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Full-Text Articles in Engineering

A New Design Method For Vanadium Redox Batteries In Renewable Energy Systems, Casey Gibson, Karla G. Morrissey Unversity Of Arkansas, Fayetteville Jan 2015

A New Design Method For Vanadium Redox Batteries In Renewable Energy Systems, Casey Gibson, Karla G. Morrissey Unversity Of Arkansas, Fayetteville

Inquiry: The University of Arkansas Undergraduate Research Journal

This study investigated the behavior of vanadium redox flow batteries (VRFBs), which are batteries capable of easily switching between charging and discharging modes, making them a suitable option for storing intermittent sources of alternative energies (solar, wind, etc). Since different sizes of the battery provide varying voltages, optimal parameters for a particular home are key for implementation. These parameters, specifically the cell and tank volumes of the battery that are capable of providing consistent on-load voltage, were determined using data from a 13 kW solar array and a medium-sized house. Charge/discharge current values were used to run a mathematical model …


Sustainability And Economic Analysis Of Propylene Carbonate And Polypropylene Carbonate Production Processes Using Co2 And Propylene Oxide, Yaşar Demirel Jan 2015

Sustainability And Economic Analysis Of Propylene Carbonate And Polypropylene Carbonate Production Processes Using Co2 And Propylene Oxide, Yaşar Demirel

Yaşar Demirel Publications

Currently, the industrially important polycarbonates are synthesized from bisphenol A and diphenyl carbonate, which are highly toxic and hence other feasible alternatives are preferable. Following the considerable advances on the catalyst for the synthesis of carbonates from CO2 and propylene oxide (PO), industrial scale processes for the productions of propylene carbonate (PC) and polypropylene carbonate (PPC) have been designed and simulated with sustainability and economic analyses. The CO2 is supplied by a nearby bioethanol plant, while the PO from a petrochemical process. The first part of the study is for the production of 200 million lb/year cyclic PC …


Nebraska Water Center Annual Report 2015, Nebraska Water Center Jan 2015

Nebraska Water Center Annual Report 2015, Nebraska Water Center

Nebraska Water Center: Administrative Materials

Contents

Foreword 4

The Nebraska Water Center: Leadership in Research, Education and Communication 6

Director’s Letter 8

For More Than 50 years: The Nebraska Water Center 10

Helping Build the Future 11

Nebraska Water Center Advisory Board 14

Water Resources Advisory Panel: A key to success 15

Information for Our Clients and the Public 16

Primary Goals 18

USGS 104b Projects 20

Dvorak, Ray Aim at Improving Water Quality for Small Communities 20

October Retreat at UNK 24

Public Water Lectures 25

2015 Special Seminars 26

2015 Water Symposium and Water Law Conference 28

Water Tour Visits Republican River Basin …


Romania's Participation To The European Assessment Project Titled Hyunder, Multi-Criterial Analyses Of Salt Cavern Locations, Ioan Iordache, Dorin Schitea, Adriana Marinoiu, Mihaela Buga, Mihai Balan, Ioan Stefanescu, Adrian Gheorghe, Mihaela Iordache, Viviana Cigolotti (Ed.), Chiara Barchiesi (Ed.), Michela Chianella (Ed.) Jan 2015

Romania's Participation To The European Assessment Project Titled Hyunder, Multi-Criterial Analyses Of Salt Cavern Locations, Ioan Iordache, Dorin Schitea, Adriana Marinoiu, Mihaela Buga, Mihai Balan, Ioan Stefanescu, Adrian Gheorghe, Mihaela Iordache, Viviana Cigolotti (Ed.), Chiara Barchiesi (Ed.), Michela Chianella (Ed.)

Engineering Management & Systems Engineering Faculty Publications

The scope of the work is to assess the potential, the actors and relevant business cases for large scale storage of renewable electricity by hydrogen underground storage in Romania. This presentation intends to provide a picture of the multi-criterial analyses of salt cavern locations in Romania.

