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21st Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Abstracts and meeting program from the 21st annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, July 30 - August 1, 1979.

Periodate Oxidations Of Aminoglycosides, Araxy M Deronian

Archived Theses and Dissertations

No abstract provided.

A Feasibility Analysis Of A Directly Sun-Pumped Carbon Dioxide Laser In Space, Seiichi Morimoto

Dissertations and Theses

The possibility of using sunlight to pump a CW carbon dioxide laser has been analyzed. Such a laser could be of interest for such applications as space communication and power transmission. In order to optically pump CO₂ using sunlight, the intense vibrational-rotational absorption bands of CO₂ in the 4.3 micron spectral region would have to be utilized. The total pumping power from sunlight can be calculated from the known data of the solar spectral irradiance outside the atmosphere and the infrared absorption by carbon dioxide at 4.3 microns. The pumping power is proportional to the collector area of …

Wood Finishing For Tree Samples Of Five Honduran Species, Amilcar A. Cruz

Graduate Research Papers

This research report will study the application of four wood finishing techniques to samples of each of five species of Honduran hardwood.

These four wood finishing methods are: The varnish-method, the lacquer method, the antiquing method and the oil-rub method. The researcher will attempt to determine which is the best method for each of the five species.

Curing And Flow Of Thermosetting Resins For Composite Materials Pultrusion, Howard L. Price Jr.

Mechanical & Aerospace Engineering Theses & Dissertations

Fibrous composite materials for mechanical and structural applications often are expensive due to high labor costs. One economical way of making composites is pultrusion, a manufacturing process in which resin-impregnated fibers are pulled at a constant speed through a heated die which shapes the resin-fiber mass and cures the resin. Most of the work which has been done on the process has been of an empirical nature, with limited understanding of the process principles. Most of the experience with pultrusion has been gained with polyester resins and glass fibers. Very little experience has been gained with higher performance, more costly …

A Metallurgical Evaluation Of The Mi Vida Prospect: A Mixed Copper Sulfide-Carbonate Ore Body, Sells, Pima County, Arizona, Kevin Michael Kenney

Masters Theses

"A copper-prospect in south-central Arizona has been evaluated on a metallurgical basis. Primary chalcocite and secondary covellite, plus the copper oxides malachite and brochantite, constitute the economic mineralization. The deposit outcrops as a steeply dipping (70°SW), intensely brecciated, copper-bearing quartz vein with discontinuous lenticular ore shoots.

Acid leaching techniques alone and in conjunction with froth flotation utilizing four copper oxide specific collectors were used to evaluate the amenability of this ore to processing. Direct acid leaching was examined and found to be ineffective. Removal of the chalcocite by froth flotation with xanthate was easy and gave better results to subsequent …

Nonlinear Anelasticity And The Martensitic Transformation, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

Zener's model of a standard linear solid is extended to include nonlinearities characteristic of metals and alloys in the vicinity of a martensitic transformation. The equation of motion of a nonlinear anelastic solid is derived and solved using van der Pol's method. The characteristics of the solutions indicate that auto-oscillations of finite amplitude can be excited externally. It is proposed that the streaming oscillations represent the beat between the external excitation and the auto-oscillation. © 1979.

Recovery Of Lead From Lead Smelter Mattes, Cheng-Ping Chang

Masters Theses

"A by-product of lead smelting is a matte which consists mostly of lead and copper sulfides. Experiments were conducted to determine the feasibility of removing lead from molten matte by adding iron as a reducing agent. The effectiveness of iron at 1000 and 1100°C was a function of matte composition, but not of temperature except near iron saturation. The lead content of matte could be decreased to as low as 9.0 to 11.6 wt pct (2.3 to 3.0 at. pct) at 1000°C, depending on composition. The effect of oxygen in the matte on lead recovery from iron-saturated mattes was also …

Pelletizing Of A Lead Sinter Machine Feed, Hung-Yang Tsai

Masters Theses

"A typical lead sinter machine feed can be pelletized in a drum pelletizer using tap water as a binding liquid. The green pellets produced have return sinter as cores, and an outer layer of new material and fluxes. The moisture content of the pellets produced is about 5%. The pelletizing procedure developed used raw materials from the Amax Lead Smelter, with only a minor amount of feed preparation. The importance of proper moisture control, use of binders, method of adding moisture, speed of pelletizing drum, etc. were investigated. The stability of pellets under extreme storage conditions was also determined"--page ii.

