Engineering Commons^™

High Temperature Reactions Of 1,2-Dichloroethane With Water Vapor In A Tubular Reactor, Charles E. Anderson

Theses

This study examines the reaction of l,2-dichloroethane with water vapor. The linear-flow method is utilized, assuming plug flow without axial diffusion. Normal operation is at atmospheric pressure and the reactor is a quartz tube in a thermal region 45 cm in length. Two reactor diameters of 0.4 cm and l.05 cm are used. Water and l,2-dichloroethane enter the system in liquid phase via syringe pumps. After vaporizing in heated tubing, they are combined with argon, the reactor carrier gas. The molar ratio of water to l,2-dichloroethane is 55:l and varied residence times are achieved by changing the argon flowrate. Reactor …

Investigation Of Water-Binding Properties Of Industrial Sludges Using Thermal Analysis As A Monitoring Tool, Ron Josephson

Theses

As part of a program to develop new and more cost-effective dewatering approaches for industrial hazardous wastes, sludges and synthetic "model" materials were analyzed by thermal methods in an attempt to comprehend their water-binding qualities and differentiate free and bound water. These thermal methods included Differential Thermal Analysis (DTA), Thermogravimetric Analysis (TG), and Differential Scanning Calorimetry (DSC). Industrial sludges and laboratory models were compared using both standard heating techniques and subambient cooling (to -60°C). This latter technique provides direct indication of the amount of free water. This information can be very useful in evaluating and improving dewatering techniques for industrial …

Analysis And Prediction Of The Water Temperature Of The Mckenzie River, Oregon Using The Equilibrium Temperature Approach, R. Peder Hansen

Dissertations and Theses

A one dimensional, steady flow, unsteady temperature model is used to evaluate the effects of two U.S. Army Corps of Engineers (COE) dams and resulting reservoirs on hourly water temperatures of the mainstem McKenzie River from Delta Park (RM 62.1) to Leaburg Dam (RM 38.8). Both COE projects are on tributaries to the McKenzie River and at present have only bottom withdrawl capabilities.

Water temperatures were simulated using the equilibrium temperature approach with air temperature used to estimate equilibrium temperature and also using computed hourly equilibrium temperature. Results obtained using computed equilibrium temperatures were less satisfactory than results using air …

Epa Regulation Of Mining Wastes Under Rcra And Cercla, Robert E. Walline

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

9 pages.

The New Cercla Amendments—What Are They? What Do They Mean?, David R. Andrews

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

35 pages.

Natural Resources Damage Litigation [Appendix], Michael Donovan

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

80 pages (includes illustrations).

Contains references and historical notes.

Appendix contains 3 attachments:

1) Comprehensive Environmental Response, Compensation and Liability Act, ("CERCLA"), 42 U.S.C. 9601 et seq. (1980)

2) National Contingency Plan, 40 C.F.R. Part 440, 50 Fed. Reg. No. 224, Part III (November 20, 1985)

3) Natural Resource Damage Assessments - Proposed Rule, Department of Interior, 43 C.F.R. Part 11, 50 Fed. Reg. No. 245, Part IV (December 20, 1985)

Review On The Administrative Record In Cercla Actions And Settlement Policy Summary, Stephen D. Ramsey

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

50 pages.

Contains references.

Revised Definition Of Solid Waste, John D. Fognani

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

15 pages.

The 1985/1986 Amendments To The Comprehensive Environmental Response, Compensation, And Liability Act: A Background Paper, Alan J. Gilbert

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

20 pages.

Contains 2 attachments.

Agenda: Getting A Handle On Hazardous Waste Control, University Of Colorado Boulder. Natural Resources Law Center

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

The conference chairman was University of Colorado School of Law professor Lawrence J. MacDonnell.

During the past ten years Congress has made the regulation of hazardous waste a priority. This conference focuses on the Resource Conservation and Recovery Act, as amended in 1984, and the Comprehensive Environmental Response, Compensation and Liability Act.

This conference attracted about 100 registrants from 16 states plus the District of Columbia. John G. Welles, Regional Director for EPA Region 8, presented a luncheon address.

The New Small Quantity Generator Rules: Rcra Reaches Small Business, Hal Winslow

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

16 pages.

Contains 1 footnote.

The 1984 Hswa Amendments: The Land Disposal Restrictions, James R. Spaanstra

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

28 pages.

Contains references.

Reduction Of Hazardous Waste—Pay Me Now Or Pay Me Later, Frank B. Friedman

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

8 pages.

Contains 1 attachment.

Colorado’S Hazardous Waste Program: Current Activities And Issues, Richard L. Griffith

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

17 pages.

An Evaluation Of Rcra, David J. Lennett

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

68 pages (includes 1 illustration).

Contains 1 page of references.

Contains 5 attachments.

