Engineering Commons^™

3d Printing Of Stainless Steel For Engineering Applications, Michael Doyle

Undergraduate Research Symposium

3-D metal printing has the potential to solve problems in the medical, prototyping, automotive, aerospace, defense, and other engineering industries. To reach the potential of any manufacturing process, the final product’s material characteristics and how the process affects those characteristics must be understood to meet the demands of industrial applications. There is a gap in standard testing information regarding metal based 3-D metal printing processes. The purpose of this research is to fill that gap of valuable information for this manufacturing process, so that its principles can be used to design better products. Fundamental tensile and compression tests were executed …

Magnetic Shape Memory Micro-Pump For Intra-Cranial Drug Delivery, Sam Barker, Eric Rhoads, Andrew Morrison, Miranda Buttram, Paul Lindquist

College of Engineering Presentations

Magnetic shape-memory alloys exhibit strong magneto-structural coupling enabling large magnetic-field-induced deformation. Local control of twinning via variable inhomogeneous magnetic fields initiates local reversible deformation. Previous work produced a valve-less micropump consisting of a Ni-Mn-Ga single crystal, a casing, and a rod magnet. The micropump successfully pumped fluid in opposite directions when the magnet was turned clockwise and counter clockwise. Our current work modifies this micropump for application in rat a head stage, which would simultaneously monitor electroencephalograph data and deliver 0.5-5.0 μl of a drug solution at 100-500 nl/min directly to the rat’s brain. These improvements and the application of …

Molecular Modification Of Cnt Junctions, Kari Mclaughlin*, Hanna Meinikheim*, Angela "Nikki" Chang

College of Arts and Sciences Presentations

Carbon nanotube networks (CNNs) are increasingly finding applications as thin film transistors (TFTs), integrated circuits, and display drivers on flexible, transparent substrates. This is attributed to the higher carrier mobility of CNNs as compared to amorphous silicon and organic TFTs [1,2]. However, high electrical [3-5] and thermal [6,7] resistances at individual nanotube junctions (NJs) limit the performance of CNN devices. The resistances of the junctions are no less than an order of magnitude higher than those of individual carbon nanotubes (CNTs). This causes high power dissipation at the NJs. In the end this causes degradation of the overall device performance …

The Properties And Structure Of Zinc Magnesium Phosphate Glasses, Charmayne E. Smith (Lonergan), Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Zn-Mg-phosphate (ZMP) glasses, including those with the nominal molar compositions (50 - x)ZnO xMgO 50P₂O₅ (0 ≥ x ≥ 50) and (60 - y)ZnO yMgO 40P₂O₅(0 ≥ y ≥ 60), were prepared and properties such as density, refractive index, coefficient of thermal expansion and glass transition temperature (Tg), were measured. The glass transition temperature increases by 100-150 C and the room temperature dissolution rates in water decrease by 1-2 orders of magnitude when MgO replaces ZnO while maintaining a constant P₂O₅ content. Glass structures were characterized by Raman spectroscopy and …

Effect Of Ionic Crosslinking On The Swelling And Mechanical Response Of Model Superabsorbent Polymer Hydrogels For Internally Cured Concrete, Qian Zhu, Christopher W. Barney, Kendra Erk

School of Materials Engineering Faculty Publications

The chemical and physical structure-property relationships of model superabsorbent polymer (SAP) hydrogels were characterized with respect to swelling behavior and mechanical properties in different ionic solutions (Na+, Ca2+, and Al3+). The model hydrogels were composed of poly(sodium acrylate-acrylamide) (PANa-PAM) copolymer with varying concentrations of PANa (0, 17, 33, 67, and 83 wt.%) and covalent crosslinking densities of 1, 1.5, and 2 wt.%. By synthesizing the hydrogels in-house, systems with independently tunable amounts of covalent crosslinking and anionic functional groups were created, allowing for the relative effects of covalent and ionic crosslinking on the properties of the hydrogels to be directly …

Simulation Of The Relaxation Potential Profile Of An Ac-Dc-Ac Test, Kerry N. Allahar, Michael F. Hurley, Erik D. Sapper, Darryl P. Butt

Materials Science and Engineering Faculty Publications and Presentations

The relaxation period of the accelerated ac-dc-ac test for coatings is associated with the transient electrochemistry that occurs when the immersed coated system is allowed to return to a stable open-circuit condition after being subjected to a cathodic potential. A mathematical model of the transient electrochemistry that occurs during this relaxation period is presented for coated aluminum. Expressions for the corrosion potential and corrosion current as functions of the local pH at the metal-coating interface were developed using reported experimental results. These expressions enabled the simulation of the transient electrochemistry under the constraint of balanced anodic and cathodic current densities. …

Oxidation Kinetics Of Nicrofer-6025ht For Use In Elevated Temperature Electrochemical Devices, Tyler Cook, Alan Meier, Ph.D.

