
Study On Effect Of 3d Printing Parameters On Surface Roughness And Tensile Strength Using Analysis Of Variance, Faqih Fadillah, Heru Suryanto, Suprayitno Suprayitno
Journal of Mechanical Engineering Science and Technology (JMEST)
Fused deposition modeling of 3D printing is the process of making workpieces or parts by adding filaments to each layer. Some indicators of a high-quality product of 3D printing are the precisions dimensions, the surface roughness, and tensile strength. This research aims to find the parameters most affecting surface roughness and tensile strength. The research design used an experimental method with input parameters: (1) print speed (15-35 mm/s), (2) print temperature (200-210C), (3) layer height (0.1 – 0.3 mm), (4) infill line directions (0-90), and dependent variables were surface roughness and tensile strength. The data distribution used the L9 orthogonal …
Mechanical Characterization Of Naoh-Treated Agel Fiber-Cotton Composites, I Gusti Ngurah Nitya Santhiarsa, I Gusti Bagus Wijaya Kusuma, I Gede Artha Negara
Mechanical Characterization Of Naoh-Treated Agel Fiber-Cotton Composites, I Gusti Ngurah Nitya Santhiarsa, I Gusti Bagus Wijaya Kusuma, I Gede Artha Negara
Journal of Mechanical Engineering Science and Technology (JMEST)
Composites comprising two or more distinct materials are fabricated to enhance the mechanical properties of the constituent materials. A common approach for generating composites is vacuum infusion. This technique enables the infusion of two materials utilizing a vacuum. In the field of composite science, textile composites have emerged as an important new development. Agel rope, derived from twisting agel fibers, exhibits inferior bending strength and elongation compared to ropes fabricated from synthetic fibers. Moreover, agel rope is susceptible to bacterial decay. This study aims to characterize the mechanical properties of textile composites comprising woven agel rope subjected to NaOH treatment. …
Heat Conduction In Cylindrical Coordinates With Time-Varying Conduction Coefficients: A Practical Engineering Approach, Lulut Alfaris, Ruben Cornelius Siagian, Aldi Cahya Muhammad, Ukta Indra Nyuswantoro, Budiman Nasution
Heat Conduction In Cylindrical Coordinates With Time-Varying Conduction Coefficients: A Practical Engineering Approach, Lulut Alfaris, Ruben Cornelius Siagian, Aldi Cahya Muhammad, Ukta Indra Nyuswantoro, Budiman Nasution
Journal of Mechanical Engineering Science and Technology (JMEST)
This research aims to develop a mathematical method for expressing the Laplace operator in cylindrical coordinates and applying it to solve heat conduction equations in various scenarios. The method commences by transforming Cartesian coordinates into cylindrical coordinates and identifying the necessary substitutions. The result is the expression of the Laplace operator in cylindrical coordinates, which is subsequently employed to address heat conduction equations within cylindrical coordinates. Various cases encompassing different initial and boundary conditions, as well as variations in the conduction coefficient over time, are meticulously considered. In each instance, precise mathematical solutions are determined and subjected to thorough analysis. …
Numerical Study On Resistance Of Stepped Planing Hull, Fajri Ashfi Rayhan, Andika Masrul, Arya Khairullah Akbar, Bima Anugerah Putra
Numerical Study On Resistance Of Stepped Planing Hull, Fajri Ashfi Rayhan, Andika Masrul, Arya Khairullah Akbar, Bima Anugerah Putra
Journal of Mechanical Engineering Science and Technology (JMEST)
A stepped planing hull, also known as a step hull, is a hull modification that reduces the wetted surface area. Although this type of hull has proven effective in several ships, it is still rarely used. The step hull possesses numerous advantages that make it ideal for activities involving small and fast boats. However, regrettably, its full potential remains untapped at present. The purpose of this study was to identify the effect of variations in the angle of the step hull on resistance or drag. The study utilized the CFD method, and three hull configuration models were used at each …
