Engineering Commons^™

Comment On The Nature Of The Disaccommodation In Hcp Co-C Alloys, J. Keiser, Manfred Wuttig

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Polynary Telluride Glasses Containing Silver, H. E. Anthonis, N. J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Pbo Transformation Induced By Water, Charles A. Sorrell

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

The Morphology Of Cellular Precipitation In Aluminum Rich Aluminum-Silver Alloys, Santiago Ibarra Jr.

Doctoral Dissertations

"The morphology of cellular precipitation in Al-29.8wt%Ag alloy has been investigated in bulk specimens by transmission electron microscopy and in solution treated specimens by means of hot stage microscopy. Both cellular and general precipitation were observed to occur simultaneously in quench-aged and isothermally aged alloys. By studying the early stages of precipitation in the hot stage, the mechanism for the growth of cells in Al-Ag alloys was developed. According to this mechanism, the grain boundary allotriomorphs begin to form, the boundary then interacts with the allotriomorphs by bowing, and then either trailing precipitation forms on the allotriomorphs or new lamellae …

Grain Boundary Diffusion In Ionic Crystals, Kulwant Singh Sabharwal

Doctoral Dissertations

"The diffusion of ¹³¹I in single crystals and along the tilt grain boundaries of pure and calcium chloride doped (142±5 ppm) bicrystals of sodium chloride, grown by Czochralski technique, was investigated using a microtome sectioning technique. Results on bulk diffusion in pure NaCl agree well with the results of earlier investigators and are represented by the D=(504 cm²/sec)exp (-2.27 ev/kT). Enhanced diffusion of ¹³¹I is observed along the grain boundaries and the presence of the dopant lowers the grain boundary diffusivity over the entire temperature range of 430ºC - 570ºC studied in the present investigation. Thermal activation and electrical polarization …

Synthesis And Properties Of Cadmium Manganese Ferrites, B. W. Jong

Doctoral Dissertations

"The formation sequence of (Cd,Mn,Fe) (Mn,Fe)₂O₄ from the individual oxides,x CdO + (1-x) MnCO₃ + α-Fe₂O₃,was found by X-Ray diffraction. Cd(Mn,Fe)₂O₄ was formed completely from CdO·Fe₂O₃ and CdO·Fe₂O₄ at 900°C and reacted with MnFe₂O₄ for 0 < x < 0.5 and with α-Fe₂O₃ for 0.5 < x < 1.0 to form a single phase of (Cd,Mn,Fe) (Mn,Fe)₂O₄ at 1150°C. This is the first time that the details involved in the formation sequence of CdMn-ferrite have been shown. A mixture of 0.5 CdO + 0.5 MnCO₃ + α-Fe₂O₃ was calcined at 900°C for 2 hrs forming Cd(Mn,Fe)₂O₄ with no Cd present in the other phases. Sintering was accomplished at 1150°C for 30 minutes forming a single phase of Cd₀.₅Mn₀.₅Fe₂O₄ with a bulk sintered density of 98-99% of the X-Ray density. The rate of changing density followed the relationship, p = K ln t + c, at temperatures between 1050°C and 1300°C. Magnetic properties of CdₓMn₁₋ₓFe₂O₄ were affected by composition x. A relationship, B = gx + h, was found between maximum magnetic flux density B and composition x at room temperature for 0 <̲ x <̲ 0.3. This was rationalized by a modification of Néel's theory. The maximum magnetic flux density decreased with increasing cadmium concentration for 0.3 < x <̲ 0.5. This decrease was attributed to the changing direction of the magnetic moment in the octahedral site sub-lattice according to the superexchange theory. No magnetic properties were observed due to the formation of a compensated antiferromagnetic phase for 0.5 < x <̲ 1.0. Maximum magnetic flux density increased with bulk density, while the coercive force decreased with the grain growth and the initial permeability increased with the bulk density and grain size. A stator core used for a-c electric motor application was formed by pre-sintering at 900⁰C for 2 hrs. Slots were then sawed with a tungsten carbide blade and final sintering was accomplished at 1150⁰C for 1 hr"--Abstract, pages iii-iv.

