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Articles 14431 - 14460 of 16696

Full-Text Articles in Engineering

Powder Microelectrode Modified With Nafion-Os(Bpy)3Â 2+ And Pvp Composite And Its Catalysis For No2- Reduction, Pei-Fang Liu, Jia-Wei Yan May 2000

Powder Microelectrode Modified With Nafion-Os(Bpy)3Â 2+ And Pvp Composite And Its Catalysis For No2- Reduction, Pei-Fang Liu, Jia-Wei Yan

Journal of Electrochemistry

The modified powder microelectrode was prepared by etching a Pt (0.1 mm diameter) disk microelectrode and filling in thus formed cavity with Nation-Os(bpy)32+/PVP composite modified carbon powder. The composite modified powder microelectrode showed cyclic voltammetric behaviors changing with the mole ratio (denoted X) of SO3- to Os(bpy)32+ in Nafion. When X=3, a single pair of current peaks appeared near 0.6V (vs. SCE) due to Os(bpy)32+/3+ redox couple. In contrast, for X=20, a pair of additional current peaks occurred near 0.4V. Both X=3 and X=20 modified powder microelectrodes strongly catalyzed the first …

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Technical Investigaton Of Thin-Film Plasticizing Lithium Ion Battery, Xin-Ping Ai, Xin-Lin Hong, Quan-Feng Dong, Sheng-Xian Li, Han-Xi Yang May 2000

Technical Investigaton Of Thin-Film Plasticizing Lithium Ion Battery, Xin-Ping Ai, Xin-Lin Hong, Quan-Feng Dong, Sheng-Xian Li, Han-Xi Yang

Journal of Electrochemistry

A number of polymer materials as candidates of host matrix of plastic polymer electrolyte were examined and techniques for preparation of thin-film electrolyte were reported. The results showed that the polymer electrolyte prepared with P(VDF-HFP) copolymer as host matrix and DBP as plasticizer exhibit the satisfactory mechanical strength and ionic conductivity. In comprison with liquid electrolyte systems, thin-film lithium ion battery has almost similar charge-discharge capacity and cycleability. The manufacture methods and the technical factors in making plasticizing lithium ion battery were also described in details.

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Study On Carbon From Pyrolyzing Phenol-Formaldehyde Resin For The Negative Electrode Of Li-Ion Secondary Battery, Zhi-Yuan Tang, Xin-Guo Zhuang, Yu-Mei Zhai, Jian-Gang Li, Jian-Jun Xue, Chun-Yan Liu May 2000

Study On Carbon From Pyrolyzing Phenol-Formaldehyde Resin For The Negative Electrode Of Li-Ion Secondary Battery, Zhi-Yuan Tang, Xin-Guo Zhuang, Yu-Mei Zhai, Jian-Gang Li, Jian-Jun Xue, Chun-Yan Liu

Journal of Electrochemistry

Li-ion secondary batteries negative electrodes were prepared by low temperature (<1 000 ℃) pyrolysis of commercial phenol-formaldhyde resin. A thermogravimetric analysis (TGA) and an X-ray diffraction (XRD) studies were peoformed for the pyrolytic carbonaceous materials. The results indicated that these samples are amorphous polyacenic structure materials. With increasing pyrolytic temperature, these materials become structurally order, and the first charge-discharge special capacities reduce. The specific capacities base on pyrolytic temperature, involving lithium storage nanometer cavities.

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Preparation And Characteristics Of A Enzyme Electrode Based On Immobilization Of Tyrosinase In Electropolymerized Polypyrrole Film, Liu-Shui Yan, Qia Wei, Cheng-Yi Wang, Rong-Rong Shi, Xiao-Tong Ma May 2000

Preparation And Characteristics Of A Enzyme Electrode Based On Immobilization Of Tyrosinase In Electropolymerized Polypyrrole Film, Liu-Shui Yan, Qia Wei, Cheng-Yi Wang, Rong-Rong Shi, Xiao-Tong Ma

Journal of Electrochemistry

A sensitive and stable amperometric enzyme electrode was constructed, based on the immobilization of tyrosinase in potentiostatically electropolymerized polypyrrole film at a platinum electrode. The influence of pH and potential on immbilization was discussed. SEM micrographs and CV curves of films obtained before and after incorparation of tyrosinase molecular were analyzed and compared each other. The enzyme electrode responds linearly to p-cresol over a concentration range of 5×10 -8 ～1×10-6 mol/L with an optimum pH of 6.6, It exhibited kinetic characteristics of the typical enzyme-catalyzed reaction with an apparent Michaelis constant of 2.2 ×10-5 mol/L.