Analyzing Transition Metallic Catalytic Converter Impact On Four-Stroke Motorcycle Fuel Consumption, Sudirman Rizki Ariyanto, Ata Syifa’ Nugraha, Wahyu Robby Cahyadi, Yelma Dianastiti, Muhammad Yandi Pratama
Analyzing Transition Metallic Catalytic Converter Impact On Four-Stroke Motorcycle Fuel Consumption, Sudirman Rizki Ariyanto, Ata Syifa’ Nugraha, Wahyu Robby Cahyadi, Yelma Dianastiti, Muhammad Yandi Pratama
Journal of Mechanical Engineering Science and Technology (JMEST)
Increased exhaust emissions from motor vehicles have become a major concern in efforts to reduce air pollution. One developed solution is the use of transition metallic catalytic converter (TMCC) technology in vehicle exhaust systems. This study aims to compare the fuel consumption efficiency of three types of exhaust systems, namely standard exhaust without a catalyst (STD WC), the standard exhaust with Original Equipment Manufacturer catalyst (STD OEM), and an exhaust system equipped with a Copper-Coated Chrome Metallic Catalytic Converter (TMCC CuCr). The data analysis method employed a quantitative approach by collecting fuel consumption data at each rpm and analyzing the …
Effect Of The Homogenization Process On Titanium Oxide-Reinforced Nanocellulose Composite Membranes, Taufiq Mahsuli, Aisyah Larasati, Aminnudin Aminnudin, Jibril Maulana
Effect Of The Homogenization Process On Titanium Oxide-Reinforced Nanocellulose Composite Membranes, Taufiq Mahsuli, Aisyah Larasati, Aminnudin Aminnudin, Jibril Maulana
Journal of Mechanical Engineering Science and Technology (JMEST)
Indonesian pineapple production can reach 200 tons per day; however, pineapples generate a significant amount of waste. Pineapple peel waste can be used to make membranes. Composite membranes containing TiO2 have dense properties, low porosity, and increase the mechanical strength of the cellulose sheet. This research uses various ultrasonic homogenizers to homogenize the distribution of nanocellulose and TiO2 (50% and 100% power with 30, 60, and 90 minutes). The casting method is used to shape the membrane. The SEM test shows that the higher the power used and the longer the sonication time, the less agglomeration of about 1.63%/ cm2 …
Effect Of Heating Temperature, Holding Time And Stabilization Temperature On The Al-Foam Properties, Dewi Puspitasari, Poppy Puspitasari, Mazli Mustapha, Turnad Lenggo Ginta
Effect Of Heating Temperature, Holding Time And Stabilization Temperature On The Al-Foam Properties, Dewi Puspitasari, Poppy Puspitasari, Mazli Mustapha, Turnad Lenggo Ginta
Journal of Mechanical Engineering Science and Technology (JMEST)
The interest in metallic foam is increasing since their cellular structures have a unique combination of properties such as high stiffness, low density, lightweight, high specific strength, and thermal insulation. Commonly, the performance of metallic foam can be improved by the heat treatment process. However, the previous heat treatment methods still present the brittle crack path and the research on heat treatments of the metal foam properties is very limited. In this study, individual parameters in stress relieving treatment that contribute to Al-Foam properties were investigated. The stress-relieving process of the samples was performed using a vacuum furnace. The composition …
Vertical Shaft Kinetic Turbine Performance Using A Cup-Shape Blade, Kennie A. Lempoy, Nita C. V. Monintja, Arwanto M. A. Lakat
Vertical Shaft Kinetic Turbine Performance Using A Cup-Shape Blade, Kennie A. Lempoy, Nita C. V. Monintja, Arwanto M. A. Lakat
Journal of Mechanical Engineering Science and Technology (JMEST)
The abundant availability of alternative energy sources forms the fundamental foundation for rural energy development. In particular, renewable energy sources are indispensable in rural areas due to their ecofriendly nature and widespread accessibility, which helps preserve the environment by avoiding pollution. Indonesia, a country blessed with vast water resources, especially its rivers, holds enormous potential for harnessing kinetic energy derived from fast-flowing river waters. Effective utilization of this kinetic energy has the potential to address energy shortages in the country. In this context, there is a pressing need to enhance the efficiency of kinetic turbines designed to function as electricity …