Effects Of Cr-Plating And Environment On The Cracking Of Low Alloy Steels At High Temperatures, Robert C. Tooke

Doctoral Dissertations

"The cracking of low alloy Cr-Mo-V steels under cyclic stress at 1000-1100°C. was studied using a specially designed test apparatus. The results obtained from specimens plated with hard chromium are compared to those of unplated specimens. Tests conducted in gas mixtures of carbon monoxide and carbon dioxide showed that a high CO/CO₂ ratio retards cracking in both plated and unplated specimens. Both external and internal oxidation are used to explain these results. Inherent microcracks in the hard chromium plating promoted cracking in all CO/CO₂ environments. It was also found that these steels are severely embrittled in the presence …

A Study Of The Solid Regions In The System Zr-Te, Frances Dolores Jenkins

Doctoral Dissertations

"Relative intensity measurements of X-ray powder diffraction lines were made of compositions in the region ZrTe₀.₅ to ZrTe₂.₀, fired between 600º and 817ºC in evacuated sealed tubes. The experimental relative intensities of samples between ZrTe and ZrTe₂ were compared with values calculated for several theoretical models with different Zr vacancy ordering schemes and Te vacancy concentrations. The most probable structural model for compositions in the range ZrTe to ZrTe₁.₅ is one in which the number of Zr vacancies located at z = 0 ranges from 0% to 30%, with the concentration of Te vacancies ranging from 0 to 35%. A …

The Effect Of Impurities And Additives On The Electrowinning Of Zinc, Haruhisa Fukubayashi

Doctoral Dissertations

"The effect of various impurities, commonly found in zinc electro-winning solutions, on the surface morphology of deposited zinc was investigated. Individual additions of the impurities Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, PbO₂ , PbSO₄, and HCl were studied. In a few cases additives of animal glue, gum arabic, and Na₂SiO₃, were used individually or in combination, to determine their effect on the surface structure of the deposited zinc. Comparisons were then made with deposits from a pure electrolyte consisting of H₂SO₄ and Zn⁺², 200 and 65 g/l, respectively. The zinc was deposited on a …

Thermal Expansion Of Tungsten At Low Temperatures, Jayant S. Shah, Martin E. Straumanis

Materials Science and Engineering Faculty Research & Creative Works

Lattice parameters, thermal expansion coefficients, and Grüneisen parameters of tungsten are determined by an x-ray method in the temperature range of 180-40 K without the use of liquid gases. Lattice parameters are expressed as a function of temperature. Thermal-expansion coefficients decrease with temperature and show no anomaly in contrast to a hypothesis proposed by Featherston and Neighbours. Grüneisen parameters γ are decreasing with temperature in accordance with the theoretical predictions. © 1971 The American Institute of Physics.

13th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 13th annual meeting of the Rocky Mountain Spectroscopy Conference, hosted by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 9-10, 1971.

Mechanical Testing Of Small, Clear Timber, Paul V. Mcclannahan

Graduate Research Papers

The purposes of the research project were:

1. To investigate the technological methods employed in mechanical testing of small clear timber.

2. To discover the uses, importance, and need for mechanical testing within the wood industry.

3. To experiment with the construction and development of various types of testing equipment similar to that being used by industry.

4. To explore the possibility of adapting mechanical testing of wood samples to the junior or senior high industrial arts wood laboratory

Direct Design Of A Portal Frame, Angel Fajardo Ugaz

Dissertations and Theses

This investigation was undertaken to develop plastic design aids to be used in the direct design of optimum frames. It uses the concept of minimum weight of plastically designed steel frames, and the concept of linear programming to obtain general solutions. Among the special characteristics of this study are: A. The integration of both gravity and combined loading conditions into one linear programming problem. B. The application of the revised simplex method to the dual of a parametric original problem. C. The application of A and B above in the development of design aids for the optimum design of symmetrical …

On The Interaction Of Aluminium And Iron Calcium Borate Glasses And Its Effect On The Properties Of Their Composites, Sherif K. Arif

Archived Theses and Dissertations

No abstract provided.

