Engineering Commons^™

The Effects Of Secondary Trapping Mechanisms On Geologic Storage Of Carbon Dioxide, Catherine Ruprecht

All Dissertations

The goal of this Dissertation is to further the understanding of secondary trapping mechanisms in geologic CO₂ storage systems to improve storage design and security. This Dissertation takes the form of three chapters. The objective of the first chapter was to analyze the storage performance of supercritical and brine saturated CO₂ injection strategies to determine their advantages and disadvantages on distribution and immobilization of CO₂ and pressure buildup. Results showed dissolved CO₂ injection was favorable in terms of storage security in all cases as it resulted in smaller areal extents on the caprock and did not …

Methane Production By A Packed-Bed Anaerobic Digester Fed Dairy Barn Flush Water, Sean Richard Thomson

Master's Theses

Packed-bed digesters are an alternative to covered lagoon digesters for methane production and anaerobic treatment of dilute wastewaters such as dairy barn flush water. The physical media of packed-beds retain biofilms, often allowing increased treatment rates. Previous studies have evaluated several types of media for digestion of dilute wastewaters, but cost and media fouling have setback commercial development. A major operational cost has been effluent recirculation pumping.

In the present effort, a novel approach to anaerobic digestion of flush dairy water was developed at pilot-scale: broken walnut shells were used as a low-cost packed-bed medium and effluent recirculation was replaced …

Field And Greenhouse Studies Of Phytoremediation With California Native Plants For Soil Contaminated With Petroleum Hydrocarbons, Pahs, Pcbs, Chlorinated Dioxins/Furans, And Heavy Metals, Matthew Robert Poltorak

Master's Theses

Native and naturalized California plant species were screened for their phytoremediation potential for the cleanup of soil contaminated with petroleum hydrocarbons (PHCs), poly-aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), chlorinated dioxins/furans, and heavy metals. This screening was followed by controlled greenhouse experiments to further evaluate the phytoremediation potential of the best candidates. Field specimens and soils used for this study were collected from the former Energy Technology Engineering Center (ETEC) at the Santa Susana Field Laboratory in Southern California that was operated by the Department of Energy (DOE). Soils at this site contain all of the contaminants of interest (COIs). Nine …

Toward Understanding The Thermodynamics And Mechanisms Of Actinide Sorption Reactions, Shanna Estes

All Dissertations

The environmental fate of actinides is greatly influenced by interfacial reactions, including sorption onto solid surfaces. Because changes in the primary hydration sphere of the actinide are expected to greatly influence the thermodynamics (i.e., reaction enthalpy and entropy) of these reactions, examining actinide sorption thermodynamics may provide insight into actinide sorption mechanisms. Additionally, examining actinide sorption thermodynamics may enhance the ability to model or predict these reactions in environmental or engineered systems where variable or elevated temperatures are expected. However, few researchers have studied actinide sorption thermodynamics. Therefore, this research examined the thermodynamics of Eu(III) (a trivalent actinide analog), Th(IV), …

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

United States Patent Application Publication, John H. Posselius, Christopher A. Foster, Santosh Pitla, Scott A. Shearer, Joe D. Luck, Michael P. Sama, Rodrigo S. Zandonadi

Department of Agricultural and Biological Systems Engineering: Faculty Publications

A multiple robot control architecture including a plurality of robotic agricultural machines including a first and second robotic agricultural machine. Each robotic agricultural machine including at least one controller configured to implement a plurality of finite state machines Within an individual robot control architecture (IRCA) and a global information module (GIM) communicatively coupled to the IRCA. The GIMs of the first and second robotic agricultural machines being configured to cooperate to cause said first robotic agricultural machine and said second agricultural machine to perform at least one agricultural task.

Development Of A Reusable Nutrient Recovery System To Sustainably Integrate Small-Scale Sanitation And Agriculture, Jorge Luis Calabria

USF Tampa Graduate Theses and Dissertations

Emerging technologies in sanitation and food production foster the potential to advance progress towards key sustainable development goals of ensuring adequate sanitation and food security to all. Non-Sewered Sanitation Systems (NSSSs), as detailed by the recent International Organization for Standardization’s (ISO) 30500 standard, are being developed to overcome challenges of lacking sanitation infrastructure and resource scarcity by providing autonomous, off-grid wastewater treatment (WWT) service in a much smaller footprints than large centralized treatment facilities. A promising NSSS platform is the anaerobic membrane bioreactor (AnMBR) that can achieve high (WWT) throughput in a small footprint using ultrafiltration (UF) membrane filtration to …

