Engineering Commons^™

An Investigation Of The Dissolution Of Hafnium-Free Zirconium In Hydrofluoric Acid And The Effect Of Fluoride Additions, Alfred S. Neiman

Masters Theses

"Hafnium-free zirconium has assumed great importance in commercial use in recent years. When economical methods were developed in 1950 to remove hafnium from Zr, a metal was produced which not only exhibited good corrosion resistance and desirable physical properties, but also had a very low absorption cross section for thermal neutrons. Such a metal could obviously be utilized to advantage as a structural material for nuclear reactors. This application is the most important one for Zr at present.

Good corrosion resistance to most mineral acids is one of the outstanding non-nuclear properties of Zr. Hf-free Zr has good corrosion resistance …

Statistical Analysis Of X-40 (Stellite-31) Production Blends., Edward P. Patterson

Masters Theses

"An investigation was undertaken to statistically analyze the data obtained on X-40 (Stellite 31) production blends which were tested to the requirements of AMS 5382. For our purpose a blend is one or more furnace heats, the shot of which has been thoroughly mixed to produce greater uniformity of product. The mixed shot is charged to the arc furnaces and cast into parts, and test specimens. A great range of test results have been obtained in testing blends, and it was felt that a statistical analysis of a few of the variables might yield information which could be applied toward …

Determination Of Lattice Constants, And Thermal Expansion Coefficients Of Ti₂O₃ And Of Its Solid Solutions With Ti, Tatsuhiko Ejima

Masters Theses

"For the determination of the precise lattice constants of Ti₂O₃, it is very important to use a Ti₂O₃ as pure as possible.

Due to the formation of solid solution with titanium or oxygen, ranging from 32.5 to. 34.5% O₂ by weight in the Ti-O binary system, it is very difficult to get a pure Ti₂O₃ (33.8% O₂ by weight) in the laboratory.

To determine the precise lattice constants of pure Ti₂O₃, therefore, the extrapolation method was used.

This method computes the respective constants for pure Ti₂O₃ from the values obtained With Ti₂O₃-Ti solid solutions by extrapolation. To carry out such …

An Experimental And Theoretical Investigation Of The Preferred Orientation In Deformed And Recrystallized Hafnium, David S. Gould

Doctoral Dissertations

"The research problem, as presented, therefore became two-fold; first to investigate and determine the feasibility of fabrication of hafnium and secondly to study the deformation characteristics of the material in light of the overall study of hexagonal metals aimed at the development of an overall general theory of plastic deformation. This appeared to envolve a study of the operating deformation systems in hafnium and the theoretical and experimental study of the textures resulting from plastic deformation. These were to be analyzed in comparison with the other hexagonal metals.

It became evident immediately that the research techniques which must be evolved …

A Thermodynamic Study Of The Titanium Sulfides, Reinhard Paul Abendroth

Doctoral Dissertations

"The determination of the thermodynamic properties of chemical compounds is in essence an experimental one. The purpose of this investigation was (1) to make an experimental determination of the thermodynamic properties of the titanium sulfides (2) to determine what sulfide phases are present in the titanium-sulfur system (3) to show the relationships between the various phases present"--The Problem, Statement of the Problem, page 3.

Evaluation Of Commercial Titanium Alloys, Robert Loucks

Bachelors Theses and Reports, 1928 - 1970

Uses of titanium and its alloys range from aircraft structures to corrosion-resistance applications. The properties of the metal, including physical metallurgy, naturally dictate the folds of application. The interstitial elements, plus aluminum and tin, preferentially stabilize the alpha phase of titanium.

The Design And Construction Of A Laboratory Model Fluidized Bed Reactor, Godfrey Paul Howard

Bachelors Theses and Reports, 1928 - 1970

Fluidization has become a new and important unit operation in roasting, calcining, and drying ores because of the economy and ease of handling that it affords. Because of these reasons, and since the Montana School of Mines Metallurgical Laboratory does not have an operating model of a fluidized bed reactor, it was decided to design and construct an operating model for future research in the laboratory.