Photocatalytic Scheme With External Magnetic Field On Coffee Waste In Hydrogen Production, Abid Fahreza Alphanoda, Eko Prasetyo, Wisnu Broto
Photocatalytic Scheme With External Magnetic Field On Coffee Waste In Hydrogen Production, Abid Fahreza Alphanoda, Eko Prasetyo, Wisnu Broto
Journal of Mechanical Engineering Science and Technology (JMEST)
Photocatalytic is considered a deadlock-breaking technology for renewable energy and lowering environmental pollutants. Photocatalytic efficiency efforts are improved by activating the photocatalyst to introduce an external magnetic field. This review highlights recent breakthroughs by comparing original coffee waste, activation of coffee waste with the addition of catalysts, and manipulation of spin electrons by applying external magnets. Characterization was done with FTIR to look at chemical bonds, UV-Vis with Tauc's Relation approach to measure bandgap, and material morphology using SEM EDX. The increase in photocatalyst activation aligns with the decrease in bandgap value. The rate of decline in bandgap is in …
Artificial Neural Network-Based Modeling Of Performance Spark Ignition Engine Fuelled With Bioethanol And Gasoline, Susi Marianingsih, Farhanna Mar’I, Hendry Y. Nanlohy
Artificial Neural Network-Based Modeling Of Performance Spark Ignition Engine Fuelled With Bioethanol And Gasoline, Susi Marianingsih, Farhanna Mar’I, Hendry Y. Nanlohy
Journal of Mechanical Engineering Science and Technology (JMEST)
Machine learning technology can distinguish the relationship between engine characteristics and performances. Therefore, the goal of the present work is to predict the performance parameters of a singlecylinder 4-stroke gasoline engine at different ignition timings using a blended mixture of gasoline and bioethanol by an artificial neural network (ANN). Experimental data for training and testing in the proposed ANN was obtained at a dynamic speed and full load condition. An ANN model was developed based on standard Back-Propagation algorithm for the spark ignition engine. Multi-layer perception network (MLP) was used for non-linear mapping between the input and output parameters. An …
The Effect Of Adding Aluminium On The Performance Of Zno Nrs/Pani In Their Application As Photoelectrochemical Water Splitting, Eprilia Trikusuma Sari, Nandang Mufti, Anissa Chairani Alfin Nadhira, Hari Wisodo, Markus Diantoro
The Effect Of Adding Aluminium On The Performance Of Zno Nrs/Pani In Their Application As Photoelectrochemical Water Splitting, Eprilia Trikusuma Sari, Nandang Mufti, Anissa Chairani Alfin Nadhira, Hari Wisodo, Markus Diantoro
Journal of Mechanical Engineering Science and Technology (JMEST)
Photoelectrochemical (PEC) is a new renewable energy technology that converts H2O into hydrogen and oxygen gas with the help of sunlight. A photoelectrochemical cell device consists of three main components, one of which is the photoanode. One of the materials that can be used as a photoanode is ZnO which has good electrical properties and is non-toxic. Nanorods-structured ZnO has the advantage of being able to increase light absorption due to its high surface area. However, the resulting performance is still quite low. So it is necessary to make modifications to the photoanode, one of which is by adding aluminium …
Preparation And Lithium Storage Properties Of Carbon Confined Li3Vo4 Nano Materials, Jia-Qi Fan, Huan-Qiao Song, Jia-Ying An, Amantai A-Yi-Da-Na, Mo Chen
Preparation And Lithium Storage Properties Of Carbon Confined Li3Vo4 Nano Materials, Jia-Qi Fan, Huan-Qiao Song, Jia-Ying An, Amantai A-Yi-Da-Na, Mo Chen
Journal of Electrochemistry
Li3VO4, as a promising anode material for lithium ion batteries, has been widely studied because of its low and safe voltage, and large capacity. However, its poor electronic conductivity impedes the practical application of Li3VO4 particularly at high rates. In this paper, carbon confined Li3VO4 nano materials (Li3VO4/C) were synthesized by hydrothermal and solid-phase method, and for comparison, the Li3VO4 (N) nano materials without carbon confinement and Li3VO4 (B) materials were also synthesized by pure solid-phase method. The composition, structure, …