Can Protected Bike Lanes Help Close The Gender Gap In Cycling? Lessons From Five Cities, Jennifer Dill, Tara Goddard, Christopher Monsere, Nathan Mcneil

Urban Studies and Planning Faculty Publications and Presentations

Even in areas with increased levels of bicycling, there remains a significant “gender gap” in bicycling in the United States, in contrast to many other countries with high rates of bicycling. The primary objective of this paper was to explore whether protected bike lanes could help reduce the gender gap. To do so, the authors used survey data from a comprehensive evaluation of protected bike lanes in five large U.S. cities (Austin, TX, Chicago, IL, Portland, OR, San Francisco, CA, and Washington, DC) that included survey responses of 1,111 intercepted bicyclists and 2,283 residents. Both men and women overwhelmingly felt …

Nutrient Runoff Following Swine Manure Application, Seth J. Lamb

Department of Environmental Engineering: Theses and Other Student Research

A field study was completed to compare the effects of land application methods, swine growth stage, and varying flow rates following the application of varying amounts of swine manure to 0.75-m by 2.00-m long plots. Three different manure sources were used to represent key different growth stages including growers, finishers, and sows and gilts. The different swine manures were applied in May and Jun 2011 to meet a 1 year nitrogen (N) requirement for corn. Three different land application methods were used to apply the swine manure, broadcast, incorporation, and injection. Runoff water quality was measured during three 30 minute …

Reply To ‘Co2 Emissions From Crop Residue-Derived Biofuels’, Adam Liska, Haishun Yang, Matthew P. Pelton, Andrew E. Suyker

Adam Liska Papers

The soil organic carbon (SOC) model that we used was parameterized with data from arable land under normal farming conditions in North America, Europe, Africa and Asia, but the equation is insensitive to changes in tillage, soil texture and moisture. The model has reasonable accuracy, however, in predicting changes in SOC, residue remaining and CO₂ emissions from initial SOC, carbon inputs from residue, and daily temperature; the shoot-to-root ratio used in the geospatial simulation was 0.29 (that is, root carbon is 29% of total aboveground carbon), which did not underestimate carbon input to soil (Supplementary Figure 2 in Ref. …

Soil Carbon Accumulation Under Switchgrass Barriers, Humberto Blanco-Canqui, John E. Gilley, Dean E. Eisenhauer, Paul J. Jasa, Alan L. Boldt

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The benefits of grass barriers or hedges for reducing offsite transport of non-point-source water pollutants from croplands are well recognized, but their ancillary benefits on soil properties have received less attention. We studied the 15-yr cumulative effects of narrow and perennial switchgrass (Panicum virgatum L.) barriers on soil organic C (SOC), total N, particulate organic matter (POM), and associated soil structural properties as compared with the cropped area on an Aksarben silty clay loam (fine, smectitic, mesic Typic Argiudoll) with 5.4% slope in eastern Nebraska. Five switchgrass barriers were established in 1998 at ~38-m intervals parallel to the crop rows …

Interactive Comment On “Iodine Oxide In The Global Marine Boundary Layer” By C. Prados-Roman Et Al., Marcelo I. Guzman

Chemistry Faculty Publications

No abstract provided.

Estimating Mineral Weathering Rates In Catskills Watersheds, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

No abstract provided.

The Structure-Function Relationship Of Pamam Dendrimers As Robust Oil Dispersants, Nicholas K. Geitner, Bo Wang, Rachel E. Andorfer, David A. Ladner, Pu Chen Ke, Feng Ding

Publications

PAMAM dendrimers have recently been investigated as efficient and biocompatible oil dispersants utilizing their encapsulation capacity; however, their high cationic charge density has been shown to be cytotoxic. It is therefore imperative to mitigate cationic charge-induced toxicity and understand the effects of such changes. Presented here is a synergistic experimental and computational approach to examine the effects of varying terminal surface charge on the capacity of dendrimers to disperse model liner, polycyclic aromatic, and hybrid hydrocarbons. Uncharged dendrimers collapse by forming intramolecular hydrogen bonds, which reduce the hosting capability. On the other hand, changing the surface charges from positive to …

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

A New Passive Surface Water Flux Meter For Simultaneous Measurement Of Contaminant And Water Fluxes In Streams And Rivers, Stephen A. Sassman

