Engineering Commons^™

Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright

Theses and Dissertations--Biosystems and Agricultural Engineering

In 1982, a study was initiated in the Field Branch watershed, in the University of Kentucky’s Robinson Forest, to evaluate forestry best management practice (BMP) effectiveness after intensive harvesting. The study utilized a paired watershed approach on three adjacent Field Branch subcatchments. One subcatchment was left as the control, one had BMPs implemented (including a 50-ft undisturbed buffer along the stream), and one was clear-cut to the stream’s banks without the use of BMPs (i.e. logger’s choice). Prior research has shown that logging can negatively impact watershed functions by altering stream hydrology, geomorphology, water quality, and instream habitat. Thus, the …

Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry

Theses and Dissertations--Biosystems and Agricultural Engineering

Regional curves and hydraulic geometry curves relate bankfull channel dimensions to drainage area and bankfull discharge, respectively. These curves are used in the natural channel design process to help identify bankfull and to estimate bankfull dimensions of the design channel. Nineteen streams were surveyed to determine their bankfull parameters (cross-sectional area, width, mean depth, discharge, slope, and Manning’s n), along with 27 streams previously surveyed in other studies. The data were used to create regional and hydraulic geometry curves for three hydrologic landscape regions (HLR 9, HLR 11, and HLR 16, individually) in the Eastern Kentucky Coalfields (EKC) as well …

Modeling Wastewater Indicators And Effects Of Contaminant Removal Strategies On Groundwater And Spring Discharge In A Karst Aquifer, Erin Reed

Electronic Theses and Dissertations

This dissertation reports on research related to groundwater and contaminant transport to the Volusia Blue Spring (VBS), an Outstanding Florida Water Body located in Volusia County (Florida). The integration of springshed water quality and contaminant fate and transport (CFT) modeling played key roles in the evaluation of anthropogenic recharge impacts on VBS. To study anthropogenic recharge into the karst limestone aquifer, wastewater effluent, golf course ponds, septic tanks, groundwater monitoring wells, and VBS discharge were sampled for boron, nitrate-nitrogen, nitrate-oxygen and their isotopes spatially throughout the VBS springshed. Data related to natural water features, rainfall, land use, water use, treated …

Modeling Mass Transfer And Assessing Cost And Performance Of A Hollow Fiber Nanofiltration Membrane Process, David Yonge

Electronic Theses and Dissertations

Bench-scale water treatment testing of three next generation hollow-fiber (HF) nanofiltration (NF) membranes was conducted to characterize divalent ion rejection capabilities and investigate removal mechanisms. Existing mathematical models were investigated to describe solute transport using synthetic magnesium sulfate solutions including the size exclusion model, homogenous solution diffusion (HSD) model, dimensional analysis, and the HSD model incorporating film theory. Solute transport for two of the membranes were described by HSD theory and were predictive of their 90% divalent ion removal. A third membrane was more accurately modeled using size exclusion and was found to be predictive of its 40% divalent ion …

Maximizing The Spatial Representativeness Of No2 Monitoring Data Using A Combination Of Local Wind-Based Sectoral Division And Seasonal And Diurnal Correction Factors, Aoife Donnelly, Owen Naughton, Bruce Misstear, Brian Broderick

Articles

This article describes a new methodology for increasing the spatial representativeness of individual monitoring sites. Air pollution levels at a given point are influenced by emission sources in the immediate vicinity. Since emission sources are rarely uniformly distributed around a site, concentration levels will inevitably be most affected by the sources in the prevailing upwind direction. The methodology provides a means of capturing this effect and providing additional information regarding source/pollution relationships. The methodology allows for the division of the air quality data from a given monitoring site into a number of sectors or wedges based on wind direction and …

Polychlorinated Biphenyl Compound And Metal Contamination And Remediation In Torch Lake, Houghton County, Mi, Ankita Mandelia

Dissertations, Master's Theses and Master's Reports

Torch Lake was subject to approximately 100 years of industrial pollution due to the dumping of waste associated with copper mining in the Keweenaw Peninsula, which lasted from approximately the 1860s through the 1960s. It is well-known that this waste included copper-containing mine tailings. What was less understood are the impacts of polychlorinated biphenyls (PCBs) and heavy metals besides copper on the lake system.