Comparative Study Of Lightweight And Normal Weight Concrete In Flexure, Mohammad Zareh

Dissertations and Theses

This investigation represents a comparative study of the flexural behavior of lightweight and normal weight concrete. Both theoretical and experimental moment-curvature characteristics of the tested specimens were used to study the flexural behavior.

A generalized computer program to determine the moment-curvature relationships of a singly reinforced rectangular concrete beam was developed.

For this limited study it was observed that lightweight concrete beams when compared to normal concrete beams achieve comparable moment capacity (about 92% of normal weight concrete) but exhibit higher deflections (about 40% more than normal weight concrete).

The Effect Of Cathodic Protection On The Stress Corrosion Characteristics Of 300m Low Alloy Steel, John Pechonick

Masters Theses

"The objective of this investigation was to determine if stress corrosion failure of 300M steel is accelerated by the application of cathodic protection. Testing was conducted on notch tensile specimens that were coated with vacuum cadmium, electroplated cadmium, and vacuum aluminum. All specimens were stressed and placed in an aqueous sodium chloride environment. The failure times for the specimens were monitored and graphs were drawn which characterized the stress corrosion resistance of 300M steel and the cathodic protection systems. Fractography techniques were used to study the failure surfaces to determine the type of failure mechanism. The results of this thesis …

The Anodic Dissolution Reaction Of Insb: Etch Patterns, Electron Number, Anodic Disintegration, And Film Formation, Martin E. Straumanis, Lih Da Hu

Materials Science and Engineering Faculty Research & Creative Works

The etching behavior of the inverse {111} planes of undoped, semiconducting, n-type, InSb single crystals was explored. Depending upon the etchant, including anodic dissolution, various etch patterns were obtained on the inverse planes. In general, the etch pits on the In{111} plane were round, and the face was shiny, whereas the face of the inverse plane was dark and rough. The rates of dissolution in the electrolytes used were very low, especially in absence of oxidizers. The components dissolve as In3+ and Sb3 +. At current densities above 40 or 60 mA cm-2 (on Sb{111} or In{111}), growth of a …

A Magnetic Aftereffect In Dilute H.C.P. Co-C Alloys, J. R. Keiser, Manfred Wuttig

Materials Science and Engineering Faculty Research & Creative Works

A magnetic Dis accommodation in dilute h.c.p. Co-C alloys has been observed around 90°C. The thermally activated process giving rise to the Dis accommodation is characterized by an activation energy of 26 kcal mole-1 and an attack frequency on the order of 10+13 sec-1. An application of the selection rules shows that the Dis accommodation cannot be caused by the redistribution of tetrahedral or octahedral interstitials or any nearest neighbor interstitial pairs as long as the defects interact linearly with the internal magnetic field. © 1971.

A Study Of The Dislocation Instability And Reverse Martensitic Transformation In Fe-Ni System, Chung Lim

Masters Theses

"Since the martensitic reaction is a strain transformation, the transformation of the lattice structure can be induced by an external stresses. This also means that the macroscopic total elastic constant should decrease as the temperature is lowered to M_s on cooling. For the reverse transformation an anomalous decrease of the elastic constant is to be expected as the temperature increases to A_s on heating. In this experiment measurements of the velocity change of an ultrasonic wave in Fe-Ni alloys were carried out for the reverse martensitic transformation. The deviation from the linear relationship of the velocity change as …

The Pm3m-Fm3m Transformation And Phase Equilibrium In Solid Solutions Of Csc1 With Kc1, Rbc1, And Csbr, John David Weyand