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An Investigation On The Corrosion Potential Imaging At The Interface Of Concrete/Reinforcing Bar In Corrosion Media, Rong-Zong Hu, Chang-Jian Lin, Xiang Zhou, Jian-Guang Tan, Xiong-Chao Zhao May 2000

An Investigation On The Corrosion Potential Imaging At The Interface Of Concrete/Reinforcing Bar In Corrosion Media, Rong-Zong Hu, Chang-Jian Lin, Xiang Zhou, Jian-Guang Tan, Xiong-Chao Zhao

Journal of Electrochemistry

The iron array electrode covered with concrete as a new electrochemical technique is applied to map the potential imaging and to investigate on the iron electrode corrosion process under concrete: In Cl- solution the corrosion of the iron array electrode covered with concrete had been prevented for a short term since the concrete protection, but the corrosion still occurreed and developed after immersed for a long time. In SO42- solution although the sample had being immersed for a long time and the concrete was possibly broken, the corrosion did not develop. In Cl- solution the corrosion …

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Template Synthesis And Uv-Vis Absorption Spectra Of The Nanowire Arrays Of Cadmium Chalcogenides, Shi-Min Xu, Kuan-Hong Xue, Jing-Lin Kong, Dong-Mei Sun, Yu-Ying Feng, Hai-Yan Lu, Guang-Hou Wang May 2000

Template Synthesis And Uv-Vis Absorption Spectra Of The Nanowire Arrays Of Cadmium Chalcogenides, Shi-Min Xu, Kuan-Hong Xue, Jing-Lin Kong, Dong-Mei Sun, Yu-Ying Feng, Hai-Yan Lu, Guang-Hou Wang

Journal of Electrochemistry

The porous alumina membrane formed in the anodic oxidation of highly pure aluminum foil has attracted a great deal of attention in recent years. It can be served as a desired template to prepare nanometer scale materials due to its unique structure of discrete and cylindrical nanopores, paralleled one another, with the homogeneous size and distribution. Chalcogenide semiconductors have promising prospect in the applications of photovoltaic and photoconducting devices and have been extensively exploited for many years. Olbright and his co-workers studied experimentally and theoretically the optical nonlinearties of CdSxSe1-x-doped glass; Britt and Ferekides reported that …

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Electrochemical Quartz Crystal Microbalance Study On The Promoted Electron Transfer Process At Gold Electrode, Xia-Qin Wu, Zhe-Su Wang, Xiao-Yun Meng, Zong-Rang Zhang May 2000

Electrochemical Quartz Crystal Microbalance Study On The Promoted Electron Transfer Process At Gold Electrode, Xia-Qin Wu, Zhe-Su Wang, Xiao-Yun Meng, Zong-Rang Zhang

Journal of Electrochemistry

The adsorption behavior of amino acids, such as L-cysteine, histidine and arginine at gold-quartz crystal microbalance (Au-QCM) was investigated. The adsorption quantity of cysteine is more appreciable than others because of the stronger interaction between its thiol group and the gold electrode surface. The electron-transfer process of superoxide dismutase (SOD) in presence of cysteine at Au-QCM has also been studied using the electrochemical quartz crystal microbalance (EQCM) technique which reveals clearly the quasi-reversible electron-transfer process accompanied by the frequency shift cycle. The reversible adsorption and disorption processes are discussed.