Development Of Impervious Low Thermal Expansion Petalite Bodies, Suchinda Chotipanich

Masters Theses

"Impervious petalite bodies were formulated from petalite, lithium aluminosilicate frit and kaolin. Thermal expansion coefficients for selected bodies were less than 2 x 10⁻⁶ /°C(20 - 600 °C). Mineralogy and the reactions in systems containing petalite, lithium aluminosilicate frit and kaolin were observed. Silica-poor high quartz solid solution was found to be the reaction product formed from the reaction between frit and kaolin before conversion to ß-spodumene solid solution at higher temperatures. The crystallization of the ß-spodumene solid solution phases in this system did not occur at the same temperature resulting in variation in the size of the crystallites. The …

Molybdenum Stability In Coal Slags At 1400⁰C: Corrosion Properties For Mhd Electrode Applications., Kenton Brian Wright

Masters Theses

"Molten coal slag corrosion studies conducted on molybdenum at 1400°C used static and stirred slag experiments and electrical current experiments to parallel electrode conditions of slagging duct MHD generators. Crucibles containing molybdenum and slag were exposed to combustion-type gases in a tube furnace. Carbon monoxide-carbon dioxide gas mixtures controlled oxygen partial pressures at selected values between 10^-11 and 10^-3 atm. Metallograph and microprobe examination of polished sample sections defined corrosion characteristics.

At 1400°C, molybdenum metal is stable below 10^-9 atm oxygen pressure. Molybdenum dioxide is stable at higher pressure, but volatile molybdenum trioxides prevent formation of stable …

Boehmite-Bonded High-Alumina Refractories, Gerhard H. Schiroky

Masters Theses

"High-alumina refractories (99+ % Al₂O₃) were produced by pressing a mixture of 70% tabular alumina and 30% reactive alumina and autoclaving in saturated steam at 1.4 MPa (200 psia)/194 °C to 3.4 MPa (500 psia)/242 °C for 12 to 96 h. Autoclaving converted the reactive alumina to boehmite which acted as the bond phase. At room temperature the MOR ranged up to 37 MPa depending upon boehmite content. The hot-MOR decreased steadily with increasing temperature, but was still 8 MPa at 1400 °C which exceeds that of comparable cement-bonded or conventionally fired high-alumina refractories. The estimated autoclaving costs are lower …

Processing Of Copper Refinery Anode Slimes, Shrirang Anant Kulkarni

Masters Theses

"A study of commercial copper refinery anode slimes has been conducted to evaluate the separation of valuable metals contained in the slimes. The slimes contain substantial quantities of Ag, Sn, Au, Pb, and Cu. The values were present principally as AgCl, SnO₂, Au, PbSO₄, Cu and CuSO₄.

A Roast-Leach-Roast-Leach (RLRL) technique solubilized up to 91 pct of the Ag and 99 pct of the Cu from raw slimes.

The Pb-Sn separation was investigated using the following hydrometallurgical techniques: 1) DETA (diethylene triamine) leaching; 2) NaOH leaching; 3) (NH₄)₂CO₃ leaching; …

Thermally Stimulated Polarization Current Technique For Measuring The Electrical Conductivity Of Vitreous Solids, Chi-Ming Hong, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

The electrical conductivity of glasses determined by TSPC agrees well with that measured by conventional ac or dc techniques. The TSPC technique is a rapid and easy method of measuring the dc conductivity over the range 10−15-10−7 (Ω cm)−1 and is especially suited for conductivities <10−12 (Ω cm)−1. Polarization at the electrodes is easily detected and avoided.

Phase Equilibria In Aqueous Magnesium Chloride, Sulfate, Chromate And Phosphate Systems, Ladawan Urwongse

Doctoral Dissertations

"In the first part of the present study, which is presented in Paper I, solubility of MgO in aqueous HCl solutions at 23° ± 3°C was measured and combined with analyses of neat magnesium oxychloride cements to construct an equilibrium phase diagram for the system MgO-MgCl₂-H₂O. Invariant liquids in equilibrium with Mg(OH)₂ and 5Mg(OH)₂·MgCl₂·8H₂O (5.1.8), with 5·1·8 and 3Mg(OH)₂·MgCl₂·8H₂O (3·1·8), and with 3·1·8 and MgCl₂·6H₂O were located at 0.8 ± 0.2 MgO, 17.0 ±0.5 MgCl₂; at 1.0 …

