Engineering Commons^™

Synthesis And Characterization Of Polyaniline And Poly (3-Methylthiophene) As Conducting Polymers, Fatma Khalifa Obaid Dalmouk

Theses

The performance of materials in general depends on their properties. There is a continuous need of new materials to meet the technological revolution that was witnessed by the end of last century. In this work, a new class of materials was synthesized. The host matrix is an Organic Conducting Polymer (OCP) of either poly(3-methylthiophene) (PMT) or poly(aniline) (PAN). The synthesis of OCP is achieved using electrochemical methods of applying constant potential or cyclic voltammetry at a platinum or graphite substrate in an acetonitrile containing tetra-alkyl-ammonium salt. The set up is three-electrode system of a platinum counter electrode and a silver/silver …

Bulk Polymerization And Structure-Property Relationship Of Medical Grade Polyurethane, Mariam Nasser Al-Saedi

Theses

Polyurethanes as biomaterials have been used in the augmentation and repair of the human body with great success. The choice of material for a particular application often hinges on the body's response to the polymer, the mechanical and thermal properties of the polymer and the stoichiometric ratio of active ingredients used in the synthesis.

A large number of polyurethanes used in medical applications are polyester-based and cannot be used in long-term implant applications because they are very susceptible to hydrolysis. Other medical-grade polyurethanes, which are suitable for implants are polyether-based which might to some extent, suffer from environmental stress cracking …

Processing And Optimization Of Natural Fiber Reinforced Composites Using Date Palm Fibers, Khalifa Musabbeh Suwaidan Hamad Al-Kaabi

Theses

During the last twenty years, ecological concerns have resulted in a renewed interest in natural materials. Composite materials usually depend on using man-made fibers as the reinforcing element. The possibility of using natural fibers instead of synthetic fibers is gaining acceptance among users. This work aims to investigate the possibility of extracting natural fibers from date palm trees to be used as reinforcement with polymeric materials. The objective was achieved by characterizing fibers through different chemical, physical and mechanical tests and using different treatment methods in order to modify the fiber properties. Date Palm Fibers (DPF) exhibit a cylindrical shape …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead-Alloys Coolant Systems, Yitung Chen, Jinsuo Zhang, Jichun Li

Transmutation Sciences Materials (TRP)

The goal of the proposed research project is to provide basic understanding of the protective oxide layer behaviors and to develop oxide layer growth models of steels in non-isothermal leadalloys (lead or lead-bismuth eutectic) coolant systems. It is widely recognized that the corrosiveness of the lead-alloys is a critical obstacle and challenge for which it can be safely used or applied in the nuclear coolant systems. Active oxygen control technique can promote the formation of the “self-healing” oxide films on the structural material surface, drastically reducing steel corrosion and coolant contamination. Many experiments of steels exposed to flowing leadalloys have …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV) and Idaho State University (ISU) is to evaluate the feasibility of determining residual stresses of welded, bent (three-point-bend), and cold-worked engineering materials using a new nondestructive technique based on positron annihilation spectroscopy (PAS). The proposed technique is to use γ-rays from a small MeV electron linear accelerator (Linac) to generate positrons inside the test sample via 2 pair production. This method can be used for materials characterization and investigation of defects in thick samples that usually cannot be accomplished by conventional positron technique or other …

Corrosion Research On Rock Bolts And Steel Sets For Sub-Surface Reinforcement Of The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen, Amy J. Smiecinski

Publications (YM)

Corrosion resistance of Yucca Mountain (YM) carbon steel rock bolt (0.44%C) and I-beam steel sets (0.08%C) towards electrochemical/general corrosion, stress corrosion cracking (SCC), and hydrogen embrittlement (HE) susceptibility has been determined using simulated YM waters in this Task 18 for YM site underground repository tunnel support. These findings show the corrosion behavior of these structural support members with and without applied stresses in simulated YM environments. The simulated YM waters were increased in nominal concentrations from Ix to lOOx (three different levels) for electrochemical and other corrosion studies. The effect of temperature, of significance to YM repository, on the corrosion …

Polarized Neutron Measurement Of Magnetic Order In Yba2⁢Cu3⁢O6.45, Herbert A. Mook, Pengcheng Dai, Stephen M. Hayden, Arno Hiess, Sh Lee, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Orbital current order of the d-density-wave type has been postulated to explain the pseudo gap in high temperature superconductors. We have performed neutron scattering experiments to search for this order and show here the results obtained on an YBa_2⁢Cu₃⁢O_6.45 sample using the best neutron spectrometers available. We argue that the data are consistent with a small, largely c-axis-directed moment, found below about 200 K.

