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Articles 961 - 990 of 5701

Full-Text Articles in Engineering

Editorial: Disease Biomarker Analysis Based On Optical Biosensing, Tianshu Chen, Fanben Meng, Binwu Ying, Xiaoli Zhu Apr 2023

Editorial: Disease Biomarker Analysis Based On Optical Biosensing, Tianshu Chen, Fanben Meng, Binwu Ying, Xiaoli Zhu

Department of Mechanical and Materials Engineering: Faculty Publications

Disease biomarker analysis has become a crucial tool for diagnosing and evaluating disease prognosis, especially with the increasing understanding of diseases at the molecular level. Abnormalities in various biomarkers can indicate diseased states, and can be used to rapidly and specifically detect and quantify diseases using optical biosensing techniques (Gao et al., 2023). Optical biosensing techniques have several advantages over traditional methods including higher sensitivity, specificity, and faster analysis times (Plikusiene and Ramanaviciene, 2023). It also allows for non-invasive sample collection. With advancements in optical biosensing technology, many medical conditions including cancers, infectious diseases, and autoimmune disorders can be accurately …


Editorial: Disease Biomarker Analysis Based On Optical Biosensing, Tianshu Chen, Fanben Meng, Binwu Ying, Xiaoli Zhu Apr 2023

Editorial: Disease Biomarker Analysis Based On Optical Biosensing, Tianshu Chen, Fanben Meng, Binwu Ying, Xiaoli Zhu

Department of Mechanical and Materials Engineering: Faculty Publications

Disease biomarker analysis has become a crucial tool for diagnosing and evaluating disease prognosis, especially with the increasing understanding of diseases at the molecular level. Abnormalities in various biomarkers can indicate diseased states, and can be used to rapidly and specifically detect and quantify diseases using optical biosensing techniques (Gao et al., 2023). Optical biosensing techniques have several advantages over traditional methods including higher sensitivity, specificity, and faster analysis times (Plikusiene and Ramanaviciene, 2023). It also allows for non-invasive sample collection. With advancements in optical biosensing technology, many medical conditions including cancers, infectious diseases, and autoimmune disorders can be accurately …


Considering The Influence Of Coronary Motion On Artery‑Specific Biomechanics Using Fluid–Structure Interaction Simulation, Nicholas A. T. Fogell, Miten Patel, Pan Yang, Roosje M. Ruis, David B. Garcia, Jarka Naser, Fotios Savvopoulos, Clint Davies Taylor, Anouk L. Post, Ryan M. Pedrigi, Ranil De Silva, Rob Krams Apr 2023

Considering The Influence Of Coronary Motion On Artery‑Specific Biomechanics Using Fluid–Structure Interaction Simulation, Nicholas A. T. Fogell, Miten Patel, Pan Yang, Roosje M. Ruis, David B. Garcia, Jarka Naser, Fotios Savvopoulos, Clint Davies Taylor, Anouk L. Post, Ryan M. Pedrigi, Ranil De Silva, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

The endothelium in the coronary arteries is subject to wall shear stress and vessel wall strain, which influences the biology of the arterial wall. This study presents vessel-specific fluid–structure interaction (FSI) models of three coronary arteries, using directly measured experimental geometries and boundary conditions. FSI models are used to provide a more physiologically complete representation of vessel biomechanics, and have been extended to include coronary bending to investigate its effect on shear and strain. FSI both without- and with-bending resulted in significant changes in all computed shear stress metrics compared to CFD (p = 0.0001). Inclusion of bending within …


A Threshold Helium Leakage Detection Switch With Ultra Low Power Operation, Sulaiman Mohaidat, Fadi M. Alsaleem Apr 2023

A Threshold Helium Leakage Detection Switch With Ultra Low Power Operation, Sulaiman Mohaidat, Fadi M. Alsaleem

Department of Mechanical and Materials Engineering: Faculty Publications

Detecting helium leakage is important in many applications, such as in dry cask nuclear waste storage systems. This work develops a helium detection system based on the relative permittivity (dielectric constant) difference between air and helium. This difference changes the status of an electrostatic microelectromechanical system (MEMS) switch. The switch is a capacitive-based device and requires a very negligible amount of power. Exciting the switch’s electrical resonance enhances the MEMS switch sensitivity to detect low helium concentration. This work simulates two different MEMS switch configurations: a cantilever-based MEMS modeled as a single-degreefreedom model and a clamped-clamped beam MEMS molded using …