The objectives of this thesis are to summarize the status of contamination and remediation activities in Torch Lake and to estimate the magnitude of potential sources of PCBs to Torch Lake. First, a brief overview of …

A Characterization Of The Water Quality Conditions And Pollutant Loads In Surface Waters Near The Northeast Ohio Regional Sewer District’S Combined Sewer System In Cleveland, Ohio, Nathan Zgnilec

Dissertations, Master's Theses and Master's Reports

The Northeast Ohio Regional Sewer District (NEORSD, Cleveland, OH) serves over one million citizens through the operation of three waste water treatment plants. NEORSD provides this service through combined and separated sewer systems, which, during rainfall events, are known to deliver large volumes of untreated wastewater containing high concentrations of Escherichia coli (E.coli), ammonia nitrogen, and phosphorus. NEORSD is currently investing $3 billion over the next 25 years to mitigate its combined sewer overflows and plans to allocate additional funds to improve remaining pollutant sources related to its system, e.g. separated sewers. A suite of PC-SWMM pollutant loading models have …

Assessing The Impacts Of Climate Change On The Surface Temperature Of Inland Lakes In Michigan, Kaitlin Reinl

Dissertations, Master's Theses and Master's Reports

The aim of this study was to validate and apply a lake model for predicting the susceptibility of small inland lakes in Michigan to changes in thermal regime and increased cyanobacteria growth as a result of future climate conditions. The Freshwater Lake Model was selected, tested for sensitivity to various inputs, and validated through comparison to observed conditions. The sensitivity analysis showed that the lake model was most sensitive to solar radiation, air temperature, and air humidity. Comparison of predicted climate data with observed conditions revealed highly variable climate model error. The lake model validation was conducted using 10 lakes …

Temporal Trends And Spatial Variabilities Of Pcb Concentrations In Lake Trout From Lake Superior From 1995 To 2013, Hongyi Lin

Dissertations, Master's Theses and Master's Reports

It has been frequently reported that concentrations of PCBs in the Great Lakes fish have declined dramatically since their ban on production and use in 1979 in the United States, although some studies suggested that recent rates of decline are leveling off. In order to examine the temporal trends and spatial variabilities of PCB concentrations in lake trout (Salvelinus namaycush) from Lake Superior during the past two decades, statistical analyses were performed on fish sample data collected by two national agencies (U.S. EPA, Environment and Climate Change Canada) and three state agencies (Michigan Department of Environmental Quality, Minnesota …

Chemical Removal Of Total Phosphorus From Wastewater To Low Levels And Its Analysis, Farah Ateeq

Theses and Dissertations (Comprehensive)

Numerous studies have been conducted on the removal of inorganic phosphorus (P) from wastewater, but a push towards lower effluent targets necessitates the additional removal of organic phosphorus as well. This study tested the ability of manganese oxide nanoparticles and iron oxide as potential catalysts for conversion of organic P into more readily removable inorganic forms, as well as the role of iron(III) chloride as coagulant to subsequently allow P to be removed by solids/liquid separation. Removals of 99-101% were obtained for model compounds at pH 5-7, 0.05-0.5 M H₂O₂, and Fe:P molar ratio of 5:1. …

Sulfate-Reducing Bacteria Community Analysis: Isco/Isb Coupled Remediation, Christopher K. Bartlett

Theses and Dissertations (Comprehensive)

Improved techniques for remediating groundwater systems are required for the more than 500,000 contaminated sites in North America. Many of these sites are the legacy of historical industrial operations, inappropriate disposal practices and accidental releases. The most widely observed contaminant at many of these sites is petroleum hydrocarbons (PHCs). Recently, remediation efforts that involve the sequential application of treatment technologies have gained widespread interest. One specific sequential technology application or treatment train employs the aggressive nature of a chemical oxidation followed by bioremediation for polishing. When persulfate is used as the chemical oxidant its natural degradation by-product is sulfate, an …

Phosphorus Removal Using Titanium Dioxide Nanoparticles In Wastewater Treatment, Suyoung Choi Mr.

Theses and Dissertations (Comprehensive)

Due to eutrophication caused by nutrients such as phosphorus (P), local surface water near military garrisons and camps has been deteriorated for several years in the Republic of Korea. Thus, in order to remove excessive P in local fresh water, various size of titanium dioxide (TiO₂) were used.