Teaching Corporate Culture: An Engineer's Survival Guide, Richard N. Savage

Materials Engineering

The transition from new engineering graduate to successful member of corporate America is a difficult journey. Often the skills required are not part of a student’s traditional undergraduate education. At Cal Poly, we have integrated a new course into our existing Senior Project curriculum which enables students to develop the professional skills necessary to become an effective member of any corporation. Key skills such as communication, problem solving and project management are practiced through active learning techniques. These as well as other topics studied are required for ABET certification. The new course investigates the mission and values that are at …

Studies On Yba2nbo6 And Yba2cu3-Xnbxoy Buffer Layers, S. Sathiraju, R. Wheeler, Paul N. Barnes, T. L. Peterson, Iman Maartense, A. L. Campbell, N. A. Yust, T. J. Haugan, Q. Jia, Paul Arendt, Sharmila M. Mukhopadhyay, S. Vemulakonda

Mechanical and Materials Engineering Faculty Publications

No abstract provided.

Superplasticity In Cast A356 Induced Via Friction Stir Processing, Z. Y. Ma, Rajiv S. Mishra, M. W. Mahoney

Materials Science and Engineering Faculty Research & Creative Works

Super plasticity was investigated in friction stir processed A356 alloy at temperatures of 470-570 °C and initial strain rates of 3x10 -4-1x10-1 s-1. Maximum superplastic elongation of 650% was obtained at 530 °C and an initial strain rate of 1x10-3 s-1 where a maximum strain rate sensitivity of 0.45 was observed. © 2004 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Analysis Of Kancil's Car Knuckle Prototype, Tresna P. Soemardi, Aida Mahmudah

Makara Journal of Technology

Analysis of Kancil’s Knuckle Prototype. The objective of this work is to execute strength analysis of knuckle, which is made from FCD 50, by using static analysis on maximum loading. This maximum loading is obtained from front axle loading calculation on particular operating condition. That is, vehicle is braking while cornering in down hill. From previous vehicle loading calculation, we get a number of loading values on different speed and deceleration. At the end, we get a value of speed and deceleration that guarantee the vehicle safety if it is braking while cornering in down hill. As comparison, loading calculation …

Pid Fuzzy Logic Controller System For Dc Motor Speed Control, H. Samsul Bachri M.

Makara Journal of Technology

PID Fuzzy Logic Controller System for DC Motor Speed Control. A good controller system must have resilience to disturbance and must be able to response quickly and accurately. Problem usually appears when PID controller system was built sensitively hence the system’s respon to the disturbance will yield big overshot/undershot then the possibility of oscillation to be happened is excelsior. When the controller system was built insensitively, the overshot/undershot will be small but the recovery time will be longer. Hybrid controller system could overcome those problems by combining PID control system with fuzzy logic. The main control of this system is …

Anisotropy Of Exchange Stiffness And Its Effect On The Properties Of Magnets, K. D. Belashchenko

Kirill Belashchenko Publications

Using the spin-spiral formulation of the tight-binding linear muffin-tin orbital method, the principal components of the exchange stiffness tensor are calculated for typical hard magnets including tetragonal CoPt-type and hexagonal YCo₅ alloys. The exchange stiffness is strongly anisotropic in all studied alloys. This anisotropy makes the domain wall surface tension anisotropic. Competition between this anisotropic surface tension and magnetostatic energy controls the formation and dynamics of nanoscale domain structures in hard magnets. Anisotropic domain wall bending is described in detail from the general point of view and with application to cellular Sm–Co magnets. It is shown that the repulsive …

Quarternair Cugasete And Cuga0.5in 0.5te2 Thin Films Fabrication Using Flash Evaporation, A. Harsono Soepardjo

Makara Journal of Technology

Quarternair CuGaSeTe and CuGa0.5In 0.5Te2 Thin Films Fabrication Using Flash Evaporation. Quarternair materials CuGaSeTe and CuGa0.5In 0.5Te2 are the basic materials to solar cell fabrication. These materials have high absorption coefficients around 103 – 105 cm-1 and band gap energy in the range of 1-5 eV. In this research, the films were made by flash evaporation method using quarternair powder materials of CuGaSeTe and CuGa0.5In 0.5Te2 to adhere in a glass substrate. After the films were obtained, the properties of these films will be characterized optically and electrically. The lattice parameter of the films and the crystalline film structure were …

