Engineering Commons^™

Ultrafine Mineral Associations In Superhigh-Organic-Sulfur Kentucky Coals, James C. Hower, Debora Berti, Michael F. Hochella Jr.

Center for Applied Energy Research Faculty and Staff Publications

Two high-organic-sulfur Kentucky coals, the eastern Kentucky River Gem coal and the western Kentucky Davis coal, are examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), both including elemental analysis by energy-dispersive spectroscopy (EDS). From the SEM–EDS analysis, it is observed that the western Kentucky coal had areas with Pb and Cd in addition to the expected Fe and S and the eastern Kentucky coal had individual Fe–S-rich areas with La and Ni and with Si, Al, Cr, Ni, and Ti. TEM and selected area electron diffraction (SAED) analyses demonstrate that anglesite with a rim of Pb-bearing amorphous …

Removal Efficiencies, Uptake Mechanisms And Competitive Effects Of Copper And Zinc In Various Stormwater Filter Media, Emily Heleva-Ponaski

Dissertations and Theses

Polluted stormwater, if not treated, can compromise water quality throughout our hydrologic cycle, adversely affecting aquatic ecosystems. Common stormwater pollutants, copper and zinc, have been identified as primary toxicants in multiple freshwater and marine environments. For small-scale generators, stormwater management can be cumbersome and implementation of common BMPs impractical thus catch basins are popular though not the most environmentally conscious and sustainable option. This study aims to characterize the potential of a mobile media filter operation for the treatment and on-site recycling of catch basin stormwater. The removal capacities of various commercially available filter media (e.g. a common perlite; Earthlite™, …

2018 Fall Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Fall 2018 ENGR333 project focused on renewable energy generation.

I asked the students “What is the largest possible reduction in Calvin’s annual energy costs from a $5M investment in renewable energy?”

Customer

The customer for this project was Russell Bray, Director of Calvin’s Physical Plant.

Report Of Community Conversations About Gender Roles In Livestock, Mamusha Lemma, Wole Kinati, Annet Mulema, Zekarias Bassa, Abiro Tigabe, Hiwot Desta, Mesfin Mekonnen, Tadious Asfaw

Daugherty Water for Food Global Institute: Faculty Publications

The International Livestock Research Institute (ILRI) and the International Center for Research in the Dry Areas (ICARDA) gender and animal health teams facilitated community conversations (CCs) about gender roles in livestock husbandry in three districts in the Southern Nations, Nationalities and Peoples Region (SNNPR) and Amhara region from 30 May–07 June 2018. These dictricts were: Doyogena (Hawora Arara and Ancha Sadicha kebeles) of SNNPR from 30 and 31 May; and Menz Gera district (Sine Amba kebele) and Menz Mama district (Key Afer kebele) of Amhara from June 6–7. In Doyogena, the team held the conversations in farmer training centres (FTCs) …

What You Don’T See, Brent Sturlaugson

Architecture Faculty Publications

Follow the supply chains of architecture and you’ll find not just product manufacturers but also environmental polluters and elusive networks of financial power and political influence.

Engineered Nanoparticles Interact With Nutrients To Intensify Eutrophication In A Wetland Ecosystem Experiment, Marie Simonin, Benjamin P. Colman, Steven M. Anderson, Ryan S. King, Matthew T. Ruis, Astrid Avellan, Christina M. Bergemann, Brittany G. Perrotta, Nicholas K. Geitner, Mengchi Ho, Belen De La Barrera, Jason M. Unrine, Gregory V. Lowry, Curtis J. Richardson, Mark R. Wiesner, Emily S. Bernhardt

Plant and Soil Sciences Faculty Publications

Despite the rapid rise in diversity and quantities of engineered nanomaterials produced, the impacts of these emerging contaminants on the structure and function of ecosystems have received little attention from ecologists. Moreover, little is known about how manufactured nanomaterials may interact with nutrient pollution in altering ecosystem productivity, despite the recognition that eutrophication is the primary water quality issue in freshwater ecosystems worldwide. In this study, we asked two main questions: (1) To what extent do manufactured nanoparticles affect the biomass and productivity of primary producers in wetland ecosystems? (2) How are these impacts mediated by nutrient pollution? To address …