In the first investigation, TiO₂ mixed bulk powder (particle size > 5µm) showed maximum P removal with pH dependence (higher pH shows lower P removal), that was approximately 27%. To determine adsorption isotherms, Langmuir and Freudlich models were used. The experimental data was better fit by a Langmuir model compared …

Bio-Physical Closure Criteria Without Reference Sites: Realistic Targets In Modified Rivers, Melanie L. Blanchette, Mark Lund, Robyn Stoney, Digby Short, Colm Harkin

Research outputs 2014 to 2021

The use of reference sites for establishing closure criteria in areas disturbed by mining activities is common practice. ‘Reference’ sites are those considered to be largely unimpacted by anthropogenic activity (retaining desirable natural characteristics), and occurring near disturbed sites. Sites are considered rehabilitated when their biophysical condition approximates that of the reference site. However, this approach often creates impossible or unrealistic targets for miners seeking to close rehabilitated lands. For example, reference sites are often limited in availability (or non-existent) due to impacts by other land uses. Further, any available reference sites might not be realistic matches for the rehabilitated …

Particle Mediated Enhanced Mass Transfer Of Diethylhexyl Phthalate: A Pilot Scale System Design, Melissa Buechlein

Masters Theses

"Phthalates are a class of SVOCs that are widely used as plasticizers and recently epidemiological and toxicological research has found a link between phthalate exposure and increased occurrences of adverse health effects. SVOCs can potentially partition into household dust and airborne particles. Models and micro chamber studies have identified that airborne particles effectively increase SVOC deposition to or emissions from surfaces; SVOCs partition to aerosols in the bulk air, the aerosols then migrate to the surfaces due to eddy and Brownian motion, and then the SVOCs is released inside the SVOC concentration boundary layer adjacent to the surface. Concentration boundary …

Phytoforensics Tools: The Degradation And Detection Of Chlorinated Solvents In Integrated Systems, Tommy J. Goodwin Jr.

Masters Theses

"Due to decades of mismanaged pollutants entering groundwater, subsurface pollution of various compounds has become a widespread challenge. Chlorinated solvents are the most common groundwater contaminants that persist in aquifers, and remediation of these wide-spread plumes is difficult. Bioremediation, permeable reactive barriers, and phytoremediation are remedial technologies that have been developed and applied to chlorinated solvents in groundwater systems. This study integrates these technologies in different combinations to demonstrate the remediation potential of this approach. Zerovalent iron (ZVI) and bioaugmentation with a Dehalococcoides sp. (DHC) culture were applied separately and in combination for degradation of perchloroethene (PCE). Salix pentandra were …

Imaging Reinforced Concrete: A Comparative Study Of Ground Penetration Radar And Rebarscope, Abhishek Kodi

Masters Theses

"Geophysical techniques have been playing a very vital role in subsurface imaging in the recent past. Technology has been making it both reliable and convenient to utilize non-destructive geophysics techniques like Ground Penetration Radar, Induction current based Rebarscope, Seismic methods, ERT, etc. The applications range from shallow subsurface investigation of Bridge decks to old tunnels, mapping of rabars in a pre-existing construction and analyzing the concrete strength.

The thesis constitutes of a comparative study and analysis of a Ground Penetration Radar system and a Rebarscope. Individual parameters obtained directly from the study and obtained indirectly from the study shall be …

Silicone Hollow Fiber Membrane Bioreactors For Mixed Aerobic And Anaerobic Treatment Of Gas Phase Toluene And Trichloroethylene, Alexander Lee Korff

Masters Theses

"Volatile Organic Compounds (VOCs) are common in effluent waste streams from many sectors of industry and low-cost emission control technologies have the potential to mitigate long-term impacts on the environment. Federal Regulations, such as the Clean Air Act and National Emission Standards for Hazardous Air Pollutants (NESHAPS), as well as state regulations are imposing stricter requirements on point-source emissions, with an emphasis on toxic VOCs. Trichloroethylene (TCE) and tetrachloroethylene (PCE), which are toxic VOCs, have been used since the 1920's for a variety of industrial applications like: degreasing, paint and printing operations, as extraction solvents, and for cleaning and drying …

Assessing Downstream Stormwater Impacts For Urban Watershed Planning, Johanna Meyer Pavlowsky

Masters Theses

"The urbanization of watersheds has caused debilitating effects to downstream aquatic ecosystems in catchments and streams. The implementation of green infrastructure (GI), such as permeable pavements and bioretention facilities, has been shown to alleviate these effects by both reducing runoff and mitigating pollutants; however, the implements are often not designed with a specific goal of water improvement. This study targets understanding a small, impaired urban watershed, and the benefits green infrastructure may have to provide environmental, social, and economic improvement to the watershed.