Masters Theses

"Thermal expansion and the Pm3m t Fm3m transition of cesium chloride have been studied with high temperature diffractometry, differential thermal analysis, and heating and quenching techniques. The onset temperature of the transition in pure CsCl, on heating, is 471ºC. There are no observable premonitory effects below the transition temperature and no apparent structural relationships between the polymorphs is apparent. Both phases coexist over a 20º to 50ºC temperature range and equilibrium thermal hysteresis occurs on heating and cooling. Hysteresis behavior is explained by addition of strain energy parameters to the free energy function. Initiation of the Pm3m t Fm3m transformation …

Evaluation Of A Cation Isotopic Substitution Technique In Conjunction With A High Temperature Gas Pycnometer For Determining The Stoichiometry Of Materials, Michael Clair Graves

Masters Theses

"This study was concerned with the evaluation of a high temperature gas pycnometer, used in conjunction with a cation isotopic substitution technique, for determining the stoichiometry of materials. Three methods were investigated for determining the correction factors for the thermal gradient effects in the gas pycnometer. The correction factors were shown to be dependent on the temperature, the sample volume, and the height of the sample in the sample chamber. Under the conditions of these experiments, the correction factors were shown to be essentially independent of sample grain size and pycnometer atmosphere. The determination of the stoichiometry of cadmium oxide …

The Effect Of 15% Mno On The Phase Relations In The System Cao-Feo-Sio₂ At 1450ºc, Aquil Ahmad

Masters Theses

"A study was made of the phase relations at 1450ºC in the systems CaO-FeO-SiO₂ and CaO-FeO-SiO₂ -15% MnO, in equilibrium with metallic iron. The stability region of different phases was determined by microscopic examination and electron-beam microprobe analysis of the quenched specimens. The effect of 15% MnO on the liquid saturation boundary of the system CaO-(FeO+MnO)-SiO₂ was discussed in terms of the effect of MnO on slag making reactions in the Basic Oxygen Furnace steelmaking process"--Abstract, page ii.

Phase Equilibrium And Thermodynamic Study Of Lime-Iron Oxide Solid Solutions, Shin Suk Kang

Masters Theses

"The solubility limits of iron oxide in solid lime were determined as a function of oxygen pressure at 1300º and 1400ºG in the system CaO-iron oxide. The stability region of dicalcium ferrite was determined with respect to formation of lime-iron oxide solid solution and liquid oxide. In addition, the hydration behavior in moist air of pure lime and sintered mixtures of lime and iron oxide was also observed. Pelletized samples were equilibrated under known oxygen partial pressures and quenched. Phases present in the quenched samples were identified by microscopy. The solubility limit of iron oxide in CaO is strongly dependent …

Quenching Defects In Aluminum Plus Ten Atomic Per Cent Zinc, James Thomas Grider

Masters Theses

"This study was undertaken to resolve the conflict which has recently arisen as to the as-quenched microstructure in the Al-Zn system as revealed by thin film transmission electron microscopy. The composition range of most active study has been that from 5 to 15 atomic per cent Zn in superpurity AL. Consequently a composition of 10 atomic per cent Zn was chosen for this study. There are no discontinuties in the phase diagram in this composition range which would influence the above choice. It exists as a single phase solid solution at high temperatures and as a two phase alloy at …

Final Sintering Of Cr₂O₃ With Minor Additions Of Mgo And Sintering Of Mgo With Minor Additions Of Cr₂O₃, Gordon E. Jungquist

Masters Theses

"The effect of oxygen activity on the sintering of Cr₂O₃ with minor additions of MgO, and of MgO with minor additions of Cr₂O₃ at 1600ºC was investigated. A peak density (99.4% of theoretical) was obtained for high purity Cr₂O₃ by maintaining the equilibrium oxygen partial pressure needed to maintain the Cr₂O₃ phase. The addition of 0.1 wt. % MgO increased the sintered density at the same oxygen pressure to 99.8%. Further MgO additions decreased the density. The density of pure MgO was independent of the P_O₂ over the range investigated. Addition of Cr₂O₃ to MgO decreased the density at …

Alkali Mobility And Mechanical Relaxation In Mixed-Alkali Silicate Glasses, James W. Fleming Jr.