The energy sector is facing with the necessity to store large energy quantities for short to long term in order to adapt to the increasingly intermittent renewable energy. The results of this presentation have originated from an ongoing European assessment project by the name of HyUnder (FCH JU, grant 303417) regarding utilization of salt …


Applying The Analytic Hierarchy Process To Oil Sands Environmental Compliance Risk Management, Izak Johannes Roux Jan 2015

Applying The Analytic Hierarchy Process To Oil Sands Environmental Compliance Risk Management, Izak Johannes Roux

Walden Dissertations and Doctoral Studies

Oil companies in Alberta, Canada, invested $32 billion on new oil sands projects in 2013. Despite the size of this investment, there is a demonstrable deficiency in the uniformity and understanding of environmental legislation requirements that manifest into increased project compliance risks. This descriptive study developed 2 prioritized lists of environmental regulatory compliance risks and mitigation strategies and used multi-criteria decision theory for its theoretical framework. Information from compiled lists of environmental compliance risks and mitigation strategies was used to generate a specialized pairwise survey, which was piloted by 5 subject matter experts (SMEs). The survey was validated by a …


Functional Characterization Of Green Sorption Media And Scaling Of Pilot Studies For Copper Removal In Stormwater Runoff, Cameron Houmann Jan 2015

Functional Characterization Of Green Sorption Media And Scaling Of Pilot Studies For Copper Removal In Stormwater Runoff, Cameron Houmann

Electronic Theses and Dissertations

Green adsorption media with the inclusion of renewable and recycled materials can be applied as a stormwater best management practice for copper removal. A green adsorption media mixture composed of recycled tire chunk, expanded clay aggregate, and coconut coir was physicochemically evaluated for its potential use in an upflow media filter. The results found that the use of the green adsorption media mixture in isolation or the coconut coir with an expanded clay filtration chamber could be an effective and reliable stormwater best management practice for copper removal. A suite of tests were conducted on the media mixture and the …


Bromide Removal From Surface Waters By Silver Impregnated Activated Carbon, Chen Chen Jan 2015

Bromide Removal From Surface Waters By Silver Impregnated Activated Carbon, Chen Chen

All Theses

Bromide is a precursor of disinfection by-products (DBPs) during potable water treatment, because it causes the formation of brominated DBPs that are more cyto- and geno-toxic than their chlorinated analogues. Due to the potential health risks of DBPs, the United States Environmental Protection Agency (USEPA) has been imposing increasingly stringent regulations for controlling the DBPs. Therefore, removal of bromide ions from source waters becomes critical for controlling the DBPs formation. In my study, it was hypothesized that silver impregnated activated carbon (SIAC) can be a promising adsorbent for bromide removal from water. The main research objectives of this study were …


A Computational Study Of A Photovoltaic Compound Parabolic Concentrator, William M. Vance Jan 2015

A Computational Study Of A Photovoltaic Compound Parabolic Concentrator, William M. Vance

Browse all Theses and Dissertations

Routines have been written and added to the Wright State developed solar system simulation program called Solar_PVHFC to model incident solar radiation for a compound parabolic concentrator (CPC) that uses solar panels (photovoltaic panels) to produce electrical energy. Solar_PVHFC is a program that models a solar energy system composed of solar panels to produce electricity from the sun, hydrogen storage tanks to chemically store the energy produced by the solar panels, and fuel cells to convert between electrical and chemical energy when required. Solar_PVHFC features several adjustable parameters to model a solar panel, hydrogen storage, and fuel cell system. Now …


Differences In Waste Generation, Waste Composition, And Source Separation Across Three Waste Districts In A New York Suburb, Omkar Aphale, Krista L. Thyberg, David J. Tonjes Jan 2015

Differences In Waste Generation, Waste Composition, And Source Separation Across Three Waste Districts In A New York Suburb, Omkar Aphale, Krista L. Thyberg, David J. Tonjes

Technology & Society Faculty Publications

Six tonnes of discards and recyclables from three waste districts in a New York suburb were sorted in 2012. The districts were chosen because one had a higher recycling percentage, one had median performance, and one was a low performing district. ASTM standards were followed for the waste composition sorting. The results showed, as expected, that the waste district with the highest recycling rate appeared to have the highest separation efficiencies, leading to greater amounts of recyclable materials being source separated. The waste districts also had different overall waste generation, both in terms of the amounts of wastes generated, and …