Peg-Water Electrolyte For High-Performance Zinc Iodine Dual-Ion Batteries, Xiao-Feng Qu, Yu-Ting Tang, Xin-Cheng He, Jia-Sheng Zhou, Zi-Heng Tang, Wen-Hua Feng, Jun Liu
Peg-Water Electrolyte For High-Performance Zinc Iodine Dual-Ion Batteries, Xiao-Feng Qu, Yu-Ting Tang, Xin-Cheng He, Jia-Sheng Zhou, Zi-Heng Tang, Wen-Hua Feng, Jun Liu
Journal of Electrochemistry
Thanks to abundant resource and rapid redox reaction kinetics, iodine is regarded as promising positive materials inthe batteries. However, the shuttling effect due to the high solubility of iodine in the electrolyte makes the performance of battery poor. In this paper, polyethylene glycol (PEG400) and potassium iodide were added into zinc-ion aqueous electrolyte. PEG400 could complex with iodine to reduce the dissolution of iodine, therefore alleviating the formation of soluble triiodide (I3–) from iodine and iodide ions. Furthermore, this electrolyte was used in the battery with double carbon cloths as the current collectors, double separators and zinc …
Lif-Sn Composite Modification Layer To Modify Garnet/Lithium Metal Interface, Wu Yang, Xue-Fan Zheng, Yu-Qi Wu, Zheng-Liang Gong
Lif-Sn Composite Modification Layer To Modify Garnet/Lithium Metal Interface, Wu Yang, Xue-Fan Zheng, Yu-Qi Wu, Zheng-Liang Gong
Journal of Electrochemistry
The growing demands for electric vehicles and consumer electronics; as well as the expanding renewable energy storage market; have promoted extensive research on energy storage technologies with low costhigh energy density and safety. Lithium (Li) metal and solid-state electrolytes are considered as important components for next-generation batteries because of their great potential for improvements in energy density and safety performance. Inorganic garnet-type solid electrolytes with high Li-ion conductivity (about 10-3 S·cm-1) and high shear modulus (55 GPa) are considered to be ideal solid-state electrolytes; however; the issue of Li dendrite growth still obstructs their practical application. Herein; …
Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang
Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang
Journal of Electrochemistry
The development of green and sustainable water-splitting hydrogen production technology is beneficial to reducing the over-reliance on fossil fuels and realizing the strategic goal of "carbon neutral". As one of the half reactions for water splitting, oxygen evolution reaction has suffered the problems of sluggish four-electron transfer process and relatively slow reaction kinetics. Therefore, exploring efficient and stable catalysts for oxygen evolution reaction is of critical importance for water-splitting technology. Metal alkoxides are a series of compounds formed by the coordination function of metal ions with alcohol molecules. Metal alkoxides possess the double advantages of organic materials and inorganic materials, …
Study On Performance And Dynamic Response Of Composite Stress Absorber Layer, Yang Sanqiang, Li Pengfei, Liu Lu, Cao Zilong
Study On Performance And Dynamic Response Of Composite Stress Absorber Layer, Yang Sanqiang, Li Pengfei, Liu Lu, Cao Zilong
Journal of China & Foreign Highway
In order to compare the performance difference among the composite stress absorption layer, SBS stress absorption layer, and glass grille stress absorption layer, the dynamic response law of the composite stress absorption layer was explored. In this paper, based on the composite stress absorption layer composed of glass grille + rubber-modified asphalt gravel sealing layer, the UTM-25 test system was employed to carry out inter-layer shear, inter-layer tension, low temperature bending, and four-point fatigue test. By laying test sections and sensors, strain information of the stress absorption layer under different conditions was collected. It was found that the bonding force …
The Effects Of Engineering Summer Camps On Middle And High School Students’ Engineering Interest And Identity Formation: A Multi-Methods Study, Timothy Robinson, Adam Kirn, Jenny Amos, Indira Chatterjee