The Effect Of Strontium Sulfate Addition On The Lead Content Of Electrolytic Zinc, Arthur E. Morris

Bachelors Theses and Reports, 1928 - 1970

The production of electrolytic zinc involves the passage of an electric current through an aqueous solution of zinc sulfate and sulfuric acid. While all plants use procedures fundamentally the same, there are principal differences in the acidity of electrolyte, the zinc content of the electrolyte and the current density used.

Streaming Potential Studies, Andrew L. Mular

Bachelors Theses and Reports, 1928 - 1970

The application of streaming potential to mineral-dressing is comparatively recent. Although colloidal chemists, for some time, have been familiar with streaming potential and the electrical double layer, A.M. Gaudin, Richards Professor of mineral-dressing, M.I.T, and D.W. Fuerstenau, his assistant, were the first to publish a series of experiments dealing directly with streaming potential applied to flotation. The apparatus described in this thesis was used by Fuerstenau and was developed by him especially for this type of investigation.

Synthetic Manganese Dioxide Production, Russell Marion Dugdale

Bachelors Theses and Reports, 1928 - 1970

Before World War I the United States procured all of its battery grade manganese dioxide from the Caucasus. Even at this time some experimentation was under way to produce this depolarizing substance synthetically and the experiments were successful to a large extent so that when the ore from the Caucasus was cut off, the necessary material was produced synthetically. The shortage was relieved when a deposit of manganese dioxide was discovered in Montana, which was superior to the ore from the Caucasus.

Production Of Iron, Chromium And Nickel By Amalgam Metallurgy, Richard Earl Westerman

Bachelors Theses and Reports, 1928 - 1970

Certain properties of mercury, such as its affinity for other metals, its high hydrogen overpotential, and its unique liquid state, have made its use desirable for many applications in the fields of physical and process metallurgy. Though considerable research has been done on mercury amalgams, only comparatively recently has it been shown that mercury amalgams follow certain definite laws with regard to phase exchange phenomena and electrochemical properties. It is now possible to predict, with considerable accuracy, the results of amalgam reactions.

The Zone-Refining Of A Lead-Bismuth Alloy, Edward James Westerman

Bachelors Theses and Reports, 1928 - 1970

Zone-refining, the purification of a metallic ingot resulting from the passing over its length of a comparatively short molten zone, has been found useful in the purification of several metallic elements. The impurities present in an elemental metal are often more soluble in the molten zone than in the solid material, and are carried to one end of the bar in the molten zone. This molten-zone movement can be repeated any number of times on a metallic ingot, with the zone always being moved in the same direction.

A Study Of Gas Porosity In Aluminum Casting Alloys Using Radioactive Hydrogen As A Tracer, Osborne Milton

Professional Degree Theses

"A method will be described wherein the absorption of hydrogen by aluminum is evaluated using hydrogen 3 as a tracer element. Results show that hydrogen gas is readily absorbed into the melt when it is injected directly, but is not taken on from the combustion products, that quantities of it are released when the metal freezes, and that the commonly used methods of fluxing with chlorine and nitrogen gas are of value for degassing"--Preface, page iii.

Phase Relationships In The Quaternary System Lime-Titania-Zirconia-Silica, Robert Martin Gruver

Doctoral Dissertations

"The phase compatibility relationships for the quaternary system lime-titania-zirconia-silica have been determined by a solid-phase-reaction technique.

Preliminary division of the system into Alkemade tetrahedra was based on the phases found in samples by X-ray diffraction analysis. These samples covered the entire volume of the tetrahedron in a systematic fashion. When the quaternary system had been divided into regions or compatible phases, an analytical method was used to calculate the phase composition of each sample. The relative amounts of each phase in a sample determined by X-ray analysis were compared with the calculated quantities, and agreement between the two methods verified …

Plastic Mounting Technique For Herbaria, Albert Robinson Jr.

Journal of the Arkansas Academy of Science

No abstract provided.