A Management Framework For Municipal Solid Waste Systems And Its Application To Food Waste Prevention, Krista L. Thyberg, David J. Tonjes Jan 2015

A Management Framework For Municipal Solid Waste Systems And Its Application To Food Waste Prevention, Krista L. Thyberg, David J. Tonjes

Technology & Society Faculty Publications

Waste management is a complex task involving numerous waste fractions, a range of technological treatment options, and many outputs that are circulated back to society. A systematic, interdisciplinary systems management framework was developed to facilitate the planning, implementation, and maintenance of sustainable waste systems. It aims not to replace existing decision-making approaches, but rather to enable their integration to allow for inclusion of overall sustainability concerns and address the complexity of solid waste management. The framework defines key considerations for system design, steps for performance monitoring, and approaches for facilitating continual system improvements. It was developed by critically examining the …


Quantification Of Food Waste Disposal In The United States: A Meta-Analysis, Krista L. Thyberg, David J. Tonjes, Jessica Gurevitch Jan 2015

Quantification Of Food Waste Disposal In The United States: A Meta-Analysis, Krista L. Thyberg, David J. Tonjes, Jessica Gurevitch

Technology & Society Faculty Publications

Food waste has major consequences for social, nutritional, economic, and environmental issues, and yet the amount of food waste disposed in the U.S. has not been accurately quantified. We introduce the transparent and repeatable methods of meta-analysis and systematic reviewing to determine how much food is discarded in the U.S., and to determine if specific factors drive increased disposal. The aggregate proportion of food waste in U.S. municipal solid waste from 1995 to 2013 was found to be 0.147 (95% CI 0.137-0.157) of total waste, which is lower than that estimated by USEPA for the same period (0.176). The proportion …


Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Rachel Levine, Yun Zhang, J. Brett Sallach Jan 2015

Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Rachel Levine, Yun Zhang, J. Brett Sallach

Nebraska Water Center: Faculty Publications

A total of 43 papers published in 2014 were reviewed ranging from detailed descriptions of analytical methods, to fate and occurrence studies, to measuring and predicting biological effects for a wide variety of emerging contaminants likely to occur in agricultural environments. New methods and studies on veterinary pharmaceuticals, natural and synthetics steroids, and antibiotic resistance genes in agricultural environments continue to expand our knowledge base on the occurrence and potential impacts of these compounds. This review is divided into the following sections: Introduction, Analytical Methods, Occurrence and Fate, Antibiotic Resistance Genes, and Risk Assessment.


Analysis Of Carbon Policies For Electricity Networks With High Penetration Of Green Generation, Felipe Feijoo Jan 2015

Analysis Of Carbon Policies For Electricity Networks With High Penetration Of Green Generation, Felipe Feijoo

USF Tampa Graduate Theses and Dissertations

In recent decades, climate change has become one of the most crucial challenges for humanity. Climate change has a direct correlation with global warming, caused mainly by the green house gas emissions (GHG). The Environmental Protection Agency in the U.S. (EPA) attributes carbon dioxide to account for approximately 82\% of the GHG emissions. Unfortunately, the energy sector is the main producer of carbon dioxide, with China and the U.S. as the highest emitters. Therefore, there is a strong (positive) correlation between energy production, global warming, and climate change. Stringent carbon emissions reduction targets have been established in order to reduce …


Processing And Property Evaluation Of Tungsten-Based Mixed Oxides For Photovoltaics And Optoelectronics, Mirella Vargas Jan 2015

Processing And Property Evaluation Of Tungsten-Based Mixed Oxides For Photovoltaics And Optoelectronics, Mirella Vargas

Open Access Theses & Dissertations

Tungsten Oxide (WO3) films and low-dimensional structures have proven to be promising candidates in the fields of photonics and electronics. WO3 is a well-established n-type semiconductor characterized by unique electrochromic behavior, an ideal optical band gap that permits transparency over a wide spectral range, and high chemical integrity. The plethora of diverse properties endow WO3 to be highly effective in applications related to electrochromism, gas sensing, and deriving economical energy. Compared to the bulk films, a materials system involving WO3 and a related species (elements or metal oxides) offer the opportunity to tailor the electrochromic response, and an overall enhancement …


Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke Jan 2015

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …


Learning By Doing - Energy Systems Management, Nima Shahriari, Adrian V. Gheorghe Jan 2015