Enhancement Of Pneumatic Nebulization Efficiency Through Application Of An Electric Field, Richard N. Savage, G. M. Hieftje

Materials Engineering

A novel technique is described for reducing the size of aerosol droplets produced by a pneumatic nebulizer of the kind commonly used in flame or plasma spectrometry. The technique involves the application of an electric field to the tip of the nebulizer, resulting in an induced surface charge on the liquid being nebulized. In turn, the surface charge reduces the liquid's surface tension and results in the generation of a finer aerosol. In this study, the effect of the electric field is quantified in terms of the spatial dispersion and size distribution of aerosol droplets formed in the presence and …

20th Annual Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Abstracts and program from the 20th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, August 7-9, 1978.

Numerical Control Milling, Roger Schroeder

Graduate Research Papers

This research paper centers on two general problems:

1) Development of machine angles on the point-to-point NC mill by utilizing different combinations of feed rates on the X and Y axes.

2) Developing a learning activity package which includes a product to be produced by students on the numerical control milling machine that is safe, fast and inexpensive. The experiences gained in this activity will give the students a good working knowledge of numerical control principles.

Structural Design Of Built-Up Plywood Box Beams, Michael J. Sneddon

Graduate Research Papers

The purpose of this study, given the background mentioned above, is to investigate the structural design of built-up plywood box beams and to develop an instructional unit based on their design.

The scope shall be limited to statically determinate beams with either uniformly distributed loads or typical girder loadings.

The resulting instructional unit will be designed as an addition to a course in structural wood design at the vocational-technical/community college level.

Crack Propagation In Aluminum Sheets Reinforced With Boron-Epoxy, George Lawrence Roderick

Mechanical & Aerospace Engineering Theses & Dissertations

The literature has shown that crack propagation in cracked metal sheets can be significantly reduced by bonding an uncracked reinforcement to the metal sheet. However, cyclic debonding typically occurs over a localized area near the crack. Herein, an analysis was developed to predict both the crack growth and debond growth in a reinforced system. The analysis was based on the use of complex variable Green's functions for cracked, isotropic sheets and uncracked, orthotropic sheets to calculate inplane and interlaminar stresses, stress intensities and strain-energy-release rates. An iterative solution was developed that used the stress intensities and strain-energy-release rates to predict …

Studies Of Fracture And Deformed Surfaces Of High Strength Aluminum Alloys By X-Ray Diffraction, Tamma K. Kumar

Mechanical & Aerospace Engineering Theses & Dissertations

X-ray observations of fatigue fracture and deformed surfaces of 7075-T6 aluminum were conducted in this study. The (111) and (222) diffraction peaks were obtained from the fractured and deformed surfaces. It was observed that in comparison with the base metal, the fracture exhibited line broadening similar to that due to cold working. The broadening is indicative of plastic deformation in the vicinity of the advancing crack tip during the fracture process. Also the different regions of fracture exhibited varying degrees of line broadening. With respect to the fatigue crack, the slow crack growth region showed a greater broadening, and, hence, …

Analysis Of Moisture Absorption And Diffusion In Fiber Reinforced Polymeric Resin-Matrix Composite Materials, Stephen Stern Tompkins

Mechanical & Aerospace Engineering Theses & Dissertations

The diffusion of moisture through fiber reinforced polymeric-matrix composite materials has been studied analytically. The diffusion in the orthotropic, nonhomogeneous material was modeled, in detail, with a two-dimensional transient diffusion analysis. An effective diffusivity for the composite was determined in terms of the fiber volume fraction and the resin diffusivity. This effective diffusivity is in better agreement with recent data than those previously determined using less complex models.