TECHxpo

Recent advances in high temperature electrochemical devices have prompted research into potential materials for component fabrication.

Processing And Characterization Of Zr-Based Metallic Glass By Laser Direct Depositon, Heehun Bae

Open Access Theses

Bulk Metallic Glass has become famous for its exceptional mechanical and corrosion properties. Especially, Zirconium has been the prominent constituent in Bulk Metallic Glass due to its superior glass forming ability, the ability to form amorphous phase with low cooling rate, thereby giving advantages in structural applications.

In this study, Zirconium powder was alloyed with Aluminum, Nickel and Copper powder at an atomic ratio of 65:10:10:15, respectively. Using the ball milling process to mix the powders, Zr65 Al10 Ni 10 Cu15 amorphous structure was manufactured by laser direct deposition.

Laser power and laser scanning speed were optimized to increase the …

Shear Rheological Characterization Of Gel Healing Response And Construction Of Rheo-Piv System, Abhishek Deepak Bawiskar

Open Access Theses

Thermo-reversible gels are solvent-filled 3D networks of polymer chains interconnected by physical (transient) crosslinks. On applying a high shear stress, the crosslinks are broken and these gels show a typical stress-strain behavior due to cohesive fracture of the gel. When heated above a critical temperature and cooled back to room temperature, all the crosslinks are re-formed. Interestingly, partial to full recovery of broken crosslinks is also observed by simply letting the gel stand at room temperature. In this study, the fracture and healing behavior of a model acrylic triblock copolymer gel has been characterized by shear rheometry. A mathematical model …

Effect Of Multivalent Ions On The Swelling And Mechanical Behavior Of Superabsorbent Polymers (Saps) For Mitigation Of Mortar Autogenous Shrinkage, Qian Zhu

Open Access Theses

The chemical and physical structure-property relationships of model superabsorbent polymer (SAP) hydrogels were characterized with respect to swelling behavior and mechanical properties in different ionic solutions (Na+ , Ca2+ , and Al3+ ). The model hydrogels were composed of poly(sodium acrylate-acrylamide) (PANa-PAM) copolymer with varying concentrations of PANa (0, 17, 33, 67, and 83 wt.%) and covalent crosslinking densities of 1, 1.5, and 2 wt.%. By synthesizing the hydrogels in-house, systems with independently tunable amounts of covalent crosslinking and anionic functional groups were created, allowing for the relative effects of covalent and ionic crosslinking on the properties of the hydrogels …

Design Of A Uv Curing Cartridge For 3d Inkjet Printing, Richard Wiswell

Thinking Matters Symposium Archive

In printing multi-layer electronic circuits, each layer must be formed as a continuous pattern in high resolution from ink jetted liquid droplets and be in precise alignment with the other layers, precluding substrate removal for UV curing. This research seeks to determine the optimal method for in-situ UV curing of the ink jetted material in a single pass. The inkjet replacement cartridge designed for this purpose was constructed of aluminum, fit into the printer head assembly in good alignment with the other ink cartridges, and contained a UV LED for in-situ curing and a cooling fan to maintain safe operating …

Section Abstracts: Astronomy, Mathematics, And Physics With Materials Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics, and Physics with Materials Science Section for the 92nd Annual Meeting of the Virginia Academy of Science, May 13-15, 2014, Virginia Commonwealth University, Richmond, Virginia

Examining The Freezing And Thawing Behavior Of Concretes With Improved Performance Through Internal Curing And Other Methods, Wesley A. Jones