Assessing The Relationship Between Groundwater Nitrate Concentrations And Environmental Variables Through Repeat Sampling And Statistical Machine Learning: Dutch Flats, Nebraska, Martin Wells

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Nitrate-contaminated aquifers are common in landscapes dominated by agricultural land use. Health concerns related to consuming nitrate-contaminated groundwater are well documented and continued research aimed at decreasing concentrations is critical. A 1990s U.S. Geological Survey (USGS) study focused on groundwater characteristics in the Dutch Flats area of western Nebraska. Agricultural-related practices were determined to largely influence groundwater recharge and nitrate concentrations ([NO₃^-]). Since the conclusion of the USGS study, a transition to more efficient irrigation technology has been observed in this region. The emphasis of this 2016 study was to resample several well nests examined in 1998 …

Twelve Questions For The Participatory Modeling Community, Rebecca Jordan, Steven Gray, Moira Zellner, Pierre D. Glynn, Alexey Voinov, Beatrice Hedelin, Eleanor J. Sterling, Kirsten Leong, Laura Schmitt Olabisi, Klaus Hubacek, Pierre Bommel, Todd K. Bendor, Antoine J. Jetter, Bethany Laursen, Alison Singer, Philippe J. Giabbanelli, Nagesh Kolagani, Laura Basco Carrera, Karen Jenni, Christina Prell, National Socio-Environmental Synthesis Center Participatory Modeling Pursuit Working Group

Engineering and Technology Management Faculty Publications and Presentations

Participatory modeling engages the implicit and explicit knowledge of stakeholders to create formalized and shared representations of reality and has evolved into a field of study as well as a practice. Participatory modeling researchers and practitioners who focus specifically on environmental resources met at the National Socio-Environmental Synthesis Center (SESYNC) in Annapolis, Maryland, over the course of 2 years to discuss the state of the field and future directions for participatory modeling. What follows is a description of 12 overarching groups of questions that could guide future inquiry.

Short-Term Organic Carbon Release And Chlorine Disinfectant Decay For Cross-Linked Polyethylene (Pex) Plumbing Pipes, Miriam Tariq, Christian J. Ley, Maryam Salehi, Andrew J. Whelton

The Summer Undergraduate Research Fellowship (SURF) Symposium

The use of cross-linked polyethylene (PEX) plumbing pipes has grown in popularity for residential applications. However, PEX pipes can leach organic materials into water that can enable biofilm growth, cause off-tastes and -odors, and may react with disinfectants to form disinfection by-products (DBP). Varied manufacturing processes that are applied to create PEX pipes add to the complexity of understanding organic materials released. In this study, organic carbon release from three PEX pipe brands was monitored for up to five days using a series of stagnation periods. Seven stagnation periods of 1, 2, 4, 8, 24, 72, and 120 hours were …

Cover Crops Have Negligible Impact On Soil Water In Nebraska Maize–Soybean Rotation, J. Burdette Barker, Derek M. Heeren, Katja Koehler-Cole, Charles Shapiro, Humberto Blanco-Canqui, Roger W. Elmore, Christopher A. Proctor, Suat Irmak, Charles A. Francis, Tim M. Shaver, Ali T. Mohammed

Department of Agricultural and Biological Systems Engineering: Faculty Publications

One perceived cost of integrating winter cover cropping in maize (Zea mays L.) and soybean [Glycine max (L.) Merr.] rotation systems is the potential negative impact on soil water storage available for primary crop production. The objective of this 3-year study was to evaluate the effects of winter cover crops on soil water storage and cover crop biomass production following no-till maize and soybean rotations. Locations were near Brule (west-central), Clay Center (south-central), Concord (northeast), and Mead (east-central), Nebraska, United States. Treatments included crop residue only (no cover crop) and a multi-species cover crop mix, both broadcast-seeded before …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Opto-Thermal Characterization Of Plasmon And Coupled Lattice Resonances In 2-D Metamaterial Arrays, Vinith Bejugam