Leipzig Applicator Dose Study Progress And Mesh Computational Phantoms, Julianna Davis Apr 2023

Leipzig Applicator Dose Study Progress And Mesh Computational Phantoms, Julianna Davis

Undergraduate Research Competition

Leipzig applicators are tools used to administer brachytherapy, which is a treatment for skin cancer that is typically used when it occurs on the face of the patient. This treatment requires the patient to have lead shielding over their eyes to protect the sensitive lenses. This study is in the progress of modeling this scenario in order to determine the radiation dose delivered to the patient’s eyes due to the lead shielding. This is being done in a Monte Carlo computational radiation transport program, EGS (Electron Gamma Shower,) which was previously unable to handle mesh computational phantoms. After working with …


A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen Apr 2023

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent studies on precipitation-hardened high-entropy alloys (HEAs) demonstrate their high strength and thermal stability, making them promising materials for high-temperature structural applications such as nuclear reactors. However, many existing HEAs contain cobalt (Co), which is unsuitable for nuclear applications because of the long-term activation issue of Co. Co is also expensive and considered a critical material for other applications. Therefore, it is desired to exclude Co from the composition. a Co-free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA was developed and studied in this work. in contrast to previous Co-free HEAs, this alloy is close to Equi atomic in its composition and promises a more …


Development Of Novel Electrodes And Electrolytes For Safer Aqueous Ammonium Ion Batteries With Enhanced Performance., Shelton Farai Kuchena Apr 2023

Development Of Novel Electrodes And Electrolytes For Safer Aqueous Ammonium Ion Batteries With Enhanced Performance., Shelton Farai Kuchena

LSU Doctoral Dissertations

The Lithium-ion battery (LIBs) system has dominated the battery market because of its superior energy and power density. Problems related to LIBs such as safety, scarcity of cobalt and lithium have led researchers to explore alternative battery systems. NH4+ ion is a nonmetal charge carrier with lower molar mass (18 mol g-1) and smaller hydrated ionic size (3.31 Å) which results in excellent electrochemical properties. Furthermore, NH4+ ion has a tetrahedral structure that has no preferred orientation as compared to spherical metal ions giving a different intercalation chemistry based on hydrogen bonding. These properties …


Crystalline–Amorphous Nanostructures: Microstructure, Property And Modelling, Binqiang Wei, Lin Li, Lin Shao, Jian Wang Apr 2023

Crystalline–Amorphous Nanostructures: Microstructure, Property And Modelling, Binqiang Wei, Lin Li, Lin Shao, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Crystalline metals generally exhibit good deformability but low strength and poor irradiation tolerance. Amorphous materials in general display poor deformability but high strength and good irradiation tolerance. Interestingly, refining characteristic size can enhance the flow strength of crystalline metals and the deformability of amorphous materials. Thus, crystalline–amorphous nanostructures can exhibit an enhanced strength and an improved plastic flow stability. In addition, high-density interfaces can trap radiation-induced defects and accommodate free volume fluctuation. In this article, we review crystalline–amorphous nanocomposites with characteristic microstructures including nanolaminates, core–shell microstructures, and crystalline/amorphous-based dual-phase nanocomposites. The focus is put on synthesis of characteristic microstructures, deformation …


Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University Apr 2023

Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University

Engineering Newsletters

No abstract provided.


Plasmon Enhanced Quantum Properties Of Single Photon Emitters With Hybrid Hexagonal Boron Nitride Silver Nanocube Systems, Mohammadjavad Dowran, Andrew Butler, Suvechhya Lamichhane, Adam Erickson, Ufuk Kilic, Sy_Hwang Liou, Christos Argyropoulos, A. Laraoui Apr 2023

Plasmon Enhanced Quantum Properties Of Single Photon Emitters With Hybrid Hexagonal Boron Nitride Silver Nanocube Systems, Mohammadjavad Dowran, Andrew Butler, Suvechhya Lamichhane, Adam Erickson, Ufuk Kilic, Sy_Hwang Liou, Christos Argyropoulos, A. Laraoui