Regulation Of Wastes From The Metals Mining Industry: The Shape Of Things To Come, Lawrence J. Macdonnell

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

37 pages.

Contains 5 pages of endnotes.

Underground Storage Tank Regulations, J. Kemper Will

Getting a Handle on Hazardous Waste Control (Summer Conference, June 9-10)

17 pages (includes 1 illustration and 1 form).

Contains 3 pages of references.

Contains 4 attachments.

A Study Of Hazardous Wastes Generated In New Jersey With Regard To The Siting Of Waste Disposal Facilities In The State, Shreerang Narayan Dharasker

Theses

The effective treatment and disposal of hazardous wastes is one of the most urgent problems facing the State of New Jersey today. New Jersey is the most densely populated state and is a leader in industry. Nearly every major industry in the nation is represented by one or many production units all of which generate copious amounts of hazardous and toxic wastes each year. Although the state has the toughest rules and regulations on the management of hazardous waste, there are very few options exercised or facilities cited for the effective treatment and disposal of wastes within the state boundaries. …

The Effect Of Toxic Substances On The Index Properties Of Soils, Ronald Dicola

Theses

Contaminated soils were tested to determine if a relationship existed between their index properties and hydraulic conductivity. Atterberg Limit tests and Particle Size Analysis tests were performed on Woodbury, Raritan and Brunswick formation soils. The chemicals examined were Benzene, Phenol and Trichloroethylene (TCE). Tests were performed following the ASTM Standard Test Methods with only slight modification to accommodate the use of contaminated soils. Two different methods of soil contamination were used, one for chemical solutions and the other for pure chemicals.

Particle Size Analysis tests were performed both with and without dispersing agent. Hydrometer tests with dispersing agent resulted in …

Air Pollutant Emissions From Non-Vented Radiant Kerosene Heater, Anil Kumar Mishra

Theses

Gaseous emissions from non-vented kerosene heaters can generate and create significant indoor air concentrations of various gaseous pollutants. Indoor air concentrations resulting from operating a portable non-vented radiant type kerosene heater in three rooms of size 38.7, 58.1 and 137 M³ were studied. Studies in the environmental chamber having a size of 38.7 M³ under two sets of ventilation conditions showed elevated levels of CO₂, total hydrocarbons and CO. An emission rate model was used to estimate the strength of pollutant source, for total hydrocarbons, CO₂ and CO with data reported in terms of mass …

Human Resources Planning In Construction Through Operations Research, Maria Pyla-Christodoulou

Theses

The purpose of this thesis is to examine different methods in the allocation of human resources in construction, using decision making through Operations Research. The methods described are divided into methods using mathematical models, and methods using heuristics. The mathematical models yield the optimum solution, while heuristics result in a satisfactory solution which can be improved by applying the optimization procedures described herein.

The human factor in construction is also examined, and methods of improving motivation among the construction workers are discussed.

Biodegradation Of Multiple Substrates In A Batch Reactor, Nilesh Naik

Theses

The biological degradation of multiple substrates was studied at room temperature in aerated 5-liter batch reactors using mixed liquor from the Passaic Valley Sewerage Commissioners wastewater treatment plant (Newark, New Jersey).

Two substrate mixtures were used (with initial concentration indicated in parenthesis): (1) phenol(100ppm) + nitrobenzene(10ppm) + 2,6-dichiorophenol(10ppm); (2) 2-chlorphenol(20ppm) + nitrobenzene(10ppm) + 2,6-dichlorphenol(10ppm). From concentration versus time data, kinetic rate constants for zero-order, first-order, and Monod models were determined. Most of the data were best fit by either the Monod or zero-order model. For all compounds tested biodegradation was the primary removal mechanism, and in many cases the rate …

Biodegradation Of Mixed Phenolic Substrates, Prasad Gonnabathula

Theses

The biological degradation of phenol, with either 2-chlorophenol, 2,6-dichlorophenol, or nitrobenzene as cosubstrates was studied in aerated five - liter batch reactors using mixed liquor from the Passaic Valley Sewarage Commissioners wastewater treatment plant (Newark, NJ). The initial substrate concentrations were: 100 – 150 ppm phenol, 10 - 20 ppm 2-cp, 10 ppm 2,3 dcp, and 10 - 20 ppm nitrobenzene. The concentration vs. time data were fit to three kinetic models: zero-order, first-order, and Monod(assuming constant biomass). Most of the data were best fit by either the Monod or zero-order model. For all compounds tested, biodegradation was the primary …

Saturated Hydraulic Conductivity Of Brunswick Soil With Aqueous Benzene Solution, Thomas R. Pisciotta

Theses

Tests measuring saturated hydraulic conductivity and dispersivity were conducted on Brunswick soil using an aqueous solution of benzene. The tests were performed using a flexible wall permeameter which was modified to allow extraction of effluent samples immediately upon exit of the test specimen. Influent and effluent samples were analyzed with a gas chromatograph in order to quantify dispersion and sorption in the specimen.