Masters Theses

"Internal friction and sodium and potassium self-diffusion coefficients for (1-X)Na₂O · XK₂O· 3SiO₂ glasses were measured. Alkali diffusion was measured between 300 and 500ºC using radioactive isotopes and a thin-sectioning technique. Internal friction was measured from room temperature to 500ºC, 0.1 to 2000 Hz. Comparison between alkali diffusion and internal friction data for Na-K glasses with those for other mixed-alkali glasses shows that the mixed-alkali peak is related to alkali mobility. It is concluded that the mechanism for mixed-alkali internal friction is a cooperative rearrangement of dissimilar alkali ions, with the slower moving ion controlling the rate of reorientation"--Abstract, page …

Electrolytic Reduction Of Zinc From Acidic Sulfate Solutions, Kenneth Dale Gielow

Masters Theses

"Cathode polarization curves were obtained for the electrodeposition of zinc from sulfate solutions with pH 2 and zinc concentrations of 10.0, 40.0, 80.0, and 100.0 gpl zinc. Both pure zinc and pure aluminum were used as cathodes with some difference in results noted. The effect of animal glue additions of 0.01, 0.10, and 0.50 gpl of solution on the cathodic polarization curves and the resulting deposit morphologies were determined. These glue additions correspond to 0.20, 2.0, and 10.0 pounds of glue per ton of zinc deposited, respectively. The slope of the Tafel region of the polarization curves was found to …

A Study Of The Void-Strengthening Of Aluminum And Its Nature, Purushottam G. Manusmare

Masters Theses

"Strengthening of aluminum by formation of the voids and the nature of resultant strengthening, viz., the temperature and the strain rate dependence of its yield strength were studied. Aluminum wires with 99.999% purity and of 3.1 mm diameter were quenched and heat treated to form voids of the approximate density 10¹³-10¹⁴ voids/cm³ and were tested for their yield strength. Voids in selected samples were observed by transmission electron microscopy using the Hitachi HU-11A microscope. The yield strength of the void strengthened samples was measured at various temperatures from 77ºK to 593ºK using two strain rates, 3.33 x 10⁻²/sec and 1.67 …

Factors Affecting The Ductility And Microstructure Of Ti-6al-6v-2sn Titanium Alloy Weldments, Michael John Ball

Masters Theses

"The purpose of the investigation was to study the effect of material thickness, weld heat input and post weld heat treatment on the tensile properties and microstructure of Ti-6Al-6V-2Sn Titanium, and obtain a practical weld/thermal treatment cycle. The objectives were accomplished by electron beam and gas tungsten arc welding 0.060, 0.125 and 0.250 inch thick material and then heat treating at various temperatures and times. Electron beam and gas tungsten arc welding enabled an approximate 4:1 ratio of heat inputs to be utilized. Resultant welded and heat treated material was tensile tested and metallographically examined. Heat treatments involved both air …

Evaporation And Condensation Of Zinc, Shailesh Bhanuprasad Vora

Masters Theses

"Evaporation rates of liquid zinc were determined experimentally within the temperature range of 450º C to 575º C and at argon pressures ranging from 730mm Hg to 130mm Hg. Extrapolated values of these rates are found to be consistent with the previously reported rates obtained by St. Clair and Spendlove at lower pressures. Between 100 microns and one atmosphere pressure rates of evaporation seem to vary according to an equation of the form W = APᴮ, where Pis pressure and, A and B are constants. Similar experiments were performed with brass powders in atmospheres of argon and helium at temperatures …