The Effects Of Engineering Summer Camps On Middle And High School Students’ Engineering Interest And Identity Formation: A Multi-Methods Study, Timothy Robinson, Adam Kirn, Jenny Amos, Indira Chatterjee
Journal of Pre-College Engineering Education Research (J-PEER)
This multi-methods study explores changes in engineering interest and identity of middle and high school students (n = 79) attending introductory-level engineering summer camps at a large western land grant university. Middle school is a critical time when student interest, identity, and subsequently career choice begin to emerge and hence it is important that at this age students are given accurate information about engineering majors in college and future career opportunities in engineering. Data were collected over a period of two years in six summer camps. Three separate populations of middle and high school students participated in the summer …
Pursuing Excitonic Energy Transfer With Programmable Dna-Based Optical Breadboards, Divita Mathur, Sebastián A. Díaz, Niko Hildebrandt, Ryan D. Pensack, Bernard Yurke, Austin Biaggne, Lan Li, Joseph S. Melinger, Mario G. Ancona, William B. Knowlton, Igor L. Medintz
Pursuing Excitonic Energy Transfer With Programmable Dna-Based Optical Breadboards, Divita Mathur, Sebastián A. Díaz, Niko Hildebrandt, Ryan D. Pensack, Bernard Yurke, Austin Biaggne, Lan Li, Joseph S. Melinger, Mario G. Ancona, William B. Knowlton, Igor L. Medintz
Materials Science and Engineering Faculty Publications and Presentations
DNA nanotechnology has now enabled the self-assembly of almost any prescribed 3-dimensional nanoscale structure in large numbers and with high fidelity. These structures are also amenable to site-specific modification with a variety of small molecules ranging from drugs to reporter dyes. Beyond obvious application in biotechnology, such DNA structures are being pursued as programmable nanoscale optical breadboards where multiple different/identical fluorophores can be positioned with sub-nanometer resolution in a manner designed to allow them to engage in multistep excitonic energy-transfer (ET) via Förster resonance energy transfer (FRET) or other related processes. Not only is the ability to create such complex …
Atomistic-Informed And Machine Learning-Assisted Crystal Plasticity Modeling For Materials Interface, Ibrahim Altarabsheh
Atomistic-Informed And Machine Learning-Assisted Crystal Plasticity Modeling For Materials Interface, Ibrahim Altarabsheh
Doctoral Dissertations
This dissertation presents a comprehensive study that addresses two critical challenges in the field of computational materials science and engineering from nano- to mesoscale. First, to overcome the well-acknowledged length scale limitation associated with atomistic simulations, a novel two-step approach is introduced for a probabilistic prediction of stress-strain curves in terms of material volume. The method combines Molecular Dynamics (MD) simulations and a multioutput Gaussian process (MOGP) with Bayesian analysis to model stress-strain behavior and predict stress and strain values. The model effectively captures the intricate three-stage curve shape exhibited in stress-strain plots, discerning key points such as yielding, hardening, …
Carrier Dynamics In Green Iii-Nitride Leds Using Small-Signal Electroluminescence, Xuefeng Li
Carrier Dynamics In Green Iii-Nitride Leds Using Small-Signal Electroluminescence, Xuefeng Li
Optical Science and Engineering ETDs
Solid-state lighting has achieved significant success over the past two decades, but the low quantum efficiency of green LEDs (i.e., the “green gap”) remains a barrier to full red-green-blue (RGB) displays in numerous applications. Combating efficiency reduction in longer-wavelength LEDs requires understanding the relative roles of intrinsic effects (e.g., wave-function overlap, carrier-current density relationship, phase-space filling (PSF)) vs. extrinsic effects (e.g., material degradation due to increased defect density, compositional inhomogeneities, etc.). A systematic study of the carrier dynamics in InGaN/GaN LEDs is very important for understanding the origin of the green gap and for providing solutions to improve the efficiency …