Learning By Doing - Energy Systems Management, Nima Shahriari, Adrian V. Gheorghe

Engineering Management & Systems Engineering Faculty Publications

Climate change concerns have confronted energy policy makers by unprecedented challenges in the 21st century. Revolution of renewable energy technologies, as well as more efficient energy systems, has been promising in the context of global warming. However, these technologies are not maturing and chaning. Consequently planning for development of these resources requires dealing with various multidisciplinary research questions such as financial feasibility of renewable energy projects. Nevertheless, there is considerable lack of education programs offering multidisciplinary approach for addressing the current energy challenges. Based on the 21st evolving energy landscape, an interdisciplinary graduate certificate course work was designed at Old …


Dispersion Modeling Of Nitrogen Dioxide (No2) And Fine Particulate Matter (Pm2.5) From Backup Generators At Data Centers In Prineville, Oregon, Brooke E. Harmon Jan 2015

Dispersion Modeling Of Nitrogen Dioxide (No2) And Fine Particulate Matter (Pm2.5) From Backup Generators At Data Centers In Prineville, Oregon, Brooke E. Harmon

Civil and Environmental Engineering Master's Project Reports

As our society becomes increasingly dependent on digital communication (e.g., social media and email) and computerized storage (e.g., digitized medical records and government documents), tech giants such as Google, Facebook, and Apple are constructing and managing an increasing number of massive Internet data centers. These data centers house a network’s most critical systems and are vital to the continuity of daily operations. Requiring as much electricity as a medium size city, data centers rely on complex auxiliary power systems to prevent disruption to service. These backup systems consist of tens of multi-megawatt diesel-powered generators that release combustion byproducts, including over …


Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch Jan 2015

Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch

Theses and Dissertations--Biosystems and Agricultural Engineering

Surface mining is a commonly used method for extracting coal in the Appalachian Coalfields of the U.S. This mining practice produces excess spoil or overburden, which is often placed in adjacent valleys resulting in the creation of valley fills. These valley fills bury headwater streams, which in turn can negatively impact downstream ecosystems. In 2008, the University of Kentucky designed and constructed 1,020 m of ephemeral, intermittent and headwater streams on an existing valley fill (Guy Cove) as a proof-of-concept. The goal of the project was to evaluate whether or not a stream recreation could occur on mined lands, particularly …


Mathematical Modeling For Platform-Based Product Configuration Considering Total Life-Cycle Sustainability, Tian Lan Jan 2015

Mathematical Modeling For Platform-Based Product Configuration Considering Total Life-Cycle Sustainability, Tian Lan

Theses and Dissertations--Mechanical and Aerospace Engineering

Many companies are using platform-based product designs to fulfill the requirements of customers while maintaining low cost. However, research that integrates sustainability into platform-based product design is still limited. Considering sustainability during platform-based design process is a challenge because the total life-cycle from pre-manufacturing, manufacturing and use to post-use stages as well as economic, environmental and societal performance in these stages must be considered. In this research, an approach for quantifying sustainability is introduced and a mathematical model is developed for identifying a more sustainable platform. Data from life-cycle assessment is used to quantify environmental factors; criteria from the Product …


A Framework For Sustainable Material Selection For Multi-Generational Components, Ryan T. Bradley Jan 2015

A Framework For Sustainable Material Selection For Multi-Generational Components, Ryan T. Bradley

Theses and Dissertations--Mechanical and Aerospace Engineering

The early stages of a product’s design are a critical time for decisions that impact the entire life-cycle cost. Product designers have mastered the first generation; however, they currently do not have the ability to know the impact of their decisions on the multi-generational view. This thesis aims at closing the gap between total life-cycle information and the traditional design process in order to harbor sustainable value creation among all stakeholders involved. A framework is presented that uses a combination of a life-cycle costing methodology and an evolutionary algorithm in order to achieve a sustainability assessment for a true multi-generational …


Exploratory Study Of Seasonal Indoor Bioaerosols And The Associated Health Outcomes In Low-Income Communities In El Paso, Texas, 2014, Eric Martinez Jan 2015