Department of Mechanical and Materials Engineering: Faculty Publications

Hexagonal boron nitride (hBN) has emerged as a promising ultrathin host of single photon emitters (SPEs) with favorable quantum properties at room temperature, making it a highly desirable element for integrated quantum photonic networks. One major challenge of using these SPEs in such applications is their low quantum efficiency. Recent studies have reported an improvement in quantum efficiency by up to two orders of magnitude when integrating an ensemble of emitters such as boron vacancy defects in multilayered hBN flakes embedded within metallic nanocavities. However, these experiments have not been extended to SPEs and are mainly focused on multiphoton effects. …


Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang Mar 2023

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang

Journal of Electrochemistry

Practical applications of lithium-sulfur (Li-S) batteries are hindered mainly by the low sulfur utilization and severe capacity fading derived from the polysulfide shuttling. Catalysis is an effective remedy to those problems by promoting the conversion of polysulfides to reduce their accumulation in the electrolyte, which needs the catalyst to have efficient adsorption ability to soluble polysulfides and high activity for their conversion. In this work, we have proposed a bimetallic compound of NiCo2S4 anchored onto sulfur-doped graphene (NCS@SG) to fabricate a catalytic interlayer for Li-S batteries. Compared to CoS, the NiCo2S4 demonstrated much higher …


Physics-Based Crystal Plasticity Model For Predicting Microstructure Evolution And Dislocation Densities, Juyoung Jeong Mar 2023

Physics-Based Crystal Plasticity Model For Predicting Microstructure Evolution And Dislocation Densities, Juyoung Jeong

LSU Doctoral Dissertations

This work presents three different studies investigating plastic deformation mechanisms in metals and alloys using crystal plasticity finite element (CPFE) modeling. The first study presents a new nonlocal crystal plasticity model for face-centered cubic single crystals under heterogeneous inelastic deformation. The model incorporates generalized constitutive relations that incorporate the thermally activated and drag mechanisms to cover different kinetics of viscoplastic flow in metals and describes the plastic flow and yielding of single-crystals using dislocation densities. The model is compared to micropillar compression experiments for copper single crystals and clarifies the complex microstructural evolution of dislocation densities in metals. The second …


Preface To The Special Issue On Lithium-Sulfur Batteries, Jia-Jia Chen, Ren-Jie Chen, Zhong Jin Mar 2023

Preface To The Special Issue On Lithium-Sulfur Batteries, Jia-Jia Chen, Ren-Jie Chen, Zhong Jin

Journal of Electrochemistry

No abstract provided.


Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang Mar 2023

Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang

Journal of Electrochemistry

All solid-state lithium-sulfur batteries (ASSLSBs) are considered to be one of the most promising next-generation energy storage systems, due to the promises of high energy density and safety. Although the use of solid-state electrolytes could effectively suppress the "shuttle effect" and self-discharge of the conventional liquid lithium-sulfur (Li-S) battery, the commercialization of ASSLSBs has been seriously hampered by the electrolyte degradation, electrode/electrolyte interfacial deterioration, electrochemo-mechanical failure, lithium dendrite growth and electrode pulverization, etc. This paper provides a comprehensive review of recent research progresses on the solid-state electrolytes, sulfur-containing composite cathodes, lithium metal and lithium alloy anodes, and electrode/electrolyte interfaces in …


A Review On Solid-State Li-S Battery: From The Conversion Mechanism Of Sulfur To Engineering Design, Huan-Huan Jia, Chen-Ji Hu, Yi-Xiao Zhang, Li-Wei Chen Mar 2023

A Review On Solid-State Li-S Battery: From The Conversion Mechanism Of Sulfur To Engineering Design, Huan-Huan Jia, Chen-Ji Hu, Yi-Xiao Zhang, Li-Wei Chen

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries attract sustained attention because of their ultrahigh theoretical energy density of 2567 Wh·kg–1 and the actual value over 600 Wh·kg–1. Solid-state Li-S batteries (SSLSBs) emerge in the recent two decades because of the enhanced safety when compared to the liquid system. As for the SSLSBs, except for the difference in the conversion mechanism induced by the cathode materials themselves, the physical-chemical property of solid electrolytes (SEs) also significantly affects their electrochemical behaviors. On account of various reported Li-S batteries, the advantages and disadvantages in performance and the failure mechanism are discussed in this review. …