Graduate Theses and Dissertations

Growing population and climate change inevitably requires longstanding dependency on sustainable sources of energy that are conducive to ecological balance, economies of scale and reduction of waste heat. Plasmonic-photonic systems are at the forefront of offering a promising path towards efficient light harvesting for enhanced optoelectronics, sensing, and chemical separations. Two-dimensional (2-D) metamaterial arrays of plasmonic nanoparticles arranged in polymer lattices developed herein support thermoplasmonic heating at off-resonances (near infrared, NIR) in addition to regular plasmonic resonances (visible), which extends their applicability compared to random dispersions. Especially, thermal responses of 2-D arrays at coupled lattice resonance (CLR) wavelengths were comparable …

Sustainability Of Utilizing Renewable And Nuclear Energy In Saudi Arabia Using Different Types Of Life Cycle Assessment, Kamel Almutairi

Graduate Theses and Dissertations

Evaluating the global environmental impacts of the current and future energy policies in Saudi Arabia using Life cycle assessment (LCA) method was the main objective of this dissertation. First, the attributional life cycle assessment (ALCA) framework was used to evaluate the Saudi’s air conditioning systems, as they are responsible for about 70% of the total Saudi residential electricity consumption. The ALCA’s results showed that the AC use phase produces the largest share of the environmental impact and the magnitude of the environmental impacts is influenced by the type of primary fuel used for electricity generation.

Emerging non-fossil sources of electricity …

Irrigation Management, Environment, And Profits: Who Wins?, Emily O'Donnell

Department of Agricultural Economics: Dissertations, Theses, and Student Research

The impact of irrigation technology on farmers’ management strategies and resulting environmental benefits depends upon agronomic properties and market forces. We evaluate the role of deficit irrigation using soil moisture probe technology on corn yield and evapotranspiration, which is a measure of water use efficiency. Evapotranspiration represents the water that transits through the plant during planting to harvest (transpiration) and the evaporation from the soil into the environment, or the displaced water in the production process. We develop yield and evapotranspiration response functions to inform a constrained profit maximization model used to identify the optimal irrigation level across a variety …

Including Farmer Irrigation Behavior In A Sociohydrological Modeling Framework With Application In North India, Jimmy O’Keeffe, Simon Moulds, Emma Bergin, Nick Brozovic, Ana Mijic, Wouter Buytaert

Daugherty Water for Food Global Institute: Faculty Publications

Understanding water user behavior and its potential outcomes is important for the development of suitable water resource management options. Computational models are commonly used to assist water resource management decision making; however, while natural processes are increasingly well modeled, the inclusion of human behavior has lagged behind. Improved representation of irrigation water user behavior within models can provide more accurate and relevant information for irrigation management in the agricultural sector. This paper outlines a model that conceptualizes and proceduralizes observed farmer irrigation practices, highlighting impacts and interactions between the environment and behavior. It is developed using a bottom-up approach, informed …

Cross Photoreaction Of Glyoxylic And Pyruvic Acids In Model Aqueous Aerosol, Sha-Sha Xia, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

Aerosols of variable composition, size, and shape are associated with public health concerns as well as with light-particle interactions that play a role in the energy balance of the atmosphere. Photochemical reactions of 2-oxocarboxylic acids in the aqueous phase are now known to contribute to the total secondary organic aerosol (SOA) budget. This work explores the cross reaction of glyoxylic acid (GA) and pyruvic acid (PA) in water, the two most abundant 2-oxocarboxylic acids in the atmosphere, under solar irradiation and dark thermal aging steps. During irradiation, PA and GA are excited and initiate proton-coupled electron transfer or hydrogen abstraction …

Validating The Accuracy Of Neatwork, A Rural Gravity Fed Water Distribution System Design Program, Using Field Data In The Comarca Ngöbe-Bugle, Panama, Maria Briones

USF Tampa Graduate Theses and Dissertations

Despite the sustainable development goals to increase access to improved water there are still 884 million people in the world without access to an improved water source (WHO, 2017). One method to improve access to water in rural, mountainous areas, is through construction of gravity fed water distribution systems. These systems should be designed based upon fundamental principles of hydraulics. One method of doing so in a time efficient manner with minimal engineering knowledge is to utilize a downloadable computer program such as Neatwork, which aids in design of rural, gravity fed water distribution systems and has been used by …

Forewarned Is Forearmed: Review Of Curbing Catastrophe: Natural Hazards And Risk Reduction In The Modern World By Timothy H. Dixon (2017), Jason Makansi

Numeracy

Timothy H. Dixon. 2017. Curbing Catastrophe: Natural Hazards and Risk Reduction in the Modern World. (New York, NY: Cambridge University Press) 300 pp. ISBN 978-1108113663.