Open Access Dissertations

A passive surface water flux meter (PSFM) for measurement of contaminant concentration/flux in rivers and streams is described and tested. The novel PSFM design was developed for portability and ease of adaptability for a variety of contaminant classes. Although previous designs have been evaluated under constant flow conditions, the PSFM has never been used for measurement of pesticides or hormones and this is the first time that it has been tested under transient flow. Discharge through the PSFM is assessed by measuring miscible displacement of alcohol tracers from granular activated carbon (GAC). The tracer retardation factors (R) measured by miscible …

Irrigation With Treated Wastewater: Potential And Limitations, Anne Dare

Open Access Dissertations

As the world population increases and resources become more coveted, water emerges as a key component to global food security. The Middle East and North Africa (MENA) is among the driest regions in the world: containing just one percent of the world's freshwater resources. An increasing population creates greater quantities of wastewater and demands greater quantities of food, so an obvious connection arises. However logical wastewater reuse may be for bridging the irrigation supply-demand gap in this arid region, significant limitations prevent widespread adoption. The overall goal of this research is to take a holistic view of the limitations facing …

Water Conservation To Reduce Wet Weather Pollution Loads To The Gowanus Canal, Brooklyn, Ny, Suzanne Carol Stempel

Dissertations, Theses, and Capstone Projects

Public participation plays an important role in wet weather pollution management. However, the effects of participation programs on local water quality are often difficult to quantify. This project aims to quantify the potential effects of a community based, non-structural, BMP aimed at controlling inputs to combined sewage systems by encouraging residents to reduce their water use during rain events. A household could participate by reducing the amount of water they use for flushing toilets, washing dishes, taking showers, etc. during rain events; thereby reducing stress on the system during the time of highest demand. The Gowanus Canal sewershed in Brooklyn, …

Fate Of Micropollutants During Pyrolysis Of Biosolids, John Ross

Master's Theses (2009 -)

Approximately 250 tons of organic micropollutants, including pharmaceuticals, antimicrobials, and hormones, are discharged to the environment during land application of wastewater biosolids annually. Reusing wastewater biosolids is vital to the sustainability of wastewater treatment, but current treatment processes do not remove micropollutants from biosolids in an efficient manner. Pyrolysis―the heating of biomass to temperatures between 400 and 800 °C under oxygen-free conditions―was proposed as a biosolids treatment process that could produce a beneficial soil amendment product, biochar, and remove micropollutants. The objective of this research was to determine the effect of pyrolysis temperature and residence time on the removal of …

Hydro-Climate Temporal Variations And Their Influences On Net Primary Production In A Eurasian Steppe Watershed, Xiaomin Yang

Civil & Environmental Engineering Theses & Dissertations

Climate, which is the most important factor that influences Net Primary Productivity, has been detected changing all over the world. The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann-Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large anomalies. In this research, by formulating a trend analysis approach that considers nonstationary due to step changes, trends and extreme occurrences of precipitation, temperature, and runoff in annual, seasonal, and monthly scales were analyzed in a mid-latitude Eurasian steppe watershed in northeast China, and …

Reaction Engineering Routes To Waste Gasification For Sustainable Living Environments, Stephen A. Reeves, Mohammed S. Suleiman, Joshua M. Cmar, Jorge E. Gatica

Undergraduate Research Posters 2014

There is an increasing pressure to reduce waste generation and dependence upon fossil fuels in our society. The approach investigated in this project aims to address both concerns by formulating a low-temperature gasification process to process long-chain polymers typically found in municipal waste. Gasification routes which convert plastic and bio-waste into useful fuel syngas products has been extensively investigated. The novelty of the approach examined here consists on the use of a variety of catalysts, which can promote high conversion in gasification reactions at much lower temperature and pressure conditions. This route overcomes some of the financial and environmental shortcomings …

2014 Fall Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Fall 2014 ENGR333 project focused on net zero homes.

I asked the students “What would it take for a home in Grand Rapids to become net-zero?”

Customer

The customers for this project were several homeowners in the Grand Rapids area.

Drinking Water Treatment: Reverse Osmosis, Bruce I. Dvorak, Sharon O. Skipton

Department of Civil and Environmental Engineering: Faculty Publications

Reverse osmosis (RO) membrane filters frequently are used to reduce the levels of total dissolved solids and suspended particles within water. Some contaminants treated effectively by RO membrane filters are listed in Table I. This table is not an exhaustive list of contaminants that RO may remove, but rather lists those for which RO can be a practical treatment method for treating household drinking water.