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Effects Of Temperature On The Proton Diffusion Of Doped Ni(Oh)2, Jian-Hua Liu, Jing-Wu Yang, Zhi-Yuan Tang May 2000

Effects Of Temperature On The Proton Diffusion Of Doped Ni(Oh)2, Jian-Hua Liu, Jing-Wu Yang, Zhi-Yuan Tang

Journal of Electrochemistry

The Chronoamperometry of powder spherical Ni(OH)2 microelectrode was used to study the proton diffusion coefficients of Ni(OH)2. The proton diffusion coeefficients and the apparent diffusion active energy in anode and cathode processes at different temperature were obtained. Compared with pure Ni(OH)2, the apparent diffusion active energy (Ea) of Ni(OH)2 doped with Co and Co + Zn was decreased and the diffusion constant (Do) was increased in the anode and the cathode processes, respectively, the effect of Co was greater. In contrast, for Ni(OH)2 doped with Zn, its Ea …

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Aqueous Processing And Mechanical Properties Of Plzt Green Tapes, Jian-Huei Feng, Fatih Dogan May 2000

Aqueous Processing And Mechanical Properties Of Plzt Green Tapes, Jian-Huei Feng, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Aqueous tape casting of lanthanum-modified lead zirconate titanate (PLZT) was performed using commercial poly (vinyl alcohol) (PVA) binders and various plasticizers. Colloidal properties of PLZT suspensions containing only polyelectrolyte dispersant were characterized by zeta potential, conductivity, and viscosity measurements. The effects of molecular weight as well as chemical structures of plasticizers and binders on green tapes were investigated by tensile testing. The tapes made from low molecular weight plasticizers showed higher plasticity, and glycerol was found to be the most effective plasticizer for PVA. Strong hydrogen bonding in high hydrolysis PVAs led to green tapes with high strength and high …

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Activated Carbon And Process For Making Same, Francis John Derbyshire, Marit Jagtoyen May 2000

Activated Carbon And Process For Making Same, Francis John Derbyshire, Marit Jagtoyen

Chemical and Materials Engineering Faculty Patents

A process is described for the manufacture of activated carbon in the form of a powder, as granules or as extrudates. The process includes treating a biomass feedstock, such as woods, coconut shells, fruit pits, peats, lignites and all ranks of coal with a processing agent and an activation agent. The processing agent may be a natural or synthetic monomer, oligomer, polymer or mixtures thereof capable of interacting or co-polymerizing with the biomass feedstock. The activation agent may be, for example, phosphoric acid, zinc chloride or mixtures thereof. A high surface area, high hardness extruded activated carbon may be produced …

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Longitudinal Cracking Of Concrete Slab In Composite Beams, Talat Fawzi Abu-Amra May 2000

Longitudinal Cracking Of Concrete Slab In Composite Beams, Talat Fawzi Abu-Amra

Archived Theses and Dissertations

No abstract provided.

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One-Dimensional Nature Of The Magnetic Fluctuations In Yba2cu3o6.6, Herbert A. Mook, Pengcheng Dai, Fatih Dogan, Rodney Dale Hunt Apr 2000

One-Dimensional Nature Of The Magnetic Fluctuations In Yba2cu3o6.6, Herbert A. Mook, Pengcheng Dai, Fatih Dogan, Rodney Dale Hunt

Materials Science and Engineering Faculty Research & Creative Works

There is increasing evidence that inhomogeneous distributions of charge and spin—so-called ‘striped phases’—play an important role in determining the properties of the high-temperature superconductors. For example, recent neutron-scattering measurements on the YBa2Cu3O7-x family of materials show both spin and charge fluctuations that are consistent with the striped-phase picture. But the fluctuations associated with a striped phase are expected to be one-dimensional, whereas the magnetic fluctuations observed to date appear to display two-dimensional symmetry. We show here that this apparent two-dimensionality results from measurements on twinned crystals, and that similar measurements on substantially detwinned crystals of …

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Making Large, Single Crystal, 123 Ybco Superconductors, Kay Y. Blohowiak, Darryl F. Garrigus, Thomas S. Luhman, Kevin E. Mccrary, Michael Strasik, Ilhan Aksay, Fatih Dogan, William C. Hicks, Corrie B. Martin Apr 2000

Making Large, Single Crystal, 123 Ybco Superconductors, Kay Y. Blohowiak, Darryl F. Garrigus, Thomas S. Luhman, Kevin E. Mccrary, Michael Strasik, Ilhan Aksay, Fatih Dogan, William C. Hicks, Corrie B. Martin