Exploratory Study Of Seasonal Indoor Bioaerosols And The Associated Health Outcomes In Low-Income Communities In El Paso, Texas, 2014, Eric Martinez

Open Access Theses & Dissertations

Introduction: Structural degradation, moisture levels, and building failures can influence poor indoor air quality and create a good environment for bioaerosols. People spend much of their time indoors and can potentially be exposed to these bioaerosols. Several studies have correlated exposures to high concentrations of bioaerosols to various health problems, severe allergies, asthma, or other respiratory illness. Objectives: The objectives of this study are to describe bioaerosol concentrations, meteorological factors, and health outcomes during the summer and fall seasons; characterize bioaerosols (bacteria and fungi) collected in low-income communities; compare bioaerosol concentrations by season; compare meteorological factors to bioaerosol concentrations by …


Simulating Energy Efficient Control Of Multiple-Compressor Compressed Air Systems, Sean Murphy, J. Kelly Kissock Jan 2015

Simulating Energy Efficient Control Of Multiple-Compressor Compressed Air Systems, Sean Murphy, J. Kelly Kissock

Mechanical and Aerospace Engineering Faculty Publications

In many industrial facilities it is common for more than one air compressor to be operating simultaneously to meet the compressed air demand. The individual compressor set-points and how these compressors interact and respond to the facility demand have a significant impact on the compressed air system total power consumption and efficiency. In the past, compressors were staged by cascading the pressure band of each compressor in the system. Modern automatic sequencers now allow more intelligent and efficient staging of air compressors.

AirSim, a compressed air simulation tool, is now able to simulate multiple-compressor systems with pressure band and automatic …


Comprehensive Benefits Of Green Roofs, Madison R. Gibler Jan 2015

Comprehensive Benefits Of Green Roofs, Madison R. Gibler

Masters Theses

"Green infrastructure uses vegetation, soils, and natural processes to manage water and create healthier urban environments, providing traditional roof services and alternative stormwater management technologies. Other benefits and impacts are not yet fully understood or valued. Research conducted assesses specific stormwater benefits of green roofs, providing information on nutrient leaching from media; and analyzes potential energy benefits through side-by-side comparisons of full-scale white, traditional black rubber, and green roofs in the mid-continent Missouri climate. Roofing media selection impacted leaching of nutrients, suspended solids, and organic carbon from the tested green roof media. Thermal properties were investigated at the building level, …


Advanced Sustainable Concrete Materials For Infrastructure Applications, Kaylea Ann Smith Jan 2015

Advanced Sustainable Concrete Materials For Infrastructure Applications, Kaylea Ann Smith

Masters Theses

"This study was performed to examine the effects of cement replaced by high volumes of Class C fly-ash on durability characteristics of concrete up to 120 days. Specifically, this study investigates possibility of amending American Society for Testing and Materials (ASTM) to allow High Volume Fly-ash (HVFA) concrete to cure until later ages prior to testing instead of 28 days. Five mix designs were compared with varying fly-ash percentages from 0 to 70% (by total cementitious mass). No other additives were present in any of the five mix designs. Water-to-cementitious ratio (w/cm) and total cementitious material remained constant as 0.40 …


Advanced Computational Modeling Of The Internal Structure Of Smart Wind-Turbine Blades, Sanket Seetaram Bhogle Jan 2015

Advanced Computational Modeling Of The Internal Structure Of Smart Wind-Turbine Blades, Sanket Seetaram Bhogle

Dissertations, Master's Theses and Master's Reports - Open

Implementation of stable aeroelastic models with the ability to capture the complex features of Multi concept smartblades is a prime step in reducing the uncertainties that come along with blade dynamics. The numerical simulations of fluid structure interaction can thus be used to test a realistic scenarios comprising of full-scale blades at a reasonably low computational cost.