A Study Of The Deleading Of Zinc Sulfide Concentrates, Larry Leroy Gidley

Masters Theses

"The object of this research was to study the basic principles and optimum conditions for the deleading of commercial zinc sulfide concentrates by sublimation of the lead in the form of a sulfide. Present commercial practice conducts this sublimation in hearth roasters. This research considered only the variables affecting sublimation of the lead sulfide, not the types of applicable equipment, or other possible processes. However, the laboratory conditions were at least partially similar to those that could be obtained in commercial practice"--Object, page 1.

Construction Of A Mechanically Agitated Autoclave, Stephen A. O'Hare

Bachelors Theses and Reports, 1928 - 1970

Since the beginning of World War II a great deal of investigation has been done on the tungsten deposits in the western United States. These deposits are principally composed of scheelite. The scheelite deposits in the western United States are low grade, and disseminated. With the development of nonmetallic flotation methods these vast deposits of scheelite-bearing ores have become a major source of tungsten for the United States, as the high grade ore deposits have become practically depleted.

The Formation Of Zinc Ferrite From Zinc Sulfate And Ferric Oxide, Robert E. Morris

Bachelors Theses and Reports, 1928 - 1970

Samples of zinc sulfate and ferric oxide were roasted for periods of one, two and three hours at temperatures between 750° and 1000°C. The per cent zinc oxide combined, as zinc ferrite, was determined by dissolving the soluble zinc in a ammonium-ammonia chloride solution. Six samples were roasted at 750°C to determine the degree of decomposition of zinc sulfate to zinc oxide and sulfur trioxide.

A Study Of Certain Ferromagnetic Alloys In The System Copper-Manganese-Gallium, Harold L. Coolidge

Bachelors Theses and Reports, 1928 - 1970

Four alloys, with compositions near Cu2MnGa, were heat treated and magnetic measurements were obtained on a ferromagnetic torsion balance. The specimens were also examined microscopically to observe the structure.

Surface Reactivity Of Aliphatic Nitriles On Chalcopyrite And Sphalerite, Gary Mitton

Bachelors Theses and Reports, 1928 - 1970

This thesis reports an investigation concerning the adsorption of aliphatic nitriles by chalcopyrite, activated sphalerite, and unactivated sphalerite. The experimental evidence suggests that abstraction, chelation and re-adsorption may take place. On the basis of the experimental results, an equilibrium-type adsorption hypothesis is proposed.

Leaching, Purification And Precipitation Of Glen Scheelite Concentrates, Harold L. Coolidge

Bachelors Theses and Reports, 1928 - 1970

The leaching, purification and precipitation of the Glen scheelite concentrates were performed to acquaint the student with the equipment and processes involved. The concentrates were obtained through the courtesy of the Minerals Engineering Company. Leaching was carried out in the high-pressure autoclave; whereas the purification and precipitation were carried out in laboratory beakers.

The Properties Of Cold Rolled - Stress Relief Annealed 70-30 Cartridge Brass, Robert F. Hartmann

Professional Degree Theses

"Because of the possible commercial application of the proposed treatment of 70-30 brass, this work was undertaken. In addition, the data resulting from this work will result in a better understanding of the treatment of brass.

The objectives of this work were as follows:

1. Determine if higher strength and better spring properties can be realized from a process for commercial 70-30 cartridge brass wherein the regular recrystallizing anneals between rolling reductions are replaced by stress relief anneals.
2. Determine if it is possible, using the above process, to produce essentially fully recrystallized metal with an average grain size below that usually …

The Experimental Fabrication Of Titanium Magazines For 3 Inch 50 Caliber Twin And Single Gun Mounts, John Marshall Thorp

Professional Degree Theses

"The element titanium was discovered in 1790 by the Reverend William Gregor an Englishman from Cornwall England. Titanium is ninth in abundance or o.62 percent of the total of the elements making up the lithosphere. It is exceeded in amount only by oxygen, silicon, aluminum, iron, magnesium, calcium, sodium and potassium. Titanium is a constituent of practically all crystalline rocks and of sediments derived from them. Its chief mineralogical occurrence is as oxides in such minerals as ilmenite and rutile, which are the chief ores of titanium metal….