Graded Channel Mosfet Simulation With S-Pisces 2b, Hartono Siswono

Makara Journal of Technology

Graded Channel MOSFET simulation with S-Pisces 2B. Graded-Channel Metal-Oxide-Semiconductor Field-effect- Transistor or GCMOSFET is being discussed in this paper. GCMOSFET technology has been developed to meet the growing demand for low power and high performance application. In this paper, it will be shown that, compared to ungraded MOSFET, the GCMOSFET device offers the advantage of significantly higher drive current. The higher drive current is achieved because the effecctive channel length of GCMOSFET is shorter than the ungraded MOSFET’s. From the simulation result with S-PISCES 2B and MATLAB, it can been shown that the ID from GCMOSFET is higher than the …

Construction Of Depth-Structure Shelf-Edge Map For Case Study Of Kujung Formation, East Java Sea, Saifatur Rusli, Suparto Suparto

Makara Journal of Technology

Construction of Depth-Structure Shelf-edge Map for Case Study of Kujung Formation, East Java Sea. In general, reflection seismic method has capability to represent sub-surface in time domain. Seismic cross-section that depicts the formation of sub-surface usually use time domain in the format of TWT (Two Way Times). This due to in the process of seismic data acquisition, seismic wave propagates in down-going and up-going manner so that the obtained results from data processing are in the format of TWT seismic vs. shot points. This paper will describe the construction of depth-structure map for case study of Kujung Formation, East Java …

High Temperature Heat Exchanger Project: Quarterly Progress Report January 1, 2004 Through March 31, 2004, University Of Nevada, Las Vegas. Research Foundation, Robert F. D. Perret

Publications (NSTD)

Mutually satisfactory language has been developed to permit signing of a subcontract between the General Atomics Corporation and the UNLV Research Foundation. The contract is signed.

Metal Superplasticity Enhancement And Forming Process, Rajiv S. Mishra, Murray W. Mahoney

Materials Science and Engineering Faculty Research & Creative Works

A shaped metallic component is formed by friction stirring at least a segment of a single piece of bulk metal to impart superplasticity thereto and thereby yield a single superplastic metal blank from the single piece of bulk metal. The metal blank is then deformed by a metal deformation process such as forging, rolling, drawing, bending, extruding, gas forming, punching, and stamping.

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Iii Third Quarterly Report, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for superconducting cavities. The need for very clean surfaces lead to the use of a buffered chemical polishing produce for surface cleaning to get good performance of the cavities. The third phase concludes the experimental a fluid flow study and optimization study. The first quarter and second quarter of phase three also begins the experimental set-up of secondary emission studies from niobium in superconducting mode. This …

Bioactive Materials, D. E. Day, Erik M. Erbe, Marina Richard, Joshua A. Wojcik

Materials Science and Engineering Faculty Research & Creative Works

Bioactive substantially silica-free glass material with a hydroxyapatite layer thereon is described, as well as methods for producing hydroxyapatite on a borate glass.

Monotonic, Creep-Rupture, And Fatigue Behavior Of Carbon Fiber Reinforced Silicon Carbide (C/Sic) At An Elevated Temperature, John M. Engesser

Theses and Dissertations

The main objective of this research effort was to examine the impact that cyclic loading frequency has on the life of a C/SiC composite at an elevated temperature of 550°C. Cyclic loading of C/SiC was investigated at frequencies of 375 Hz, 10 Hz, 1 Hz, and 0.1 Hz. Creep-Rupture tests and tests that were combinations of creep-rupture and fatigue were also accomplished. A monotonic tensile test was performed at 550°C and compared to a room temperature monotonic test. This study showed that an elevated temperature of 550°C has very little effect on the Ultimate Tensile Strength (UTS) of C/SiC. The …

Method Of Making Wood-Based Composite Board, Laurent Malanda Matuana, Julia A. King

Michigan Tech Patents

A wood composite board or panel, such as particleboard, fiberboard, oriented strand board or waferboard and a method of producing the same. The composite board or panel comprises a plurality of wood pieces, thermoset resin to bind the wood pieces and a filler having a high thermal conductivity. Examples of such a filler include natural and synthetic graphites, metal, carbon, silicon carbide and other similar compounds and their mixtures.