Curbing Catastrophe for the most part lives up to what is claimed in the foreword: “…a compelling account of recent and historical disasters, both natural and human-caused, drawing on common themes and providing a holistic understanding of hazards, disasters, and mitigation for anyone interested in this important and topical subject.” This is a pretty thorough treatment of an extraordinarily complex subject, and the gaps identified in this review should be considered explications more than …

The Effect Of Processing Conditions On The Energetic Diagram Of Cdte Thin Films Studied By Photoluminescence, Shamara P. Collins

USF Tampa Graduate Theses and Dissertations

The photovoltaic properties of CdTe-based thin films depend on recombination levels formed in the CdTe layer and at the heterojunction. The localized states are resultant of structural defects (metal sublattice, chalcogen sublattice, interstitial), controlled doping, deposition process, and/or post-deposition annealing. The photoluminescence study of CdTe thin films, from both the bulk and heterojunction, can reveal radiative states due to different defects or impurities. Identification of defects allows for potential explanation of their roles and influence on solar cell performance. A thorough understanding of the material properties responsible for solar cell performance is critical in further advancing the efficiency of devices. …

What Can I Do As A Student To Make A Positive Impact On The Environment?, Tammy Guthrie, Greg Herzig, Kathy Prophet, Cassie Kautzer

Middle School Lesson Plans

Students discover ways they can make a positive impact on the environment.

Sustainable Production Of Bio-Based Succinic Acid From Plant Biomass, Enlin Lo

USF Tampa Graduate Theses and Dissertations

Succinic acid is a compound used for manufacturing lacquers, resins, and other coating chemicals. It is also used in the food and beverage industry as a flavor additive. It is predominantly manufactured from petrochemicals, but it can also be produced more sustainably by fermentation of sugars from renewable feedstocks (biomass). Bio-based succinic acid has excellent potential for becoming a platform chemical (building block) for commodity and high-value chemicals.

In this study, we focused on the production of bio-based succinic acid from the fiber of sweet sorghum (SS), which has a high fermentable sugar content and can be cultivated in a …

Underground Stormwater Treatment Performance In Urban Coastal Catchments: Case Study Of Baffle Boxes In The City Of Tampa, Awet Eyob Tsegay

USF Tampa Graduate Theses and Dissertations

In coastal urban regions, underground stormwater treatment units are suitable infrastructure options because they take less space where premium land is expensive. Even then, they should be accessible and ideally small enough to fit into existing stormwater networks. Since 2003, the City of Tampa and Florida’s Department of Transportation (FDOT) have installed 47 baffle boxes into the city’s stormwater pipe networks. Baffle boxes are underground stormwater treatment structures designed to capture sediments and floating debris. Since their deployment, many challenges regarding their practical sediment capturing performance was raised by the city.

The objective of this research was to evaluate the …

Reconsidering Downwind Operation By Analysis Of The Nrel Phase Vi Data, Scott Larwood, Raymond Chow

All Faculty Articles - School of Engineering and Computer Science

Data are presented comparing upwind versus downwind operation of the National Renewable Energy Laboratory’s Phase VI wind turbine. Power was not reduced as expected for downwind, which may be attributed to inboard three-dimensional effects. Average flap bending loads were reduced with downwind coning and compared well with prediction. Fatigue loads were increased with downwind; however, fatigue was mitigated with a tower shroud. The shroud needs to align with the freestream, demonstrated by an increase in fatigue loads from a 10° shroud misalignment. Pressure data were acquired in the tower wake at the rotor location with and without the shroud. The …

Book Review: Fundamentals Of International Aviation, Alan Bender

International Journal of Aviation, Aeronautics, and Aerospace

Not applicable.