Open Access Theses

Internally cured (IC) concrete has been emerging over the last decade as an effective way to improve the performance of concrete. IC holds promise for producing concretes with an increased resistance to early-age cracking and ultimately enhancing the durability of structures. It is a simple and effective way to ensure proper hydration of cementitious material in high performance concrete mixtures; mixtures in which traditional, external, curing can be ineffective. IC supplies water that is necessary to relieve stress buildup from chemical shrinkage and in turn helping to prevent early age shrinkage cracking.^ The first part of this thesis presents and …

Microstructural Indicators Of Transition Mechanisms In Time-Dependent Fatigue Crack Growth In Nickel Base Superalloys, Ann Elizabeth Heeter

Open Access Theses

Gas turbine engines are an important part of power generation in modern society, especially in the field of aerospace. Aerospace engines are design to last approximately 30 years and the engine components must be designed to survive for the life of the engine or to be replaced at regular intervals to ensure consumer safety. Fatigue crack growth analysis is a vital component of design for an aerospace component. Crack growth modeling and design methods date back to an origin around 1950 with a high rate of accuracy. The new generation of aerospace engines is designed to be efficient as possible …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Detailed Finite Element Analysis And Preliminary Study Of The Effects Of Friction And Fastener Pre-Tension On The Mechanical Behavior Of Fastened Built-Up Members, Francisco Javier Bonachera Martin

Open Access Theses

The characterization of fatigue resistance is one of the main concerns in structural engineering, a concern that is particularly important in the evaluation of existing bridge members designed or erected before the development of fatigue design provisions. The ability of a structural member to develop alternate load paths after the failure of a component is known as member-level or internal redundancy. In fastened built-up members, these alternate load paths are affected by the combination of fastener pre-tension and friction between the structural member components in contact. In this study, a finite element methodology to model and analyze riveted and bolted …

Blast Energy Mitigation In Porous Rocks, Brittany Corinne Essink

Open Access Theses

Geo-materials are commonly used and sought after for blast mitigation applications due to their wide availability and low cost compared to industry trademarked materials. Characterization of these natural geo-materials such as volcanic rocks is of paramount importance in determining their blast mitigation capabilities. While there is a large amount of information available for materials such as concrete or sand blasts, information on the properties of volcanic rocks is far more scarce. This lack of data is due to the wide range of existing natural volcanic rocks and the variation in the minerals and pore structures of the rocks.

In this …

The Effect Of Zephyr Layer Orientation On Zephyrboard Made From Oil Palm Petiole, Lusita Wardani, Muhamad Yusram Massijaya, Yusuf Sudo Hadi, I Wayan Darmawan

Makara Journal of Technology

It is very important to utilize oil palm petiole for the production of zephyr boards. This study aimed to analyze the effect of layer orientation on zephyr board quality. Zephyr boards were made with three coating patterns (A = cross perpendicular, B= combine A and C, and C= paralell) and five zephyr layers using urea formaldehyde adhesive. They were pressed for 20 min at a pressure of 25 kgf/cm² and a temperature 120 ºC, to a target density of 0.80 g/cm³ and a size of 300 mm X 300 mm X 12 mm. Our results showed that the physical and …

Synthesis And Characterization Of Soy-Based Polyurethane Foam With Utilization Of Ethylene Glycol In Polyol, Flora Elvistia Firdaus

Makara Journal of Technology

The use of vegetable oils on replacing petroleum has attracted attention of many researchers. The chemical structure of vegetable oils are different from petrochemicals, so the structure of soybean oil has to be chemically modified through its unsaturated fatty acid chain in triglyceride. A two step process was conducted for the preparation of soy-polyol in designated temperatures; 50 °C, 60 °C, and 70 °C. Ethylene glycol (EG) as co-reagent was taking part in soy-polyol synthesis, and the soy-polyol was used as a sole polyol for polyurethane synthesis. Referred to the previous study, the existence of EG in polyurethane synthesis can …

Performances Of Free-Space Optical Communication System Over Strong Turbulence, Ucuk Darusalam, Purnomo Sidi Priambodo, Harry Sudibyo, Eko Tjipto Rahardjo