A code which was a combination of two advanced numerical models was designed and was run with the help of paralell HPC supercomputer platform. The first model was based on a variation of dimensional reduction technique proposed by Hodges and Yu. This model …


Automated Scour Detection Arrays Using Bio-Inspired Magnetostrictive Flow Sensors, Baibhav Rajbhandari Jan 2015

Automated Scour Detection Arrays Using Bio-Inspired Magnetostrictive Flow Sensors, Baibhav Rajbhandari

Dissertations, Master's Theses and Master's Reports - Open

Scour is the most common cause of catastrophic bridge failures worldwide. Approximately over 60% of bridge failures reported in the United States from 1966 to 2005 are scour related. To ensure the continued safe operation of bridges, monitoring bridge scour is of paramount importance. Most monitoring regimes that are widely used are based on expensive underwater instrumentation. This research focuses on scour detection using automated remote flow detection arrays based on bio-inspired flow sensors. This study employs an array of bio inspired flow sensors that are inexpensive and robust versions of buried-rod scour sensor arrays, coupled with low-power wireless sensor …


The Use Of Jatropha Curcas To Achieve A Self Sufficient Water Distribution System: A Case Study In Rural Senegal, Alexandra Archer Jan 2015

The Use Of Jatropha Curcas To Achieve A Self Sufficient Water Distribution System: A Case Study In Rural Senegal, Alexandra Archer

Dissertations, Master's Theses and Master's Reports - Open

The use of Jatropha curcas as a source of oil for fueling water pumps holds promise for rural communities struggling to achieve water security in arid climates. The potential for use in developing communities as an affordable, sustainable fuel source has been highly recommended for many reasons: it is easily propagated, drought resistant, grows rapidly, and has high-oil-content seeds, as well as medicinal and economic potential. This study uses a rural community in Senegal, West Africa, and calculates at what level of Jatropha curcas production the village is able to be self-sufficient in fueling their water system to meet drinking, …


A Sub-Basin Water Resource Quantification And Aquifer Productivity Assessment For The Northwest Borehole Scheme Near Opuwo, Namibia, Lucas C. Moilanen Jan 2015

A Sub-Basin Water Resource Quantification And Aquifer Productivity Assessment For The Northwest Borehole Scheme Near Opuwo, Namibia, Lucas C. Moilanen

Dissertations, Master's Theses and Master's Reports - Open

Namibia is the most arid country in southern Africa, and is classified as experiencing medium-water stress from 2010-2014 by the Water Resources Institute (WRI) (World Bank, 2015) (Gassert, 2013). Increased water-resources management responsibility at the municipal level, population growth and urbanization trends necessitate community-scale quantification of water resources.

An annual water balance for the contributing sub-basin to Opuwo, Namibia was performed. The Behnke and Maxey method was used to estimate PET, and the methodology outlined by Allen, et al was used to determine soil moisture response to individual rainfall events for one hypothetical year. Water balance results indicate that of …


Climate Change Implications For Health-Care Waste Incineration Trends During Emergency Situations, Emilia Mmbando Raila Jan 2015

Climate Change Implications For Health-Care Waste Incineration Trends During Emergency Situations, Emilia Mmbando Raila

Walden Dissertations and Doctoral Studies

Healthcare waste (HCW) incineration practices in the global South countries are among the major sources of black carbon (BC) emissions or smoke. This study analyzes HCW incineration trends during emergency situations and smoke from HCW incineration processes in Haiti. The study was prompted by the current arguments about the climate change and the growing health effects associated with BC emissions. The conceptual framework was based on both adverse health effects from BC emissions exposure and climate change potential of BC emissions. Therefore, the goal was to determine whether cardboard HCW sharps containers emit lower BC emissions to the atmosphere during …


Reaction Of Liquid Aluminium- Samarium Alloys With B4c At Ultra High Temperatures, Sanjay Shantha-Kumar Jan 2015

Reaction Of Liquid Aluminium- Samarium Alloys With B4c At Ultra High Temperatures, Sanjay Shantha-Kumar

Open Access Theses & Dissertations

Reactive studies between a packed bed of B4C and Al-Sm-Me (Me = Ti, Zr, Hf) alloy melts were carried out under a pseudo-isopiestic thermodynamic system. A graphite enclosure isolated the system under a temperature gradient with one end reaching temperatures greater than 1800 K and the opposite end of the graphite enclosure contains liquid Al with temperatures approximating 950 K. The liquid Al establishes an oxygen potential to control oxidation of very reactive elements (i.e., Al, Sm and Ti). The Al-Sm-Me alloy infuses into a packed bed of B4C reacting exothermically to form borides and carbides depending on the thermodynamic …