Portions of Rolla including much of the S&T campus drain into the impaired urban waterbody Frisco Lake, …

Evaluating Groundwater Recharge In The Saloum Region Of Senegal, Alexander Wohlgemuth

Dissertations, Master's Theses and Master's Reports

Approximately 1.2 billion people in the world live in an area facing physical, or absolute, water scarcity (defined as access to less than 1,000 cubic meters of water). This number is projected to increase to 1.8 billion by the year 2025. Thirty-eight percent of the world’s population lives in arid, semi-arid or dry subhumid regions, which translates to a high dependence on the 30% of the world’s freshwater present in the ground. Further, the rate of water use is increasing rapidly – between two and two and a half times that of population growth, over the last century.

In regions …

Pilot-Scale Study Of Low-Tech Methods Of Sustainable Class A Biosolids Production: A Trial Run, Rebecca L. Green

Dissertations, Master's Theses and Master's Reports

Water resource recovery facilities can improve sustainability by producing Class A biosolids. However, many conventional methods for achieving Class A biosolids are expensive, with high maintenance and energy costs. However, low-cost, low-tech (LCLT) treatment methods are also available. The overall goal of the larger project of which this study was a part is to develop a rational and universal approach for design of LCLT processes. To achieve this goal, pilot-scale studies of LCLT processes will be performed. The goal of this portion of the project was to perform a trial run pilot-scale study. During the trial run, the pilot-scale biosolids …

A Cultural And Technical Study Of Wastewater Treatment Plant Maintenance In A Small Community In Peru, Rebecca C. Midkiff

Dissertations, Master's Theses and Master's Reports

Management of wastewater treatment plants (WWTPs) has been found to be especially challenging in small, rural communities of the developing world. This study examined maintenance of two small WWTPs in Leymebamba and Palmira, Peru through interviews with local authorities, observation of maintenance practices, wastewater measurements, and prediction of effects from maintenance with modeling using a wastewater process simulation software, BioWin. Challenges and motivations related to maintenance were investigated with semi-structured interviews, and maintenance practices were recorded during observations. It was found that outside supervision was a key motivating factor, and the existence of an operator who is supported by the …

Designing A Permeable Reactive Barrier For The Remediation Of Copper Contaminated Groundwater., Christopher Walkons

Dissertations, Master's Theses and Master's Reports

This project details the design of a sorption based pilot-scale permeable reactive barrier (PRB) for the removal of copper from groundwater. The reactive material for the barrier is the residual of coagulants used in drinking water treatment operations. Physical and chemical properties of these water treatment residuals (WTR) have been studied to optimize PRB design. Batch reactor tests have shown that equilibrium sorption of copper can be fit to a Langmuir type isotherm. Kinetic and column experiments have been conducted to understand the significance of chemical and physical mass transfer limitations. A leaching test indicated the concentrations of hazardous elements …

A Sustainability-Based Project Selection Algorithm: Socio-Technical-Economic Project Selection (Steps) Algorithm, Bharathi Bhattu

Dissertations, Master's Theses and Master's Reports

Multi-dimensional aspects play a vital role in the task of project-decision making. Environmental effects are to be considered in addition to other technical and non-technical aspects in order to avoid undue environmental damage. This current work introduces a new decision-making algorithm (Socio-Technical-Economic Project Selection or STEPS) that is demonstrated with the use of RCA (recycled concrete aggregate) as riprap for slope stabilization and erosion control which leaches chemical arsenic when in contact with water. Arsenic has long been recognized for its lethal properties. The main intention of introducing this new algorithm is to use sustainability concepts of social, technical, and …

Modeling Impacts Of Combined Sewer Overflows In Swmm In Cleveland, Ohio, Zoe A. Miller

Dissertations, Master's Theses and Master's Reports

Despite its legacy of pollution, the City of Cleveland, Ohio, has historically been at the forefront of water quality management. Today, the Northeast Ohio Regional Sewer District (NEORSD), which serves the Greater Cleveland area, is following a consent decree with the State of Ohio to minimize combined sewer overflows (CSOs), along with implementing an integrated Clean Water Act planning study to prioritize infrastructure improvements with a broader view of water quality objectives. This report summarizes an urban watershed modeling effort to support the integrated planning (IP) process. Specifically, the development, calibration, and validation of the EPA Stormwater Management Model (SWMM) …