Makara Journal of Technology

We report an experimental of free-space optical communication (FSOC) system that use tube propagation simulator (TPS) as the turbulence medium. The FSOC system use wavelength of 1550 nm at the rate transmission of 1000 Mbps and amplified with EDFA at the output of +23 dBm. Index structure of 10-15–10-13 as the representation of atmosphere index turbulences are used for simulation of intensity distribution model or scintillation. The simulation use gammagamma and K model as well. The beam wave propagation models used in simulation are plane wave, spherical wave and Gaussian wave. Spherical wave achieves highest performance via gamma-gamma in strong …

Dynamic Characteristic Identification Of Seismic-Excited Multi-Story Buildings Through Response-Only Technique, Agung Budipriyanto, Priyo Suprobo

Makara Journal of Technology

Identifying dynamic characteristics of civil engineering structures is still a challenging task. It intends to assess behavior of the structures under time-dependent loads. This paper discusses a methodology suitable for identifying the characteristics of multi-story buildings using only their measured response under earthquake ground excitations. Appropriateness of technique used for structural identification was corroborated through coherence of the structure’s responses. The methodology was applied for identifying the characteristics of 14-story and 20-story office buildings located in a high seismic region. Responses of these two buildings recorded during three different seismic ground motions were investigated. The buildings’ response spectral densities and …

Preparations Of Nanostructured Silicide Bundles And Oxide Arrays, Hirokazu Tatsuoka, Wen Li, Erchao Meng, Daisuke Ishikwa, Kaito Nakane, Shingo Oda, Tomoji Matsushita, Natsuki Kurebayashi

Makara Journal of Technology

A variety of nanostructured silicide bundles and oxide nanowire arrays with abundant, non-toxic materials we are prepared. The CrSi2 nanowire and Mg2Si/MgO composite nanowire bundles were synthesized using a Si substrate and a SiOx nanofiber bundle, respectively. The hexagonal MoSi2 nanosheet bundles were also synthesized using a MoS2 layered material as a template. In addition, ZnO, CuO/Cu2O and a-Fe2O3 nanowire arrays were prepared on semiconductor or metallic substrates. The growth phenomena and the structural properties of the nanostructured materials awere investigated. In addition, the preparations of axial and radial nanowire structures weare examined.

Bioethanol Production From Iles-Iles And Sorghum Starch As Raw Materials (Effect Of Cacl 2 Addition And Saccharification Time), Kusmiyati Kusmiyati, Ali Mahmudi

Makara Journal of Technology

Bioethanol produced from agricultural sources is one alternative energy that has been developed to substitute for petroleum. However, the use of food sources such as corn and cassava to produce bioethanol still face obstacles that lead to the scarcity of food and an increase in food prices. The aim of this study was to produce bioethanol from sorghum and iles-iles, which are not used by humans as food, especially in Indonesia. For both materials, the variables studied were saccharification time (4, 8, 24, and 48 h) and concentration of CaCl2 added to the liquefaction slurry (0, 100, 200, 300, and …

Performance Evaluation Of An Optimized Floating Breakwater In Oblique Waves With A Higher-Order Boundary Element Method, Faisal Mahmuddin, Masashi Kashiwagi

Makara Journal of Technology

In the previous study, the optimal performance of a two-dimensional (2D) floating breakwater shape was obtained. The performance of this shape was also confirmed with a model experiment in a towing tank. Moreover, the shape’s performance in three dimensions (3D) was investigated in a subsequent study. However, to predict the shape’s performance in a real application more accurately, the shape’s characteristics in oblique waves must also be evaluated. In this study, the performance and characteristics of the model (hydrodynamic forces, body motions, wave elevations, and drift forces) are computed using a higher-order boundary element method (HOBEM). The HOBEM, which is …

Synthesis Of Nanolaminate Structures Of Alternating Layers Of Lead Telluride And Lead Selenide By Atomic Layer Deposition For Thermoelectric Applications, Arun Deepak Ramalingom Pillai

Electrical & Computer Engineering Theses & Dissertations

Alloys composed of lead, telluride and selenide compounds exhibit very high figure of merit ZT values at intermediate temperatures, making them exceptional thermoelectric materials in a particular temperature range. Advancement in thermoelectric devices and applications hinges on increasing ZT, which is a ratio of the thermoelectric power factor to the thermal conductivity. One of the proposed avenues to achieving this goal is the use of low dimensional structures such as quantum wells, quantum dots, superlattices (SL) and nanolaminates to affect heat transport. SL structures can effectively confine charge carriers as well as scatter phonons which contribute significantly to thermal conductivity. …