Modeling Hydration Kinetics Of Sustainable Cementitious Binders Using An Advanced Nucleation And Growth Approach, Taihao Han, Jie Huang, Gaurav Sant, Narayanan Neithalath, Ashutosh Goel, Aditya Kumar
Modeling Hydration Kinetics Of Sustainable Cementitious Binders Using An Advanced Nucleation And Growth Approach, Taihao Han, Jie Huang, Gaurav Sant, Narayanan Neithalath, Ashutosh Goel, Aditya Kumar
Electrical and Computer Engineering Faculty Research & Creative Works
Supplementary cementitious materials (SCMs) are utilized to partially substitute Portland cement (PC) in binders, reducing carbon-footprint and maintaining excellent performance. Nonetheless, predicting the hydration kinetics of [PC + SCM] binders is challenging for current analytical models due to the extensive diversity of chemical compositions and molecular structures present in both SCMs and PC. This study develops an advanced phase boundary nucleation and growth (pBNG) model to yield a priori predictions of hydration kinetics—i.e., time-resolved exothermic heat release profiles—of [PC + SCM] binders. The advanced pBNG model integrates artificial intelligence as an add-on, enabling it to accurately simulate hydration kinetics for …
A Computational Approach For Mapping Electrochemical Activity Of Multi-Principal Element Alloys, Jodie A. Yuwono, Xinyu Li, Tyler D. Dolezal, Adib J. Samin, Javen Qinfeng Shi, Zhipeng Li, Nick Birbilis
A Computational Approach For Mapping Electrochemical Activity Of Multi-Principal Element Alloys, Jodie A. Yuwono, Xinyu Li, Tyler D. Dolezal, Adib J. Samin, Javen Qinfeng Shi, Zhipeng Li, Nick Birbilis
Faculty Publications
Multi principal element alloys (MPEAs) comprise an atypical class of metal alloys. MPEAs have been demonstrated to possess several exceptional properties, including, as most relevant to the present study a high corrosion resistance. In the context of MPEA design, the vast number of potential alloying elements and the staggering number of elemental combinations favours a computational alloy design approach. In order to computationally assess the prospective corrosion performance of MPEA, an approach was developed in this study. A density functional theory (DFT) – based Monte Carlo method was used for the development of MPEA ‘structure’; with the AlCrTiV alloy used …
Syntheses, Photophysics, & Application Of Porphyrinic Metal-Organic Frameworks, Zachary L. Magnuson
Syntheses, Photophysics, & Application Of Porphyrinic Metal-Organic Frameworks, Zachary L. Magnuson
USF Tampa Graduate Theses and Dissertations
Porphyrins are a group of heterocyclic macrocycles that play crucial roles in various biological processes such as electron transfer, catalysis, and sensing. Hemoglobin, which carries oxygen in the blood of mammals, and chlorophyll, which drives photosynthesis in plants and algae, are both porphyrins. The ability of porphyrins to bind metal ions and their unique electronic and photophysical properties make them an excellent platform for designing functional materials for various applications, often drawing inspiration from their function in nature. Metal-organic frameworks (MOFs) are a class of porous materials that have been extensively studied in recent years due to their high surface …
Durability Of Cfrp/Steel Bond In Natural Weather, Mastour Alsulami
Durability Of Cfrp/Steel Bond In Natural Weather, Mastour Alsulami
USF Tampa Graduate Theses and Dissertations
Fiber reinforced polymers (FRP) are increasingly being used for infrastructurestrengthening and repair of steel structures. Though there have been several durability studies, exposures used are not representative of outdoor service conditions. Fewer studies have explored the effect of changing outdoor conditions typical in infrastructure use. The goal of the research is addressing this gap by evaluating the performance of commercially available CFRP systems under natural weather characteristic of hot, humid tropical conditions mainly and cold weather secondary in three different locations.