Materials Science and Engineering Faculty Research & Creative Works

We make large (in excess of 2 cm in diameter), Single crystal YBa-Cu-Oz-123 YBCO crystals, where X ≤ O.6, in a seventeen Step process or Some variant thereof from finely ground and well mixed 123 YBCO and 211 YBCO powders with a Small amount of Pt by controlling the rate of cooling from within a compact of the powders using a temperature gradient in the radial and axial planes (independently) of about 1-1 C./inch diameter of compact to nucleate the crystal growth. We promote crystal growth as well using a Samarium oxide seed crystal, preferably SmBa-Cu-Ozo where y ≤ 1.6. …

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Kinetics Of Laser Chemical Vapor Deposition Of Carbon And Refractory Metals, Feng Gao Apr 2000

Kinetics Of Laser Chemical Vapor Deposition Of Carbon And Refractory Metals, Feng Gao

Doctoral Dissertations

Three-dimensional laser chemical vapor deposition (3D-LCVD) has been used to grow rods of carbon, tungsten, titanium, and hafnium from a variety of hydrocarbons and metal halide-based precursors. A novel computerized 3D-LCVD system was designed and successfully used in the experiments. A focused Nd:Yag laser beam (λ = 1.06 μm) was utilized to locally heat up a substrate to deposition temperature. The rods, which grew along the axis of the laser beam, had a typical diameter of 30–80 μm and a length of about 1 mm. The precursors for carbon deposition were the alkynes: propyne, butyne, pentyne, hexyne, and octyne. Propyne …

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A Comparison Of Quasi-Static Indentation Testing To Low Velocity Impact Testing, Michael J. Douglas Apr 2000

A Comparison Of Quasi-Static Indentation Testing To Low Velocity Impact Testing, Michael J. Douglas

Mechanical & Aerospace Engineering Theses & Dissertations

A static test method for modeling low-velocity foreign object impact events to composites would prove to be very beneficial to researchers since much more data can be obtained from a static test than from an impact test. In order to examine if this is feasible, a series of static indentation and low velocity impact tests were carried out and compared. Square specimens of many sizes and thicknesses were utilized to cover the array of types of low velocity impact events. Laminates with a rt/4 stacking sequence were employed since this is by far the most common type of engineering laminate. …

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Theory Of Sic Schottky Barrier Conduction And Model Analysis For Diode Breakdown With And Without Screw Dislocations, Lifeng Zheng Apr 2000

Theory Of Sic Schottky Barrier Conduction And Model Analysis For Diode Breakdown With And Without Screw Dislocations, Lifeng Zheng

Electrical & Computer Engineering Theses & Dissertations

Silicon Carbide is a very promising candidate for applications in high-power, high-temperature, and high-radiation conditions under which conventional semiconductors cannot perform adequately. However, the SiC processing technology has not yet reached maturity. There is also limited knowledge of its physical and chemical characteristics, and its device behavior is not well understood. The aim of this thesis is to analyze two specific problems in the SiC area. The first issue involves the large discrepancy between experimental I - V characteristics of SiC Schottky diodes and their theoretical values. The observed data, especially at low voltages, is found to be orders of …

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Pulsed Optoacoustics In Solids, Zibiao Wei Apr 2000

Pulsed Optoacoustics In Solids, Zibiao Wei

Electrical & Computer Engineering Theses & Dissertations

Optoacoustic techniques are widely used to probe and characterize target materials including solids, liquids and gases. Included in such applications are diagnoses of thin films and semiconductor materials. The need to obtain greater spatial resolution requires the generation of shorter optoacoustic pulses. For such pulses, non-thermal effects may be quite important. On the other hand, even when an optoacoustic pulse is generated by an initially non-thermal technique, the thermal aspects become important in its evolution and propagation. The research undertaken in this Ph.D. dissertation included the generation and detection of optoacoustic signals through the thermal elastic mechanism. Several applications in …

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Solid-State Deuterium Nuclear Magnetic Resonance Of The Methyl Dynamics Of Poly(Alpha-Methylstyrene) And Polymethylphenylsilane, Robert D. O'Connor, Eric J. Ginsburg, Frank D. Blum Apr 2000