Functionalization Of Carbon Nanotube Yarn By Acid Treatment, Heath E. Misak, Ramazan Asmatulu, Mat O'Malley, Emil Jurak, Shankar Mall

Faculty Publications

Carbon nanotube (CNT) yarn was functionalized using sulfuric and nitric acid solutions in 3:1 volumetric ratio. Successful functionalization of CNT yarn with carboxyl and hydroxyl groups (e.g., COOH, COO–, OH, etc.) was confirmed by attenuated total reflectance spectroscopy. X-ray diffraction revealed no significant change to the atomic in-plane alignment in the CNTs; however, the coherent length along the diameter was significantly reduced during functionalization. A morphology change of wavy extensions protruding from the surface was observed after the functionalization treatment. The force required to fracture the yarn remained the same after the functionalization process; however, the linear density was increased …

Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews

Center for Applied Energy Research Faculty and Staff Publications

CO₂ capture and recycle using microalgae was demonstrated at a coal-fired power plant (Duke Energy’s East Bend Station, Kentucky). Using an in-house designed closed loop, vertical tube photobioreactor, Scenedesmus acutus was cultured using flue gas as the CO₂ source. Algae productivity of 39 g/(m² day) in June–July was achieved at significant scale (18,000 L), while average daily productivity slightly in excess of 10 g/(m² day) was demonstrated in the month of December. A protocol for low-cost algae harvesting and dewatering was developed, and the conversion of algal lipids—extracted from the harvested biomass—to diesel-range hydrocarbons via catalytic …

Investigation Of The High-Temperature Redox Chemistry Of Sr2Fe1.5Mo0.5O6-Δ Via In Situ Neutron Diffraction, Daniel E. Bugaris, Jason P. Hodges, Ashfia Hug, W. Michael Chance, Andreas Heyden, Fanglin Chen, Hans-Conrad Zur Loye

Faculty Publications

Crystallographic structural changes were investigated for Sr₂Fe_1.5Mo_0.5O_6−δ, an electrode material for symmetric solid oxide fuel cells. The samples of this material were heated and cooled in wet hydrogen and wet oxygen atmospheres, to simulate the reducing and oxidizing conditions experienced under actual fuel cell operating conditions, and their structures and oxygen contents were determined using in situ powder neutron diffraction. The existence of a reversible tetragonal to cubic phase transition was established to occur between room temperature and 400 °C, both on heating and cooling in either oxygen or hydrogen. The …

Porous Nanocomposites With Integrated Internal Domains: Application To Separation Membranes, Wenle Li, John Y. Walz

Chemical and Materials Engineering Faculty Publications

Asymmetric membranes with layered structure have made significant achievements due to their balanced properties and multi-functionalities that come from a combination of multiple layers. However, issues such as delamination and substructure resistance are generated by the intrinsic layered structure. Here, we present a strategy to integrate the traditional layered structure into an asymmetric but continuous porous network. Through infiltrations of microparticles and nanoparticles to targeted regions, active domains are created inside the porous scaffold versus having them applied externally. The fabricated internal active domains are highly adjustable in terms of its dimensions, pore size, and materials. We demonstrate that it …

Mos2 Functionalization For Ultra-Thin Atomic Layer Deposited Dielectrics, Angelica Azcatl, Stephen Mcdonnell, Santosh Kc, Xin Peng, Hong Dong, Xiaoye Qin, Rafik Addou, Greg Mordi, Ning Lu, Jiyoung Kim, Moon Kim, Kyeongjae Cho, Robert Wallace

Faculty Publications

The effect of room temperature ultraviolet-ozone (UV-O3) exposure of MoS2 on the uniformity of subsequent atomic layer deposition of Al2O3 is investigated. It is found that a UV-O3 pre-treatment removes adsorbed carbon contamination from the MoS2 surface and also functionalizes the MoS2 surface through the formation of a weak sulfur-oxygen bond without any evidence of molybdenum-sulfur bond disruption. This is supported by first principles density functional theory calculations which show that oxygen bonded to a surface sulfur atom while the sulfur is simultaneously back-bonded to three molybdenum atoms is a thermodynamically favorable configuration. The adsorbed oxygen increases the reactivity of …