Impacts Of Climate Change On The Seasonality Of Extremes In The Columbia River Basin, Mehmet Demirel, Hamid Moradkhani

Civil and Environmental Engineering Faculty Publications and Presentations

The impacts of climate change on the seasonality of extremes i.e. both high and low flows in the Columbia River basin were analyzed using three seasonality indices, namely the seasonality ratio (SR), weighted mean occurrence day (WMOD) and weighted persistence (WP). These indices reflect the streamflow regime, timing and variability in timing of extreme events respectively. The three indices were estimated from: (1) observed streamflow; (2) simulated streamflow by the VIC model using simulated inputs from ten combinations of bias corrected and downscaled CMIP5 inputs for the current climate (1979–2005); (3) simulated streamflow using simulated inputs from ten combinations of …

The Effect Of Multi-Model Averaging Of Climate Model Outputs On The Seasonality Of Rainfall Over The Columbia River Basin, Mehmet Demirel, Arun Rana, Hamid Moradkhani

Civil and Environmental Engineering Faculty Publications and Presentations

The rainfall seasonality index is the measure of precipitation distribution throughout the seasonal cycle. The aim of this study is to compare the effect of different multi-model averaging methods on the rainfall seasonality index at each 1/16 latitude-longitude cells covering the Columbia River Basin. In accordance with the same, ten different climate model outputs are selected from 45 available climate models from CMIP5 dataset. The reanalysis precipitation data is used to estimate the errors in rainfall seasonality for the climate model outputs. The inverse variance method and statistical multi criteria analysis (SMCA) method were used to estimate the weights for …

Analysis On The Issue Of Ship Sewage In Terms Of Pollution, Discharge And Reception In The Minjiang Inland Port With Countermeasures, Binsong Zheng

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Racial Disparities In Access To Community Water Supply Service In Wake County, North Carolina, Jacqueline Macdonald Gibson, Nicholas Defelice, Daniel Sebastian, Hannah Leker

Frontiers in Public Health Services and Systems Research

Anecdotal evidence suggests that historically African American communities on the fringes of cities and towns in North Carolina have been systematically denied access to municipal drinking water service. This paper presents the first statistical analysis of the role of race in determining water access in these fringe areas, known as extraterritorial jurisdictions. Using publicly available property tax data, we quantified the percentage of residences with municipal water service in each census block in Wake County (the second-largest by population in North Carolina). Using the resulting water service maps plus 2010 U.S. Census data, we employed a logistic regression to assess …

Turbulent Circular Culvert Flow: Implications To Fish Passage Design, Amin Mohebbi

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Culverts are popular conveyance structures in America and Canada to be used as a fish passage or in sewage collection and disposal systems. Fish passage design criteria is based on biological capabilities of fish whereas it should satisfy hydraulic and hydrological constraints as well. Failing to provide enough low velocity regions for aquatic organisms may result in their mass extinctions. Currently, proper road crossing design depends on either model studies or numerical simulations via Computational Fluid Dynamic (CFD) packages, both of which are expensive and time consuming. Further, although the design procedures released by FHWA recently ensures safe fish migration …

A Cost Benefit Analysis Of Improving Energy Efficiency Of A Fitness Facilty, Inuri A. Illeperuma

Journal of Environmental and Resource Economics at Colby

Abstract: Nearly 40% of the total U.S. energy consumption in 2012 was consumed in residential and commercial buildings, as recorded by U.S. Energy Information Administration. With the urgent need to reduce overall energy consumption in the U.S., many efforts are made to improve the energy efficiency of buildings. However, energy managers identify budget constraints as one of the main obstacles in improving the energy efficiency of buildings. Hence this study focuses on a cost benefit analysis of improving the energy efficiency, with a special focus on fitness facilities in college environments. As a case study, the author focuses on improving …

Avoided Water Cost Of Electricity Generation For Solar Pv And Wind Technologies In Southern California, Matthew Cohen

Master's Theses

The objective of this thesis is to provide a foundation for evaluating the water costs associated with electricity production to calculate the avoided water cost of energy for solar PV and wind technologies relative to coal, natural gas, nuclear, geothermal, concentrated solar thermal, and biomass. Water consumption is estimated for energy production (fuel extraction and preparation) and electricity generation (power plant operation) using the best available information from published articles. The quantity of water consumed for electricity production is monetized for a Southern California case study based on the water rates of Metropolitan Water District of Southern California (MET), which …