Thirty CFRP/steel joint specimens were prepared in laboratory conditions and exposed to ambient temperature on the Engineering building roofs …
Characterization Analysis And Design Of Mid-Wave Infrared Iii- V-Based Type-Ii Superlattice Nbn Photodetectors For Space Applications, Alexander Timothy Newell
Characterization Analysis And Design Of Mid-Wave Infrared Iii- V-Based Type-Ii Superlattice Nbn Photodetectors For Space Applications, Alexander Timothy Newell
Electrical and Computer Engineering ETDs
The performance of the mid-wave infrared InGaAs/InAsSb nBn photodetector is investigated and its viability for space applications is assessed. Three structures are grown with unique absorber layer doping profiles via molecular beam epitaxy. Material and device characterizations are performed and analyzed to determine the effects of doping on fundamental material parameters and detector performance. Noise-equivalent irradiance is calculated to be a factor of 4x that of an ideal detector exhibiting Rule 07 dark current and 100% quantum efficiency, demonstrating high sensitivity. The structures are then irradiated with 63 MeV protons to evaluate the extent of performance degradation over the course …
Exciton Delocalization In A Fully Synthetic Dna-Templated Bacteriochlorin Dimer, Olga A. Mass, Devan R. Watt, Lance K. Patten, Ryan D. Pensack, Jeunghoon Lee, Daniel B. Turner, Bernard Yurke, William B. Knowlton
Exciton Delocalization In A Fully Synthetic Dna-Templated Bacteriochlorin Dimer, Olga A. Mass, Devan R. Watt, Lance K. Patten, Ryan D. Pensack, Jeunghoon Lee, Daniel B. Turner, Bernard Yurke, William B. Knowlton
Materials Science and Engineering Faculty Publications and Presentations
A bacteriochlorophyll a (Bchla) dimer is a basic functional unit in the LH1 and LH2 photosynthetic pigment–protein antenna complexes of purple bacteria, where an ordered, close arrangement of Bchla pigments—secured by noncovalent bonding to a protein template—enables exciton delocalization at room temperature. Stable and tunable synthetic analogs of this key photosynthetic subunit could lead to facile engineering of exciton-based systems such as in artificial photosynthesis, organic optoelectronics, and molecular quantum computing. Here, using a combination of synthesis and theory, we demonstrate that exciton delocalization can be achieved in a dimer of a synthetic bacteriochlorin (BC …
Effect Of Hf Alloying On Magnetic, Structural, And Magnetostrictive Properties In Feco Films For Magnetoelectric Heterostructure Devices, Thomas Mion, Margo Staruch, Konrad Bussmann, Goran Karapetrov, Olaf Van 'T Erve, Sara Mills, Heonjune Ryou, Ramasis Goswami, Patrick G. Callahan, David J. Rowenhorst, Syed B. Qadri, Samuel Lofland, Peter Finkel
Effect Of Hf Alloying On Magnetic, Structural, And Magnetostrictive Properties In Feco Films For Magnetoelectric Heterostructure Devices, Thomas Mion, Margo Staruch, Konrad Bussmann, Goran Karapetrov, Olaf Van 'T Erve, Sara Mills, Heonjune Ryou, Ramasis Goswami, Patrick G. Callahan, David J. Rowenhorst, Syed B. Qadri, Samuel Lofland, Peter Finkel
College of Science & Mathematics Departmental Research
Materials with high magnetoelectric coupling are attractive for use in engineered multiferroic heterostructures with applications such as ultra-low power magnetic sensors, parametric inductors, and non-volatile random-access memory devices. Iron-cobalt alloys exhibit both high magnetostriction and high saturation magnetization that are required for achieving significantly higher magnetoelectric coupling. We report on sputter-deposited (Fe0.5Co0.5)1-xHfx (x = 0 - 0.14) alloy thin films and the beneficial influence of Hafnium alloying on the magnetic and magnetostrictive properties. We found that co-sputtering Hf results in the realization of the peening mechanism that drives film stress from highly tensile to slightly compressive. Scanning electron microscopy and …