Solid-State Deuterium Nuclear Magnetic Resonance Of The Methyl Dynamics Of Poly(Alpha-Methylstyrene) And Polymethylphenylsilane, Robert D. O'Connor, Eric J. Ginsburg, Frank D. Blum

Chemistry Faculty Research & Creative Works

The methyl-d3 dynamics of two relatively similar polymers, poly(alpha-methylstyrene) (PAMS-d3) and polymethylphenylsilane (PMPS-d3), are investigated via deuterium NMR relaxation experiments. Our analysis of the relaxation data uses the entire solid-echo spectra to maximize the precision of the experiments with regard to the information available on the methyl dynamics. The analysis is novel in that it does not use M[infinity] or M0 to fit the relaxation data. Additionally, the three-site symmetric jump model is shown to not have an observable azimuthal angular dependence for T1 relaxation. The methyl dynamics are quantified with taum, sigma, and f which are the log-average correlation …

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Chemical Mechanical Polishing Optimization For 4h-Sic, Craig L. Neslen Mar 2000

Chemical Mechanical Polishing Optimization For 4h-Sic, Craig L. Neslen

Theses and Dissertations

Scratch free surfaces are required for substrates used in epitaxial growth. Silicon carbide (SiC) is a substrate material that is used in the epitaxial growth of SiC, GaN, and InGaN electronic devices. Preliminary chemical mechanical polishing (CMP) studies of 1 3/8" 4H-SiC wafers were performed in an attempt to identify the polishing parameter values that result in a maximum material removal rate and thus reduce substrate polishing time. Previous studies reported increased material removal rates associated with increasing polishing temperature, slurry pH, pressure, and polishing pad speed. In the current study, the effects of temperature, slurry pH, polishing pressure, and …

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Xafs Study Of The Low-Temperature Tetragonal Phase Of La2−X⁢Bax⁢Cuo4: Disorder, Stripes, And Tc Suppression At X =0.125, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh Mar 2000

Xafs Study Of The Low-Temperature Tetragonal Phase Of La2−X⁢Bax⁢Cuo4: Disorder, Stripes, And Tc Suppression At X =0.125, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh

Materials Science and Engineering Faculty Research & Creative Works

Angular dependent x-ray absorption fine structure (XAFS) measurements of all La, Ba, and Cu sites determined the origin and nature of the intrinsic disorder present in the low temperature tetragonal (LTT) structural ground state of La2−x⁢Bax⁢CuO4 with x =0.125,0.15 at T =10 K. Ba doping induces major local distortions that extend as far as 5 Å from its lattice site. Despite the low Ba content the large distortions significantly affect the XAFS of the majority La and Cu sites. The distribution of the local LTT tilt angle of CuO6 octahedra was directly determined from single …

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A High Energy X-Ray And Neutron Scattering Study Of Iron Phosphate Glasses Containing Uranium, Mevlüt Karabulut, G. K. Marasinghe, C. S. Ray, Y. S. Badyal, M.-L. Saboungi, S. Shastri, D. Haeffner, George Daniel Waddill, D. E. Day Mar 2000

A High Energy X-Ray And Neutron Scattering Study Of Iron Phosphate Glasses Containing Uranium, Mevlüt Karabulut, G. K. Marasinghe, C. S. Ray, Y. S. Badyal, M.-L. Saboungi, S. Shastri, D. Haeffner, George Daniel Waddill, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

The atomic structure of iron phosphate glasses containing uranium has been studied by complementary neutron and x-ray scattering techniques. by combining x-ray and neutron structure factors, detailed information about different pair interactions has been obtained. Most of the basic structural features such as coordination numbers and O-O and P-O distances in uranium containing glasses are the same as those in the base glass of batch composition 40Fe2O3-60P2O5 (mol %). However, the Fe-O distances change slightly with the addition of uranium. The observed structural parameters support a structural model in which the waste elements occupy voids in the Fe-O-P network, hence, …

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Optical Investigation Of Molecular Beam Epitaxy AlXGa1-XN To Determine Material Quality, Judith L. Mcfall Mar 2000