The influence of both material and environmental parameters on the moisture content of the composite was determined analytically. Predicted moisture contents were compared over a wide range of values for emittance, solar …

The Effect Of Antimony, Chloride Ion, And Glue On Copper Electrorefining, Thomas J. O'Keefe, L. R. Hurst

Materials Science and Engineering Faculty Research & Creative Works

A study has been made to determine the effect of antimony, chloride ion, and glue on copper electrorefining. All deposits were made at a temperature of 65° C on a titanium cathode. Current densities of 398 A m-2 and 133 A m-2 were used. The deposits were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) to determine morphology and crystal orientation. Atomic absorption (AA) and Auger spectroscopy (AES) were used to study the chemical composition of the deposits and a simple bend test was used to determine structural integrity. It was found that when the antimony concentration in …

Concrete Ships, Mark L. Lavache

Marine Affairs Theses and Major Papers

The incentive behind this study is based on a two-fold premise: 1) that a comprehensive outline of the historical development of concrete shipbuilding and its related technologies is either non-existent or defies discovery, and 2) that although this study is neither based on a hypothesis, nor intended to resolve a problem area or promote a position, its merit lies in its inductive nature. Included are explanations of of the various compositions, uses, and construction techniques relating to reinforced concrete, ferro-cement, and prestressed concrete.

Disk And Strip Forging With Side Surface Foldower: Part 2: Evaluation Of The Upper-Bound Solutions, Ronald A. Kohser, B. Avitzur

Materials Science and Engineering Faculty Research & Creative Works

The upper-bound solutions developed in Part 1 are evaluated with regard to their ability to produce a lower value for required power (load, pressure, or work). Comparisons made with existing solutions such as the triangular field solution and one-zone bulge solution show that for strip, each solution has a domain of geometry and friction in which it is superior. The new solution produces a lower upper-bound for conditions of high interface, friction and relatively thin specimen, the area where fold over is the observed mode of flow. For solid cylindrical disks, the solution fails to improve upon existing analyses, but …

Effect Of Collagen And Chloride Additions On Electrolytic Copper Deposits, William P. Lorenz, Thomas J. O'Keefe, Carlo B. Sonnino

Materials Science and Engineering Faculty Research & Creative Works

The effects of collagen concentration and molecular weight on the morphology and crystal orientation of electrolytic copper deposits have been determined and compared. The effect of chlorides in the presence of collagen on the above properties has also been investigated. Three different molecular weight collagens were studied and the consumption rate of each was determined by chemical analysis of the electrolyte before and after electrodeposition. Two-hour deposits were made in an electrolyte containing the subject collagens in concentrations ranging from 1.2 to 38.4 mg 1-1. Scanning electron and light microscopes and X-ray diffraction were used to evaluate the electrodeposits. © …

An X-Ray Diffraction Analysis Of The Lacro₃-Laalo₃ Solid Solution Series, Robin Ashley Murphy

Masters Theses

"A crystallographic study was made of powders from the LaCr_1-x Al_xO₃, La_.90(Mg_.05 Cr_1-x Al_x )_.95O_2.83 , and La_1±xCrO₃ systems. The relationships between composition and thermal expansion, electrical conductivity, and vaporization were also investigated. The x-ray diffraction data of the LaCrCO₃ - LaAlO₃ compounds showed the system to form a single phase solid solution for any given sample from the series. The orthorhombic to rhombohedral phase transition was depressed to below room temperature at approximately 13% Al⁺³ substitution"--Abstract, page ii.

Discussion, Ronald A. Kohser

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

The Effects Of Certain Impurities And Their Interactions On Zinc Electrowinning, Donald R. Fosnacht

Doctoral Dissertations

“The effects of germanium, antimony, arsenic, cobalt, glue, and free acid concentration were studied on both commercial and synthetic electrolytes. The effects of a single factor and the combined effects of multiple factors were elucidated. The temperature, zinc concentration, and current density were also varied. It was found that the acid concentration was the most critical factor when impurity levels were at normal plant solution concentrations. The ranges where the effect of the impurity became apparent were: greater than 20 ppb for antimony; 40 ppb for germanium; 120 ppb for arsenic; and 7-8 mg/l for cobalt for a solution containing …

Evaluation Of Organic Additives For Use In Zinc Electrowinning, R. C. Kerby, H. E. Jackson, Thomas J. O'Keefe, Yar Ming Wang

Materials Science and Engineering Faculty Research & Creative Works

Organic additives are used extensively in zinc electrowinning to assist in controlling the process. A cyclic voltammetry technique has been developed to provide a rapid, quantitative evaluation of the effectiveness of selected organic additives in minimizing the deleterious effects that impurities, such as antimony, have on zinc deposition. Results have indicated that animal glues are more effective than the other organic additives tested, which included several gums, enzymes, and amino acids, in relation to the current efficiency of zinc production. Of the various animal glues compared in this research, the most effective appeared to have average molecular weights in the …