The titanium metal used in the project discussed in this thesis was …

A Study Of Titanium Diffusion Coatings By X-Ray Fluorescent Methods, Alan Bernard Burgess

Masters Theses

"As the only previous determinations of the chemical composition of the titanium coatings had been analyses of the average composition of the entire coating, the determination of the variation in chemical composition throughout the coating was suggested. From this information, it was proposed that a better insight might be gained as to the extent and mechanism of diffusion in the coatings. It was also hoped to correlate the results with concurrent work being done on the phases present in the titanium coatings. From this correlation, it might be possible to show which phases are responsible for the desirable properties of …

Deposition Of Titanium By Gaseous Reaction, Louis John Reitsma Jr.

Masters Theses

"Previous investigations undertaken at the Missouri School of Mines and Metallurgy on the deposition of titanium involved the use of fused salt baths, aqueous solutions, and cementation processes. The fused salt baths produced satisfactory coatings on small metal parts. Some difficulty was encountered however, when the coating of large articles was attempted.

For this reason, it was decided to investigate the possibility of titanium deposition by the reaction of a volatile titanium compound with a metal surface. Two different compounds were proposed for investigation, (1) a lower chloride of titanium and (2) an iodide of titanium. The reaction with the …

The Preparation Of Titanium Tetrachloride From Rutile, Nalin Sen

Masters Theses

"In recent years, considerable interest has been shown in the manufacture of titanium metal because of its outstanding properties both physical and chemical. The commercial process for the preparation of metallic titanium, known as the Kroll process, consists essentially of the reduction of titanium tetrachloride with magnesium in an inert atmosphere to produce titanium metal with magnesium chloride as a by-product.

Since, titanium tetrachloride is the basic compound from which to prepare metallic titanium by the Kroll process, much thought has been given to the preparation of titanium tetrachloride from titanium ores such as rutile or ilmenite.

The present work …

A Study Of The Structure Of Titanium Diffusion Coatings On Iron And Steel, Pao-Jen Chao

Masters Theses

"The Problem of the Thesis: A series of experiments have been made in the Metallurgical. Engineering Department of the Missouri School of Mines and Metallurgy for the investigation of titanium diffusion coatings. The technique of applying the titanium diffusion coatings on iron and steel is still in the experimental stage. A few of the physical properties and chemical compositions of such coatings have been determined, but the structures have not yet been extensively studied. As the correlations of the structures and the desirable properties are valuable for improving the quality or titanium diffusion coatings on iron and steel, an investigation …

Nanbo₃ - Batio₃ - Basno₃ Ceramic Dielectrics, William Dean Mckee

Doctoral Dissertations

"A. The Problem.

The purpose of this investigation was to form by ceramic processes a number of compositions in the ternary system NaNbO₃ - BaSnO₃ - BaTiO₃, to determine certain dielectric properties of these, to study them by means or x-ray diffraction, and to determine the extent or correlation possible between the compositional variation of dielectric properties and the x-ray results.

Compositions investigated contained 50 mole percent or less BaSnO₃. Materials and methods of forming were chosen with the intent that the final bodies should be pure oxide compositions as represented in the ternary …

Preparation And Separation Of Metallic Chlorides, Norbert Felix Neumann

Doctoral Dissertations

"The use of chlorine and chlorine compounds as metallurgical reagents has long been known to the metallurgical industry. Recent developments in corrosion resistant metals and alloys as well as new equipment and techniques have led to a revival of chlorine processes. Many of the objections to the use of chlorine in metallurgical operations have been overcome and many are being reconsidered, as evidenced by the new processes in which chlorine and chlorides are the primary reagents. The Betterton process employs chlorine or lead chloride for the dezincing of lead. Ductile zirconium and titanium have been made by reducing their chlorides …

United States Gypsum's Heath Plant, Harold L. Coolidge

Bachelors Theses and Reports, 1928 - 1970

The United States Gypsum Company's Heath plant, which is located at Heath, Montana, is one of forty-six diversified production facilities for the development and production of gypsum products. The Heath plant is located about twelve miles southeast of Lewistown, Montana, and consists of a mine, a mill and a boardplant. The Heath plant was built in 1925 by the Northwestern Gypsum Company.