Optical Characterization And Modeling Of Compositionally Matched Indium Arsenide-Antimonide Bulk And Multiple Quantum Well Semiconductors, Scott C. Phillips

Theses and Dissertations

Indium arsenide-antimonide (InAsSb) semiconductors have been determined to emit in the 3-5 micrometer range, the window of interest for countermeasures against infrared electro-optical threats. This experiment set out to cross the bulk to quantum well characterization barrier by optically characterizing two sets of compositionally matched type I quantum well and bulk well material samples. Absorption measurements determined the band gap energy of the bulk samples and the first allowed subband transition for the quantum wells. By collecting absorption spectra at different temperatures, the trend of the energy transitions was described by fitting a Varshni equation to them. The expected result …

Experimental And Computational Analysis Of Modes In A Partially Constrained Plate, Robert M. Vandawaker

Theses and Dissertations

The field of structural health monitoring (SHM) attempts to reduce labor and cost by allowing technicians to monitor selected properties of an aircraft's structure to detect impending failure. This research examines methods to detect damage to a thermal protection system (TPS) tile using representative 2024-T3 aluminum plates. Plates are subjected to modal analysis in single and joined conditions in an attempt to provide the capability of sensing damage to a tile on the surface of a vehicle while the sensors remain on the superstructure of the airframe. Jointly, the development of a means to model the system using finite element …

Continue Stress Corrosion Cracking/ Electrochemical Testing And Model Support, L. G. Mcmillion, K. S. Raja, S. Namjoshi, Amy J. Smiecinski

Publications (YM)

The work reported here is focused on measuring values for various model parameters for the General Corrosion Model (GCM). The objective of the UNR work is to obtain the parameter values under Quality Assurance protocols, so that the data can be incorporated into models that might be used to address licensing issues, for example. The derived kinetic parameters may be used in models for predicting the accumulation of general and localized corrosion damage to Alloy-22 canisters over the 10,000-year lifetime of the YM repository. The work focuses on obtaining data of the highest possible accuracy to derive kinetic parameters for …

Annealing-Induced Full Amorphization In A Multicomponent Metallic Film, J. P. Chu, C. T. Liu, T. Mahalingam, S. F. Wang, Matthew O'Keefe, Benedict Y. Johnson, C. H. Kuo

Materials Science and Engineering Faculty Research & Creative Works

We present direct experimental evidence that controllable amorphization and nanocrystallization during annealing of metastable films could serve as a precursor for exciting nanomaterials. The interesting discovery is that certain sputtered crystalline films become completely amorphous when annealed in the temperature range between the glass temperature and the crystallization temperature. Unlike other metallic glassy materials that exhibit annealing-induced devitrification, our good glass-forming films are transformed into various nanoscale and amorphous structures due to the annealing process. The formation of an amorphous phase gives rise to notable alterations in the electrical and mechanical properties of the film.

Stress Corrosion Cracking Studies, K. S. Raja, S. Namjoshi, Amy J. Smiecinski

Publications (YM)

This document reports on the activities for Task 17 of the U.S. DOE/UCCSN Cooperative Agreement Number DE-FC28-98NV12081. There are three subtasks in this Task, the experimental results, discussions, and conclusions of which are presented in the following sections. Data Sources and Electronic Data Control The Data Identification numbers for the data, graphs, and tables in this report, as submitted to the Data Management Database, are tabulated below. The table also includes the source files for the said data as well as the corresponding scientific notebooks where the data can be found. All data in the Q section of the report …

The Evaluation Of The Damping Characteristics Of A Hard Coating On Titanium, Christopher M. Blackwell

Theses and Dissertations

Engine failures due to fatigue have cost the Air Force an estimated $400 million dollars per year over the past two decades (Garrison, 2001). Damping treatments capable of reducing the internal stresses of fan and turbine blades to levels where fatigue is less likely to occur have the potential for reducing cost while enhancing reliability. This research evaluates the damping characteristics of magnesium aluminate spinel, MgO+Al₂O₃, (mag spinel) on titanium plates. The material and aspect ratio were chosen to approximate the low aspect ratio blades found in military gas turbine fans. The plates were tested with …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: First Quarterly Report 01/12/04-02/29/04, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the TRP proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

Progress In Research For Biofuel Cell, Yue Bao, Xia-Qin Wu

Journal of Electrochemistry

In this article, research progresses of the biofuel cell in recent years were summarized. The operation principle and classification of the biofuel cells were described. The role of the mediator for promoting electron transfer in biofuel cells and the techniques for improving the electric properties of biofuel cells, such as output potential, were discussed with some attracting research instances. Finally, the choke points for research of biofuel cell were explored, and the application prospect of biofuel cells was forecasted.