The test was performed using a confining pressure of 70 psi. and a hydraulic gradient of 100.3. Using a sample statically compacted to 99.2% of the Modified Proctor maximum density and tap water as a permeant, stable …

Determination Of Trace Quantities Of Selenium And Arsenic In Canned Tuna Fish Using Electroanalytical Techniques, Ann Marie Higham

Theses

Toxic metals are present in the environment and are known to be present in food. Selenium, which is considered an essential micronutrient, is recognized as a toxic metal at slightly higher concentrations. Arsenic is also recognized as a toxic metal. Selenium and Arsenic tend to accumulate in food, specifically fish and seafood.

Fifteen brands and types of tuna fish were analyzed for selenium using differential pulse cathodic stripping voltammetry. The cans with the high and low concentrations of selenium were analyzed for arsenic using differential pulse polarography. Three samples with three percent recoveries and a blank were analyzed for each …

Forecasting For Local Water Management, Douglas Alan Putnam

Dissertations and Theses

Forecast models are investigated and developed for use in local water management to aid in determining short term water requirements and availability. The forecast models include precipitation occurrence and depth using a Markov chain model, temperature and solar radiation with a multivariate autoregressive model, and streamflow with autoregressive-moving average models. The precipitation, temperature, and solar radiation forecasts are used with a soil moisture model to determine water demands. A state space approach to the Muskingum-Cunge streamflow routing technique is developed. The forecast water demands and streamflow forecasts are used as inputs to this routing model. Forecast model errors and propagation …

A Study Of Parameters Indicating Microbial Activity In Mixed Aerobic Cultures, William Smith

Theses

Mixed liquor suspended solids (MLSS), oxygen uptake rate (OUR) and general dehydrogenase activity, as expressed by the reduction of the electron-acceptor Dye 3-(4',5'-dimethylthiazol-2-yl)-2, 4-diphenyltetra-zolium bromide (MTT), were compared for their ability to measure microbial activity in mixed aerobic cultures. A fourth parameter, specific enzyme activity, was dropped from consideration because of the difficulty of developing a satisfactory experimental technique. Measurement of the parameters was applied to the biodegradation of phenol and o-chlorophenol by activated sludge from a municipal sewage treatment plant, and by two commercially available bacterial preparations.

MLSS, although the most commonly used of the three parameters tested, is …

Scheduling Effects Of 5-(3,3-Dimethyl-1-Triazeno)Imidazole-4-Carboxamide (Dtic) And 1,3-Bis-Chloroethyl-1-Nitrosourea (Bcnu) On Mouse Melanoma Cells B16cl5, Gracie V. Coffey

Theses

DTIC and BCNU have been demonstrated to have enhanced chemotherapeutic effects in mice bearing Bl6 mouse melanoma cells. The order of administration seems to be important in maintaining optimum effects. This was shown is a study by Hill et al. (unpublished).

In the present study, mouse melanoma cells, Bl6CL4, were treated with either DTIC or BCNU. The drug was allowed to remain on the cells for 2, 3, or 4 days. The drug-containing media were then removed, the cells were washed and fresh medium was added. The cells were incubated in an atmosphere of 5% CO2 and 95% air at …

The Kinetics And Hepatotoxicity Of Benzyl Chloride Vapor In Rats, Hari V. Rao

Theses

Male Sprague Dawley rats (250g) were exposed to benzyl chloride vapor at a concentration of 220 ppm for 6 hours. During inhalation, the blood benzyl chloride concentration increased to reach a steady state level of 9-10 ug/ml between 4 and 6 hours of exposure. A small concentration of benzyl chloride (0.86 ug/ml) was present in the blood four hours after the termination of exposure. The absorption half life was 0.53 hours (0.39-0.81) and the elimination half life was l.12 hour (0.93-l.40).

The absorbed benzyl chloride was largely retained in the blood and some of it (0.22 ug/g) was sequestered into …

Protective Laboratory Measures For The Flexible Wall Permeameter And The Atterberg Limits Tests Using Hazardous And Toxic Chemicals, Robert A. Tetla

Theses

Safety procedures for performing geotechnical testing with hazardous and toxic materials, excluding radioactive wastes, are developed for the Flexible Wall Permeameter and the Atterberg Limits Tests. The tests were evaluated in detail to determine the critical points at which the technician would be exposed to the hazardous and/or toxic permeant. It was found that the following safety measures should always be taken; 1) the apparatus and all testing should be undertaken in a sliding sash hood using the proper face velocity, 2) air monitoring using a personal dosimeter and/or a detector tube is required to assure that the concentration of …