Coni-Based Bimetal-Organic Framework Derived Carbon Composites Multifunctionally Modified Separators For Lithium-Sulfur Batteries, Yan-Jie Wang, Hong-Yu Cheng, Ji-Yue Hou, Wen-Hao Yang, Rong-Wei Huang, Zhi-Cong Ni, Zi-Yi Zhu, Ying Wang, Ke-Yi Wei, Yi-Yong Zhang, Xue Li Mar 2023

Coni-Based Bimetal-Organic Framework Derived Carbon Composites Multifunctionally Modified Separators For Lithium-Sulfur Batteries, Yan-Jie Wang, Hong-Yu Cheng, Ji-Yue Hou, Wen-Hao Yang, Rong-Wei Huang, Zhi-Cong Ni, Zi-Yi Zhu, Ying Wang, Ke-Yi Wei, Yi-Yong Zhang, Xue Li

Journal of Electrochemistry

The commercial application of lithium-sulfur batteries (LSB) is still limited by the irreversible capacity fading caused by the shuttle of lithium polysulfides (LIPS). To address this issue, a bimetal (nickel, cobalt)-organic framework (MOF) derived carbon, (Ni, Co)/C, was prepared to modify the separator. The multifunctionally modified separator effectively captures LIPS, ensuring the stability and reversibility of sulfur fixation, while providing catalytic activity and improving ionic conductivity. The cobalt metal has a larger coordination number, more pore structure distribution, larger specific surface area, more surface C=O, and smaller particle size to achieve a large and rapid chemical sulfur fixation. The high …


Graphene Twistronics: Tuning The Absorption Spectrum And Achieving Metamaterial Properties, Ammar Armghan, Meshari Alsharari, Khaled Aliqab, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel Mar 2023

Graphene Twistronics: Tuning The Absorption Spectrum And Achieving Metamaterial Properties, Ammar Armghan, Meshari Alsharari, Khaled Aliqab, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel

Department of Mechanical and Materials Engineering: Faculty Publications

Graphene twistronics using multilayer graphene is presented in such a way that it provides a metamaterial effect. This manuscript also analyzes the prediction of behavior using machine learning. The metamaterial effect is achieved by twisting the graphene layers. Graphene twistronics is a new concept for changing the electrical and optical properties of bilayer graphene by applying a small angle twist between the layers. The angle twists of 5o, 10o, and 15o are analyzed for the proposed graphene twistronics design. Tuning in the absorption spectrum is achieved by applying small twists to the angles of the …


Heterogeneous Sensor Data Fusion For Multiscale, Shape Agnostic Flaw Detection In Laser Powder Bed Fusion Additive Manufacturing, Benjamin Bevans, Christopher Barrett, Thomas Spears, Aniruddha Gaikwad, Alex Riensche, Harold (Scott) Halliday, Prahalada Rao Mar 2023

Heterogeneous Sensor Data Fusion For Multiscale, Shape Agnostic Flaw Detection In Laser Powder Bed Fusion Additive Manufacturing, Benjamin Bevans, Christopher Barrett, Thomas Spears, Aniruddha Gaikwad, Alex Riensche, Harold (Scott) Halliday, Prahalada Rao

Department of Mechanical and Materials Engineering: Faculty Publications

We developed and applied a novel approach for shape agnostic detection of multiscale flaws in laser powder bed fusion (LPBF) additive manufacturing using heterogenous in-situ sensor data. Flaws in LPBF range from porosity at the micro-scale (< 100 μm), layer related inconsistencies at the meso-scale (100 μm to 1 mm) and geometry-related flaws at the macroscale (> 1 mm). Existing data-driven models are primarily focused on detecting a specific type of LPBF flaw using signals from one type of sensor. Such approaches, which are trained on data from simple cuboid and cylindrical-shaped coupons, have met limited success when used for detecting multiscale flaws in complex LPBF parts. The objective of this work is to develop a heterogenous sensor data fusion …


Developable Mechanisms On Regular Cylindrical Surfaces, Jacob R. Greenwood, Spencer P. Magleby, Larry L. Howell Mar 2023