Treatment Of Dissolved Metals For Direct Potable Reuse, Cesar Alberto Alvarez

Open Access Theses & Dissertations

In the process of direct potable reuse (DPR), the bulk of the removal of dissolved metals removal is accomplished by reverse osmosis. This treatment is especially important in wastewater containing contaminants from industrial processes. The goal of this research was to evaluate the performance of DPR with respect to the removal of salinity and dissolved metals to meet drinking standards. Samples were collected from the El Paso Water Utilities Advanced Water Purification pilot system throughout various points in the treatment process. The samples were analyzed for their concentration of ions with Ion Chromatography (IC) and dissolved metals using an Inductively …

Assessing Public Health Burden Associated With Exposure To Ambient Black Carbon In The United States, Ying Li, Daven K. Henze, Darby Jack, Barron H. Henderson, Patrick L. Kinney

ETSU Faculty Works

Black carbon (BC) is a significant component of fine particulate matter (PM_2.5) air pollution, which has been linked to a series of adverse health effects, in particular premature mortality. Recent scientific research indicates that BC also plays an important role in climate change. Therefore, controlling black carbon emissions provides an opportunity for a double dividend. This study quantifies the national burden of mortality and morbidity attributable to exposure to ambient BC in the United States (US). We use GEOS–Chem, a global 3-D model of atmospheric composition to estimate the 2010 annual average BC levels at 0.5 x 0.667° …

Rubber Roads For The Rubber City: Testing The Suitability Of Rubberized Asphalt For Roads In Northeast Ohio, Jessica M. Fraser

Williams Honors College, Honors Research Projects

This research paper explores the benefits of using rubberized asphalt concrete (RAC) versus normal asphalt concrete (NAC) and why it is environmentally important. New road construction and repair of roadways due to potholes are always occurring in Northeast Ohio. Recently, the city of Akron’s transportation budget has increased, which includes projects such as reconstructing asphalt and resurfacing pavements throughout the city of Akron. Using rubberized asphalt may improve the quality of our roads and reduce roadway degradation which will likely save cities money.

Using rubberized asphalt recycles old tires, which do not decompose, and creates a positive use for them …

Application Of Secondary Analyses On Industrial Data Sets, Luis G. Perez

Open Access Theses & Dissertations

Secondary analysis on quantitative data sets is the in-depth analysis of relationships, trends, patterns or behaviors that are not obvious from a superficial examination of data but that can be very germane in the application of that data. The present work presents a framework for investigators to use in applying secondary analysis on big data that correlates to the research topic. The framework can facilitate the illumination of possible data behaviors or patterns that could be useful in arriving at an answer to a question. Behavior of monitored equipment (analyzers, meters, etc.) can easily be depicted and can be used …

Evaluation Of Point Of Use Reverse Osmosis Systems For Drinking Water In Colonias, Oscar Daniel Ramirez

Open Access Theses & Dissertations

Clean drinking water is often considered a right and not a privilege, especially in first world countries. However, thousands of residents of colonias (settlements in the U.S. that lack access to basic infrastructure) struggle to obtain clean drinking water, including some in the Paso del Norte Region. Residents of colonias located in Doña Ana County, NM, and El Paso County, TX typically rely on domestic wells and hauled water, respectively, but these sources may be of inadequate quality, potentially posing a health risk due to microbiological contamination, presence of arsenic, or elevated concentration of total dissolved solids. This project brings …

Removal Of Iron, Zinc, And Copper From Waters Impacted By Acid Mine Drainage Using Natural Zeolite, Mackayla Janae Thyfault

Open Access Theses & Dissertations

In this research, the adsorption behavior of zeolites with respect to iron (Fe), zinc (Zn), and copper (Cu) has been studied in order to assess its application to heavy metal removal in polluted settings caused by acid mine drainage (AMD). The St. Cloud zeolitic deposit used in this project was characterized using a sieve analysis; the effective diameter and coefficient of uniformity were calculated. Batch studies were performed, and the samples were analyzed using ICP-OES. Batch studies used metal concentrations ranging from 50 mg/L to 650 mg/L. Freundlich, Linear, Langmuir, and BET adsorption isotherms were applied and evaluated to the …