Optical Investigation Of Molecular Beam Epitaxy AlXGa1-XN To Determine Material Quality, Judith L. Mcfall

Theses and Dissertations

The purpose of this research was to determine the quality of AIGaN samples with various mole fractions of aluminum doped with silicon. The samples utilized for this study were composed of an AIN buffer layer sandwiched between the sapphire substrate and AIGaN epilayer grown by molecular beam epitaxy (MBE). Cathodoluminescence (CL) and photoluminescence (PL) were employed to determine the mole fraction of aluminum in each sample. These techniques also gave insight into the material's nonuniformity, defects, and impurities. CL was run at 4 different beam energies (2,5,10, & 15 keV) with four different currents (1,10,50, & 90 µA) for the …

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Mechanics Of A Functionally-Graded Titanium Matrix Composite, G. Brandt Miller Mar 2000

Mechanics Of A Functionally-Graded Titanium Matrix Composite, G. Brandt Miller

Theses and Dissertations

Functionally-graded Titanium Matrix Composites, (F/G TMCs) combine the ideal properties of titanium matrix composites with the more practical machining qualities of monolithic (unreinforced) alloy. This material shows great promise in application to aerospace structural components - even in parts whose design requirements have defied the use of composite materials in the past. Successful implementation of such a material would lead to enhanced aircraft performance. However, the basic properties of a functionally-graded titanium matrix composite need to be investigated. The composite/alloy transition region, or joint area, may be less strong than its constituents and therefore determine the overall performance of the …

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In-Situ Simultaneous Esr And Conductivity Measurements For Polyaniline, Lin Zhuang, Qing Zhou, Jun-Tao Lu Feb 2000

In-Situ Simultaneous Esr And Conductivity Measurements For Polyaniline, Lin Zhuang, Qing Zhou, Jun-Tao Lu

Journal of Electrochemistry

With a new cell design, simultaneous electrochemical ESR and conductance measurements were realized for the first time. The in-situ cell consisted of a dual working electrode, a counter electrode and a reference electrode accommodated in a capillary of 1mm diameter. The dual working electrode was composed of two closely spaced Pt electrodes: a Pt disk electrode (0.5 mm diameter) sealed in a thin glass tube and a Pt layer deposited on the outside wall of the glass tube. The two working electrodes were separated by the glass gap about 20 μm thick. Two potentiostats were used to control electrode potential …

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Cathodic Indirect Electro-Oxidation——Organic Electro-Synthesis Dimethyl Sulfone, Deng-Ping Gu, Rui-Zhi Wang, Hong-Kun Zhang, Xue-Ying Zhang, Wei Li, Bao-Qiu Cui Feb 2000

Cathodic Indirect Electro-Oxidation——Organic Electro-Synthesis Dimethyl Sulfone, Deng-Ping Gu, Rui-Zhi Wang, Hong-Kun Zhang, Xue-Ying Zhang, Wei Li, Bao-Qiu Cui

Journal of Electrochemistry

A cathodic indirect electro-oxidation system was established for indirect electro-oxidize dimethyl sulfoxide to dimethyl sulfone with electro-eduction generated H2O2 catalyzed by the pertungstate/tungstate (WO52-/WO42-) redox mediator. Influences of current density, pH, temperature, and the current efficiencies etc. On the cathodic indirect electro-oxidation of dimethyl sulfone were investigated for determining optimum reaction conditions. The current efficiency reached more than 70%. Mother-liquid could be recycled to use without pollution.

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Effect Of Different Species Of Cobalt Additive On Performance Of Nickel Hydroxide Electrode, Xian-Xia Yuan, Yin-Dong Wang, Feng Zhan Feb 2000

Effect Of Different Species Of Cobalt Additive On Performance Of Nickel Hydroxide Electrode, Xian-Xia Yuan, Yin-Dong Wang, Feng Zhan

Journal of Electrochemistry

Performances of nickel electrodes when adding or without adding Cobalt in different forms were studied, the results were interpreted by cyclic voltammetry(CV) and electrochemical impedance spectroscope (EIS). It was demonstrated that the additions of Co, CoO, CoO+Co by mechanically mixing with Ni(OH)2 all can improve the performance of nickel electrode to some extent, and when Co is added in the form of CoO the best performance can be obtained. This can be mainly attributed to the fact that three kinds of Co additives all improved the structure of nickel hydroxide and the ability of H+ in electrolyte transporting …