Regulatory Methodology And Unmitigated Wetland Loss In Southwest Florida, Kathleen B. Castor

USF Tampa Graduate Theses and Dissertations

This research used Geographical Information System (GIS) data to estimate the acreage of wetland loss due to small-scale activities (taking into account exempt, permitted, and unauthorized activities) in the Southwest District of the Department of Environmental Protection (DEP) between 2006 and 2011 and compared that net loss with the unmitigated wetland net loss that DEP documented during that time for authorized activities and violations that were discovered. The comparison allowed an estimation of the extent of undocumented small-scale unmitigated wetland loss that occurred during those six years. DEP records show that 88% of non-compliance cases remain unresolved, and the net …

Impact Of Upstream Chlorination On Filter Performance And Microbial Community Structure Of Gac And Anthracite Biofilters, Glen Andrew De Vera, Daniel Gerrity, Mitchell Stoker, Wilbur Frehner, Eric C. Wert

Civil and Environmental Engineering and Construction Faculty Research

Drinking water filters may be operated to promote or deter biological activity through upstream oxidant addition. While there are several water quality benefits from biofiltration, microbial growth in biofilters warrants further investigation. In this study, routine monitoring detected target DNA sequences for Naegleria fowleri in source water and Acanthamoeba spp. in source water and biofilter effluent, triggering further microbial community characterization. Full-scale anthracite and granular activated carbon (GAC) filters receiving chlorinated waters were compared in terms of effluent water quality (i.e., turbidity and particle counts), biological activity (i.e., adenosine triphosphate (ATP)), and the composition of the microbial community (i.e., 16S/18S …

Dynamic Modeling Of An Advanced Wastewater Treatment Plant, Komal Rathore

USF Tampa Graduate Theses and Dissertations

Advanced wastewater treatment plants have complex biological kinetics, time variant influent rates and long processing times. The modeling and operation control of wastewater treatment plant gets complicated due to these characteristics. However, a robust operational system for a wastewater treatment plant is necessary to increase the efficiency of the plant, reduce energy cost and achieve environmental discharge limits. These discharge limits are set by the National Pollutant Discharge Elimination System (NPDES) for municipal and industrial wastewater treatment plants to limit the amount of nutrients being discharged into the aquatic systems.

This document summarizes the research to develop a supervisory operational …

Recent Trends In The Frequency And Duration Of Global Floods, Nasser Najibi, Naresh Devineni

Publications and Research

Frequency and duration of floods are analyzed using the global flood database of the Dartmouth Flood Observatory (DFO) to explore evidence of trends during 1985–2015 at global and latitudinal scales. Three classes of flood duration (i.e., short: 1–7, moderate: 8–20, and long: 21 days and above) are also considered for this analysis. The nonparametric Mann–Kendall trend analysis is used to evaluate three hypotheses addressing potential monotonic trends in the frequency of flood, moments of duration, and frequency of specific flood duration types. We also evaluated if trends could be related to large-scale atmospheric teleconnections using a generalized linear model framework. …

Kinetic Study Of Free Radical-Radical Reactions Of Combustion Importance At Elevated Pressures, Chao Yan

Dissertations

Combustion mechanisms consist of hundreds elementary reactions of free radicals and stable molecules. Radical-radical elementary reactions play important roles due to the high concentration in which free radicals are accumulated in combustion systems. Radical-radical reactions are typically multi-channel. Some of the channels might be of chain propagation or even chain branching nature, while other channels might be of chain termination nature. The relative importance of different channels is pressure dependent. Compared to radical-molecule reactions, radical-radical reactions are much less studied. This is due to the difficulties of well characterized quantitative production of radical species as well as due to the …

Performance Evaluation Of Energy-Autonomous Sensors Using Power-Harvesting Beacons For Environmental Monitoring In Internet Of Things (Iot), George Dan Moiş, Teodora Sanislav, Silviu Corneliu Folea, Sherali Zeadally

Information Science Faculty Publications

Environmental conditions and air quality monitoring have become crucial today due to the undeniable changes of the climate and accelerated urbanization. To efficiently monitor environmental parameters such as temperature, humidity, and the levels of pollutants, such as fine particulate matter (PM2.5) and volatile organic compounds (VOCs) in the air, and to collect data covering vast geographical areas, the development of cheap energy-autonomous sensors for large scale deployment and fine-grained data acquisition is required. Rapid advances in electronics and communication technologies along with the emergence of paradigms such as Cyber-Physical Systems (CPSs) and the Internet of Things (IoT) have led to …