Developable Mechanisms On Regular Cylindrical Surfaces, Jacob R. Greenwood, Spencer P. Magleby, Larry L. Howell

Faculty Publications

Developable mechanisms can provide high functionality and compact stowability. This paper presents engineering models to aid in the design of cylindrical developable mechanisms. These models take into account the added spatial restrictions imposed by the developable surface. Equations are provided for the kinematic analysis of cylindrical developable mechanisms. A new classification for developable mechanisms is also presented (intramobile, extramobile, and transmobile) and two graphical methods are provided for determining this clas sification for single-DOF planar cylindrical developable mechanisms. Characteristics specific to four-bar cylindrical developable mechanisms are also discussed.


Oh, My Darling Clementine: A Detailed History And Data Repository Of The Los Alamos Plutonium Fast Reactor, Hannah K. Patenaude, Franz J. Freibert Mar 2023

Oh, My Darling Clementine: A Detailed History And Data Repository Of The Los Alamos Plutonium Fast Reactor, Hannah K. Patenaude, Franz J. Freibert

College of Sciences Graduate Student Research

The Los Alamos Plutonium Fast Reactor, Clementine, provided the first fast neutron spectrum using a metallic plutonium fuel system and liquid mercury coolant. Clementine is often mentioned in the history of fast, metal-fueled, or metal-cooled designs, with little public information regarding the specifications or timeline. This paper contains a synopsis of each report regarding the development, operation, experimental results, failures, and subsequent disassembly of Clementine to explore this unique reactor within the context of modern advanced reactor development.


Mechanical Properties And Performance Of A Novel Nano-Engineered Unitized Composite With Quasi-Isotropic Layup, Brian Matthew Pudlo Mar 2023

Mechanical Properties And Performance Of A Novel Nano-Engineered Unitized Composite With Quasi-Isotropic Layup, Brian Matthew Pudlo

Theses and Dissertations

Carbon nanotubes (CNTs) exhibit outstanding mechanical, electrical, and thermal properties, but are a challenge to effectively implement into macroscopic composites for aerospace applications. This research investigates the mechanical properties and performance of a newly developed hybrid NanoStitch composite, alongside a control polymer matrix composite, at room temperature. Both composite material systems investigated in this work have quasi-isotropic layup. Monotonic tension-tofailure, tension-tension fatigue, and creep tests were performed to characterize the performance of the composites under cyclic and sustained loading. Experimental results obtained for the quasi-isotropic NanoStitch composite were compared to those obtained for the quasi-isotropic control composite. The properties and …


Precious Plastics - Plastic Brick Machine Fabrication, Timothy Ukaobasi Kanu, Evi Paraskevi Troulis Mar 2023

Precious Plastics - Plastic Brick Machine Fabrication, Timothy Ukaobasi Kanu, Evi Paraskevi Troulis

Architectural Engineering

The goal of this research is to determine the structural parameters of the recycled plastic polypropylene when molded into bricks resembling CMU blocks. To accomplish this, three mechanisms had to be assembled: the shredder, the injector, and the 1x1 mold. A tensile and compression test were to be performed on the plastic brick, and the values would be used to compare the tensile and compressive strength of PP plastic bricks, as well as their modulus of elasticity and stress vs. Strain performance. These values would be analyzed to determine whether it would be feasible to build an entire plastic wall. …


Towards An Understanding Of The Thermodynamic Properties Of Crtao4: A Computational Perspective, Tanner B. Gordon Mar 2023

Towards An Understanding Of The Thermodynamic Properties Of Crtao4: A Computational Perspective, Tanner B. Gordon

Theses and Dissertations

Materials that can withstand higher temperatures are paramount for next-generation aircraft design. Hypersonic capabilities and jet-turbine engines operate in extreme environments. Choosing materials that have high thermal stability and oxidation resistance for these applications can increase engine efficiency, reduce size, weight and power (SWaP), and increase the maneuverability of the aircraft. The mixed oxide CrTaO4 has been experimentally observed to significantly contribute to oxidation resistance at high temperatures. However, and despite its significance, its properties remain largely unknown. This work explores the thermal properties of this material from a multi-scale approach, by obtaining an accurate description of the thermodynamics …