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Studies Of Abnormal Infrared Effects Of Nanometer Thin Films Of Transition Metals And Alloys In Acid Solutions, Shi-Gang Sun, Ming-Sen Zheng, Guo-Qiang Lu, Li-Rong Cai, Sheng-Pei Cehn, Xiao-Yin Xiao Feb 2000

Studies Of Abnormal Infrared Effects Of Nanometer Thin Films Of Transition Metals And Alloys In Acid Solutions, Shi-Gang Sun, Ming-Sen Zheng, Guo-Qiang Lu, Li-Rong Cai, Sheng-Pei Cehn, Xiao-Yin Xiao

Journal of Electrochemistry

The adsorption of CO on electrodes of nanometer thin films of transition metals (Pt, Pd, Rh, Ru) and alloys (PtPd, PtRu) prepared under cyclic voltammetric conditions has been studied by in situ FTIR spectroscopy. The abnormal infrared effects (AIREs) have been explored as a novel and general phenomenon. The AIREs consist mainly in the inversion of the direction of IR band and the significant enhancement of IR absorption by adsorbed CO species. It was revealed that the enhanced IR absoroption of adsorbed species in AIREs depends strongly on the nature of metal or alloy, and on the structure and the …

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Investigations Of Lithium Ion Battery Electrolyte Solution, Jing-Li Han, Qing-Guo Liu Feb 2000

Investigations Of Lithium Ion Battery Electrolyte Solution, Jing-Li Han, Qing-Guo Liu

Journal of Electrochemistry

Synthesis and electrochemical investigations of {LiB[(SO3)C6H3(O)(COO)]OC6H5} in EC/DMC or DMSO/PC mixtures are presented.

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Studies Of The Preparation Of Electrodes From Lead Carbonate For Lead-Acid Battery Ⅱ. The Preparation Of Paste Electrodes, Zhong-Xu Dai, Di-Hua Wang, Hao-Hao Ke, Jin-Yun Zou, Yun-Hong Zhou Feb 2000

Studies Of The Preparation Of Electrodes From Lead Carbonate For Lead-Acid Battery Ⅱ. The Preparation Of Paste Electrodes, Zhong-Xu Dai, Di-Hua Wang, Hao-Hao Ke, Jin-Yun Zou, Yun-Hong Zhou

Journal of Electrochemistry

The positive and negative pastes were prepared by mixing PbCO3 and H2SO4 solution as well as relative additives, respectively. The effects of the various formation methods and the charge/discharge conditions on discharge capacity and active material utilization of both electrodes were examined. The results indicate that the performance of the positive electrode formed at 2.0 mA/cm2 is better than that formed at higher current density under the same charge/discharge condition, the PAM utilization reaches 74.4 % under discharging at 2.0 mA/cm2; and the property of the negative electrode formed by unsymmetrical square wave …

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Inhibition Of N,N'-O-Phenylen-Bis(3-Methoxysalicylidenimine) On Copper In Halide Solutions, Hou-Yi Ma, Shen-Hao Chen, Zhen-Lan Quan, Lin Niu, Shu-Lan Li Feb 2000

Inhibition Of N,N'-O-Phenylen-Bis(3-Methoxysalicylidenimine) On Copper In Halide Solutions, Hou-Yi Ma, Shen-Hao Chen, Zhen-Lan Quan, Lin Niu, Shu-Lan Li

Journal of Electrochemistry

Inhibition of N,N'-o-phenylen-bis(3-methoxysalicylidenimine) (V-o-Ph-V) on corrosion and anodic disslution of copper in neutral NaCl and NaBr solutions was investigated in terms of potentiostatic steady-state polarization and A.C. impedance techniques. The inhibition mechanism of V-o-Ph-V to copper corrosion was interpreted in detail by comparing the electrochemical behaviors of copper in halide solutions with or without V-o-Ph-V. Besides, the inhibition effect of self-assembled V-o-Ph-V film on copper corrosion in NaCl was also studied.

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