Multifunctional Microgel-Based Cream Hydrogels For Postoperative Abdominal Adhesion Prevention, Bo Liu, Yunfan Kong, Olawale A. Alimi, Mitchell Kuss, Huiyin Tu, Wenfeng Hu, Abu Rafay, Kumar Vikas, Wen Shi, Megan Lerner, William L. Berry, Yulong Li, Mark A. Carlson, Bin Duan Feb 2023

Multifunctional Microgel-Based Cream Hydrogels For Postoperative Abdominal Adhesion Prevention, Bo Liu, Yunfan Kong, Olawale A. Alimi, Mitchell Kuss, Huiyin Tu, Wenfeng Hu, Abu Rafay, Kumar Vikas, Wen Shi, Megan Lerner, William L. Berry, Yulong Li, Mark A. Carlson, Bin Duan

Department of Mechanical and Materials Engineering: Faculty Publications

Postoperative abdominal adhesions are a common problem after surgery and can produce serious complications. Current anti-adhesive strategies focus mostly on physical barriers and are unsatisfactory and inefficient. In this study, we designed and synthesized advanced injectable cream-like hydrogels with multiple functionalities, including rapid gelation, self-healing, anti-oxidation, anti-inflammation, and anti-cellular adhesion. The multifunctional hydrogels were facilely formed by the conjugation reaction of epigallocatechin gallate (EGCG) and hyaluronic acid (HA)-based microgels and polyvinyl alcohol (PVA) based on the dynamic boronic ester bond. The physicochemical properties of the hydrogels including anti-oxidative and anti-inflammatory activities were systematically characterized. A mouse cecum-abdominal wall adhesion model …


Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun Feb 2023

Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun

Journal of Electrochemistry

Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell, which has already attracted growing popularities. However, current methanol oxidation electrocatalysts fall far short of expectations and suffer from excessive use of noble metal, mediocre activity, and rapid decay. Here we report the Pt anchored on NiFe-LDHs surface hybrid for stable methanol oxidation in alkaline media. Based on the high intrinsic methanol oxidation activity of Pt nanoparticles, the substrates NiFe-LDHs further enhanced anti-poisoning ability and maintained unaffected stability after 200,000 s cycle test compared to commercial Pt/C catalyst. The …


The Fourth Industrial Revolution: Opportunities And Challenges To The Future Of Mechanical Engineering, Ulingeta O.L. Mbamba Feb 2023

The Fourth Industrial Revolution: Opportunities And Challenges To The Future Of Mechanical Engineering, Ulingeta O.L. Mbamba

Tanzania Journal of Engineering and Technology (TJET)

This paper provides a conceptual overview of the developments of the Fourth Industrial Revolution (4IR) and derives challenges and opportunities for the future of the mechanical engineering profession. The paper broadly defines 4IR as the fusion of technologies and interaction across physical, digital and biological aspects, while defining mechanical engineering as "a multi-faceted discipline that encompasses the teaching, practice and guidance of others in the development and application of scientific principles to mechanical systems". The paper looks specifically at developments in the Internet of Things (IoT), blockchain technology, robotics, Big Data analytics, biotechnology, nanotechnology, 3D printing and artificial intelligence and …


Designing And Manufacturing Of Vegetable Slicing Machine, Juma Nuhu Msuya Feb 2023

Designing And Manufacturing Of Vegetable Slicing Machine, Juma Nuhu Msuya

Tanzania Journal of Engineering and Technology (TJET)

Agro-processing industry is faced with a challenge of slicing of vegetables for immediate consumption. This stems from the fact that the traditional slicing methods use bare hands, and knives. This method is faced with shortcomings of inefficiency, poor hygiene, and significant dangers to injury. If vegetables are not sliced, their drying takes longer, may possibly be spoiled, and cannot be stored for future uses. Therefore, this paper strives to design a vegetable slicing machine to increase the efficiency of the drying process as a post-processing step. The study employed a Pugh’s design model to design the machine and manufacture it. …


Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou Feb 2023

Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou

Journal of Electrochemistry

No abstract provided.


Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li Feb 2023

Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li

Journal of Electrochemistry

Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li2O2 is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li2O2. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li2O2, …


Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang Feb 2023

Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO2 …